CA3042119A1 - Composition lubrifiante d'une caracteristique de viscosite amelioree a basse temperature de fonctionnement - Google Patents

Composition lubrifiante d'une caracteristique de viscosite amelioree a basse temperature de fonctionnement Download PDF

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Publication number
CA3042119A1
CA3042119A1 CA3042119A CA3042119A CA3042119A1 CA 3042119 A1 CA3042119 A1 CA 3042119A1 CA 3042119 A CA3042119 A CA 3042119A CA 3042119 A CA3042119 A CA 3042119A CA 3042119 A1 CA3042119 A1 CA 3042119A1
Authority
CA
Canada
Prior art keywords
weight
lubricant composition
base oil
kinematic viscosity
meth
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA3042119A
Other languages
English (en)
Inventor
Ronny Sondjaja
Frank-Olaf Mahling
Michael Alibert
Jennifer HOLTZINGER
Stefan Karl Maier
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Evonik Oil Additives GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Evonik Oil Additives GmbH filed Critical Evonik Oil Additives GmbH
Publication of CA3042119A1 publication Critical patent/CA3042119A1/fr
Abandoned legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/02—Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/20—Lubricating compositions characterised by the base-material being a macromolecular compound containing oxygen
    • C10M107/22—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M107/28—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M143/00—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
    • C10M143/10—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing aromatic monomer, e.g. styrene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M143/00—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
    • C10M143/12—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing conjugated diene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/10—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
    • C10M145/12—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate monocarboxylic
    • C10M145/14—Acrylate; Methacrylate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/18—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/24—Polyethers
    • C10M145/26—Polyoxyalkylenes
    • C10M145/32—Polyoxyalkylenes of alkylene oxides containing 4 or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/041—Mixtures of base-materials and additives the additives being macromolecular compounds only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
    • C10M2205/0285—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/04—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/04—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene
    • C10M2205/043—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/06—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
    • C10M2209/0845—Acrylate; Methacrylate used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/02—Viscosity; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/04—Molecular weight; Molecular weight distribution
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/071—Branched chain compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/02—Pour-point; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/08—Resistance to extreme temperature

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Lubricants (AREA)
  • Graft Or Block Polymers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

L'invention concerne une composition lubrifiante comprenant un polymère à structure en peigne et une huile de base synthétique. La composition lubrifiante présente des caractéristiques de viscosité améliorées à des températures de fonctionnement basses. L'invention concerne également l'utilisation d'un polymère à structure en peigne pour produire un lubrifiant ayant un facteur R inférieur ou égal à 8, le facteur R étant défini comme étant le rapport de la viscosité cinématique à -20 °C et la viscosité cinématique à +20 °C.
CA3042119A 2016-11-02 2017-10-27 Composition lubrifiante d'une caracteristique de viscosite amelioree a basse temperature de fonctionnement Abandoned CA3042119A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP16196796 2016-11-02
EP16196796.3 2016-11-02
PCT/EP2017/077605 WO2018083027A1 (fr) 2016-11-02 2017-10-27 Composition lubrifiante d'une caractéristique de viscosité améliorée à basse température de fonctionnement

Publications (1)

Publication Number Publication Date
CA3042119A1 true CA3042119A1 (fr) 2018-05-11

Family

ID=57218823

Family Applications (1)

Application Number Title Priority Date Filing Date
CA3042119A Abandoned CA3042119A1 (fr) 2016-11-02 2017-10-27 Composition lubrifiante d'une caracteristique de viscosite amelioree a basse temperature de fonctionnement

Country Status (10)

Country Link
US (1) US20190300808A1 (fr)
EP (1) EP3535357B1 (fr)
JP (1) JP6890658B2 (fr)
KR (1) KR102455761B1 (fr)
CN (1) CN109923195B (fr)
CA (1) CA3042119A1 (fr)
ES (1) ES2854939T3 (fr)
RU (1) RU2747727C2 (fr)
SG (1) SG11201903781QA (fr)
WO (1) WO2018083027A1 (fr)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA3047194A1 (fr) * 2016-12-19 2018-06-28 Evonik Oil Additives Gmbh Composition d'huile lubrifiante comprenant des polymeres en peigne dispersants
EP3652284B1 (fr) * 2017-07-14 2021-06-02 Evonik Operations GmbH Polymères en peigne à fonctionnalité imide
ES2801327T3 (es) 2017-12-13 2021-01-11 Evonik Operations Gmbh Mejorador del índice de viscosidad con resistencia al cizallamiento y solubilidad después del cizallamiento mejoradas
US11518955B2 (en) * 2019-03-20 2022-12-06 Evonik Operations Gmbh Polyalkyl(meth)acrylates for improving fuel economy, dispersancy and deposits performance
AU2019477845A1 (en) * 2019-12-12 2022-07-28 Evonik Operations Gmbh High viscosity polyacrylate base fluids
US20210179960A1 (en) * 2019-12-16 2021-06-17 Infineum International Limited High Viscosity Index Comb Copolymer Viscosity Modifiers and Methods of Modify Lubricant Viscosity Using Same
US11384311B2 (en) * 2019-12-16 2022-07-12 Infineum International Limited High viscosity index comb polymer viscosity modifiers and methods of modifying lubricant viscosity using same
US20210179965A1 (en) * 2019-12-16 2021-06-17 Infineum International Limited High Viscosity Index Comb Copolymer Viscosity Modifiers and Methods of Modifying Lubricant Viscosity Using Same
JPWO2021132518A1 (fr) * 2019-12-27 2021-07-01
US20230323241A1 (en) * 2020-09-14 2023-10-12 Sanyo Chemical Industries, Ltd. Viscosity index improver and lubricating oil composition
DE112021004312T5 (de) * 2020-09-14 2023-08-31 Sanyo Chemical Industries, Ltd. Viskositätsindex-verbesserndes mittel und schmieröl-zusammensetzung
EP4060009B1 (fr) * 2021-03-19 2023-05-03 Evonik Operations GmbH Un agent améliorant l'indice de viscosité et composition lubrifiante

Family Cites Families (16)

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Publication number Priority date Publication date Assignee Title
GB2047266B (en) * 1979-04-09 1984-02-08 Exxon Research Engineering Co Viscosity index lubricating oils
US4611031A (en) * 1985-01-28 1986-09-09 Rohm And Haas Company Process for the preparation of a compatibilizer for concentrated polymer blends and compatibilizer product
US5393843A (en) 1992-08-31 1995-02-28 Shell Oil Company Butadiene polymers having terminal functional groups
DE4312715A1 (de) * 1993-04-20 1994-10-27 Roehm Gmbh Kammpolymere
DE4431302A1 (de) 1994-09-02 1996-03-07 Roehm Gmbh Kammpolymere
CN1124292C (zh) * 1998-03-05 2003-10-15 纳幕尔杜邦公司 粘度对温度及剪切的响应受控的聚合物薄膜
DE102005031244A1 (de) * 2005-07-01 2007-02-15 Rohmax Additives Gmbh Öllösliche Kammpolymere
DE102007046223A1 (de) * 2007-09-26 2009-04-02 Evonik Rohmax Additives Gmbh Verwendung von Kammpolymeren zur Verringerung des Kraftstoffverbrauchs
DE102007032120A1 (de) * 2007-07-09 2009-01-15 Evonik Rohmax Additives Gmbh Verwendung von Kammpolymeren zur Verringerung des Kraftstoffverbrauchs
RU2483083C2 (ru) * 2007-07-09 2013-05-27 Эвоник РоМакс Эддитивс ГмбХ Применение гребенчатых полимеров для снижения расхода горючего
DE102009001447A1 (de) * 2009-03-10 2010-09-16 Evonik Rohmax Additives Gmbh Verwendung von Kammpolymeren zur Verbesserung des Lasttragevermögens
JP5591327B2 (ja) * 2009-06-12 2014-09-17 エボニック オイル アディティヴス ゲゼルシャフト ミット ベシュレンクテル ハフツング 向上した粘度指数を有する流体
JP6014540B2 (ja) * 2013-04-17 2016-10-25 コスモ石油ルブリカンツ株式会社 内燃機関用潤滑油組成物
KR20150143721A (ko) * 2013-04-18 2015-12-23 에보니크 오일 아디티페스 게엠베하 연료 소비를 감소시키기 위한 변속기 오일 제제
WO2015097152A1 (fr) * 2013-12-24 2015-07-02 Shell Internationale Research Maatschappij B.V. Composition lubrifiante
CN107075405B (zh) * 2014-09-19 2021-09-03 出光兴产株式会社 润滑油组合物、和该润滑油组合物的制造方法

Also Published As

Publication number Publication date
RU2019116232A (ru) 2020-12-03
KR102455761B1 (ko) 2022-10-19
EP3535357B1 (fr) 2020-12-16
SG11201903781QA (en) 2019-05-30
KR20190080918A (ko) 2019-07-08
RU2747727C2 (ru) 2021-05-13
US20190300808A1 (en) 2019-10-03
JP6890658B2 (ja) 2021-06-18
EP3535357A1 (fr) 2019-09-11
RU2019116232A3 (fr) 2020-12-03
CN109923195B (zh) 2022-10-11
CN109923195A (zh) 2019-06-21
WO2018083027A1 (fr) 2018-05-11
JP2019535858A (ja) 2019-12-12
ES2854939T3 (es) 2021-09-23

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Effective date: 20230427

FZDE Discontinued

Effective date: 20230427