CN100363410C - 使用亲核试剂的含有亲电子键的聚合物的催化解聚 - Google Patents

使用亲核试剂的含有亲电子键的聚合物的催化解聚 Download PDF

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CN100363410C
CN100363410C CNB2003801092392A CN200380109239A CN100363410C CN 100363410 C CN100363410 C CN 100363410C CN B2003801092392 A CNB2003801092392 A CN B2003801092392A CN 200380109239 A CN200380109239 A CN 200380109239A CN 100363410 C CN100363410 C CN 100363410C
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alkyl
replacement
branching
alkylene
ring
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CN1742044A (zh
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J·L·赫德里克
P·基利希基兰
G·W·尼斯
R·M·威马斯
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International Business Machines Corp
Leland Stanford Junior University
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Leland Stanford Junior University
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D233/00Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/04Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D233/06Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms
    • C07D233/08Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms with alkyl radicals, containing more than four carbon atoms, directly attached to ring carbon atoms
    • C07D233/12Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms with alkyl radicals, containing more than four carbon atoms, directly attached to ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D233/16Radicals substituted by nitrogen atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/235Saturated compounds containing more than one carboxyl group
    • C07C59/245Saturated compounds containing more than one carboxyl group containing hydroxy or O-metal groups
    • C07C59/285Polyhydroxy dicarboxylic acids having five or more carbon atoms, e.g. saccharic acids
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C63/00Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings
    • C07C63/307Monocyclic tricarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/03Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C68/00Preparation of esters of carbonic or haloformic acids
    • C07C68/06Preparation of esters of carbonic or haloformic acids from organic carbonates
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D233/00Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/02Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D233/00Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/04Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D233/00Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/04Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D233/06Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D233/00Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D307/00Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/26Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D307/30Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/32Oxygen atoms
    • C07D307/33Oxygen atoms in position 2, the oxygen atom being in its keto or unsubstituted enol form
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    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00Compounds containing elements of Groups 1 or 11 of the Periodic Table
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    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00Recovery or working-up of waste materials
    • C08J11/04Recovery or working-up of waste materials of polymers
    • C08J11/10Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
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    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00Recovery or working-up of waste materials
    • C08J11/04Recovery or working-up of waste materials of polymers
    • C08J11/10Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
    • C08J11/18Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00Recovery or working-up of waste materials
    • C08J11/04Recovery or working-up of waste materials of polymers
    • C08J11/10Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
    • C08J11/18Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material
    • C08J11/28Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic compounds containing nitrogen, sulfur or phosphorus
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Polyesters Or Polycarbonates (AREA)
CNB2003801092392A 2002-12-26 2003-12-23 使用亲核试剂的含有亲电子键的聚合物的催化解聚 Expired - Lifetime CN100363410C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/330,853 US6911546B2 (en) 2002-12-26 2002-12-26 Catalytic depolymerization of polymers containing electrophilic linkages using nucleophilic reagents
US10/330,853 2002-12-26

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Application Number Title Priority Date Filing Date
CN200710137329.2A Division CN101100527B (zh) 2002-12-26 2003-12-23 使用亲核试剂的含有亲电子键的聚合物的催化解聚
CN200710137328.8A Division CN101117333B (zh) 2002-12-26 2003-12-23 使用亲核试剂的含有亲电子键的聚合物的催化解聚

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CN1742044A CN1742044A (zh) 2006-03-01
CN100363410C true CN100363410C (zh) 2008-01-23

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CNB2003801092392A Expired - Lifetime CN100363410C (zh) 2002-12-26 2003-12-23 使用亲核试剂的含有亲电子键的聚合物的催化解聚
CN200710137328.8A Expired - Lifetime CN101117333B (zh) 2002-12-26 2003-12-23 使用亲核试剂的含有亲电子键的聚合物的催化解聚
CN200710137329.2A Expired - Lifetime CN101100527B (zh) 2002-12-26 2003-12-23 使用亲核试剂的含有亲电子键的聚合物的催化解聚

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CN200710137329.2A Expired - Lifetime CN101100527B (zh) 2002-12-26 2003-12-23 使用亲核试剂的含有亲电子键的聚合物的催化解聚

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US (4) US6911546B2 (enExample)
EP (1) EP1576039B1 (enExample)
JP (2) JP4478581B2 (enExample)
KR (2) KR100754303B1 (enExample)
CN (3) CN100363410C (enExample)
AT (1) ATE518906T1 (enExample)
AU (1) AU2003299913A1 (enExample)
WO (1) WO2004060987A2 (enExample)

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JP2007295395A (ja) * 2006-04-26 2007-11-08 Fujitsu Ltd タグ用アンテナ及びそれを用いたタグ
FR2907124B1 (fr) * 2006-10-13 2008-12-05 Rhodia Recherches & Tech Procede de traitement d'un article comprenant un materiau plastique recouvert par un materiau silicone.
CN101665566B (zh) * 2008-09-01 2012-01-04 南京工业大学 一种利用双螺杆挤出机制备聚乳酸及其制品的方法
US8309618B2 (en) * 2009-07-01 2012-11-13 International Business Machines Corporation Catalytic depolymerization of polymers containing electrophilic linkages using nucleophilic reagents
US8367796B2 (en) * 2009-07-01 2013-02-05 International Business Machines Corporation Catalytic polymerization of polymers containing electrophilic linkages using nucleophilic reagents
US8226985B2 (en) * 2010-01-28 2012-07-24 International Business Machines Corporation Surface modified nanoparticles, methods of their preparation, and uses thereof for gene and drug delivery
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US8957217B2 (en) * 2011-05-31 2015-02-17 The University Of Hong Kong Phosphorescent material, their preparations and applications
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CN102675614A (zh) * 2012-05-08 2012-09-19 南京工业大学 一种制备聚氨基酸嵌段聚羟基酸共聚物的方法
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US10259922B2 (en) 2013-11-06 2019-04-16 The Board Of Trustees Of The Leland Stanford Junior University Methods for modifying a hydrophobic polymer surface and devices thereof
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US20040127744A1 (en) 2004-07-01
KR20050085901A (ko) 2005-08-29
CN1742044A (zh) 2006-03-01
EP1576039B1 (en) 2011-08-03
EP1576039A2 (en) 2005-09-21
US20050288508A1 (en) 2005-12-29
CN101117333B (zh) 2014-08-20
US7544800B2 (en) 2009-06-09
CN101100527A (zh) 2008-01-09
KR100800348B1 (ko) 2008-02-04
US20040127720A1 (en) 2004-07-01
JP5153802B2 (ja) 2013-02-27
US7053221B2 (en) 2006-05-30
US6911546B2 (en) 2005-06-28
AU2003299913A1 (en) 2004-07-29
AU2003299913A8 (en) 2004-07-29
JP2010159418A (ja) 2010-07-22
KR100754303B1 (ko) 2007-09-03
KR20070032828A (ko) 2007-03-22
US6916936B2 (en) 2005-07-12
US20050049418A1 (en) 2005-03-03
WO2004060987A2 (en) 2004-07-22
JP4478581B2 (ja) 2010-06-09
ATE518906T1 (de) 2011-08-15
JP2006512460A (ja) 2006-04-13
WO2004060987A3 (en) 2004-10-07
CN101100527B (zh) 2014-02-19
CN101117333A (zh) 2008-02-06

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