CH417964A - Verfahren zur Herstellung von Pfropfpolymeren des Vinylchlorids - Google Patents
Verfahren zur Herstellung von Pfropfpolymeren des VinylchloridsInfo
- Publication number
- CH417964A CH417964A CH6756758A CH6756758A CH417964A CH 417964 A CH417964 A CH 417964A CH 6756758 A CH6756758 A CH 6756758A CH 6756758 A CH6756758 A CH 6756758A CH 417964 A CH417964 A CH 417964A
- Authority
- CH
- Switzerland
- Prior art keywords
- vinyl chloride
- polymer
- olefin
- copolymer
- poly
- Prior art date
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims description 31
- 238000000034 method Methods 0.000 title claims description 25
- 229920000578 graft copolymer Polymers 0.000 title claims description 12
- 238000002360 preparation method Methods 0.000 title description 3
- 229920000642 polymer Polymers 0.000 claims description 26
- 229920000768 polyamine Polymers 0.000 claims description 13
- -1 polyethylene Polymers 0.000 claims description 13
- 239000004698 Polyethylene Substances 0.000 claims description 11
- 229920000573 polyethylene Polymers 0.000 claims description 11
- 238000006116 polymerization reaction Methods 0.000 claims description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 229920001577 copolymer Polymers 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- 125000001867 hydroperoxy group Chemical group [*]OO[H] 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 4
- 150000001336 alkenes Chemical class 0.000 claims description 4
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 claims description 4
- 239000012736 aqueous medium Substances 0.000 claims description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 239000000725 suspension Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 description 17
- 229920000098 polyolefin Polymers 0.000 description 17
- 239000000047 product Substances 0.000 description 16
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 12
- 229920000915 polyvinyl chloride Polymers 0.000 description 12
- 239000004800 polyvinyl chloride Substances 0.000 description 12
- 229920013639 polyalphaolefin Polymers 0.000 description 11
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 239000004711 α-olefin Substances 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000004014 plasticizer Substances 0.000 description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 238000000605 extraction Methods 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 229920001083 polybutene Polymers 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 238000010559 graft polymerization reaction Methods 0.000 description 3
- 150000002432 hydroperoxides Chemical class 0.000 description 3
- SJOCPYUKFOTDAN-ZSOIEALJSA-N methyl (4z)-4-hydroxyimino-6,6-dimethyl-3-methylsulfanyl-5,7-dihydro-2-benzothiophene-1-carboxylate Chemical compound C1C(C)(C)C\C(=N\O)C=2C1=C(C(=O)OC)SC=2SC SJOCPYUKFOTDAN-ZSOIEALJSA-N 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229960001124 trientine Drugs 0.000 description 3
- HXZMNPWABMNDQI-UHFFFAOYSA-J tris(2,2-dibutyldodecanoyloxy)stannyl 2,2-dibutyldodecanoate Chemical compound [Sn+4].CCCCCCCCCCC(CCCC)(CCCC)C([O-])=O.CCCCCCCCCCC(CCCC)(CCCC)C([O-])=O.CCCCCCCCCCC(CCCC)(CCCC)C([O-])=O.CCCCCCCCCCC(CCCC)(CCCC)C([O-])=O HXZMNPWABMNDQI-UHFFFAOYSA-J 0.000 description 3
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical group Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 229920006125 amorphous polymer Polymers 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-M hydroperoxide group Chemical group [O-]O MHAJPDPJQMAIIY-UHFFFAOYSA-M 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000000638 solvent extraction Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000012043 crude product Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000012259 ether extract Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 229920001112 grafted polyolefin Polymers 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229920001580 isotactic polymer Polymers 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000005502 peroxidation Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- 229920011532 unplasticized polyvinyl chloride Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT1832657 | 1957-12-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH417964A true CH417964A (de) | 1966-07-31 |
Family
ID=11152693
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH6756758A CH417964A (de) | 1957-12-23 | 1958-12-22 | Verfahren zur Herstellung von Pfropfpolymeren des Vinylchlorids |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE574127A (en, 2012) |
| CH (1) | CH417964A (en, 2012) |
| ES (1) | ES246503A1 (en, 2012) |
| FR (1) | FR1223390A (en, 2012) |
| GB (1) | GB894853A (en, 2012) |
-
0
- BE BE574127D patent/BE574127A/xx unknown
-
1958
- 1958-12-17 GB GB4070558A patent/GB894853A/en not_active Expired
- 1958-12-22 ES ES0246503A patent/ES246503A1/es not_active Expired
- 1958-12-22 CH CH6756758A patent/CH417964A/de unknown
- 1958-12-22 FR FR782325A patent/FR1223390A/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB894853A (en) | 1962-04-26 |
| FR1223390A (fr) | 1960-06-16 |
| ES246503A1 (es) | 1959-06-01 |
| BE574127A (en, 2012) |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE1965283C2 (de) | Verfahren zur Herstellung von Pfropf-Mischpolymerisaten mittels eines Zweistufenprozesses | |
| DE1905422C3 (de) | Verfahren zur Herstellung von Trimeren und Tetrameren von Blockmischpolymerisaten | |
| DE1301894C2 (de) | Verfahren zur pfropfpolymerisation von vinylverbindungen auf staerke | |
| DE2238555A1 (de) | Copolymere aus aethylen, kohlenmonoxid und einem termonomeren sowie hieraus gebildete massen | |
| DE1260135B (de) | Schlagfeste thermoplastische Formmassen | |
| DE1495694A1 (de) | Verfahren zur Herstellung von Polymerisaten des Vinylchlorids | |
| DE69013638T2 (de) | Kunststoffgegenstände mit Gassperrschichten aus verträglichgemachten Mischungen. | |
| DE1570661A1 (de) | Innerlich weichgestellte Vinylchloridpolymerisate und Verfahren zu deren Herstellung | |
| DE1134198B (de) | Verfahren zur Herstellung von vulkanisierten Elastomeren | |
| DE2120963A1 (de) | Äthylenmischpolymere, Verfahren zu deren Herstellung und daraus hergestellte Massen | |
| DE2305681A1 (de) | Pfropfpolymerisate auf der grundlage von aethylencopolymerisaten | |
| DE1226790B (de) | Verfahren zur Herstellung von Pfropfpolymerisaten auf Basis von Vinylchlorid | |
| DE2003331B2 (de) | Verfahren zur herstellung eines vinylchloridpfropfpolymerisates | |
| CH523928A (de) | Warmverformbare Mischung | |
| DE1595416A1 (de) | Verfahren zur Herstellung von Vinylchlorid-Polymeren | |
| AT211550B (de) | Verfahren zur Herstellung von Vinylchloridpfropfpolymeren | |
| DE1038757B (de) | Verfahren zur Herstellung von Polystyrol | |
| CH417964A (de) | Verfahren zur Herstellung von Pfropfpolymeren des Vinylchlorids | |
| DE1720950B2 (de) | Verfahren zur herstellung von vinylchloridharzmassen | |
| DE1081672B (de) | Verfahren zur Herstellung thermoplastischer Mischpolymerisate aus Vinylchlorid und einem Dialkylmaleat | |
| DE1570995A1 (de) | Verfahren zur Herstellung von Pfropfpolymerisaten | |
| DE2203276A1 (de) | Verfahren zur Herstellung von Lacton-Pfropfmischpolymerisaten | |
| DE1126613B (de) | Verfahren zur Herstellung von Mischpolymerisaten aus AEthylen und Vinylestern | |
| DE875729C (de) | Verfahren zur Herstellung von Copolymeren aus Vinylidencyanid mit einem halogenierten Butadien-1, 3-Kohlenwasserstoff | |
| DE1075836B (de) | Verfahren zur Herstellung eines plastischen Terpolymensats |