WO2018083027A1 - Composition lubrifiante d'une caractéristique de viscosité améliorée à basse température de fonctionnement - Google Patents

Composition lubrifiante d'une caractéristique de viscosité améliorée à basse température de fonctionnement Download PDF

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Publication number
WO2018083027A1
WO2018083027A1 PCT/EP2017/077605 EP2017077605W WO2018083027A1 WO 2018083027 A1 WO2018083027 A1 WO 2018083027A1 EP 2017077605 W EP2017077605 W EP 2017077605W WO 2018083027 A1 WO2018083027 A1 WO 2018083027A1
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Prior art keywords
weight
lubricant composition
base oil
kinematic viscosity
meth
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PCT/EP2017/077605
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English (en)
Inventor
Ronny Sondjaja
Frank-Olaf Mähling
Michael Alibert
Jennifer HOLTZINGER
Stefan Maier
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Evonik Oil Additives Gmbh
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Priority to CN201780067603.5A priority Critical patent/CN109923195B/zh
Priority to SG11201903781QA priority patent/SG11201903781QA/en
Priority to ES17787940T priority patent/ES2854939T3/es
Priority to US16/345,260 priority patent/US20190300808A1/en
Priority to RU2019116232A priority patent/RU2747727C2/ru
Priority to JP2019522683A priority patent/JP6890658B2/ja
Priority to CA3042119A priority patent/CA3042119A1/fr
Priority to KR1020197015692A priority patent/KR102455761B1/ko
Priority to EP17787940.0A priority patent/EP3535357B1/fr
Publication of WO2018083027A1 publication Critical patent/WO2018083027A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/02—Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/20—Lubricating compositions characterised by the base-material being a macromolecular compound containing oxygen
    • C10M107/22—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M107/28—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M143/00—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
    • C10M143/10—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing aromatic monomer, e.g. styrene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M143/00—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
    • C10M143/12—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing conjugated diene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/10—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
    • C10M145/12—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate monocarboxylic
    • C10M145/14—Acrylate; Methacrylate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/18—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/24—Polyethers
    • C10M145/26—Polyoxyalkylenes
    • C10M145/32—Polyoxyalkylenes of alkylene oxides containing 4 or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/041—Mixtures of base-materials and additives the additives being macromolecular compounds only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
    • C10M2205/0285—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/04—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/04—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene
    • C10M2205/043—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/06—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
    • C10M2209/0845—Acrylate; Methacrylate used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/02—Viscosity; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/04—Molecular weight; Molecular weight distribution
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/071—Branched chain compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/02—Pour-point; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/08—Resistance to extreme temperature

Definitions

  • the invention relates to lubricant compositions for use in industrial applications having improved low temperature viscosity characteristics.
  • Lubricants for use in industrial applications typically comprise a base oil, such as a mineral oil or synthetic oil, and one or more additives.
  • Additives deliver, for example, reduced friction and wear, increased viscosity, improved viscosity index, and resistance to corrosion, oxidation, aging or contamination.
  • a lubricant to reduce friction is dependent on its viscosity. Generally, the least viscous fluid, which still forces two moving surfaces apart, is desired. Many lubricant applications require good lubricant properties over a broad temperature range, for example, when the engine is cold as well as when it has reached its operating
  • a lubricant's viscosity should change as little as possible with temperature, to provide constant lubricant properties over a broad temperature range.
  • the temperature-dependence of a lubricant's viscosity is measured by the viscosity index (VI).
  • the viscosity index is determined from the kinematic viscosity at 40°C (KV40) and the kinematic viscosity at 100°C (KV100), which is a good reflection of most engines' operating conditions.
  • Additives which increase the viscosity index are referred to as viscosity index improvers (VI Is).
  • Polymers of alkyl (meth)acrylates, and especially polyalkyl(meth)acrylate based comb polymers, are known in the art to act as good viscosity index improvers in lubricant oils.
  • WO 2007/003238 A1 describes oil-soluble comb polymers based on polyolefin-based macromonomers, especially polybutadiene-based methacrylic esters, and C1 -C10 alkyl methacrylates.
  • the comb polymers can be used as an additive for lubricant oils, in order to improve the viscosity index and shear stability. They show a particularly high viscosity index-improving action in lubricant oils. Low temperature properties are not disclosed therein.
  • the viscosity index does not properly reflect the lubricant's properties at temperatures lower than 40°C, for instance at a low temperature range of -20°C to +20°C.
  • a lubricant having good lubricant properties at the operating temperature of a machine or an engine therefore, does not necessarily have equally good properties during the engine's cold-start phase.
  • the cold-start properties of a lubricant are, however, an important factor contributing to an improved fuel efficiency of engines.
  • the low-temperature properties of lubricants can be measured by the R-factor, which is defined as the ratio of the kinematic viscosity at -20°C to the kinematic viscosity at +20°C. Since the kinematic viscosity at -20°C is generally higher than at +20°C, the R-factor is generally greater than 1. Thus, a narrow viscosity difference between -20°C and +20°C is reflected by a low R-factor (an R-factor close to 1 ).
  • the aim of the present invention is to provide a lubricant composition with good low temperature viscosity properties.
  • the difference of the kinematic viscosity of the lubricant composition at -20°C and +20°C should be small.
  • the present invention further aims at providing an additive for a lubricant composition for lowering the difference between the kinematic viscosity at -20°C and +20°C. It has been found that the use of certain comb polymers as additives for lubricant compositions results in a surprisingly low R-factor that cannot be achieved by using conventional viscosity index improvers.
  • lubricant compositions comprising a synthetic base oil and the special comb polymers exhibit surprisingly good low-temperature viscosity characteristics, in particular a surprisingly good R-factor.
  • the present invention is therefore directed to a lubricant composition, comprising:
  • the lubricant composition is characterized by an R-factor of 8 or less, the R-factor being the ratio of the kinematic viscosity at -20°C to the kinematic viscosity at +20°C.
  • the lubricant composition is preferably defined by an R-factor of less than or equal to 8, wherein the R-factor is defined as the ratio of the kinematic viscosity of the lubricant composition at -20°C (KV -2 o) to the kinematic viscosity at +20°C (KV +20 ), KV- 2 o/KV +2 o, the kinematic viscosities are measured according to ASTM D445.
  • the lubricant composition has an R-factor of 1 to 8.
  • the composition is preferably formulated to yield a certain kinematic viscosity at 40°C according to ASTM D445. This can be achieved by adjusting the relative amounts of comb polymer, base oil and optional additives.
  • the composition has a kinematic viscosity at 40°C according to ASTM D445 of 10 to 120 mm 2 /s, more preferably 40 to 100 mm 2 /s, most preferably 70 to 80 mm 2 /s.
  • the lubricant composition comprises:
  • Suitable synthetic base oils are selected from API Group IV oils. Particularly preferred are polyalphaolefins (PAOs).
  • PAOs polyalphaolefins
  • the synthetic base oil is typically characterized by its kinematic viscosity, i.e. the kinematic viscosity of the pure base oil without any additives.
  • the synthetic base oil has a kinematic viscosity at 100°C according to ASTM D445 of 1 mm 2 /s to 20 mm 2 /s, more preferably 1 to 10 mm 2 /s, most preferably 1 to 5 mm 2 /s and especially preferred 2 to 3 mm 2 /s.
  • the synthetic base oil is a polyalphaolefin having a kinematic viscosity at 100°C according to ASTM D445 of 1 mm 2 /s to 20 mm 2 /s, more preferably 1 to 10 mm 2 /s, most preferably 1 to 5 mm 2 /s and especially preferred 2 to 3 mm 2 /s.
  • a comb polymer in the context of this invention comprises a first polymer, which is also referred to as backbone or main chain, and a multitude of further polymers which are referred to as side chains and are bonded covalently to the backbone.
  • the backbone of the comb polymer is formed by the interlinked unsaturated groups of the mentioned (meth)acrylates.
  • main chain does not necessarily mean that the chain length of the main chain is greater than that of the side chains.
  • the amount of styrene in the comb polymer is given in percent by weight based on the total weight of the monomer mixture.
  • total weight of the monomer mixture refers to the total weight of the monomers, excluding any additives, such as polymerization initiators, polymerization promotors, chain transfer agents and diluents, which might be added to the monomer mixture to facilitate polymerization.
  • total weight of the monomer mixture refers to the total weight of the monomers, excluding any additives, such as polymerization initiators, polymerization promotors, chain transfer agents and diluents, which might be added to the monomer mixture to facilitate polymerization.
  • the relative amounts of monomers in the monomer mixture correspond to the relative amounts of the
  • the comb polymer (B) comprises:
  • the hydroxylated hydrogenated polybutadiene for use in accordance with the invention has a number-average molar mass M n of 4.000 to 6.000 g/mol, preferably 4.000 to 5.000 g/mol. Because of their high molar mass, the hydroxylated hydrogenated polybutadienes can also be referred to as macroalcohols in the context of this invention.
  • the number-average weight M n is determined by size exclusion chromatography using commercially available polybutadiene standards. The determination is effected to DIN 55672-1 by gel permeation chromatography with THF as eluent.
  • the hydroxylated hydrogenated polybutadiene has a hydrogenation level of at least 99%.
  • An alternative measure of the hydrogenation level which can be determined on the copolymer of the invention is the iodine number.
  • the iodine number refers to the number of grams of iodine which can be added onto 100 g of copolymer.
  • the copolymer of the invention has an iodine number of not more than 5 g of iodine per 100 g of copolymer.
  • the iodine number is determined by the Wijs method according to DIN 53241 -1 :1995-05.
  • Preferred hydroxylated hydrogenated polybutadienes can be obtained according to GB 2270317. Some hydroxylated hydrogenated polybutadienes are also commercially available.
  • a further supplier of suitable alcohols based on hydrogenated polybutadiene is Cray Valley (Paris), a daughter company of Total (Paris), or the Sartomer Company (Exton, PA, USA).
  • Preference is given to monohydroxylated hydrogenated polybutadienes.
  • the hydroxylated hydrogenated polybutadiene is a hydroxyethyl- or hydroxy propyl- terminated hydrogenated polybutadiene.
  • Particular preference is given to hydroxypropyl- terminated polybutadienes.
  • These monohydroxylated hydrogenated polybutadienes can be prepared by first converting butadiene monomers by anionic polymerization to polybutadiene.
  • a hydroxy-functionalized polybutadiene can be prepared.
  • This hydroxylated polybutadiene can be hydrogenated in the presence of a suitable transition metal catalyst.
  • esters of (meth)acrylic acid for use in accordance with the invention and a hydroxylated hydrogenated polybutadiene described are also referred to as
  • (meth)acrylic acid refers to acrylic acid and methacrylic acid and to mixtures thereof; methacrylic acid being particularly preferred.
  • (meth)acrylate refers to esters of acrylic acid and esters of methacrylic acid and to mixtures thereof; esters of methacrylic acid being particularly preferred.
  • the macromonomers for use in accordance with the invention can be prepared by transesterification of alkyl (meth)acrylates. Reaction of the alkyl (meth)acrylate with the hydroxylated hydrogenated polybutadiene forms the ester of the invention. Preference is given to using methyl (meth)acrylate or ethyl (meth)acrylate as reactant.
  • This transesterification is widely known.
  • a heterogeneous catalyst system such as lithium hydroxide/calcium oxide mixture (LiOH/CaO), pure lithium hydroxide (LiOH), lithium methoxide (LiOMe) or sodium methoxide (NaOMe) or a homogeneous catalyst system such as isopropyl titanate (Ti(OiPr)4) or dioctyltin oxide (Sn(OCt)20).
  • a heterogeneous catalyst system such as lithium hydroxide/calcium oxide mixture (LiOH/CaO), pure lithium hydroxide (LiOH), lithium methoxide (LiOMe) or sodium methoxide (NaOMe)
  • a homogeneous catalyst system such as isopropyl titanate (Ti(OiPr)4) or dioctyltin oxide (Sn(OCt)20).
  • Ti(OiPr)4 isopropyl titanate
  • the low molecular weight alcohol released is typically removed, for example by distillation.
  • the macromonomers can be obtained by a direct esterification proceeding, for example, from (meth)acrylic acid or (meth)acrylic anhydride, preferably under acidic catalysis by p-toluenesulfonic acid or methanesulfonic acid, or from free methacrylic acid by the DCC method (dicyclohexylcarbodiimide).
  • the present hydroxylated hydrogenated polybutadiene can be converted to an ester by reaction with an acid chloride such as (meth)acryloyl chloride.
  • polymerization inhibitors are used, for example the 4-hydroxy-2,2,6,6- tetramethylpiperidinooxyl radical and/or hydroquinone monomethyl ether.
  • Some of the macromonomers for use in accordance with the invention are also commercially available, for example Kraton Liquid® L-1253 which is produced from Kraton Liquid® L-1203 and is a hydrogenated polybutadiene methacrylate-functionalized to an extent of about 96% by weight, having about 50% each of 1 ,2 repeat units and 1 ,4 repeat units, from Kraton Polymers GmbH (Eschborn, Germany).
  • Kraton® L-1253 is likewise synthesized according to GB 2270317.
  • the monomer mixture may also comprise further comonomers, for example other alkyl (meth)acrylates.
  • alkyl (meth)acrylates having 1 to 22 carbon atoms in the alkyl chain also referred to as Ci to C22 alkyl (meth)acrylates.
  • Suitable alkyl (meth)acrylates are, for example, methyl and ethyl acrylate, propyl methacrylate, butyl methacrylate (BMA) and acrylate (BA), isobutyl methacrylate (IBMA), hexyl and cyclohexyl methacrylate, cyclohexyl acrylate, 2-ethylhexyl acrylate (EHA), 2- ethylhexyl methacrylate, octyl methacrylate, nonyl methacrylate, decyl methacrylate, isodecyl methacrylate (IDMA, based on branched (C10)alkyl isomer mixture), undecyl methacrylate, dodecyl methacrylate (also known as lauryl methacrylate), tridecyl methacrylate, tetradecyl methacrylate (also known as myristyl methacrylate), pent
  • the suitable C10-15 alkyl (meth)acrylates include, for example, decyl (meth)acrylate, undecyl (meth)acrylate, 5-methylundecyl (meth)acrylate, dodecyl (meth)acrylate, 2- methyldodecyl (meth)acrylate, tridecyl (meth)acrylate, 5-methyltridecyl (meth)acrylate, tetradecyl (meth)acrylate and/or pentadecyl (meth)acrylate.
  • Particularly preferred C10-15 alkyl (meth)acrylates are (meth)acrylic esters of a linear C12-14 alcohol mixture (C12-14 alkyl (meth)acrylate).
  • the comb polymer (B) comprises:
  • the comb polymer comprises:
  • the comb polymer (B) comprises:
  • the polyalkyl(meth)acrylate based comb polymer in accordance with the invention may preferably be obtained by radical polymerization.
  • the comb polymer may also be obtained by polymer-analogous reactions and/or graft copolymerization.
  • the comb polymer may be obtained by radical polymerization involving the steps of
  • the polymerization reaction is preferably initiated by mixing the monomer mixture with a radical initiator. In some cases, it may be required to heat the reaction mixture to the reaction temperatures specified below to initiate the polymerization.
  • Radical initiators may be selected from any of the well-known free-radical-producing compounds such as peroxy, hydroperoxy and azo initiators, including, for example, acetyl peroxide, benzoyl peroxide, lauroyl peroxide, tert-butyl peroxyisobutyrate, caproyl peroxide, cumene hydroperoxide, 1 , 1 -di(tert-butylperoxy)-3,3,5-trimethylcyclohexane, azobisisobutyronitrile and tert-butyl peroctoate (also known as tert-butylperoxy-2- ethylhexanoate).
  • Preferable radical initiators are benzoyl peroxide, lauroyl peroxide, tert- butyl peroxyisobutyrate, azobisisobutyronitrile and tert-butyl peroctoate. Tert-butyl peroctoate is particularly preferred.
  • the initiator concentration is typically between 0.025 and 1 wt-%, preferably from 0.05 to 0.75 wt-%, more preferably from 0.1 to 0.5 wt-% and most preferably from 0.2 to 0.4 wt-%, based on the total weight of the monomers.
  • the polymerization is preferably conducted at a temperature below the boiling point of the reaction mixtures.
  • the temperature is in the range of 60 to 150°C, more preferably 85 to 130°C, most preferably 90 to 1 10°C.
  • One or more polymerization promoters may also be added to the monomer mixture.
  • Suitable promoters include, for example, quaternary ammonium salts such as
  • promoters are soluble in hydrocarbons. When used, these promoters are present at levels from 1 to 50 wt-%, preferably from 5 to 25 wt-%, based on total weight of initiator.
  • Chain transfer agents may also be added to control the molecular weight of the copolymer.
  • the preferred chain transfer agents are alkyl mercaptans such as lauryl mercaptan (also known as dodecyl mercaptan, DDM).
  • the amount of chain transfer agent is preferably 5 wt-% or less, more preferably 2 wt-% or less, based on the total weight of monomers.
  • Diluents may also be added to the monomer mixture.
  • the first and second reaction mixture each comprise up to 60 wt-% diluent, more preferably 5 to 60 wt-%, most preferably 10 to 60 wt-%.
  • aromatic hydrocarbons such as benzene, toluene, xylene and aromatic naphthas
  • chlorinated hydrocarbons such as ethylene dichloride, chlorobenzene and dichlorobenzene
  • esters such as ethyl propionate or butyl acetate
  • C6-C20 aliphatic hydrocarbons (such as cyclohexane, heptane and octane)
  • mineral oils such as paraffinic and naphthenic oils
  • synthetic base oils such as poly([alpha]-olefin) oligomer (PAO) lubricating oils, for example, [alpha]-decene dimers, trimers and mixtures thereof).
  • PAO poly([alpha]-olefin) oligomer
  • the lubricant composition in accordance with the present invention may further comprise auxiliary additives selected from the group consisting of pour point depressants, antiwear agents, antioxidants, dispersants, detergents, friction modifiers, antifoam agents, extreme pressure additives, and corrosion inhibitors.
  • auxiliary additives selected from the group consisting of pour point depressants, antiwear agents, antioxidants, dispersants, detergents, friction modifiers, antifoam agents, extreme pressure additives, and corrosion inhibitors.
  • the auxiliary additives are preferably added in an amount of 0.1 to 25 weight-%, based on the total weight of the lubricant
  • Suitable pour-point depressants include ethylene-vinyl acetate copolymers, chlorinated paraffin-naphthalene condensates, chlorinated paraffin-phenol condensates, polymethacrylates, polyalkylstyrenes, etc. Preferred are polymethacrylates having a mass-average molecular weight of from 5.000 to 50.000 g/mol.
  • the preferred antiwear and extreme pressure additives include sulfur-containing compounds such as zinc dithiophosphate, zinc di-C3-12-alkyldithiophosphat.es (ZnDTPs), zinc phosphate, zinc dithiocarbamate, molybdenum dithiocarbamate, molybdenum dithiophosphate, disulfides, sulfurized olefins, sulfurized oils and fats, sulfurized esters, thiocarbonates, thiocarbamates, polysulfides, etc.; phosphorus-containing compounds such as phosphites, phosphates, for example trialkyl phosphates, triaryl phosphates, e.g.
  • tricresyl phosphate amine-neutralized mono- and dialkyl phosphates, ethoxylated mono- and dialkyl phosphates, phosphonates, phosphines, amine salts or metal salts of those compounds, etc.; sulfur and phosphorus-containing anti-wear agents such as
  • thiophosphites thiophosphates, thiophosphonates, amine salts or metal salts of those compounds, etc.
  • the suitable antioxidants include, for example, phenol-based antioxidants and amine- based antioxidants.
  • Phenol-based antioxidants include, for example, octadecyl-3-(3,5-di-tert-butyl-4- hydroxyphenyl)propionate; 4,4' -methylenebis(2,6-di-tert-butylphenol); 4,4' -bis(2,6-di-t- butylphenol); 4,4' -b is(2-methyl-6-t-butylphenol); 2,2' -methylenebis(4-ethyl-6-t- butylphenol); 2,2' -methylenebis( 4-methyl-6-t-butyl phenol); 4,4' -butyl idenebis(3-methyl- 6-t-butylphenol); 4,4'-isopropylidenebis(2,6-di-t-butylphenol); 2,2'-methylenebis(4-methyl- 6-nonylphenol); 2,2'-isobutylidenebis(4,6-dimethylphenol); 2,2'-methylene
  • the amine-based antioxidants include, for example, monoalkyldiphenylamines such as monooctyldiphenylamine, monononyldiphenylamine, etc.; dialkyldiphenylamines such as 4,4' -dibutyldiphenylamine, 4,4'-dipentyldiphe nylamine, 4,4'- dihexyldiphenylamine, 4,4'- diheptyldiphenylamine, 4,4'-dioctyldiphenylamine, 4,4'-dinonyldiphenylamine, etc.;
  • monoalkyldiphenylamines such as monooctyldiphenylamine, monononyldiphenylamine, etc.
  • dialkyldiphenylamines such as 4,4' -dibutyldiphenylamine, 4,4'-dipentyldiphe nylamine, 4,4'- dihexyldiphenyl
  • polyalkyldiphenylamines such as tetrabutyldiphenylamine, tetrahexyldiphenylamine, tetraoctyldiphenylamine, tetranonyldiphenylamine, etc.; naphthylamines, concretely alpha-naphthylamine, phenyl-alpha-naphthylamine and further alkyl-substituted phenyl- alpha-naphthylamines such as butylphenyl-alpha-naphthylamine, pentylphenyl-alpha- naphthylamine, hexylphenyl-alpha-naphthylamine, heptylphenyl-alpha-naphthylamine, octylphenyl-alpha-naphthylamine, nonylphenyl-alpha-naphth
  • organophosphorus compounds for example triaryl and trialkyl phosphites
  • organocopper compounds and overbased calcium- and magnesium- based phenoxides and salicylates.
  • Appropriate dispersants include poly(isobutylene) derivatives, for example
  • PIBSIs poly(isobutylene)succinimides
  • borated PIBSIs borated PIBSIs
  • ethylene- propylene oligomers having N/O functionalities PIBSIs
  • the preferred detergents include metal-containing compounds, for example phenoxides; salicylates; thiophosphonates, especially thiopyrophosphonates, thiophosphonates and phosphonates; sulfonates and carbonates.
  • metal these compounds may contain especially calcium, magnesium and barium. These compounds may preferably be used in neutral or overbased form.
  • Friction modifiers used may include mechanically active compounds, for example molybdenum disulfide, graphite (including fluorinated graphite), poly(trifluoroethylene), polyamide, polyimide; compounds that form adsorption layers, for example long-chain carboxylic acids, fatty acid esters, ethers, alcohols, amines, amides, imides; compounds which form layers through tribochemical reactions, for example saturated fatty acids, phosphoric acid and thiophosphoric esters, xanthogenates, sulfurized fatty acids;
  • compounds that form polymer-like layers for example ethoxylated dicarboxylic partial esters, dialkyl phthalates, methacrylates, unsaturated fatty acids, sulfurized olefins or organometallic compounds, for example molybdenum compounds (molybdenum dithiophosphates and molybdenum dithiocarbamates MoDTCs) and combinations thereof with ZnDTPs, copper-containing organic compounds.
  • molybdenum compounds molybdenum dithiophosphates and molybdenum dithiocarbamates MoDTCs
  • Suitable antifoam agents are silicone oils, fluorosilicone oils, fluoroalkyl ethers, etc..
  • the above-detailed additives are described in detail, inter alia, in T. Mang, W. Dresel (eds.): “Lubricants and Lubrication”, Wiley-VCH, Weinheim 2001 ; R. M. Mortier, S. T. Orszulik (eds.): “Chemistry and Technology of Lubricants”.
  • the lubricant composition according to the invention can be useful for various reasons.
  • the invention also relates to the use of a comb polymer as described above as an additive for a base oil to produce a lubricant composition, characterized in that the lubricant composition preferably has an R-factor of less than or equal to 8, wherein the R-factor is defined as the ratio of the kinematic viscosity of the lubricant composition at -20°C to the kinematic viscosity at +20°C measured according to ASTM D445.
  • the lubricant composition has an R-factor of 1 to 8.
  • the lubricant composition comprises a synthetic base oil.
  • the base oil is preferably selected form the group consisting of polyalphaolefins, naphthenic base oils and mixtures thereof.
  • the lubricant composition comprises a polyalphaolefin base oil having a kinematic viscosity at 100°C according to ASTM D445 of 1 mm 2 /s to 20 mm 2 /s, more preferably 1 to 10 mm 2 /s, most preferably 1 to 5 mm 2 /s and especially preferred 2 to 3 mm 2 /s.
  • the lubricant composition preferably has a kinematic viscosity at 40°C according to ASTM D445 of 10 to 120 mm 2 /s, more preferably 40 to 100 mm 2 /s, most preferably 70 to 80 mm 2 /s.
  • the invention relates to a method of producing a lubricant composition having an R-factor of less than or equal to 8, preferably 1 to 8, wherein the R-factor is defined as the ratio of the kinematic viscosity of the lubricant composition at -20°C to the kinematic viscosity at +20°C measured according to ASTM D445, the method comprising the step of adding a comb polymer according to the present invention to a synthetic base oil, the synthetic base oil being preferably a polyalphaolefin base oil having a kinematic viscosity at 100°C according to ASTM D445 of 1 mm 2 /s to 20 mm 2 /s, more preferably 1 to 10 mm 2 /s, most preferably 1 to 5 mm 2 /s and especially preferred 2 to 3 mm 2 /s.
  • the method is preferably characterized by adding the comb polymer in an amount to get a lubricant composition with a kinematic viscosity at 40°C according to ASTM D445 of 10 to 120 mm 2 /s, more preferably 40 to 100 mm 2 /s, most preferably 70 to 80 mm 2 /s.
  • the macroalcohol was synthesized by an anionic polymerization of 1 ,3-butadiene with butyllithium at 20-45°C. On attainment of the desired degree of polymerization, the reaction was stopped by adding propylene oxide and lithium was removed by
  • the polymer was hydrogenated under a hydrogen atmosphere in the presence of a noble metal catalyst at up to 140°C and pressure 200 bar. After the hydrogenation had ended, the noble metal catalyst was removed and organic solvent was drawn off under reduced pressure. Finally, the base oil NB 3020 was used for dilution to a polymer content of 70% by weight.
  • the vinyl content of the macroalcohol was 61 %, the hydrogenation level > 99% and the OH functionality > 98%. These values were determined by H-NMR (nuclear resonance spectroscopy).
  • Comb polymers according to the invention were prepared according to the following free radical polymerization procedure.
  • a mixture of 100 g of all the monomers (e.g. as detailed in Table 1 ) is diluted in ester oil (e.g. diisononyl adipate) to reach approximately 60% w/w dilution at 90 ° C. Afterwards, 35% of this diluted mixture is charged into a continuously stirred glass reactor, followed by addition of 0.105 g of initiator i-butylperoxy 2-ethylhexanoate.
  • ester oil e.g. diisononyl adipate
  • the rest of the monomer mixture is gradually added into the glass reactor at constant flow rate for 3 h, in parallel with the addition of another 0.195 g of initiator i-butylperoxy 2- ethylhexanoate, also being introduced at constant flow rate for 3 h.
  • Reaction temperature is held constant at 90°C.
  • additional 2x0.2 g of initiator i-butylperoxy 2- ethylhexanoate is added to ensure the completion of the polymerization, 2 and 5 hours after the end of the monomer feeding, while the reaction is kept at 90°C.
  • additional dilution ester oil can be added.
  • Lauryl methacrylate is a mixture of linear C12 and C14 alkyl methacrylates with a ratio of C12 to CM alkyl methacrylate of around 73/27.
  • compositions of the monomer mixtures used to prepare exemplary copolymers according to the invention are given in the following Table 1 .
  • the amounts of monomers are given as weight-% based on the total weight of the comb polymer.
  • Comb polymers A and B are inventive examples and have a styrene content claimed by the present invention.
  • Comb polymer C is a comparative example and comprises a higher amount of styrene. It was prepared to show that a higher amount of styrene leads to a higher R-factor.
  • the following polyalkylmethacrylates are known viscosity index improvers and were used in comparative lubricant compositions. They were prepared to show that an R-factor within the claimed range of 1 -8 can only be reached by using comb polymers which comprise a certain amount of an ester of (meth)acrylic acid and a hydroxylated hydrogenated polybutadiene.
  • Comparative copolymer D is a polyalkylmethacrylate prepared through similar aforementioned free radical polymerization procedure from 89.97% by weight of dodecyl pentadecyl methacrylate and 10.03% by weight of methyl methacrylate.
  • Dodecyl pentadecyl methacrylate is a mixture of branched and linear C12 to C15 alkyl methacrylates with an average composition of 16 to 26% by weight of C12 alkyl methacrylate, 24 to 34% by weight of C13 alkyl methacrylate, 24 to 34% by weight of C14 alkyl methacrylate, and 16 to 26% by weight of C15 alkyl methacrylate, and approximately 80% linear alkyl methacrylates.
  • Comparative copolymer E is a polyalkylmethacrylate prepared through similar aforementioned free radical polymerization procedure from 99.80% by weight of C12 to Ci5 alkyl methacrylate (comprising 20% C12 alkyl methacrylate, 34% C13 alkyl methacrylate, 29% C14 alkyl methacrylate, and 17% C15 alkyl methacrylate, with approximately 40% linear alkyl methacrylates) and 0.20% by weight of methyl methacrylate.
  • Lubricant compositions were obtained by mixing a poly-alpha-olefin base oil (PA02) having a kinematic viscosity at 100°C of 2 mm 2 /s according to ASTM D445 and the indicated amount of copolymers as viscosity index improvers according to the following table targeting a KV40 of 76 mm 2 /s.
  • PA02 poly-alpha-olefin base oil
  • Table 2 lubricant compositions comprising comb polymers and base oil No Base oil Copolymer Amount of styrene Amount of copolymer
  • CE comparative example
  • the lubricant compositions were tested by determining the kinematic viscosity at different temperatures, the viscosity index and the R-factor.
  • the kinematic viscosity was determined according to ASTM D445, the viscosity index was determined according to ASTM D2270, and the R-factor was calculated as the ratio of the kinematic viscosity at -20°C to the kinematic viscosity at +20°C.
  • the results are given in the following Table 3.
  • compositions 1 and 2 comprising the comb polymers A and B, respectively
  • compositions 1 and 2 have a high viscosity index as well as a low R-factor.
  • the compositions according to the invention therefore, guarantee a good viscosity characteristic at low operating temperature, defined as an R-factor lower than 8.
  • compositions 3, 4 and 5, comprising comb polymers with a higher amount of styrene or conventional polyalkylmethacrylat.es D and E
  • the data therefore, show that the use of comb polymers according to the present invention has the surprising advantage over the use of conventional viscosity index improvers of improving the viscosity characteristics of a lubricant not only at normal operating temperatures but also at low operating temperatures.
  • Example 1 By using the inventive polymers (Examples 1 and 2) the viscosity increase is much lower compared to the use of standard polymers (Examples 4 and 5) or a polymer with higher styrene content (Example 3).
  • the lubricant compositions comprising the comb polymers according to the present invention show a KV20 in the range of 130 to 140 and a KV-20 in the range of 640 to 870.
  • VI is not appropriate to extrapolate viscosities down to temperatures below 40°C, e.g. to -20°C.

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Abstract

L'invention concerne une composition lubrifiante comprenant un polymère à structure en peigne et une huile de base synthétique. La composition lubrifiante présente des caractéristiques de viscosité améliorées à des températures de fonctionnement basses. L'invention concerne également l'utilisation d'un polymère à structure en peigne pour produire un lubrifiant ayant un facteur R inférieur ou égal à 8, le facteur R étant défini comme étant le rapport de la viscosité cinématique à -20 °C et la viscosité cinématique à +20 °C.
PCT/EP2017/077605 2016-11-02 2017-10-27 Composition lubrifiante d'une caractéristique de viscosité améliorée à basse température de fonctionnement WO2018083027A1 (fr)

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CN201780067603.5A CN109923195B (zh) 2016-11-02 2017-10-27 具有改进的在低操作温度下的粘度特性的润滑剂组合物
SG11201903781QA SG11201903781QA (en) 2016-11-02 2017-10-27 Lubricant composition with an improved viscosity characteristic at low operating temperature
ES17787940T ES2854939T3 (es) 2016-11-02 2017-10-27 Composición de lubricante con una característica de viscosidad mejorada a baja temperatura de operación
US16/345,260 US20190300808A1 (en) 2016-11-02 2017-10-27 Lubricant composition with an improved viscosity characteristic at low operating temperature
RU2019116232A RU2747727C2 (ru) 2016-11-02 2017-10-27 Смазывающая композиция, обладающая улучшенными характеристиками вязкости при низкой рабочей температуре
JP2019522683A JP6890658B2 (ja) 2016-11-02 2017-10-27 低い動作温度で改善された粘度特性を有する潤滑剤組成物
CA3042119A CA3042119A1 (fr) 2016-11-02 2017-10-27 Composition lubrifiante d'une caracteristique de viscosite amelioree a basse temperature de fonctionnement
KR1020197015692A KR102455761B1 (ko) 2016-11-02 2017-10-27 낮은 작동 온도에서 개선된 점도 특징을 갖는 윤활제 조성물
EP17787940.0A EP3535357B1 (fr) 2016-11-02 2017-10-27 Composition de lubrifiant avec une caractéristique de viscosité améliorée à basse température d'utilisation

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