CH191165A - Process for the preparation of a new monoazo dye. - Google Patents
Process for the preparation of a new monoazo dye.Info
- Publication number
- CH191165A CH191165A CH191165DA CH191165A CH 191165 A CH191165 A CH 191165A CH 191165D A CH191165D A CH 191165DA CH 191165 A CH191165 A CH 191165A
- Authority
- CH
- Switzerland
- Prior art keywords
- preparation
- new
- monoazo dye
- yellow
- dye
- Prior art date
Links
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 title claims description 4
- 238000000034 method Methods 0.000 title claims description 3
- 238000002360 preparation method Methods 0.000 title claims description 3
- 239000000975 dye Substances 0.000 claims description 11
- 235000005811 Viola adunca Nutrition 0.000 claims description 3
- 240000009038 Viola odorata Species 0.000 claims description 3
- 235000013487 Viola odorata Nutrition 0.000 claims description 3
- 235000002254 Viola papilionacea Nutrition 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 210000002268 wool Anatomy 0.000 claims description 3
- SXEBHIMOUHBBOS-UHFFFAOYSA-N 5-chloro-2-phenoxyaniline Chemical compound NC1=CC(Cl)=CC=C1OC1=CC=CC=C1 SXEBHIMOUHBBOS-UHFFFAOYSA-N 0.000 claims description 2
- 150000008049 diazo compounds Chemical class 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- 241000738824 Hottonia palustris Species 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/24—Monoazo dyes prepared by diazotising and coupling from coupling components containing both hydroxyl and amino directing groups
- C09B29/28—Amino naphthols
- C09B29/30—Amino naphtholsulfonic acid
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Description
Zusatzpatent zum Hauptpatent Nr. 189140. Verfahren zur Darstellung eines neuen Monoazofarbstoffes. Es wurde gefunden, dass man einen neuen, wertvollen Monoazofarbstoff erhält, wenn man die Diazoverbindung von 5-Chlor-l-amino- 2-pherroxybenzol von der Formel
EMI0001.0009
mit 2-Phenylsulforrylamirio-5-oxyrraphthalin- 1,7-disulfonsäure kuppelt.
Der neue Farbstoff, ein oranges Pulver, löst sich in Wasser gelbrot, in konzentrierter Schwefelsäure blauviolett und färbt Wolle und Seide in echten, gelbroten Tönen.
Beispiel: 21,9 Teile 5-Chlor-l-amino-2-phenoxyben- zol werden dianotiert und mit 46 Teilen 2-Phenylsulfonylamino-5-oxyrraphthalin-1,7- disulfonsäure unter gutem Rühren bei 0 C in verdünnter Lösung in Gegenwart von Bikarbonat gekuppelt. Nach Beendigung der Farbstoffbildung wird ausgesalzen und der ausgeschiedene Farbstoff filtriert und ge trocknet.
Der erhaltene Farbstoff bildet ein oranges Pulver, das sich in Wasser mit gelbroter, in konzentrierter Schwefelsäure mit blauvioletter Farbe löst und Wolle und Seide in echten gelbroten Tönen anfärbt.
Additional patent to main patent no. 189140. Process for the preparation of a new monoazo dye. It has been found that a new, valuable monoazo dye is obtained by using the diazo compound of 5-chloro-1-amino-2-pherroxybenzene of the formula
EMI0001.0009
with 2-phenylsulforrylamirio-5-oxyrraphthalene-1,7-disulfonic acid.
The new dye, an orange powder, dissolves yellow-red in water and blue-violet in concentrated sulfuric acid and dyes wool and silk in real, yellow-red tones.
Example: 21.9 parts of 5-chloro-1-amino-2-phenoxybenzene are dianotized and mixed with 46 parts of 2-phenylsulfonylamino-5-oxyrraphthalene-1,7-disulfonic acid with thorough stirring at 0 ° C. in dilute solution in the presence of Bicarbonate coupled. After the formation of the dye has ended, the mixture is salted out and the dye which has separated out is filtered and dried.
The dye obtained forms an orange powder that dissolves in water with yellow-red color, in concentrated sulfuric acid with blue-violet color and dyes wool and silk in real yellow-red tones.
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH191165T | 1936-03-05 | ||
| CH189140T | 1936-03-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH191165A true CH191165A (en) | 1937-05-31 |
Family
ID=25721747
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH191165D CH191165A (en) | 1936-03-05 | 1936-03-05 | Process for the preparation of a new monoazo dye. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH191165A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0564404A1 (en) * | 1992-04-01 | 1993-10-06 | Ciba-Geigy Ag | Process for leather dyeing with mixtures of dyes |
-
1936
- 1936-03-05 CH CH191165D patent/CH191165A/en unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0564404A1 (en) * | 1992-04-01 | 1993-10-06 | Ciba-Geigy Ag | Process for leather dyeing with mixtures of dyes |
| US5354341A (en) * | 1992-04-01 | 1994-10-11 | Ciba-Geigy Corporation | Process for dyeing leather with dye mixtures |
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