CH230265A - Process for producing a diacylimide. - Google Patents

Process for producing a diacylimide.

Info

Publication number
CH230265A
CH230265A CH230265DA CH230265A CH 230265 A CH230265 A CH 230265A CH 230265D A CH230265D A CH 230265DA CH 230265 A CH230265 A CH 230265A
Authority
CH
Switzerland
Prior art keywords
acid
inan
works
binding
anthraquinone
Prior art date
Application number
Other languages
German (de)
Inventor
Aktiengesellschaf Hydrierwerke
Original Assignee
Deutsche Hydrierwerke Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Deutsche Hydrierwerke Ag filed Critical Deutsche Hydrierwerke Ag
Publication of CH230265A publication Critical patent/CH230265A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B1/00—Dyes with anthracene nucleus not condensed with any other ring
    • C09B1/16—Amino-anthraquinones
    • C09B1/20—Preparation from starting materials already containing the anthracene nucleus
    • C09B1/26—Dyes with amino groups substituted by hydrocarbon radicals
    • C09B1/32—Dyes with amino groups substituted by hydrocarbon radicals substituted by aryl groups
    • C09B1/34—Dyes with amino groups substituted by hydrocarbon radicals substituted by aryl groups sulfonated
    • C09B1/343—Dyes with amino groups substituted by hydrocarbon radicals substituted by aryl groups sulfonated only sulfonated in the anthracene nucleus

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

  

  Verfahren zur Herstellung eines     Diacylimids.       Es     wurde        gefunden,        ,dass        rnan    zu einer       Dienen        Klasse    ,saurer     Wollfarbstoffe    der     An-          th.rachin,onreä@he        gelangt,    wenn man solche       Abkämmäage    des     Anthrachinons,

          die    in min  destens     einer        a-Stellung        austausehbare        bezw.          reakttiornsfä.hlgie        Substäuenten        enthalten,        mü          Amimoigruppen        im.    Molekül     enthaltenden        Di-          acylimiiden    zur Umsetzung     bringt.     



  Das     vorliegende    Patent betrifft demnach       ein        Verfahren    zur Herstellung eines     Di@acyl-          imildt,s,    das     dadurch        gek        ennzewb;net        ist,        dass     man     1-Amino-4-lbro@m-an,thra-chin.on-2@-sulfo-          säure        oder    deren Salze mit     3-Amiu#obenzol-          sulifon-benzolsulfonimi;d    umsetzt.

   Die erhal  tene neue     Verbindung        stellt    in Form     ihres          Natriumsälizes        ein    in     Wasser    mit,     reinblauer          Farbe        leicht        lösliches,        bronzegl@änzendles     Pulver dar und     b        frt    auf Wolle,     aufs    saurem       Baal        ausgefärbt,        sehr        lmchtechte    und     ;

  gleich-          mässig        @e        blaue    Färbungen. Die     Umsetzung          wird    zweckmässig in     Gegenwart        eäuirebinden-          der        Mittel    vorgenommen.

   Ferner können bei    denselben     mit        Vorteil        Lösungs--        acler        Ver-          dünnunigsmitteJ    sowie     Reaktionshesahleuni.-          ber,    zum     Beispiel    Kupfer und     seine        Verbin-          dungen,    angewendet werden.  



  <I>Beispiel:</I>  12     Gewichtsteile        4-brom-l-amin@o-anthm-          chinon-2-s@ulfossauTes        Natrium    werden     in    120       Teilen    Wasser gelöst, dazu fügt man     ss        Ge-          wichts.teilie        3-Amino-benz@olssiulfon-benzolsul,-          foniiimid        siow@e    6     Gewnchtsteile        wasserfreies          Natriumcairboniat    und 0,

  2     Gewichtsteile        Kup-          fer-(1)-@chliorid.        Man.        erMtzt        unter    Rühren     bis     auf 60-70 , nach 4 Stunden ist     die        Färb-          stoffbml@dunig    beendet.  



       Nach    der     üblichen        Aufarbeitung        und        Ab-          trennung        einer        rötlvchen,    schwerer löslichen       Verunreinigung        erhält    man das Reaktions  produkt     als,        leicht    in     Wasser,        mit        reinbla.uer          Farbe        lösäches,

          bronzeglänzendes        Pulver.    Die  neue Verbindung hat     folgende    Formel:    
EMI0002.0001     
         Der    Farbstoff gibt auf     '\Volle,        aus    saurem       Bad        aufgefärbt,        sehr        lichtechte        nrnrl          blaue    Färbungen.  



  Der     neue        Farbstoff    zeichnet sieh     beLon-          ders    durch gute     Nass@echtheiiten,        inshesoncIere          Walk-        lind        Schweissechtheiten    aus.



  Process for producing a diacylimide. It has been found that one reaches a serving class, acidic wool dyes of the anthraquinone, if one takes such scraps of the anthraquinone,

          the exchangeable or in at least one a-position. contain reactive substances, amimoy groups in the. Molecule-containing diacylimiids brings to implementation.



  The present patent accordingly relates to a process for the production of a di @ acyl imild, which is characterized in that 1-amino-4-lbro @ m-an, thra-chin.on-2 @ -sulfo - Acid or its salts are reacted with 3-Amiu # abovezol-sulphon-benzenesulphonimi; d.

   The new compound obtained, in the form of its sodium salt, is a bronze-shimmering powder which is easily soluble in water with a pure blue color and bears on wool, dyed on acidic baal, very faint and;

  evenly blue colorations. The reaction is expediently carried out in the presence of acid-binding agents.

   Furthermore, solvent agents and reaction accelerators, for example copper and its compounds, can be used with advantage in the same.



  <I> Example: </I> 12 parts by weight of 4-bromo-l-amin @ o-anthm- quinone-2-s @ ulfossauTes sodium are dissolved in 120 parts of water, to which one adds ss parts by weight of 3-amino -benz @ olssiulfon-benzolsul, - foniiimid siow @ e 6 parts by weight of anhydrous sodium carbonate and 0,

  2 parts by weight of copper (1) chloride. Man. It heats up to 60-70 while stirring, after 4 hours the dye is finished.



       After the usual work-up and separation of a reddish, sparingly soluble impurity, the reaction product is obtained as, easily soluble in water, with a pure blue color,

          bronze-shining powder. The new compound has the following formula:
EMI0002.0001
         The dye gives off very lightfast blue colorations when dyed in an acid bath.



  The new dye is particularly notable for its good wet @ fastness, inshecIer Walkind sweat fastness.

Claims (1)

1'-I TEN TtiN SPRI?C'II Verfahren zur Herstellung eines Diaeyl- im@ids, diadurch gekennzeichnet, da.ss ma.n. 1-Amino - 4 -br o:m-.anthrachinon - 2 -sulfosäure oder deren Salze mimt 3- Ami.no-benzo,1,sulfon- henzolsulfon: 1'-I TEN TtiN SPRI? C'II Process for the production of a diaeyl im @ id, characterized in that da.ss ma.n. 1-Amino - 4 -br o: m-.anthraquinone - 2 -sulfonic acid or its salts mimt 3-Ami.no-benzo, 1, sulfonhenenzenesulfone: imi,d umsetzt. Di:e erhaltene neue. Verbindung stellt in Form ihres Natrium- Salzes ein, in Wasser mit rei.nblauer Farhe lieiclrt l: imi, d implements. The new ones received. The compound ceases in the form of its sodium salt, in water with pure blue colors: ösliehe--z, bronze@glänzendes Pnlver da,i- und d fbt auf @,#7oJle, aus saurem Bad ans- gefärbt, sehr liehbechte und gleichmässige hla-ue Färbiin.gen. 1 i N TERANSPRüGHE 1. Verfahren nach Patentanspruch, da durch gekennzeichnet, d: ösliehe - z, bronze @ shiny powder da, i- and d fbt on @, # 7oJle, stained from an acid bath, very easy-to-borrow and evenly colored. 1 i N TERANSPRüGHE 1. Method according to claim, characterized by, d: ass inan in Gegenwart eines siiuTe@bi@ndenden Mittels arbeitet. 2. @'e,rfahren nach Patentanspruch, da- duroh gekennzeichnet, dass inan in Gegen- wa.rt von. Kul)fer-(1)-chlori,d als Reaktions- hesühli:unibger arbeitet. 3. ass inan works in the presence of a siiuTe @ binding agent. 2. @ 'e, rfahren according to patent claim, characterized in that inan in the presence of. Kul) fer- (1) -chlori, which works as a reaction hesi: unibger. 3. Verfahren nach Patentanspruch, da- durcb, äekennzeiehnet, dass man in wässini@ge@r Lösuing unit1er Zusatz von Na.ti-iumearbona.t -As säurebindendem Mütt.el a,rheitei,. Process according to patent claim, characterized in that, in aqueous solution, a unitary addition of Na.ti-iumearbona.t -As acid-binding Mütt.el a, rheitei ,.
CH230265D 1941-04-17 1942-03-24 Process for producing a diacylimide. CH230265A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE230265X 1941-04-17
DE130342X 1942-03-13

Publications (1)

Publication Number Publication Date
CH230265A true CH230265A (en) 1943-12-31

Family

ID=25751712

Family Applications (1)

Application Number Title Priority Date Filing Date
CH230265D CH230265A (en) 1941-04-17 1942-03-24 Process for producing a diacylimide.

Country Status (1)

Country Link
CH (1) CH230265A (en)

Similar Documents

Publication Publication Date Title
CH230265A (en) Process for producing a diacylimide.
DE517846C (en) Process for the production of brown Kuepen dyes of the anthraquinone series
DE534658C (en) Process for the preparation of dye intermediates and dyes of the anthraquinone arcridone series
DE518214C (en) Process for the preparation of 1-oxy-4-halogenanthraquinone-2-sulfonic acids
DE843723C (en) Process for the preparation of dyes of the phthalocyanine series
DE732040C (en) Process for the production of a Kuepen dye of the anthraquinone series and its leuco sulfuric acid ester
DE737942C (en) Process for the production of phthalocyanines
CH231255A (en) Process for the preparation of a dye intermediate.
CH268403A (en) Process for the production of a copper-containing dye.
CH220119A (en) Process for the preparation of a triazole series dye.
CH220115A (en) Process for the preparation of a triazole series dye.
CH268404A (en) Process for the production of a copper-containing dye.
DE1956236A1 (en) Process for the preparation of 2,2&#39;-diphthalimido-1,1&#39;-dianthraquinonyl
CH251123A (en) Process for the preparation of a dye mixture.
CH452083A (en) Process for the production of reactive dyes
CH304727A (en) Process for the real coloring of anodically oxidized aluminum.
CH200266A (en) Process for the production of a vat dye.
CH310251A (en) Process for the preparation of a metal-containing azo dye.
CH147160A (en) Process for the preparation of a p-oxydiarylaminocarboxylic acid.
CH302404A (en) Process for the preparation of a trisazo dye.
CH220117A (en) Process for the preparation of a triazole series dye.
CH148354A (en) Process for the preparation of an m-oxy-phenylarylamine carboxylic acid.
CH171595A (en) Process for the preparation of a chromium-containing azo dye.
CH280062A (en) Process for the preparation of a nitro dye.
CH185348A (en) Process for the preparation of a chromium complex compound of an azo dye.