CA3062863C - Methods and compositions for polyurethane dispersions using caprolactam-derived solvents - Google Patents
Methods and compositions for polyurethane dispersions using caprolactam-derived solvents Download PDFInfo
- Publication number
- CA3062863C CA3062863C CA3062863A CA3062863A CA3062863C CA 3062863 C CA3062863 C CA 3062863C CA 3062863 A CA3062863 A CA 3062863A CA 3062863 A CA3062863 A CA 3062863A CA 3062863 C CA3062863 C CA 3062863C
- Authority
- CA
- Canada
- Prior art keywords
- solvent
- polymer
- caprolactam
- polyurethane dispersion
- cpl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
- C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0838—Manufacture of polymers in the presence of non-reactive compounds
- C08G18/0842—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents
- C08G18/0847—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of solvents for the polymers
- C08G18/0852—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of solvents for the polymers the solvents being organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3203—Polyhydroxy compounds
- C08G18/3206—Polyhydroxy compounds aliphatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
- C08G18/807—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with nitrogen containing compounds
- C08G18/8077—Oximes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
- C09J175/08—Polyurethanes from polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
- C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Polyurethanes Or Polyureas (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201762524786P | 2017-06-26 | 2017-06-26 | |
| US62/524,786 | 2017-06-26 | ||
| US201762579636P | 2017-10-31 | 2017-10-31 | |
| US62/579,636 | 2017-10-31 | ||
| PCT/US2018/038924 WO2019005596A1 (en) | 2017-06-26 | 2018-06-22 | METHODS AND COMPOSITIONS FOR POLYURETHANE DISPERSIONS USING SOLVENTS DERIVED FROM CAPROLACTAM |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA3062863A1 CA3062863A1 (en) | 2019-01-03 |
| CA3062863C true CA3062863C (en) | 2023-02-28 |
Family
ID=62948339
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA3062863A Active CA3062863C (en) | 2017-06-26 | 2018-06-22 | Methods and compositions for polyurethane dispersions using caprolactam-derived solvents |
Country Status (20)
| Country | Link |
|---|---|
| US (2) | US11542360B2 (pt) |
| EP (2) | EP3510070B1 (pt) |
| JP (1) | JP7049448B2 (pt) |
| KR (3) | KR20200023637A (pt) |
| CN (1) | CN110799562B (pt) |
| AU (3) | AU2018292248B2 (pt) |
| BR (1) | BR122023007664B1 (pt) |
| CA (1) | CA3062863C (pt) |
| DE (1) | DE18742632T1 (pt) |
| DK (1) | DK3510070T3 (pt) |
| ES (1) | ES2930407T3 (pt) |
| GB (1) | GB2570067B (pt) |
| HU (1) | HUE060250T2 (pt) |
| MX (1) | MX2019014869A (pt) |
| NZ (1) | NZ759115A (pt) |
| PL (1) | PL3510070T3 (pt) |
| PT (1) | PT3510070T (pt) |
| SA (1) | SA519410616B1 (pt) |
| TW (1) | TWI680991B (pt) |
| WO (1) | WO2019005596A1 (pt) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3510070B1 (en) | 2017-06-26 | 2022-08-24 | AdvanSix Resins & Chemicals LLC | Methods and compositions for polyurethane dispersions using caprolactam-derived solvents |
| US11299580B2 (en) * | 2018-03-27 | 2022-04-12 | Advansix Resins & Chemicals Llc | Thixotropic rheology modifying agent compositions |
| US20220145101A1 (en) * | 2019-03-14 | 2022-05-12 | Byk-Chemie Gmbh | Rheology control additive containing cyclic amides |
| EP3973018A1 (en) * | 2019-05-22 | 2022-03-30 | AdvanSix Resins & Chemicals LLC | Polymer compositions for forming an enamel coating on a wire |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2048383A5 (en) | 1969-06-25 | 1971-03-19 | Leuna Werke Veb | N-alkyllactams prodn |
| CH573404A5 (pt) | 1972-07-28 | 1976-03-15 | Inventa Ag | |
| DE2456469C2 (de) | 1974-11-29 | 1983-01-13 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von in Wasser löslichen bzw. dispergierbaren blockierten Polyisocyanaten und ihre Verwendung als Beschichtungsmittel |
| US4820762A (en) | 1986-08-22 | 1989-04-11 | S.C. Johnson & Son, Inc. | Resin-fortified emulsion polymers and methods of preparing the same |
| DE3735904A1 (de) | 1987-08-15 | 1989-02-23 | Bayer Ag | Verfahren zur herstellung von n-alkylierten caprolactamen |
| US4835210A (en) | 1988-05-27 | 1989-05-30 | Uniroyal Chemical Company, Inc. | Water emulsified ketoxime blocked polyurethane |
| RO102421B1 (ro) | 1988-12-29 | 1991-10-31 | Centrul De Cercetari Pentru Fibre Chimice | Procedeu de obtinere a n-metil-epsilon-caprolactamei |
| US5157074A (en) | 1991-07-23 | 1992-10-20 | Miles Inc. | Aqueous compositions containing an at least partially blocked polyisocyanates and a trimerization catalyst and coatings and binders prepared therefrom |
| DE4125457A1 (de) | 1991-08-01 | 1993-02-04 | Bayer Ag | Verfahren zur herstellung von n-substituierten lactamen |
| DE10215053A1 (de) * | 2002-04-05 | 2003-10-23 | Bayer Ag | Polyurethan-Dispersionen auf Basis von Fettsäuredialkanolamiden |
| DE102004012751A1 (de) | 2004-03-15 | 2005-10-06 | Basf Ag | Verwendung von N-Ethyl-2-pyrrolidon |
| DE102005057336A1 (de) | 2005-12-01 | 2007-06-14 | Bayer Materialscience Ag | Herstellung einer Vernetzer-Dispersion mit blockierten Isocyanatgruppen |
| DE102007028890A1 (de) * | 2006-11-27 | 2008-05-29 | Basf Se | Neue Lösungsmittel in der Herstellung von Polyurethandispersionen |
| EP2190895A1 (de) | 2007-09-12 | 2010-06-02 | Construction Research and Technology GmbH | Kontinuierliche herstellung von polyurethanen / polyharnstoffen |
| FR2922887B1 (fr) | 2007-10-31 | 2010-01-01 | Rhodia Operations | Procede ameliore de fabrication de diesters. |
| CN102333805B (zh) | 2009-02-26 | 2014-01-01 | 宇部兴产株式会社 | 水性聚氨酯树脂分散体及其制造方法 |
| BRPI1013052A2 (pt) * | 2009-06-10 | 2016-04-05 | Basf Se | dispersão de poliuretano aquosa, processo para preparar dispersões de poliuretano, e, usos de dispersões de poliuretano, e de n-(ciclo) alquilpirrolidonas substituídas. |
| EP2632965B1 (en) * | 2010-10-29 | 2017-04-26 | Lubrizol Advanced Materials, Inc. | Aqueous cationic polyurethane dispersions |
| BE1020269A5 (nl) | 2012-01-17 | 2013-07-02 | Taminco | Gebruik van vervangende oplosmiddelen voor n-methylpyrrolidon (nmp). |
| JP2013227528A (ja) | 2012-03-29 | 2013-11-07 | Sanyo Chem Ind Ltd | ポリウレタン系樹脂水性分散体 |
| WO2014039306A1 (en) * | 2012-09-07 | 2014-03-13 | Lubrizol Advanced Materials, Inc. | Fabric pretreatment for digital printing |
| JP2017523263A (ja) * | 2014-06-10 | 2017-08-17 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | アシルモルホリンを含有するポリマー分散液 |
| US20150353771A1 (en) * | 2014-06-10 | 2015-12-10 | Bayer Materialscience Llc | Coating compositions with an aqueous dispersion containing a polyurethane and an acid reactive crosslinking agent |
| JP6590671B2 (ja) | 2015-12-04 | 2019-10-16 | 三井化学株式会社 | 水性ウレタン樹脂、水性ウレタン樹脂の製造方法、および、防錆処理剤 |
| EP3510070B1 (en) | 2017-06-26 | 2022-08-24 | AdvanSix Resins & Chemicals LLC | Methods and compositions for polyurethane dispersions using caprolactam-derived solvents |
-
2018
- 2018-06-22 EP EP18742632.5A patent/EP3510070B1/en active Active
- 2018-06-22 NZ NZ759115A patent/NZ759115A/en unknown
- 2018-06-22 HU HUE18742632A patent/HUE060250T2/hu unknown
- 2018-06-22 PL PL18742632.5T patent/PL3510070T3/pl unknown
- 2018-06-22 JP JP2020520198A patent/JP7049448B2/ja active Active
- 2018-06-22 BR BR122023007664-8A patent/BR122023007664B1/pt active IP Right Grant
- 2018-06-22 PT PT187426325T patent/PT3510070T/pt unknown
- 2018-06-22 US US16/611,384 patent/US11542360B2/en active Active
- 2018-06-22 DK DK18742632.5T patent/DK3510070T3/da active
- 2018-06-22 KR KR1020207002022A patent/KR20200023637A/ko not_active IP Right Cessation
- 2018-06-22 KR KR1020227004770A patent/KR102482434B1/ko active IP Right Grant
- 2018-06-22 AU AU2018292248A patent/AU2018292248B2/en active Active
- 2018-06-22 ES ES18742632T patent/ES2930407T3/es active Active
- 2018-06-22 MX MX2019014869A patent/MX2019014869A/es unknown
- 2018-06-22 WO PCT/US2018/038924 patent/WO2019005596A1/en active Application Filing
- 2018-06-22 KR KR1020227045109A patent/KR102573146B1/ko active IP Right Grant
- 2018-06-22 GB GB1905203.4A patent/GB2570067B/en active Active
- 2018-06-22 CA CA3062863A patent/CA3062863C/en active Active
- 2018-06-22 DE DE18742632.5T patent/DE18742632T1/de active Pending
- 2018-06-22 EP EP22191090.4A patent/EP4134385A1/en active Pending
- 2018-06-22 CN CN201880042364.2A patent/CN110799562B/zh active Active
- 2018-06-25 TW TW107121752A patent/TWI680991B/zh active
-
2019
- 2019-11-23 SA SA519410616A patent/SA519410616B1/ar unknown
-
2021
- 2021-06-09 AU AU2021203814A patent/AU2021203814C1/en active Active
-
2022
- 2022-11-23 US US17/993,382 patent/US12024584B2/en active Active
-
2023
- 2023-02-03 AU AU2023200582A patent/AU2023200582B2/en active Active
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Legal Events
| Date | Code | Title | Description |
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| EEER | Examination request |
Effective date: 20191107 |
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| EEER | Examination request |
Effective date: 20191107 |
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| EEER | Examination request |
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| EEER | Examination request |
Effective date: 20191107 |