CH417094A - Verfahren zum Stabilisieren von Polyvinylchlorid - Google Patents
Verfahren zum Stabilisieren von PolyvinylchloridInfo
- Publication number
- CH417094A CH417094A CH676763A CH676763A CH417094A CH 417094 A CH417094 A CH 417094A CH 676763 A CH676763 A CH 676763A CH 676763 A CH676763 A CH 676763A CH 417094 A CH417094 A CH 417094A
- Authority
- CH
- Switzerland
- Prior art keywords
- salt
- polyvinyl chloride
- group
- carboxyacrylate
- bis
- Prior art date
Links
- 229920000915 polyvinyl chloride Polymers 0.000 title claims description 13
- 239000004800 polyvinyl chloride Substances 0.000 title claims description 13
- 238000000034 method Methods 0.000 title claims description 6
- 230000000087 stabilizing effect Effects 0.000 title claims description 6
- 150000003839 salts Chemical class 0.000 claims description 10
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052788 barium Inorganic materials 0.000 claims description 4
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052793 cadmium Inorganic materials 0.000 claims description 4
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- 125000002947 alkylene group Chemical group 0.000 claims description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 3
- JPBHXVRMWGWSMX-UHFFFAOYSA-N 1,4-dimethylidenecyclohexane Chemical group C=C1CCC(=C)CC1 JPBHXVRMWGWSMX-UHFFFAOYSA-N 0.000 claims description 2
- 150000001335 aliphatic alkanes Chemical group 0.000 claims description 2
- 125000004450 alkenylene group Chemical group 0.000 claims description 2
- -1 ethylene, propylene, butylene, methylethylene, methylpropylene Chemical group 0.000 description 17
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical class CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 13
- 239000003381 stabilizer Substances 0.000 description 8
- 150000001661 cadmium Chemical class 0.000 description 4
- WUILYKHTEDWVOM-UHFFFAOYSA-N carboxy prop-2-enoate Chemical compound OC(=O)OC(=O)C=C WUILYKHTEDWVOM-UHFFFAOYSA-N 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 159000000007 calcium salts Chemical class 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 150000003751 zinc Chemical class 0.000 description 3
- 229920001342 Bakelite® Polymers 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000004637 bakelite Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 238000005979 thermal decomposition reaction Methods 0.000 description 2
- SORHAFXJCOXOIC-UHFFFAOYSA-N 4-[2-(3-carboxyprop-2-enoyloxy)ethoxy]-4-oxobut-2-enoic acid Chemical compound OC(=O)C=CC(=O)OCCOC(=O)C=CC(O)=O SORHAFXJCOXOIC-UHFFFAOYSA-N 0.000 description 1
- UQTVWGHDJHVLEP-UHFFFAOYSA-N CCCC[Zn]CCCC Chemical class CCCC[Zn]CCCC UQTVWGHDJHVLEP-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 1
- 229910001863 barium hydroxide Inorganic materials 0.000 description 1
- 159000000009 barium salts Chemical class 0.000 description 1
- 239000012496 blank sample Substances 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- BXVLQFGQYHYURU-UHFFFAOYSA-N diethyltin Chemical class CC[Sn]CC BXVLQFGQYHYURU-UHFFFAOYSA-N 0.000 description 1
- HRFMZHBXTDWTJD-UHFFFAOYSA-N dihexyltin Chemical class CCCCCC[Sn]CCCCCC HRFMZHBXTDWTJD-UHFFFAOYSA-N 0.000 description 1
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N dimethylmethane Natural products CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 1
- PWEVMPIIOJUPRI-UHFFFAOYSA-N dimethyltin Chemical class C[Sn]C PWEVMPIIOJUPRI-UHFFFAOYSA-N 0.000 description 1
- HGQSXVKHVMGQRG-UHFFFAOYSA-N dioctyltin Chemical class CCCCCCCC[Sn]CCCCCCCC HGQSXVKHVMGQRG-UHFFFAOYSA-N 0.000 description 1
- QGYQRCXVEPBRHG-UHFFFAOYSA-N dipentyltin Chemical class CCCCC[Sn]CCCCC QGYQRCXVEPBRHG-UHFFFAOYSA-N 0.000 description 1
- FOPKRSSYSAUFNZ-UHFFFAOYSA-N dipropyltin Chemical class CCC[Sn]CCC FOPKRSSYSAUFNZ-UHFFFAOYSA-N 0.000 description 1
- 238000007786 electrostatic charging Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical group C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
- C07F7/2224—Compounds having one or more tin-oxygen linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
- C08K5/57—Organo-tin compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Adhesives Or Adhesive Processes (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201255A US3305568A (en) | 1962-06-11 | 1962-06-11 | Dialkyltin and divalent metal salts of acyclic polycarboxylic acids |
| US598565A US3376256A (en) | 1962-06-11 | 1966-10-18 | Polyvinyl chloride stabilized with metal salts of acyclic polycarboxylic acids |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH417094A true CH417094A (de) | 1966-07-15 |
Family
ID=26896558
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH676763A CH417094A (de) | 1962-06-11 | 1963-05-31 | Verfahren zum Stabilisieren von Polyvinylchlorid |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3376256A (enExample) |
| BE (1) | BE633441A (enExample) |
| CH (1) | CH417094A (enExample) |
| GB (1) | GB981661A (enExample) |
| NL (2) | NL293847A (enExample) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2523989A1 (fr) * | 1982-03-25 | 1983-09-30 | Solvay | Compositions a base de polymeres du chlorure de vinyle presentant une fumigenicite reduite |
| US4696754A (en) * | 1986-08-11 | 1987-09-29 | Morton Thiokol, Inc. | Lubricant-stabilizer compositions for halogen-containing organic polymers and polymer compositions thereof |
| CN112940347A (zh) * | 2019-12-10 | 2021-06-11 | 黄山佳宝新材料科技有限公司 | 一种高效抗析出粉体锌基pvc热稳定剂及其制备方法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1086182A (fr) * | 1953-01-02 | 1955-02-10 | Dynamit Nobel Ag | Procédé de stabilisation de polymérisats vinyliques halogénés |
| US2715111A (en) * | 1953-12-21 | 1955-08-09 | Metal & Thermit Corp | Organo tin compounds and compositions containing same |
-
0
- NL NL128914D patent/NL128914C/xx active
- BE BE633441D patent/BE633441A/xx unknown
- NL NL293847D patent/NL293847A/xx unknown
-
1963
- 1963-05-31 CH CH676763A patent/CH417094A/de unknown
- 1963-06-10 GB GB23035/63A patent/GB981661A/en not_active Expired
-
1966
- 1966-10-18 US US598565A patent/US3376256A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US3376256A (en) | 1968-04-02 |
| NL128914C (enExample) | 1900-01-01 |
| BE633441A (enExample) | 1900-01-01 |
| GB981661A (en) | 1965-01-27 |
| DE1544936A1 (de) | 1969-07-24 |
| NL293847A (enExample) | 1900-01-01 |
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