CH376477A - Verfahren zum Aktivieren von körnigen Nickel-Aluminium-Katalysatoren - Google Patents
Verfahren zum Aktivieren von körnigen Nickel-Aluminium-KatalysatorenInfo
- Publication number
- CH376477A CH376477A CH6709758A CH6709758A CH376477A CH 376477 A CH376477 A CH 376477A CH 6709758 A CH6709758 A CH 6709758A CH 6709758 A CH6709758 A CH 6709758A CH 376477 A CH376477 A CH 376477A
- Authority
- CH
- Switzerland
- Prior art keywords
- catalyst
- aluminum
- nickel
- catalysts
- solution
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims description 73
- 238000000034 method Methods 0.000 title claims description 30
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 title claims description 16
- 230000003213 activating effect Effects 0.000 title claims description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 54
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 27
- 229910052782 aluminium Inorganic materials 0.000 claims description 26
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 23
- 239000000243 solution Substances 0.000 claims description 20
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 17
- 229910052739 hydrogen Inorganic materials 0.000 claims description 17
- 239000001257 hydrogen Substances 0.000 claims description 17
- 229910045601 alloy Inorganic materials 0.000 claims description 16
- 239000000956 alloy Substances 0.000 claims description 16
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 15
- 229910000838 Al alloy Inorganic materials 0.000 claims description 13
- 229910052759 nickel Inorganic materials 0.000 claims description 11
- 239000003513 alkali Substances 0.000 claims description 10
- 239000007864 aqueous solution Substances 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 230000001419 dependent effect Effects 0.000 claims 2
- 238000001994 activation Methods 0.000 description 30
- 230000004913 activation Effects 0.000 description 22
- 238000005984 hydrogenation reaction Methods 0.000 description 15
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 14
- 238000006243 chemical reaction Methods 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 238000002474 experimental method Methods 0.000 description 12
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 5
- 230000000717 retained effect Effects 0.000 description 5
- -1 alkali metal aluminates Chemical class 0.000 description 4
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 150000002894 organic compounds Chemical class 0.000 description 4
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 230000007420 reactivation Effects 0.000 description 3
- 229910001388 sodium aluminate Inorganic materials 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 2
- 230000001174 ascending effect Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010960 commercial process Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 231100000989 no adverse effect Toxicity 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J25/00—Catalysts of the Raney type
- B01J25/02—Raney nickel
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US701322A US2950260A (en) | 1957-12-09 | 1957-12-09 | Process of activating nickel-aluminum catalysts |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH376477A true CH376477A (de) | 1964-04-15 |
Family
ID=24816899
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH6709758A CH376477A (de) | 1957-12-09 | 1958-12-09 | Verfahren zum Aktivieren von körnigen Nickel-Aluminium-Katalysatoren |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US2950260A (en, 2012) |
| BE (1) | BE573234A (en, 2012) |
| CH (1) | CH376477A (en, 2012) |
| DE (1) | DE1173876B (en, 2012) |
| FR (1) | FR1210259A (en, 2012) |
| GB (1) | GB837535A (en, 2012) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB899015A (en) * | 1960-04-26 | 1962-06-20 | Ici Ltd | Preparation of catalyst |
| US3139408A (en) * | 1961-12-21 | 1964-06-30 | Huseyin V Tumer | Process for preparing raney nickel catalyst |
| US3448060A (en) * | 1966-05-02 | 1969-06-03 | Inst Gas Technology | Supported skeletal nickel catalyst |
| US3691093A (en) * | 1969-02-12 | 1972-09-12 | Du Pont | Efficiency of nickel-aluminum catalysts by water washing |
| US3676364A (en) * | 1970-09-23 | 1972-07-11 | Du Pont | Regeneration of nickel-aluminum catalysts by polycarboxylic acid washing |
| US3712856A (en) * | 1970-12-02 | 1973-01-23 | E Betz | Metallic catalyst and aluminum oxide containing supports from acid leached alloys |
| JPS5338719B2 (en, 2012) * | 1972-12-25 | 1978-10-17 | ||
| US3980720A (en) * | 1972-12-25 | 1976-09-14 | Toyo Soda Manufacturing Co., Ltd. | Method of producing diol by hydrogenolysis of peroxide polymers with reactivation of Raney nickel catalyst |
| JP2019532059A (ja) | 2016-09-23 | 2019-11-07 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | Ｃｏの存在下およびモノリシック触媒成形体を含む触媒固定床の存在下で有機化合物を水素化する方法 |
| JP2019530570A (ja) * | 2016-09-23 | 2019-10-24 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | ドープされた構造化触媒成形体を含む触媒固定床を提供する方法 |
| EP3515595A1 (de) | 2016-09-23 | 2019-07-31 | Basf Se | Verfahren zur bereitstellung eines katalytisch aktiven festbetts für die hydrierung organischer verbindungen |
| SG11201901567PA (en) | 2016-09-23 | 2019-04-29 | Basf Se | Process for activating a catalyst |
| TWI787215B (zh) * | 2016-11-22 | 2022-12-21 | 美商Ｗ Ｒ 康格雷氏公司 | 降低損耗的催化劑及其製造方法 |
| KR102696611B1 (ko) | 2017-09-20 | 2024-08-22 | 바스프 에스이 | 촉매 성형체의 제조 방법 |
| US10398076B1 (en) | 2018-03-23 | 2019-09-03 | Cnh Industrial Canada, Ltd. | Method and system for preventing plugging of an agricultural particulate material |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2391283A (en) * | 1942-04-11 | 1945-12-18 | Du Pont | Process for the hydrogenation of benzene |
| GB642861A (en) * | 1948-08-13 | 1950-09-13 | Peter William Reynolds | Improvements in and relating to the preparation of foraminate catalysts |
-
1957
- 1957-12-09 US US701322A patent/US2950260A/en not_active Expired - Lifetime
-
1958
- 1958-09-15 FR FR1210259D patent/FR1210259A/fr not_active Expired
- 1958-10-13 GB GB32616/58A patent/GB837535A/en not_active Expired
- 1958-11-22 BE BE573234A patent/BE573234A/xx unknown
- 1958-12-09 CH CH6709758A patent/CH376477A/de unknown
- 1958-12-09 DE DEP21858A patent/DE1173876B/de active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| US2950260A (en) | 1960-08-23 |
| FR1210259A (fr) | 1960-03-08 |
| BE573234A (en, 2012) | 1959-03-16 |
| GB837535A (en) | 1960-06-15 |
| DE1173876B (de) | 1964-07-16 |
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