CH211852A - Process for the production of an acidic wool dye of the anthraquinone series. - Google Patents

Process for the production of an acidic wool dye of the anthraquinone series.

Info

Publication number
CH211852A
CH211852A CH211852DA CH211852A CH 211852 A CH211852 A CH 211852A CH 211852D A CH211852D A CH 211852DA CH 211852 A CH211852 A CH 211852A
Authority
CH
Switzerland
Prior art keywords
dye
production
amino
anthraquinone series
anthraquinone
Prior art date
Application number
Other languages
German (de)
Inventor
Aktiengesellsc Farbenindustrie
Original Assignee
Ig Farbenindustrie Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ig Farbenindustrie Ag filed Critical Ig Farbenindustrie Ag
Publication of CH211852A publication Critical patent/CH211852A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B1/00—Dyes with anthracene nucleus not condensed with any other ring
    • C09B1/16—Amino-anthraquinones
    • C09B1/20—Preparation from starting materials already containing the anthracene nucleus
    • C09B1/26—Dyes with amino groups substituted by hydrocarbon radicals
    • C09B1/32—Dyes with amino groups substituted by hydrocarbon radicals substituted by aryl groups
    • C09B1/34—Dyes with amino groups substituted by hydrocarbon radicals substituted by aryl groups sulfonated
    • C09B1/343—Dyes with amino groups substituted by hydrocarbon radicals substituted by aryl groups sulfonated only sulfonated in the anthracene nucleus

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)

Description

  

  <B>Zusatzpatent</B> zum     Hauptpatent    Nr. 209166.    Verfahren zur Herstellung eines sauren     Wollfarbstoffes    der     Anthrachinonreihe.       Gegenstand     dieses        Zusatzpatentes    ist ein  Verfahren zur Herstellung eines sauren     Woll-          farbstoffes    'der     Anthrachinonreihe,    welches       darin    besteht,

   dass man auf das Konden  sationsprodukt aus     1-Amino-4-bromanthra-          chinon-2-sulfonsäuT.e        und.        3'-Amino-4'-me-          thyl-o-benzoyl-benzoesäure        Methogybenzo@l    in  Gegenwart von Schwefelsäure einwirken  lässt.  



  Die Umsetzung wird zweckmässig so  durchgeführt,     dass,die        Reaktionskomponenten     in Gegenwart von     konzentrierter    Schwefel  säure während     einiger    Stunden bei einer  Temperatur von     etwa    0   C bis<B>25'C</B> verrührt  werden.  



  Der so erhaltene neue Farbstoff dient zum  Färben der     tierischen    Faser. Er wird in  Form eines dunkelblauen, wasserlöslichen  Pulvers erhalten und färbt Wolle in grün  stiehig blauen Tönen.  



  <I>Beispiel:</I>  10     Gewichtsteile    des nach dem Verfah  ren der Schweizer     Patentschrift    Nr. 153201    erhältlichen     Kondensationsproduktes    aus       1-Amino    -4 -     brom-anthrachinon-2-sulfonsäure     und     3'-Amino-4'-methyl-o-benzoylbenzoe-          siure    werden     in.    100     Gewichtsteilen    konzen  trierter Schwefelsäure gelöst und bei 20' C  mit 10     Gewichtsteilen        Methogybenzol    eine  Stunde     verrührt.    Das     Reaktionsgemisch        

  wird     aus     Eis    gegeben; der in dunkelblauen  Flocken     ausgeschiedene    Farbstoff wird ab  gesaugt. Zur Reinigung löst man ihn in ver  dünntem Ammoniak, filtriert     und    fällt ihn  mit verdünnter Salzsäure aus. Er wird in  Form eines dunkelblauen,     wasserlöslichen          Pulvere    erhalten. Der Farbstoff färbt Wolle  in     grünstichig    blauen Tönen, .die sehr     wasser-,     wasch- und lichtbeständig sind.



  <B> Additional patent </B> to main patent no. 209166. Process for the production of an acidic wool dye of the anthraquinone series. The subject of this additional patent is a process for the production of an acidic wool dye of the anthraquinone series, which consists in

   that on the condensation product of 1-amino-4-bromanthraquinone-2-sulfonsäuT.e and. 3'-Amino-4'-methyl-o-benzoyl-benzoic acid Methogybenzo @ l can act in the presence of sulfuric acid.



  The reaction is expediently carried out in such a way that the reaction components are stirred in the presence of concentrated sulfuric acid for a few hours at a temperature of about 0 ° C. to 25 ° C.



  The new dye thus obtained is used to dye the animal fiber. It is obtained in the form of a dark blue, water-soluble powder and dyes wool in green, deep blue tones.



  <I> Example: </I> 10 parts by weight of the condensation product of 1-amino -4-bromo-anthraquinone-2-sulfonic acid and 3'-amino-4'-methyl-o, obtainable by the method of Swiss patent specification No. 153201 Benzoylbenzoic acid are dissolved in 100 parts by weight of concentrated sulfuric acid and stirred at 20 ° C. with 10 parts by weight of methogybenzene for one hour. The reaction mixture

  is given from ice; the dye separated in dark blue flakes is sucked off. To clean it, it is dissolved in dilute ammonia, filtered and precipitated with dilute hydrochloric acid. It is obtained in the form of a dark blue, water-soluble powder. The dye dyes wool in greenish blue tones, which are very water, wash and lightfast.

Claims (1)

PATENTANSPRUCH: Verfahren zur Herstellung eines sauren Wollfarbstoffes der Anthrachinonreihe, da durch gekennzeichnet, dass man auf das Kondensationsprodukt aus 1-Amino-4-brom- anthrachinon-2-sulfonsäure und 3'-Amino-4'- methyl-o-benzoyl-benzoesä.ure liletho-xybenzol in Gegenwart von Sch\vefelsäure einwirken lässt. PATENT CLAIM: A process for the production of an acidic wool dye of the anthraquinone series, characterized in that the condensation product of 1-amino-4-bromo-anthraquinone-2-sulfonic acid and 3'-amino-4'-methyl-o-benzoyl-benzoic acid is used .ure lilethoxybenzene is allowed to act in the presence of sch \ vefelsäure. Der so erhaltene neue Farbstoff dient zum Färben der tierischen Faser. Er wird in Form eines dunkelblauen, wasserlöslichen Pulvers erhalten und färbt Wolle in grünstichig blauen Tönen. UNTERANSPRUCH: Verfahren nach Patentanspruch, dadurch gekennzeichnet, dass man die Reaktionskom ponenten in Gegenwart von konzentrierter Schwefelsäure etwa zwei Stunden bei einer Temperatur bis etwa 20. C verrührt. The new dye thus obtained is used to dye the animal fiber. It is obtained in the form of a dark blue, water-soluble powder and dyes wool in greenish blue tones. SUBSTANTIAL CLAIM: Process according to claim, characterized in that the reaction components are stirred in the presence of concentrated sulfuric acid for about two hours at a temperature of up to about 20. C.
CH211852D 1938-02-11 1939-01-10 Process for the production of an acidic wool dye of the anthraquinone series. CH211852A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE211852X 1938-02-11
CH209166T 1939-01-10

Publications (1)

Publication Number Publication Date
CH211852A true CH211852A (en) 1940-10-15

Family

ID=25724668

Family Applications (1)

Application Number Title Priority Date Filing Date
CH211852D CH211852A (en) 1938-02-11 1939-01-10 Process for the production of an acidic wool dye of the anthraquinone series.

Country Status (1)

Country Link
CH (1) CH211852A (en)

Similar Documents

Publication Publication Date Title
CH211852A (en) Process for the production of an acidic wool dye of the anthraquinone series.
DE450922C (en) Process for the preparation of dyes of the naphthophenazine series
DE458447C (en) Process for the production of Kuepen dyes
CH145884A (en) Process for the production of a new dye.
DE542540C (en) Process for the preparation of a stable, water-soluble yellow sulfuric acid ester
CH97360A (en) Process for the preparation of a condensation product of the anthraquinone series which can be used as dye and dye intermediate.
CH129482A (en) Process for the production of a new azo dye.
CH191165A (en) Process for the preparation of a new monoazo dye.
CH268440A (en) Process for the production of a new dye.
CH143602A (en) Process for the preparation of an acidic wool dye.
CH301343A (en) Process for the preparation of a sulfonic acid amide of the anthraquinone series.
CH116154A (en) Process for the preparation of a new chromable dye of the triphenylmethane series.
CH145870A (en) Process for the production of a new dye.
CH180582A (en) Process for the production of a new dye.
CH234040A (en) Process for the production of a sulfur dye.
CH130623A (en) Process for the preparation of a dye.
CH152482A (en) Process for the preparation of an azo dye.
CH145318A (en) Process for the preparation of an azophthalein dye.
CH306863A (en) Process for the preparation of a metallizable disazo dye.
CH216324A (en) Process for the production of an acidic wool dye.
CH220664A (en) Process for the production of a sulfur dye.
CH157526A (en) Process for the production of a new azo dye.
CH153830A (en) Process for the preparation of a vat dye.
CH149704A (en) Process for the preparation of an azo dye.
CH263847A (en) Process for the production of a vat dye.