CH624709A5 - - Google Patents
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- Publication number
- CH624709A5 CH624709A5 CH1578776A CH1578776A CH624709A5 CH 624709 A5 CH624709 A5 CH 624709A5 CH 1578776 A CH1578776 A CH 1578776A CH 1578776 A CH1578776 A CH 1578776A CH 624709 A5 CH624709 A5 CH 624709A5
- Authority
- CH
- Switzerland
- Prior art keywords
- ion
- iron
- iii
- hydrogen peroxide
- agent
- Prior art date
Links
- 238000004061 bleaching Methods 0.000 claims description 47
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 44
- 239000003795 chemical substances by application Substances 0.000 claims description 33
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims description 28
- 239000003599 detergent Substances 0.000 claims description 24
- 150000004697 chelate complex Chemical class 0.000 claims description 20
- 150000003839 salts Chemical class 0.000 claims description 20
- 239000000243 solution Substances 0.000 claims description 19
- 239000007864 aqueous solution Substances 0.000 claims description 18
- 238000005406 washing Methods 0.000 claims description 18
- 125000000129 anionic group Chemical group 0.000 claims description 10
- 238000004140 cleaning Methods 0.000 claims description 9
- 239000004094 surface-active agent Substances 0.000 claims description 9
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 8
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 claims description 7
- 229960001484 edetic acid Drugs 0.000 claims description 7
- 239000004744 fabric Substances 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 claims description 6
- 125000002091 cationic group Chemical group 0.000 claims description 5
- 229960003330 pentetic acid Drugs 0.000 claims description 5
- URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 claims description 4
- 239000004753 textile Substances 0.000 claims description 4
- 150000007513 acids Chemical class 0.000 claims description 3
- PUIXOJJCTJVSBX-UHFFFAOYSA-N 2-[2-aminoethyl(ethyl)amino]ethanol Chemical compound NCCN(CC)CCO PUIXOJJCTJVSBX-UHFFFAOYSA-N 0.000 claims 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 20
- 239000007844 bleaching agent Substances 0.000 description 15
- 239000000203 mixture Substances 0.000 description 14
- 229960001922 sodium perborate Drugs 0.000 description 13
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 13
- 238000012360 testing method Methods 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000002738 chelating agent Substances 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 9
- -1 hydroxyethylamino Chemical group 0.000 description 9
- 229910052742 iron Inorganic materials 0.000 description 9
- 239000000843 powder Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 229910021645 metal ion Inorganic materials 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 239000002994 raw material Substances 0.000 description 7
- 239000010941 cobalt Substances 0.000 description 6
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 6
- 244000269722 Thea sinensis Species 0.000 description 5
- 230000004913 activation Effects 0.000 description 5
- 229910052783 alkali metal Inorganic materials 0.000 description 5
- 229910017052 cobalt Inorganic materials 0.000 description 5
- 239000007859 condensation product Substances 0.000 description 5
- 229910001385 heavy metal Inorganic materials 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 150000001340 alkali metals Chemical class 0.000 description 4
- 239000013522 chelant Substances 0.000 description 4
- 150000001879 copper Chemical class 0.000 description 4
- WJJMNDUMQPNECX-UHFFFAOYSA-N dipicolinic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=N1 WJJMNDUMQPNECX-UHFFFAOYSA-N 0.000 description 4
- SIOXPEMLGUPBBT-UHFFFAOYSA-N picolinic acid Chemical compound OC(=O)C1=CC=CC=N1 SIOXPEMLGUPBBT-UHFFFAOYSA-N 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 230000003213 activating effect Effects 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 239000012459 cleaning agent Substances 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000001694 spray drying Methods 0.000 description 3
- YQOUWOJPPGRPPW-UHFFFAOYSA-N 2-bis(4-methylphenyl)phosphanylethyl-bis(4-methylphenyl)phosphane Chemical compound C1=CC(C)=CC=C1P(C=1C=CC(C)=CC=1)CCP(C=1C=CC(C)=CC=1)C1=CC=C(C)C=C1 YQOUWOJPPGRPPW-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 229940045872 sodium percarbonate Drugs 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 1
- CMHJKGDUDQZWBN-UHFFFAOYSA-N 2-(methylamino)-3-oxobutanoic acid Chemical compound CNC(C(C)=O)C(O)=O CMHJKGDUDQZWBN-UHFFFAOYSA-N 0.000 description 1
- XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 240000000731 Fagus sylvatica Species 0.000 description 1
- 235000010099 Fagus sylvatica Nutrition 0.000 description 1
- 101001091385 Homo sapiens Kallikrein-6 Proteins 0.000 description 1
- 102100034866 Kallikrein-6 Human genes 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 244000078856 Prunus padus Species 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical class [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Substances CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 150000003868 ammonium compounds Chemical class 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 229910001429 cobalt ion Inorganic materials 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 150000002193 fatty amides Chemical class 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 1
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 125000005342 perphosphate group Chemical group 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009296 quaternary effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000001235 sensitizing effect Effects 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- MKWYFZFMAMBPQK-UHFFFAOYSA-J sodium feredetate Chemical compound [Na+].[Fe+3].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O MKWYFZFMAMBPQK-UHFFFAOYSA-J 0.000 description 1
- 239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
- KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 229940087291 tridecyl alcohol Drugs 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
- D06L4/12—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB51859/75A GB1565807A (en) | 1975-12-18 | 1975-12-18 | Process and compositions for cleaning fabrics |
Publications (1)
Publication Number | Publication Date |
---|---|
CH624709A5 true CH624709A5 (en, 2012) | 1981-08-14 |
Family
ID=10461670
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CH1578776A CH624709A5 (en, 2012) | 1975-12-18 | 1976-12-15 |
Country Status (20)
Country | Link |
---|---|
US (1) | US4119557A (en, 2012) |
JP (1) | JPS5276281A (en, 2012) |
AT (1) | AT362034B (en, 2012) |
BE (1) | BE849540A (en, 2012) |
BR (1) | BR7608454A (en, 2012) |
CA (1) | CA1079007A (en, 2012) |
CH (1) | CH624709A5 (en, 2012) |
DE (1) | DE2657043A1 (en, 2012) |
DK (1) | DK571876A (en, 2012) |
ES (1) | ES454217A1 (en, 2012) |
FI (1) | FI61714C (en, 2012) |
FR (1) | FR2335593A1 (en, 2012) |
GB (1) | GB1565807A (en, 2012) |
IT (1) | IT1108151B (en, 2012) |
NL (1) | NL184483C (en, 2012) |
NO (1) | NO146244C (en, 2012) |
NZ (1) | NZ182870A (en, 2012) |
PT (1) | PT65982B (en, 2012) |
SE (1) | SE425319B (en, 2012) |
ZA (1) | ZA767500B (en, 2012) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1993023515A1 (de) * | 1992-05-18 | 1993-11-25 | Henkel Kommanditgesellschaft Auf Aktien | Verfahren zur farbstabilisierung von tensiden |
Families Citing this family (56)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4238192A (en) * | 1979-01-22 | 1980-12-09 | S. C. Johnson & Son, Inc. | Hydrogen peroxide bleach composition |
JPS5598750A (en) * | 1979-01-23 | 1980-07-28 | Fuji Photo Film Co Ltd | Photographic bleaching composition |
FR2503746A1 (fr) * | 1981-04-09 | 1982-10-15 | Air Liquide | Composition activante pour le blanchiment au moyen de produits peroxydes |
GR76237B (en, 2012) | 1981-08-08 | 1984-08-04 | Procter & Gamble | |
US4481129A (en) * | 1981-12-23 | 1984-11-06 | Lever Brothers Company | Bleach compositions |
US4400361A (en) * | 1982-03-30 | 1983-08-23 | Purtec Systems, Inc. | Method of removing H2 S from a gas stream utilizing boron-vanadium and iron complexes |
US4478733A (en) * | 1982-12-17 | 1984-10-23 | Lever Brothers Company | Detergent compositions |
US4488980A (en) * | 1982-12-17 | 1984-12-18 | Lever Brothers Company | Detergent compositions |
GB8310698D0 (en) * | 1983-04-20 | 1983-05-25 | Procter & Gamble | Detergent compositions |
GB8311865D0 (en) * | 1983-04-29 | 1983-06-02 | Procter & Gamble Ltd | Bleach compositions |
GB8312185D0 (en) * | 1983-05-04 | 1983-06-08 | Unilever Plc | Bleaching and cleaning composition |
GB8329762D0 (en) * | 1983-11-08 | 1983-12-14 | Unilever Plc | Manganese adjuncts |
GB8908416D0 (en) * | 1989-04-13 | 1989-06-01 | Unilever Plc | Bleach activation |
AU9158491A (en) * | 1990-12-19 | 1992-07-22 | Allergan, Inc. | Compositions and methods for contact lens disinfecting |
WO1994004167A1 (en) * | 1991-02-26 | 1994-03-03 | THE UNITED STATES OF AMERICA represented by THE SECRETARY, DEPARTEMENT OF HEALTH AND HUMAN SERVICES | Metal-based formulations with high microbicidal efficiency valuable for disinfection and sterilization |
EP0588413A1 (en) * | 1992-09-15 | 1994-03-23 | Unilever N.V. | Detergent composition |
US5686014A (en) * | 1994-04-07 | 1997-11-11 | The Procter & Gamble Company | Bleach compositions comprising manganese-containing bleach catalysts |
EP0754218B1 (en) * | 1994-04-07 | 1998-09-02 | The Procter & Gamble Company | Bleach compositions comprising metal-containing bleach catalysts and antioxidants |
AU2614895A (en) * | 1994-06-13 | 1996-01-05 | Unilever N.V. | Bleach activation |
GB2294268A (en) | 1994-07-07 | 1996-04-24 | Procter & Gamble | Bleaching composition for dishwasher use |
US5578136A (en) | 1994-08-31 | 1996-11-26 | The Procter & Gamble Company | Automatic dishwashing compositions comprising quaternary substituted bleach activators |
KR100350924B1 (ko) * | 1994-12-06 | 2002-10-31 | 제일제당주식회사 | 표백안정성을개선한표백제함유세제조성물 |
MX9705985A (es) * | 1995-02-02 | 1997-11-29 | Procter & Gamble | Composiciones de lavado de vajilla automatico que comprenden catalizadores de cobalto quelatados. |
US5968881A (en) * | 1995-02-02 | 1999-10-19 | The Procter & Gamble Company | Phosphate built automatic dishwashing compositions comprising catalysts |
WO1996023861A1 (en) * | 1995-02-02 | 1996-08-08 | The Procter & Gamble Company | Automatic dishwashing compositions comprising cobalt (iii) catalysts |
BR9609284A (pt) * | 1995-06-16 | 1999-05-11 | Procter & Gamble | Composições para lavar louça em máquina automática compreendendo catalisadores de cobalto |
AU5796296A (en) * | 1995-06-16 | 1997-01-15 | Procter & Gamble Company, The | Bleach compositions comprising cobalt catalysts |
US5703034A (en) * | 1995-10-30 | 1997-12-30 | The Procter & Gamble Company | Bleach catalyst particles |
EP0778342A1 (en) | 1995-12-06 | 1997-06-11 | The Procter & Gamble Company | Detergent compositions |
US5876625A (en) * | 1996-07-22 | 1999-03-02 | Carnegie Mellon University | Metal ligand containing bleaching compositions |
US5904734A (en) * | 1996-11-07 | 1999-05-18 | S. C. Johnson & Son, Inc. | Method for bleaching a hard surface using tungsten activated peroxide |
DE19721886A1 (de) | 1997-05-26 | 1998-12-03 | Henkel Kgaa | Bleichsystem |
JP2001523500A (ja) | 1997-11-21 | 2001-11-27 | ザ、プロクター、エンド、ギャンブル、カンパニー | 製品アプリケータ |
WO2004069979A2 (en) | 2003-02-03 | 2004-08-19 | Unilever Plc | Laundry cleansing and conditioning compositions |
KR100647976B1 (ko) * | 2004-05-03 | 2006-11-23 | 애경산업(주) | 표백촉매로서 거대고리 망간 착화합물 및 이를 함유한표백제 및 표백세제 조성물 |
US7833423B2 (en) * | 2004-06-01 | 2010-11-16 | Regenesis Bioremediation Products | Enhanced oxidation process for removal of water and soil contaminants |
EP1933941A2 (en) | 2005-08-25 | 2008-06-25 | Philip R. Houle | Treatment systems for delivery of sensitizer solutions |
US20070138674A1 (en) | 2005-12-15 | 2007-06-21 | Theodore James Anastasiou | Encapsulated active material with reduced formaldehyde potential |
KR20090002506A (ko) * | 2007-06-29 | 2009-01-09 | 제일모직주식회사 | 상변화 메모리 소자 연마용 cmp 슬러리 조성물 및 이를이용한 연마 방법 |
US20090001339A1 (en) * | 2007-06-29 | 2009-01-01 | Tae Young Lee | Chemical Mechanical Polishing Slurry Composition for Polishing Phase-Change Memory Device and Method for Polishing Phase-Change Memory Device Using the Same |
US8980816B2 (en) | 2012-01-04 | 2015-03-17 | The Procter & Gamble Company | Fibrous structures comprising particles and methods for making same |
EP3075832B1 (en) | 2015-03-30 | 2021-04-14 | Dalli-Werke GmbH & Co. KG | Manganese-amino acid compounds in cleaning compositions |
FR3036126B1 (fr) | 2015-05-12 | 2017-06-09 | Zodiac Pool Care Europe | Appareil nettoyeur de piscine a dispositif de filtration extractible depuis une paroi laterale |
US10244762B1 (en) | 2016-02-25 | 2019-04-02 | Arch Chemicals, Inc. | Solid aquatic organism control composition and method of use |
US20180119070A1 (en) | 2016-11-01 | 2018-05-03 | The Procter & Gamble Company | Leuco colorants as bluing agents in laundry care compositions, packaging, kits and methods thereof |
PL3535370T3 (pl) | 2016-11-01 | 2020-12-28 | The Procter & Gamble Company | Sposoby wykorzystania leuko barwników jako środków nadających niebieski odcień w kompozycjach środków piorących |
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US11697905B2 (en) | 2017-01-27 | 2023-07-11 | The Procter & Gamble Company | Active agent-containing articles that exhibit consumer acceptable article in-use properties |
US11697904B2 (en) | 2017-01-27 | 2023-07-11 | The Procter & Gamble Company | Active agent-containing articles that exhibit consumer acceptable article in-use properties |
GB2604760B (en) | 2017-01-27 | 2022-11-30 | Procter & Gamble | Active agent-containing articles that exhibit consumer acceptable article in-use properties |
EP3444328A1 (en) | 2017-08-18 | 2019-02-20 | The Procter & Gamble Company | Cleaning agent |
JP7364677B2 (ja) | 2018-12-14 | 2023-10-18 | ザ プロクター アンド ギャンブル カンパニー | 粒子を含む起泡性繊維構造体及びその製造方法 |
WO2023031328A1 (en) * | 2021-09-01 | 2023-03-09 | Unilever Ip Holdings B.V. | Bleach catalysts, bleach systems and cleaning compositions |
WO2023030951A1 (en) * | 2021-09-01 | 2023-03-09 | Unilever Ip Holdings B.V. | Bleach catalysts, bleach systems and cleaning compositions |
WO2023031026A1 (en) * | 2021-09-01 | 2023-03-09 | Unilever Ip Holdings B.V. | Oral care composition |
CN115726191B (zh) * | 2022-11-15 | 2024-04-02 | 苏州联胜化学有限公司 | 一种棉针织低温精炼剂及其制备方法 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3156654A (en) * | 1961-06-19 | 1964-11-10 | Shell Oil Co | Bleaching |
GB1182143A (en) * | 1966-03-01 | 1970-02-25 | United States Borax Chem | Bleaching Compositions and Methods. |
US3488288A (en) * | 1968-03-04 | 1970-01-06 | Peter Strong & Co Inc | Denture cleansers |
US4028281A (en) * | 1975-12-08 | 1977-06-07 | Scott Paper Company | Metal plate treating solution |
-
1975
- 1975-12-18 GB GB51859/75A patent/GB1565807A/en not_active Expired
-
1976
- 1976-12-13 IT IT69958/76A patent/IT1108151B/it active
- 1976-12-13 FI FI763578A patent/FI61714C/fi not_active IP Right Cessation
- 1976-12-13 NZ NZ182870A patent/NZ182870A/xx unknown
- 1976-12-14 AT AT923776A patent/AT362034B/de not_active IP Right Cessation
- 1976-12-14 ES ES454217A patent/ES454217A1/es not_active Expired
- 1976-12-15 US US05/750,787 patent/US4119557A/en not_active Expired - Lifetime
- 1976-12-15 CH CH1578776A patent/CH624709A5/de not_active IP Right Cessation
- 1976-12-16 DE DE19762657043 patent/DE2657043A1/de active Granted
- 1976-12-16 NO NO764273A patent/NO146244C/no unknown
- 1976-12-16 BR BR7608454A patent/BR7608454A/pt unknown
- 1976-12-17 DK DK571876A patent/DK571876A/da not_active Application Discontinuation
- 1976-12-17 NL NLAANVRAGE7614001,A patent/NL184483C/xx not_active IP Right Cessation
- 1976-12-17 FR FR7638181A patent/FR2335593A1/fr active Granted
- 1976-12-17 BE BE173382A patent/BE849540A/xx not_active IP Right Cessation
- 1976-12-17 SE SE7614253A patent/SE425319B/xx not_active IP Right Cessation
- 1976-12-17 ZA ZA00767500A patent/ZA767500B/xx unknown
- 1976-12-17 JP JP51151857A patent/JPS5276281A/ja active Granted
- 1976-12-17 CA CA268,140A patent/CA1079007A/en not_active Expired
- 1976-12-17 PT PT65982A patent/PT65982B/pt unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1993023515A1 (de) * | 1992-05-18 | 1993-11-25 | Henkel Kommanditgesellschaft Auf Aktien | Verfahren zur farbstabilisierung von tensiden |
Also Published As
Publication number | Publication date |
---|---|
ES454217A1 (es) | 1978-03-01 |
BR7608454A (pt) | 1977-12-13 |
FR2335593A1 (fr) | 1977-07-15 |
IT1108151B (it) | 1985-12-02 |
CA1079007A (en) | 1980-06-10 |
NL7614001A (nl) | 1977-06-21 |
DE2657043A1 (de) | 1977-06-23 |
FI61714C (fi) | 1982-09-10 |
ZA767500B (en) | 1978-07-26 |
FI763578A7 (en, 2012) | 1977-06-19 |
NL184483B (nl) | 1989-03-01 |
GB1565807A (en) | 1980-04-23 |
NO146244B (no) | 1982-05-18 |
DE2657043C2 (en, 2012) | 1990-08-16 |
FI61714B (fi) | 1982-05-31 |
ATA923776A (de) | 1980-09-15 |
JPS5276281A (en) | 1977-06-27 |
NL184483C (nl) | 1989-08-01 |
DK571876A (da) | 1977-06-19 |
NZ182870A (en) | 1978-06-20 |
PT65982B (en) | 1978-11-07 |
PT65982A (en) | 1977-01-01 |
JPS5520520B2 (en, 2012) | 1980-06-03 |
US4119557A (en) | 1978-10-10 |
FR2335593B1 (en, 2012) | 1979-03-09 |
NO764273L (en, 2012) | 1977-06-21 |
NO146244C (no) | 1982-08-25 |
AT362034B (de) | 1981-04-27 |
SE425319B (sv) | 1982-09-20 |
SE7614253L (sv) | 1977-06-19 |
BE849540A (fr) | 1977-06-17 |
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