CH619442A5 - Process for the preparation of a mixture of acrolein and acrylic acid, or methacrolein and methacrylic acid. - Google Patents

Process for the preparation of a mixture of acrolein and acrylic acid, or methacrolein and methacrylic acid. Download PDF

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Publication number
CH619442A5
CH619442A5 CH355076A CH355076A CH619442A5 CH 619442 A5 CH619442 A5 CH 619442A5 CH 355076 A CH355076 A CH 355076A CH 355076 A CH355076 A CH 355076A CH 619442 A5 CH619442 A5 CH 619442A5
Authority
CH
Switzerland
Prior art keywords
catalyst
catalytic material
mixture
catalysts
general formula
Prior art date
Application number
CH355076A
Other languages
German (de)
English (en)
Inventor
David Roger Bridgeman
Serge Roman Dolhyj
Ernest Carl Milberger
Original Assignee
Standard Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Co filed Critical Standard Oil Co
Publication of CH619442A5 publication Critical patent/CH619442A5/de

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/88Molybdenum
    • B01J23/887Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876Arsenic, antimony or bismuth
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00168Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212Plates; Jackets; Cylinders
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00168Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00256Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles in a heat exchanger for the heat exchange medium separate from the reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796Details of the reactor or of the particulate material
    • B01J2208/00823Mixing elements
    • B01J2208/00858Moving elements
    • B01J2208/00876Moving elements outside the bed, e.g. rotary mixer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CH355076A 1975-04-21 1976-03-22 Process for the preparation of a mixture of acrolein and acrylic acid, or methacrolein and methacrylic acid. CH619442A5 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US57012675A 1975-04-21 1975-04-21

Publications (1)

Publication Number Publication Date
CH619442A5 true CH619442A5 (en) 1980-09-30

Family

ID=24278352

Family Applications (1)

Application Number Title Priority Date Filing Date
CH355076A CH619442A5 (en) 1975-04-21 1976-03-22 Process for the preparation of a mixture of acrolein and acrylic acid, or methacrolein and methacrylic acid.

Country Status (20)

Country Link
JP (1) JPS51127013A (fr)
AT (1) AT343091B (fr)
BE (1) BE839955A (fr)
BR (1) BR7602429A (fr)
CA (1) CA1065341A (fr)
CH (1) CH619442A5 (fr)
CS (1) CS193541B2 (fr)
DD (1) DD124592A5 (fr)
DE (1) DE2611249A1 (fr)
ES (1) ES446290A1 (fr)
FR (1) FR2308609A1 (fr)
GB (1) GB1529384A (fr)
IN (1) IN142430B (fr)
IT (1) IT1058418B (fr)
MX (1) MX3250E (fr)
NL (1) NL7604153A (fr)
NO (1) NO146707C (fr)
PT (1) PT64923B (fr)
RO (1) RO69673A (fr)
YU (1) YU72876A (fr)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1523772A (en) * 1974-07-22 1978-09-06 Standard Oil Co Oxidation catalysts
IL55073A (en) * 1977-07-28 1982-01-31 Standard Oil Co Catalysts for the oxidation and ammoxidation of olefins
CA1133505A (fr) * 1977-07-28 1982-10-12 Andrew T. Guttmann Methode d'oxydation de olefines
JPS5517306A (en) * 1978-07-20 1980-02-06 Standard Oil Co Olefin oxidation using catalyst containing various promoter elements
DE3125061C2 (de) * 1981-06-26 1984-03-15 Degussa Ag, 6000 Frankfurt Verfahren zur Herstellung von Acrolein bzw. Methacrolein durch katalytische Oxidation von Propylen bzw. Isobutylen oder tertiär-Butanol in sauerstoffhaltigen Gasgemischen
SG50687A1 (en) * 1989-12-06 1998-07-20 Nippon Catalytic Chem Ind Process for producing methacrolein and methacrylic acid
JPH0784400B2 (ja) * 1990-04-03 1995-09-13 株式会社日本触媒 不飽和アルデヒドおよび不飽和酸の製造方法
DE69109746T2 (de) * 1990-06-06 1995-10-26 Mitsui Toatsu Chemicals Verfahren zur Herstellung von Acrolein oder Methacrolein.
DE4023239A1 (de) * 1990-07-21 1992-01-23 Basf Ag Verfahren zur katalytischen gasphasenoxidation von propen oder iso-buten zu acrolein oder methacrolein
KR950004031B1 (ko) * 1991-02-27 1995-04-22 미쓰이도오아쓰가가꾸 가부시끼가이샤 메타크롤레인의 제조방법 및 메타크롤레인의 제조에 사용하는 촉매의 제조방법
DE4132263A1 (de) * 1991-09-27 1993-04-01 Basf Ag Verfahren zur katalytischen gasphasenoxidation von acrolein zu acrylsaeure
DE4431957A1 (de) * 1994-09-08 1995-03-16 Basf Ag Verfahren zur katalytischen Gasphasenoxidation von Propen zu Acrolein
JP3943311B2 (ja) 2000-05-19 2007-07-11 株式会社日本触媒 不飽和アルデヒドおよび不飽和カルボン酸の製造方法
JP4867129B2 (ja) 2003-12-15 2012-02-01 三菱化学株式会社 (メタ)アクリル酸または(メタ)アクロレインの製造方法
JP2005213179A (ja) * 2004-01-29 2005-08-11 Mitsubishi Rayon Co Ltd 触媒層およびその形成方法、固定床管型反応器、メタクロレインまたはメタクリル酸の製造方法
US20050171365A1 (en) * 2004-02-03 2005-08-04 Grey Roger A. Epoxidation process using a mixed catalyst system
JP5130562B2 (ja) * 2007-11-06 2013-01-30 日本化薬株式会社 メタクロレイン及び/又はメタクリル酸の製造方法
JP2020093216A (ja) * 2018-12-12 2020-06-18 株式会社Ihi 触媒反応装置

Also Published As

Publication number Publication date
CA1065341A (fr) 1979-10-30
IT1058418B (it) 1982-04-10
NO761326L (fr) 1976-10-22
DE2611249A1 (de) 1976-11-04
NO146707B (no) 1982-08-16
JPS51127013A (en) 1976-11-05
RO69673A (fr) 1981-08-17
MX3250E (es) 1980-08-06
NO146707C (no) 1982-11-24
BR7602429A (pt) 1976-10-19
PT64923A (en) 1976-04-01
YU72876A (en) 1982-05-31
AT343091B (de) 1978-05-10
FR2308609A1 (fr) 1976-11-19
BE839955A (fr) 1976-07-16
CS193541B2 (en) 1979-10-31
GB1529384A (en) 1978-10-18
ATA252676A (de) 1977-09-15
FR2308609B1 (fr) 1980-10-03
PT64923B (en) 1977-08-24
DD124592A5 (de) 1977-03-02
NL7604153A (nl) 1976-10-25
ES446290A1 (es) 1977-06-16
IN142430B (fr) 1977-07-09

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