CH205160A - Verfahren zur Herstellung einer kapillaraktiven Verbindung. - Google Patents

Verfahren zur Herstellung einer kapillaraktiven Verbindung.

Info

Publication number
CH205160A
CH205160A CH205160DA CH205160A CH 205160 A CH205160 A CH 205160A CH 205160D A CH205160D A CH 205160DA CH 205160 A CH205160 A CH 205160A
Authority
CH
Switzerland
Prior art keywords
capillary
producing
active connection
ether
mass
Prior art date
Application number
Other languages
English (en)
Inventor
Aktiengesellsc Farbenindustrie
Original Assignee
Ig Farbenindustrie Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ig Farbenindustrie Ag filed Critical Ig Farbenindustrie Ag
Publication of CH205160A publication Critical patent/CH205160A/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C305/00—Esters of sulfuric acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C217/00—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton
    • C07C217/02—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C217/04—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C217/28—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having one amino group and at least two singly-bound oxygen atoms, with at least one being part of an etherified hydroxy group, bound to the carbon skeleton, e.g. ethers of polyhydroxy amines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C305/00—Esters of sulfuric acids
    • C07C305/02—Esters of sulfuric acids having oxygen atoms of sulfate groups bound to acyclic carbon atoms of a carbon skeleton
    • C07C305/04—Esters of sulfuric acids having oxygen atoms of sulfate groups bound to acyclic carbon atoms of a carbon skeleton being acyclic and saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C305/00—Esters of sulfuric acids
    • C07C305/02—Esters of sulfuric acids having oxygen atoms of sulfate groups bound to acyclic carbon atoms of a carbon skeleton
    • C07C305/04—Esters of sulfuric acids having oxygen atoms of sulfate groups bound to acyclic carbon atoms of a carbon skeleton being acyclic and saturated
    • C07C305/10—Esters of sulfuric acids having oxygen atoms of sulfate groups bound to acyclic carbon atoms of a carbon skeleton being acyclic and saturated being further substituted by singly-bound oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01—Sulfonic acids
    • C07C309/02—Sulfonic acids having sulfo groups bound to acyclic carbon atoms
    • C07C309/03—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C309/17—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing carboxyl groups bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01—Sulfonic acids
    • C07C309/02—Sulfonic acids having sulfo groups bound to acyclic carbon atoms
    • C07C309/03—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C309/17—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing carboxyl groups bound to the carbon skeleton
    • C07C309/18—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing carboxyl groups bound to the carbon skeleton containing amino groups bound to the same carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/02—Preparation of ethers from oxiranes
    • C07C41/03—Preparation of ethers from oxiranes by reaction of oxirane rings with hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/04—Saturated ethers
    • C07C43/13—Saturated ethers containing hydroxy or O-metal groups
    • C07C43/135—Saturated ethers containing hydroxy or O-metal groups having more than one ether bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165—Ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/262—Sulfated compounds thiosulfates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D06M13/342—Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/438—Sulfonamides ; Sulfamic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Paper (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Description


  Verfahren zur Herstellung einer     kapillaraktiven    Verbindung.    Es wurde gefunden, dass man eine     kapil-          laraktive        Verbindung    dadurch erhält, dass    man den 1.     3-Di-a-äthylhexyläther    des     Gly-          cerins    mit der Formel  
EMI0001.0008     
    mit     Chlorsulfonsäure    behandelt und den er  haltenen sauren     Schwefelsäureester        in    das       Natriumsalz    überführt.  



  Das Reaktionsprodukt stellt     eine    farb  lose,     bienenwachsähnliche    Masse dar, die sich  leicht in Wasser, aber auch     in        organischen          Lösungsmitteln,    wie Äthylalkohol,     Diäthyl-          äther    löst. Seine     etwa    33     öige        wässrige    Lö  sung ist eine gelbgefärbte, gallertartige  Masse.

   Die     wässrigen    Lösungen besitzen auch  in schwächsten     Konzentrationen    hervor  ragendes Netzvermögen, namentlich bei neu-         traler    und alkalischer Reaktion. Besonders  ausgeprägt ist das     galtnetzvermögen    dieser       Lösungen.     



  Den 1     .3-Di-a-äthylhexyläther    des     Gly-          cerins    erhält man zum Beispiel durch Um  setzung von     Epichlorhydrin        mit    2     112o1        a-          Äthylhexylalkohol    in Gegenwart von     Ätz-          alkali.     



  <I>Beispiel:</I>  45     Gewichtsteile        1.3-Di(a-Äthylhexyl)-          glycerinäther    von der Formel  
EMI0001.0041     
      werden in 80 Gewichtsteilen     Diäthyläther     gelöst und bei - 5   C unter Rühren mit 17  Gewichtsteilen     Chlorsulfonsäure    versetzt.  Nach etwa 4 bis 5 Stunden giesst man die  klare Lösung auf Eis und neutralisiert mit       Sodalösung.    Das Reaktionsprodukt ver  dünnt man hierauf mit Wasser, bis Schich  tung eintritt. Durch Zugabe von Kochsalz  lösung löst sich das Reaktionsprodukt in  Äther.

   Nach Abtrennen der Ätherschicht und  Verdampfen des Äthers erhält man ein       bienenwachsähnliches    Produkt, das in der    doppelten Menge Wasser gelöst wird und so  eine gelbe gallertartige Masse darstellt. Die  ses Produkt zeichnet sich durch hervorragende  Netzwirkung aus, die besonders gegenüber  Baumwolle und in der     gälte    auffallend in  Erscheinung tritt.

Claims (1)

  1. PATENTANSPRUCH: Verfahren zur Herstellung einer kapillar- aktiven Verbindung, dadurch gekennzeich net, dass man den 1 . 3-Di-a-äthylhexyläther des Glycerins EMI0002.0009 mit Chlorsulfonsäure behandelt und den er haltenen sauren Schwefelsäureester in das Natriumsalz überführt. Das Reaktionsprodukt ist eine farblose, bienenwachsähnliche Masse, die sich leicht in Wasser, aber auch in organischen Lö sungsmitteln löst. Seine etwa 33%ige wäss- rige Lösung ist eine gelbgefärbte gallert artige Masse.
    Die wässrigen Lösungen be sitzen hervorragendes Netzvermögen.
CH205160D 1937-04-14 1938-04-12 Verfahren zur Herstellung einer kapillaraktiven Verbindung. CH205160A (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE205160X 1937-04-14
GB12019/37A GB499879A (en) 1937-04-14 1937-04-27 Manufacture of capillary-active compounds
GB30006/38A GB500033A (en) 1937-04-14 1937-04-27 Manufacture of capillary-active compounds

Publications (1)

Publication Number Publication Date
CH205160A true CH205160A (de) 1939-06-15

Family

ID=96585179

Family Applications (1)

Application Number Title Priority Date Filing Date
CH205160D CH205160A (de) 1937-04-14 1938-04-12 Verfahren zur Herstellung einer kapillaraktiven Verbindung.

Country Status (3)

Country Link
CH (1) CH205160A (de)
FR (1) FR836639A (de)
GB (2) GB499879A (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1991018871A1 (de) * 1990-06-06 1991-12-12 Henkel Kommanditgesellschaft Auf Aktien Verfahren zur herstellung von glycerinethersulfaten

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2450234A (en) * 1943-12-07 1948-09-28 Shell Dev Autocondensation polymers of unsaturated glycidyl ethers and method of producing same
US3346633A (en) * 1964-05-05 1967-10-10 Warner Lambert Pharmaceutical Nu, nu'-(2-hydroxytrimethylene) bis

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1991018871A1 (de) * 1990-06-06 1991-12-12 Henkel Kommanditgesellschaft Auf Aktien Verfahren zur herstellung von glycerinethersulfaten

Also Published As

Publication number Publication date
GB499879A (en) 1939-01-27
FR836639A (fr) 1939-01-23
GB500033A (en) 1939-01-27

Similar Documents

Publication Publication Date Title
CH205160A (de) Verfahren zur Herstellung einer kapillaraktiven Verbindung.
CH208288A (de) Verfahren zur Herstellung eines Netzmittels.
DE539806C (de) Verfahren zur Darstellung von Isopropylallylbarbitursaeure
CH222974A (de) Verfahren zur Herstellung eines gemischten Harnstoffes mit löslichmachenden Gruppen.
CH125868A (de) Verfahren zur Herstellung einer beständigen Diazoverbindung.
CH207824A (de) Verfahren zur Herstellung einer kapillaraktiven Verbindung.
AT135343B (de) Verfahren zur Darstellung von wasserlöslichen Metallkomplexverbindungen.
CH130881A (de) Verfahren zur Darstellung einer quaternären Ammoniumverbindung.
CH168369A (de) Verfahren zur Herstellung des Wismutsalzes einer Arsenoverbindung.
CH126127A (de) Verfahren zur Darstellung einer Goldverbindung der Thiobenzimidazolreihe.
CH177158A (de) Verfahren zur Herstellung einer Lösung des 3.6-Diamino-10-methylacridiniumsalzes der p-Glykolylaminophenylarsinsäure.
CH242493A (de) Verfahren zur Herstellung eines neuen Benzolsulfonamidderivates.
CH213548A (de) Verfahren zur Herstellung einer höher molekularen a-substituierten Benzylaminsulfonsäure.
CH217133A (de) Verfahren zur Herstellung eines wasserlöslichen, höhermolekularen, a-substituierten Benzylaminderivates.
CH190913A (de) Verfahren zur Herstellung eines Salzes der Monoguajacylphosphorsäure.
CH153965A (de) Verfahren zur Herstellung einer 2-Oxymethylbenzimidazol-arsinsäure.
CH244769A (de) Verfahren zur Herstellung eines Schwefelsäureesters.
CH284072A (de) Verfahren zur Herstellung von 3,4-Dimethyl-5-phenyl-2-imino-thiazolidin.
CH156337A (de) Verfahren zur Herstellung eines Kupferkomplexsalzes.
CH212786A (de) Verfahren zur Herstellung einer höher molekularen a-substituierten Benzylaminsulfonsäure.
CH200241A (de) Verfahren zur Herstellung einer wasserlöslichen Verbindung der aromatischen Reihe.
CH172570A (de) Verfahren zur Darstellung einer höher molekularen Schwefelverbindung.
CH243781A (de) Verfahren zur Herstellung eines neuen Benzimidazolderivates.
CH182580A (de) Verfahren zur Herstellung eines als Netz-, Wasch-, Emulgier-, Dispergier-, Egalisier- und Weichmachungsmittel verwendbaren Produktes.
CH113833A (de) Verfahren zur Darstellung einer komplexen Wismutverbindung des aus Tyrosin und Formaldehyd erhältlichen Reaktionsproduktes.