CH268406A - Process for the preparation of an azo dye. - Google Patents
Process for the preparation of an azo dye.Info
- Publication number
- CH268406A CH268406A CH268406DA CH268406A CH 268406 A CH268406 A CH 268406A CH 268406D A CH268406D A CH 268406DA CH 268406 A CH268406 A CH 268406A
- Authority
- CH
- Switzerland
- Prior art keywords
- mol
- amino
- azo dye
- preparation
- dye
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B43/00—Preparation of azo dyes from other azo compounds
- C09B43/12—Preparation of azo dyes from other azo compounds by acylation of amino groups
- C09B43/136—Preparation of azo dyes from other azo compounds by acylation of amino groups with polyfunctional acylating agents
- C09B43/16—Preparation of azo dyes from other azo compounds by acylation of amino groups with polyfunctional acylating agents linking amino-azo or cyanuric acid residues
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Description
Zusatzpatent zum Hauptpatent Nr. 264908. Verfahren zur Herstellung eines Azofarbstoffes. Es wurde gefunden, dass man zu einem wertvollen Azofarbstoff gelangt, wenn man 1 Mol des aus 1 Mol Cy anurchlorid, 2 Mol 2-Amino-5-oxynaphthalin-7-sulfonsäure und 1 Mol Aminobenzol erhältlichen t,ernären Kon densationsproduktes mit 2 Mol diazotiertem 3-Amino-4-oxy-acetophenon vereinigt.
Der neue Farbstoff bildet ein schwarzes Pulver, das Baumwolle nach dem ein- oder zweibadigen Nachkupferungsverfahren in wasch- und lichtechten rubinroten Tönen färbt.
Die Kupplung wird beim vorliegenden Ver fahren mit Vorteil in alkalischem, z. B. erd- alkali-hydroxydalkalischem,Medium durchge führt.
Beispiel: 15,1 Teile 3-Amino-4-oxy-acetophenon wer den unter Zusatz von 6,9 Teilen Natriumnitrit und 27 Teilen 30 o/oiger Salzsäure bei<B>00</B> diazo- tiert und die Diazoverbindung mit 36,8 Teilen des ternären Kondensationsproduktes aus 1 Mol Cy anurehlorid,
2 Mol 2-Amino-5-oxy- naphthalin-7-sulfonsäure und 1 Mol Amino- benzol, das als Natriumsalz unter Zusatz von 50 Teilen 20 o/oigem Calciumhydroxyd in 500 Teilen Wasser gelöst wurde, vereinigt. Nach 4 Stunden wird der gebildete Farbstoff mit tels Salzsäure abgeschieden und abfiltriert. Der Filterrüekstand wird als Natriumsalz ge löst. Aus der Lösung wird der Farbstoff mit Kochsalz abgeschieden, filtriert und getrock net.
Additional patent to main patent No. 264908. Process for the production of an azo dye. It has been found that a valuable azo dye is obtained if 1 mole of the diazotized ternary condensation product obtainable from 1 mole of cyano chloride, 2 moles of 2-amino-5-oxynaphthalene-7-sulfonic acid and 1 mole of aminobenzene is used 3-Amino-4-oxy-acetophenone combined.
The new dye forms a black powder that dyes cotton in washable and lightfast ruby-red shades using the one or two-bath post-copper plating process.
The coupling will drive in the present Ver with advantage in alkaline, z. B. earth-alkali-hydroxyd-alkaline medium runs through.
Example: 15.1 parts of 3-amino-4-oxy-acetophenone are diazotized with the addition of 6.9 parts of sodium nitrite and 27 parts of 30% hydrochloric acid at 00 and the diazo compound with 36 , 8 parts of the ternary condensation product from 1 mol of Cy anurehlorid,
2 moles of 2-amino-5-oxynaphthalene-7-sulfonic acid and 1 mole of aminobenzene, which was dissolved as the sodium salt with the addition of 50 parts of 20% calcium hydroxide in 500 parts of water, combined. After 4 hours, the dye formed is deposited using hydrochloric acid and filtered off. The filter residue is dissolved as the sodium salt. The dye is precipitated from the solution with common salt, filtered and net getrock.
Claims (1)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH264908T | 1947-07-04 | ||
CH268406T | 1947-07-04 |
Publications (1)
Publication Number | Publication Date |
---|---|
CH268406A true CH268406A (en) | 1950-05-15 |
Family
ID=25730772
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CH268406D CH268406A (en) | 1947-07-04 | 1947-07-04 | Process for the preparation of an azo dye. |
Country Status (1)
Country | Link |
---|---|
CH (1) | CH268406A (en) |
-
1947
- 1947-07-04 CH CH268406D patent/CH268406A/en unknown
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