CS193541B2 - Process for preparing unsaturated aldehydes and acids by the reaction of mixture of propylene or isobutylene and molecular oxygene in the presence of oxidarive catalyst - Google Patents

Process for preparing unsaturated aldehydes and acids by the reaction of mixture of propylene or isobutylene and molecular oxygene in the presence of oxidarive catalyst

Info

Publication number
CS193541B2
CS193541B2 CS762622A CS262276A CS193541B2 CS 193541 B2 CS193541 B2 CS 193541B2 CS 762622 A CS762622 A CS 762622A CS 262276 A CS262276 A CS 262276A CS 193541 B2 CS193541 B2 CS 193541B2
Authority
CS
Czechoslovakia
Prior art keywords
oxidarive
oxygene
isobutylene
propylene
catalyst
Prior art date
Application number
CS762622A
Other languages
English (en)
Inventor
David R Bridgeman
Serge R Dolhyj
Ernest C Milberger
Original Assignee
Standard Oil Co Ohio
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Co Ohio filed Critical Standard Oil Co Ohio
Publication of CS193541B2 publication Critical patent/CS193541B2/cs

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212—Plates; Jackets; Cylinders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00256—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles in a heat exchanger for the heat exchange medium separate from the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00823—Mixing elements
    • B01J2208/00858—Moving elements
    • B01J2208/00876—Moving elements outside the bed, e.g. rotary mixer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CS762622A 1975-04-21 1976-04-21 Process for preparing unsaturated aldehydes and acids by the reaction of mixture of propylene or isobutylene and molecular oxygene in the presence of oxidarive catalyst CS193541B2 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US57012675A 1975-04-21 1975-04-21

Publications (1)

Publication Number Publication Date
CS193541B2 true CS193541B2 (en) 1979-10-31

Family

ID=24278352

Family Applications (1)

Application Number Title Priority Date Filing Date
CS762622A CS193541B2 (en) 1975-04-21 1976-04-21 Process for preparing unsaturated aldehydes and acids by the reaction of mixture of propylene or isobutylene and molecular oxygene in the presence of oxidarive catalyst

Country Status (20)

Country Link
JP (1) JPS51127013A (cs)
AT (1) AT343091B (cs)
BE (1) BE839955A (cs)
BR (1) BR7602429A (cs)
CA (1) CA1065341A (cs)
CH (1) CH619442A5 (cs)
CS (1) CS193541B2 (cs)
DD (1) DD124592A5 (cs)
DE (1) DE2611249A1 (cs)
ES (1) ES446290A1 (cs)
FR (1) FR2308609A1 (cs)
GB (1) GB1529384A (cs)
IN (1) IN142430B (cs)
IT (1) IT1058418B (cs)
MX (1) MX3250E (cs)
NL (1) NL7604153A (cs)
NO (1) NO146707C (cs)
PT (1) PT64923B (cs)
RO (1) RO69673A (cs)
YU (1) YU72876A (cs)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1523772A (en) * 1974-07-22 1978-09-06 Standard Oil Co Oxidation catalysts
CA1133505A (en) * 1977-07-28 1982-10-12 Andrew T. Guttmann Process for the oxidation of olefins
IL55073A (en) * 1977-07-28 1982-01-31 Standard Oil Co Catalysts for the oxidation and ammoxidation of olefins
JPS5517306A (en) * 1978-07-20 1980-02-06 Standard Oil Co Olefin oxidation using catalyst containing various promoter elements
DE3125061C2 (de) * 1981-06-26 1984-03-15 Degussa Ag, 6000 Frankfurt Verfahren zur Herstellung von Acrolein bzw. Methacrolein durch katalytische Oxidation von Propylen bzw. Isobutylen oder tertiär-Butanol in sauerstoffhaltigen Gasgemischen
EP0456837B1 (en) * 1989-12-06 1996-10-09 Nippon Shokubai Co., Ltd. Process for producing methacrolein and methacrylic acid
JPH0784400B2 (ja) * 1990-04-03 1995-09-13 株式会社日本触媒 不飽和アルデヒドおよび不飽和酸の製造方法
DE69109746T2 (de) * 1990-06-06 1995-10-26 Mitsui Toatsu Chemicals Verfahren zur Herstellung von Acrolein oder Methacrolein.
DE4023239A1 (de) * 1990-07-21 1992-01-23 Basf Ag Verfahren zur katalytischen gasphasenoxidation von propen oder iso-buten zu acrolein oder methacrolein
KR950004031B1 (ko) * 1991-02-27 1995-04-22 미쓰이도오아쓰가가꾸 가부시끼가이샤 메타크롤레인의 제조방법 및 메타크롤레인의 제조에 사용하는 촉매의 제조방법
DE4132263A1 (de) * 1991-09-27 1993-04-01 Basf Ag Verfahren zur katalytischen gasphasenoxidation von acrolein zu acrylsaeure
DE4431957A1 (de) * 1994-09-08 1995-03-16 Basf Ag Verfahren zur katalytischen Gasphasenoxidation von Propen zu Acrolein
JP3943311B2 (ja) 2000-05-19 2007-07-11 株式会社日本触媒 不飽和アルデヒドおよび不飽和カルボン酸の製造方法
JP4867129B2 (ja) 2003-12-15 2012-02-01 三菱化学株式会社 (メタ)アクリル酸または(メタ)アクロレインの製造方法
JP2005213179A (ja) * 2004-01-29 2005-08-11 Mitsubishi Rayon Co Ltd 触媒層およびその形成方法、固定床管型反応器、メタクロレインまたはメタクリル酸の製造方法
US20050171365A1 (en) * 2004-02-03 2005-08-04 Grey Roger A. Epoxidation process using a mixed catalyst system
JP5130562B2 (ja) * 2007-11-06 2013-01-30 日本化薬株式会社 メタクロレイン及び/又はメタクリル酸の製造方法
JP2020093216A (ja) * 2018-12-12 2020-06-18 株式会社Ihi 触媒反応装置

Also Published As

Publication number Publication date
GB1529384A (en) 1978-10-18
CH619442A5 (en) 1980-09-30
DE2611249A1 (de) 1976-11-04
RO69673A (ro) 1981-08-17
NO146707B (no) 1982-08-16
ES446290A1 (es) 1977-06-16
NO761326L (cs) 1976-10-22
NL7604153A (nl) 1976-10-25
NO146707C (no) 1982-11-24
MX3250E (es) 1980-08-06
AT343091B (de) 1978-05-10
DD124592A5 (de) 1977-03-02
BR7602429A (pt) 1976-10-19
IT1058418B (it) 1982-04-10
BE839955A (fr) 1976-07-16
ATA252676A (de) 1977-09-15
IN142430B (cs) 1977-07-09
YU72876A (en) 1982-05-31
PT64923B (en) 1977-08-24
FR2308609A1 (fr) 1976-11-19
JPS51127013A (en) 1976-11-05
FR2308609B1 (cs) 1980-10-03
PT64923A (en) 1976-04-01
CA1065341A (en) 1979-10-30

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