CA3005870A1 - Structural adhesive with improved failure mode - Google Patents
Structural adhesive with improved failure mode Download PDFInfo
- Publication number
- CA3005870A1 CA3005870A1 CA3005870A CA3005870A CA3005870A1 CA 3005870 A1 CA3005870 A1 CA 3005870A1 CA 3005870 A CA3005870 A CA 3005870A CA 3005870 A CA3005870 A CA 3005870A CA 3005870 A1 CA3005870 A1 CA 3005870A1
- Authority
- CA
- Canada
- Prior art keywords
- structural adhesive
- adhesive film
- adhesive composition
- metal
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 151
- 239000000853 adhesive Substances 0.000 title claims abstract description 146
- 239000000203 mixture Substances 0.000 claims abstract description 221
- 229910052751 metal Inorganic materials 0.000 claims abstract description 108
- 239000002184 metal Substances 0.000 claims abstract description 108
- 239000004593 Epoxy Substances 0.000 claims abstract description 102
- 239000002313 adhesive film Substances 0.000 claims abstract description 100
- 150000001875 compounds Chemical class 0.000 claims abstract description 53
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 48
- 239000012798 spherical particle Substances 0.000 claims abstract description 40
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 20
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 20
- 239000000463 material Substances 0.000 claims description 55
- 229910000831 Steel Inorganic materials 0.000 claims description 50
- 239000010959 steel Substances 0.000 claims description 50
- 238000000034 method Methods 0.000 claims description 45
- 229920001187 thermosetting polymer Polymers 0.000 claims description 36
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 31
- 238000012360 testing method Methods 0.000 claims description 29
- 229910002804 graphite Inorganic materials 0.000 claims description 17
- 239000010439 graphite Substances 0.000 claims description 17
- 230000004913 activation Effects 0.000 claims description 15
- 229910052782 aluminium Inorganic materials 0.000 claims description 14
- 239000011521 glass Substances 0.000 claims description 14
- 239000004411 aluminium Substances 0.000 claims description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 13
- 229910052799 carbon Inorganic materials 0.000 claims description 12
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 11
- 239000010935 stainless steel Substances 0.000 claims description 11
- 229910001220 stainless steel Inorganic materials 0.000 claims description 11
- 239000010936 titanium Substances 0.000 claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 10
- 229910052719 titanium Inorganic materials 0.000 claims description 10
- 229910045601 alloy Inorganic materials 0.000 claims description 8
- 239000000956 alloy Substances 0.000 claims description 8
- 230000001788 irregular Effects 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 8
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 6
- 239000011777 magnesium Substances 0.000 claims description 6
- 229910052749 magnesium Inorganic materials 0.000 claims description 6
- 239000002131 composite material Substances 0.000 claims description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 239000002023 wood Substances 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- 239000006229 carbon black Substances 0.000 claims description 3
- 239000010954 inorganic particle Substances 0.000 claims description 3
- 230000007797 corrosion Effects 0.000 abstract description 12
- 238000005260 corrosion Methods 0.000 abstract description 12
- 230000002349 favourable effect Effects 0.000 abstract description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 40
- 229920005992 thermoplastic resin Polymers 0.000 description 29
- 239000012745 toughening agent Substances 0.000 description 26
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 25
- 239000002245 particle Substances 0.000 description 25
- 239000000306 component Substances 0.000 description 24
- -1 cycloaliphatic Chemical group 0.000 description 24
- 239000010408 film Substances 0.000 description 21
- 239000000758 substrate Substances 0.000 description 21
- 239000012764 mineral filler Substances 0.000 description 19
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 16
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 15
- 239000004604 Blowing Agent Substances 0.000 description 14
- 239000000292 calcium oxide Substances 0.000 description 14
- 239000005350 fused silica glass Substances 0.000 description 14
- 229920000647 polyepoxide Polymers 0.000 description 14
- 239000003085 diluting agent Substances 0.000 description 13
- 239000003822 epoxy resin Substances 0.000 description 11
- 125000000217 alkyl group Chemical group 0.000 description 10
- 230000000712 assembly Effects 0.000 description 10
- 238000000429 assembly Methods 0.000 description 10
- 229920001971 elastomer Polymers 0.000 description 10
- 239000005060 rubber Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 230000000694 effects Effects 0.000 description 9
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 8
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 8
- 229920001577 copolymer Polymers 0.000 description 8
- 239000011258 core-shell material Substances 0.000 description 8
- 150000002118 epoxides Chemical class 0.000 description 8
- 239000004615 ingredient Substances 0.000 description 8
- 239000010410 layer Substances 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- 239000013034 phenoxy resin Substances 0.000 description 7
- 229920006287 phenoxy resin Polymers 0.000 description 7
- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 6
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 6
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 6
- 239000012790 adhesive layer Substances 0.000 description 6
- 150000001336 alkenes Chemical class 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 6
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Inorganic materials [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 6
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 6
- 125000003700 epoxy group Chemical group 0.000 description 6
- 239000000945 filler Substances 0.000 description 6
- 229910021485 fumed silica Inorganic materials 0.000 description 6
- NOTVAPJNGZMVSD-UHFFFAOYSA-N potassium monoxide Inorganic materials [K]O[K] NOTVAPJNGZMVSD-UHFFFAOYSA-N 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 150000004760 silicates Chemical class 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000003981 vehicle Substances 0.000 description 6
- 230000032683 aging Effects 0.000 description 5
- 229910052681 coesite Inorganic materials 0.000 description 5
- 229910052906 cristobalite Inorganic materials 0.000 description 5
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 229920002857 polybutadiene Polymers 0.000 description 5
- 239000002243 precursor Substances 0.000 description 5
- 238000007789 sealing Methods 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 5
- 229910052682 stishovite Inorganic materials 0.000 description 5
- 229910052905 tridymite Inorganic materials 0.000 description 5
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000004594 Masterbatch (MB) Substances 0.000 description 4
- 241000238367 Mya arenaria Species 0.000 description 4
- 229920000459 Nitrile rubber Polymers 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 4
- 239000004721 Polyphenylene oxide Substances 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 150000001337 aliphatic alkines Chemical class 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 125000003545 alkoxy group Chemical group 0.000 description 4
- 239000011324 bead Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 4
- 239000002666 chemical blowing agent Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 4
- 150000001993 dienes Chemical class 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 150000002825 nitriles Chemical class 0.000 description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 229920001155 polypropylene Polymers 0.000 description 4
- 229920003048 styrene butadiene rubber Polymers 0.000 description 4
- 229920003319 Araldite® Polymers 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 3
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 150000001913 cyanates Chemical class 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 230000000670 limiting effect Effects 0.000 description 3
- 230000000873 masking effect Effects 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000565 sealant Substances 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- 229910000951 Aluminide Inorganic materials 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- 229910001335 Galvanized steel Inorganic materials 0.000 description 2
- 244000043261 Hevea brasiliensis Species 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- 239000004695 Polyether sulfone Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 239000002174 Styrene-butadiene Substances 0.000 description 2
- 241000282485 Vulpes vulpes Species 0.000 description 2
- 150000008065 acid anhydrides Chemical class 0.000 description 2
- 150000004645 aluminates Chemical class 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000004760 aramid Substances 0.000 description 2
- 229920006231 aramid fiber Polymers 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 150000001638 boron Chemical class 0.000 description 2
- 150000001642 boronic acid derivatives Chemical class 0.000 description 2
- 235000013877 carbamide Nutrition 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 229940072282 cardura Drugs 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Natural products OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000001143 conditioned effect Effects 0.000 description 2
- 239000008358 core component Substances 0.000 description 2
- 230000004069 differentiation Effects 0.000 description 2
- RUZYUOTYCVRMRZ-UHFFFAOYSA-N doxazosin Chemical compound C1OC2=CC=CC=C2OC1C(=O)N(CC1)CCN1C1=NC(N)=C(C=C(C(OC)=C2)OC)C2=N1 RUZYUOTYCVRMRZ-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 2
- 239000010433 feldspar Substances 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 239000008397 galvanized steel Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 150000002357 guanidines Chemical class 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 150000004679 hydroxides Chemical class 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 229910052809 inorganic oxide Inorganic materials 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 238000005304 joining Methods 0.000 description 2
- 150000001247 metal acetylides Chemical class 0.000 description 2
- 229910000000 metal hydroxide Inorganic materials 0.000 description 2
- 150000004692 metal hydroxides Chemical class 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical group 0.000 description 2
- 229910052914 metal silicate Inorganic materials 0.000 description 2
- 239000004005 microsphere Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229920003052 natural elastomer Polymers 0.000 description 2
- 229920001194 natural rubber Polymers 0.000 description 2
- CRSOQBOWXPBRES-UHFFFAOYSA-N neopentane Chemical compound CC(C)(C)C CRSOQBOWXPBRES-UHFFFAOYSA-N 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 229920003986 novolac Polymers 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 125000000466 oxiranyl group Chemical group 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 230000036961 partial effect Effects 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 2
- 229920006393 polyether sulfone Polymers 0.000 description 2
- 239000004848 polyfunctional curative Substances 0.000 description 2
- 229920001195 polyisoprene Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910021332 silicide Inorganic materials 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- IATRAKWUXMZMIY-UHFFFAOYSA-N strontium oxide Inorganic materials [O-2].[Sr+2] IATRAKWUXMZMIY-UHFFFAOYSA-N 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 150000003573 thiols Chemical class 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 229920006163 vinyl copolymer Polymers 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- KYVBNYUBXIEUFW-UHFFFAOYSA-N 1,1,3,3-tetramethylguanidine Chemical compound CN(C)C(=N)N(C)C KYVBNYUBXIEUFW-UHFFFAOYSA-N 0.000 description 1
- HCNHNBLSNVSJTJ-UHFFFAOYSA-N 1,1-Bis(4-hydroxyphenyl)ethane Chemical compound C=1C=C(O)C=CC=1C(C)C1=CC=C(O)C=C1 HCNHNBLSNVSJTJ-UHFFFAOYSA-N 0.000 description 1
- BXGYYDRIMBPOMN-UHFFFAOYSA-N 2-(hydroxymethoxy)ethoxymethanol Chemical compound OCOCCOCO BXGYYDRIMBPOMN-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 1
- AFLAQDQMOHKVQM-UHFFFAOYSA-N 2-carbonoperoxoyl-3,4,5-trihydroxy-6-methylbenzoic acid Chemical compound CC1=C(C(C(=O)OO)=C(C(=C1O)O)O)C(=O)O AFLAQDQMOHKVQM-UHFFFAOYSA-N 0.000 description 1
- KXGPWOMNWKUGMU-UHFFFAOYSA-N 2-carbonoperoxoyl-3,4,6-trihydroxy-5-methylbenzoic acid Chemical compound CC=1C(=C(C(C(=O)OO)=C(C=1O)O)C(=O)O)O KXGPWOMNWKUGMU-UHFFFAOYSA-N 0.000 description 1
- YBRVSVVVWCFQMG-UHFFFAOYSA-N 4,4'-diaminodiphenylmethane Chemical compound C1=CC(N)=CC=C1CC1=CC=C(N)C=C1 YBRVSVVVWCFQMG-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- SKZTVRIDSVBAJG-UHFFFAOYSA-N 4-(3-methyl-4-bicyclo[2.2.1]hept-2-enyl)-2-benzofuran-1,3-dione Chemical compound CC1=CC(C2)CCC12C1=CC=CC2=C1C(=O)OC2=O SKZTVRIDSVBAJG-UHFFFAOYSA-N 0.000 description 1
- PXRKCOCTEMYUEG-UHFFFAOYSA-N 5-aminoisoindole-1,3-dione Chemical compound NC1=CC=C2C(=O)NC(=O)C2=C1 PXRKCOCTEMYUEG-UHFFFAOYSA-N 0.000 description 1
- ULKLGIFJWFIQFF-UHFFFAOYSA-N 5K8XI641G3 Chemical compound CCC1=NC=C(C)N1 ULKLGIFJWFIQFF-UHFFFAOYSA-N 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229920001342 Bakelite® Polymers 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- MWRWFPQBGSZWNV-UHFFFAOYSA-N Dinitrosopentamethylenetetramine Chemical compound C1N2CN(N=O)CN1CN(N=O)C2 MWRWFPQBGSZWNV-UHFFFAOYSA-N 0.000 description 1
- 229920003344 Epilox® Polymers 0.000 description 1
- 229910001200 Ferrotitanium Inorganic materials 0.000 description 1
- 101001128431 Homo sapiens Myeloid-derived growth factor Proteins 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- 102220471582 Islet amyloid polypeptide_F48S_mutation Human genes 0.000 description 1
- 229920000271 Kevlar® Polymers 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- 102100031789 Myeloid-derived growth factor Human genes 0.000 description 1
- QNCJDQOPWGDTKN-UHFFFAOYSA-N NC(=O)N.CC=1C(N=C=O)=CC(N=C=O)=CC1 Chemical compound NC(=O)N.CC=1C(N=C=O)=CC(N=C=O)=CC1 QNCJDQOPWGDTKN-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 239000004693 Polybenzimidazole Substances 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004697 Polyetherimide Substances 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- HHEFNVCDPLQQTP-UHFFFAOYSA-N ammonium perchlorate Chemical compound [NH4+].[O-]Cl(=O)(=O)=O HHEFNVCDPLQQTP-UHFFFAOYSA-N 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000019399 azodicarbonamide Nutrition 0.000 description 1
- 239000004637 bakelite Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 239000004643 cyanate ester Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- IUNMPGNGSSIWFP-UHFFFAOYSA-N dimethylaminopropylamine Chemical compound CN(C)CCCN IUNMPGNGSSIWFP-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 229920001973 fluoroelastomer Polymers 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical group 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 235000013847 iso-butane Nutrition 0.000 description 1
- 239000004761 kevlar Substances 0.000 description 1
- 239000004850 liquid epoxy resins (LERs) Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 239000007777 multifunctional material Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 230000000269 nucleophilic effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000007719 peel strength test Methods 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 229920000747 poly(lactic acid) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920002480 polybenzimidazole Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920001601 polyetherimide Polymers 0.000 description 1
- 239000004626 polylactic acid Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 229910000033 sodium borohydride Inorganic materials 0.000 description 1
- 239000012279 sodium borohydride Substances 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
- C09J5/06—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving heating of the applied adhesive
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/35—Heat-activated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2650/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G2650/28—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type
- C08G2650/56—Polyhydroxyethers, e.g. phenoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/408—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2463/00—Presence of epoxy resin
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Adhesive Tapes (AREA)
- Epoxy Resins (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP15195469.0 | 2015-11-19 | ||
| EP15195469.0A EP3170877B1 (en) | 2015-11-19 | 2015-11-19 | Structural adhesive with improved failure mode |
| PCT/US2016/062498 WO2017087651A1 (en) | 2015-11-19 | 2016-11-17 | Structural adhesive with improved failure mode |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA3005870A1 true CA3005870A1 (en) | 2017-05-26 |
Family
ID=54754439
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA3005870A Abandoned CA3005870A1 (en) | 2015-11-19 | 2016-11-17 | Structural adhesive with improved failure mode |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20180273811A1 (enExample) |
| EP (2) | EP3170877B1 (enExample) |
| JP (3) | JP2019503406A (enExample) |
| KR (1) | KR20180083413A (enExample) |
| CN (1) | CN108291130B (enExample) |
| BR (1) | BR112018010315A2 (enExample) |
| CA (1) | CA3005870A1 (enExample) |
| MX (1) | MX2018006138A (enExample) |
| WO (1) | WO2017087651A1 (enExample) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3170860B1 (en) | 2015-11-19 | 2020-07-29 | 3M Innovative Properties Company | Structural adhesive with improved corrosion resistance |
| WO2017151898A1 (en) * | 2016-03-02 | 2017-09-08 | 3M Innovative Properties Company | Composition including epoxy adhesive and aluminum flakes and method for making the same |
| US11279795B2 (en) | 2017-06-29 | 2022-03-22 | 3M Innovative Properties Company | Curable composition |
| EP3587526B1 (en) | 2018-06-29 | 2022-02-16 | 3M Innovative Properties Company | Both sides coated automotive paint compatible liner for structural adhesive film |
| EP3587527A1 (en) | 2018-06-30 | 2020-01-01 | 3M Innovative Properties Company | Full (per)fluoro polymer liner for adhesive tapes |
| JP2021534266A (ja) | 2018-08-06 | 2021-12-09 | ゼフィロス インコーポレイテッド | 改善された破壊ひずみを有する高弾性率構造発泡体材料 |
| EP3670626A1 (en) * | 2018-12-17 | 2020-06-24 | 3M Innovative Properties Company | Thermosettable precursor of a structural adhesive composition with corrosion resistance |
| JP7045768B2 (ja) | 2019-04-03 | 2022-04-01 | 信越化学工業株式会社 | 生体電極組成物、生体電極、及び生体電極の製造方法 |
| JP7082082B2 (ja) | 2019-04-03 | 2022-06-07 | 信越化学工業株式会社 | 生体電極組成物、生体電極、及び生体電極の製造方法 |
| JP7411537B2 (ja) | 2020-01-22 | 2024-01-11 | 信越化学工業株式会社 | 生体電極組成物、生体電極、及び生体電極の製造方法 |
| JP7410065B2 (ja) | 2020-03-19 | 2024-01-09 | 信越化学工業株式会社 | 生体電極、生体電極の製造方法及び生体信号の測定方法 |
| JP7406516B2 (ja) | 2020-04-01 | 2023-12-27 | 信越化学工業株式会社 | 生体電極組成物、生体電極及び生体電極の製造方法 |
| JP7524148B2 (ja) | 2020-10-13 | 2024-07-29 | 信越化学工業株式会社 | 生体電極組成物、生体電極、生体電極の製造方法、高分子化合物及び複合体 |
| JP7569298B2 (ja) | 2020-11-05 | 2024-10-17 | 信越化学工業株式会社 | 生体電極組成物、生体電極、生体電極の製造方法及び反応複合体 |
| JP7507136B2 (ja) | 2020-11-05 | 2024-06-27 | 信越化学工業株式会社 | 生体電極組成物、生体電極、及び生体電極の製造方法 |
| JP7507737B2 (ja) | 2020-11-26 | 2024-06-28 | 信越化学工業株式会社 | 生体電極組成物、生体電極、生体電極の製造方法、及び反応複合体 |
| JP7611807B2 (ja) | 2021-01-06 | 2025-01-10 | 信越化学工業株式会社 | 生体電極組成物、生体電極、及び生体電極の製造方法 |
| KR102890598B1 (ko) | 2021-03-12 | 2025-11-24 | 신에쓰 가가꾸 고교 가부시끼가이샤 | 생체 전극, 생체 전극의 제조 방법 및 생체 신호의 측정 방법 |
| JP7627671B2 (ja) | 2021-04-16 | 2025-02-06 | 信越化学工業株式会社 | 生体電極組成物、生体電極、及び生体電極の製造方法 |
| WO2023190322A1 (ja) * | 2022-03-28 | 2023-10-05 | 三菱ケミカル株式会社 | 接着シート |
| JP2024014732A (ja) | 2022-07-21 | 2024-02-01 | 信越化学工業株式会社 | 生体電極組成物、生体電極、及びその製造方法 |
| CN115678475A (zh) * | 2022-11-17 | 2023-02-03 | 上海希奈新材料科技有限公司 | 一种阻燃耐水煮耐高低温冲击的双组份环氧灌封胶及制备方法和应用 |
| JP2024137755A (ja) | 2023-03-23 | 2024-10-07 | 信越化学工業株式会社 | 生体電極組成物、生体電極、及び生体電極の製造方法 |
| JP2025011039A (ja) | 2023-07-10 | 2025-01-23 | 信越化学工業株式会社 | 生体電極組成物、生体電極、及び生体電極の製造方法 |
| JP2025174080A (ja) | 2024-05-16 | 2025-11-28 | 信越化学工業株式会社 | 生体電極組成物、生体電極、及び生体電極の製造方法 |
Family Cites Families (61)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5751772A (en) * | 1980-09-12 | 1982-03-26 | Toagosei Chem Ind Co Ltd | Powdered adhesive |
| AU602822B2 (en) * | 1988-10-05 | 1990-10-25 | National Starch & Chemical Corporation | Self fixturing structural adhesives |
| EP0814121B1 (en) | 1996-06-20 | 2001-09-26 | Minnesota Mining And Manufacturing Company | Low density, fire retardant one-part epoxy composition |
| US6057382A (en) | 1998-05-01 | 2000-05-02 | 3M Innovative Properties Company | Epoxy/thermoplastic photocurable adhesive composition |
| JP2002518579A (ja) * | 1998-06-22 | 2002-06-25 | ミネソタ マイニング アンド マニュファクチャリング カンパニー | 熱硬化性接着剤 |
| US6000118A (en) | 1998-10-30 | 1999-12-14 | Chrysler Corporation | Method of forming a sealed edge joint between two metal panels |
| JP4536974B2 (ja) | 1999-06-09 | 2010-09-01 | 三洋機工株式会社 | 金属板材のヘミング構造 |
| US6368008B1 (en) | 2000-05-24 | 2002-04-09 | Daimlerchrysler Corporation | Sealed edge joint between two metal panels |
| US20020182955A1 (en) | 2001-03-29 | 2002-12-05 | Weglewski James T. | Structural bonding tapes and articles containing the same |
| JP2003147052A (ja) * | 2001-11-12 | 2003-05-21 | Nec Corp | 難燃性エポキシ樹脂組成物 |
| US8501858B2 (en) | 2002-09-12 | 2013-08-06 | Board Of Trustees Of Michigan State University | Expanded graphite and products produced therefrom |
| JP2004189856A (ja) * | 2002-12-10 | 2004-07-08 | Tokai Rubber Ind Ltd | 接着体およびそれを用いたリサイクル方法 |
| GB0229810D0 (en) | 2002-12-20 | 2003-01-29 | Vantico Ag | Flame retardant polymer compositions |
| DE602004004501T3 (de) | 2004-03-12 | 2015-05-28 | Dow Global Technologies Inc. | Epoxidharz Klebstoffzusammensetzung |
| EP1616924A1 (en) * | 2004-07-13 | 2006-01-18 | Huntsman Advanced Materials (Switzerland) GmbH | Fire retardant composition |
| JP2006225544A (ja) | 2005-02-18 | 2006-08-31 | Nagase Chemtex Corp | エポキシ樹脂接着剤 |
| JP4573677B2 (ja) * | 2005-03-16 | 2010-11-04 | サンスター技研株式会社 | 接着剤組成物 |
| ATE378711T1 (de) | 2005-04-12 | 2007-11-15 | Schunk Kohlenstofftechnik Gmbh | Verfahren zur herstellung von kohlebürsten und nach diesem verfahren hergestellte kohlebürsten |
| EP1746119A1 (en) | 2005-07-22 | 2007-01-24 | 3M Innovative Properties Company | Thermally curable precursor of a toughened thermo-expanded film and a film made thereof |
| EP1876194A1 (de) | 2006-06-30 | 2008-01-09 | Sika Technology AG | Hitzehärtende Zusammensetzung geeignet zum Verkleben von beschichteten Substraten |
| PL2049611T3 (pl) | 2006-07-31 | 2019-04-30 | Henkel Ag & Co Kgaa | Utwardzalne kompozycje klejowe oparte na żywicach epoksydowych |
| US7745006B2 (en) | 2006-12-15 | 2010-06-29 | Ashland Licensing And Intellectual Property, Llc | Low odor, fast cure, toughened epoxy adhesive |
| WO2008127925A2 (en) | 2007-04-11 | 2008-10-23 | Dow Global Technologies, Inc. | Structural epoxy resins containing core-shell rubbers |
| KR101467602B1 (ko) | 2007-04-11 | 2014-12-01 | 다우 글로벌 테크놀로지스 엘엘씨 | 내열 구조 에폭시 수지 |
| JP5150361B2 (ja) * | 2007-05-17 | 2013-02-20 | 株式会社フジクラ | エポキシ系接着剤、カバーレイ、プリプレグ、金属張積層板、プリント配線基板 |
| JP2010536953A (ja) | 2007-08-17 | 2010-12-02 | ダウ グローバル テクノロジーズ インコーポレイティド | 二液型耐衝撃性エポキシ接着剤 |
| CA2703907C (en) * | 2007-10-30 | 2016-11-01 | Henkel Ag & Co. Kgaa | Epoxy paste adhesives resistant to wash-off |
| EP2062928A1 (de) | 2007-11-21 | 2009-05-27 | Sika Technology AG | Schlagzähigkeitsverbesserer für Epoxidharzzusammensetzungen |
| GB2455292A (en) | 2007-12-03 | 2009-06-10 | Zephyros Inc | Improvements in or relating to the production of joints |
| EP2222808A2 (en) | 2007-12-05 | 2010-09-01 | 3M Innovative Properties Company | Assembly bonded to a structural adhesive and method and applicator for making it |
| JP2009144072A (ja) * | 2007-12-14 | 2009-07-02 | Sekisui Chem Co Ltd | 絶縁シート及び積層構造体 |
| JP5446105B2 (ja) * | 2008-03-11 | 2014-03-19 | 株式会社カネカ | 軟質塩化ビニル系樹脂組成物及び成形品の製造方法 |
| JP2009242459A (ja) | 2008-03-28 | 2009-10-22 | Toho Tenax Co Ltd | 樹脂組成物、プリプレグ、及びそれらの製造方法 |
| ES2662646T3 (es) | 2008-06-12 | 2018-04-09 | Henkel IP & Holding GmbH | Composiciones adhesivas epóxicas estructurales de dos partes, altamente reforzadas, de nueva generación |
| JP2011529118A (ja) | 2008-07-23 | 2011-12-01 | スリーエム イノベイティブ プロパティズ カンパニー | 二液型エポキシ系構造用接着剤 |
| BRPI0911723A2 (pt) | 2008-07-29 | 2015-10-06 | Dow Global Technologies Llc | painel veicular reforçado, método para preparar um painel veicular reforçado, estrutura de carroceria veicular e método para preparar uma estrutura de carroceria veicular |
| KR101682255B1 (ko) | 2008-09-10 | 2016-12-02 | 다우 글로벌 테크놀로지스 엘엘씨 | 기재에 반응성 접착제를 결합시키기 위한 개선된 방법 |
| JP2010150362A (ja) | 2008-12-25 | 2010-07-08 | Sumitomo Electric Ind Ltd | フィルム状接着剤及び異方導電性接着剤 |
| JP2010189542A (ja) * | 2009-02-18 | 2010-09-02 | Cemedine Henkel Co Ltd | Ｃｋｄ輸送対応ヘミング接着剤 |
| GB201007793D0 (en) | 2010-05-10 | 2010-06-23 | Zephyros Inc | Improvements in or relating to structural adhesives |
| GB201012595D0 (en) | 2010-07-27 | 2010-09-08 | Zephyros Inc | Oriented structural adhesives |
| JP2012082347A (ja) * | 2010-10-13 | 2012-04-26 | Yokohama Rubber Co Ltd:The | 接着剤 |
| JP5784134B2 (ja) | 2010-11-12 | 2015-09-24 | スリーエム イノベイティブ プロパティズ カンパニー | 硬化性組成物 |
| KR101794389B1 (ko) | 2010-11-12 | 2017-11-06 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 경화성 조성물 및 경화된 조성물 |
| US8796361B2 (en) | 2010-11-19 | 2014-08-05 | Ppg Industries Ohio, Inc. | Adhesive compositions containing graphenic carbon particles |
| WO2012087459A2 (en) | 2010-12-22 | 2012-06-28 | 3M Innovative Properties Company | Epoxy-based coating compositions |
| GB201102672D0 (en) | 2011-02-15 | 2011-03-30 | Zephyros Inc | Improved structural adhesives |
| KR101621991B1 (ko) * | 2011-04-29 | 2016-05-17 | 주식회사 엘지화학 | 전지 봉지용 접착제 조성물 및 접착필름 |
| KR101992831B1 (ko) | 2011-05-19 | 2019-06-25 | 다우 글로벌 테크놀로지스 엘엘씨 | 신규 구조 접착제 및 그의 용도 |
| GB201119287D0 (en) | 2011-11-08 | 2011-12-21 | Zephyros Inc | Improvements in or relating to structrual adhesives |
| US8895148B2 (en) | 2011-11-09 | 2014-11-25 | Cytec Technology Corp. | Structural adhesive and bonding application thereof |
| JP6005949B2 (ja) * | 2012-02-24 | 2016-10-12 | デンカ株式会社 | 導電性粘着シート及び電子部品の製造方法 |
| EP2700683B1 (en) | 2012-08-23 | 2016-06-08 | 3M Innovative Properties Company | Structural adhesive film |
| JP6002518B2 (ja) * | 2012-09-21 | 2016-10-05 | デクセリアルズ株式会社 | 異方性導電フィルム、接続方法、及び接合体 |
| EP2966106A4 (en) | 2013-03-06 | 2016-11-09 | Dainippon Ink & Chemicals | EPOXY RESIN COMPOSITION, HARDENED PRODUCT, HEAT EXTRACTION MATERIAL AND ELECTRONIC COMPONENT |
| US10577522B2 (en) | 2013-07-26 | 2020-03-03 | Zephyros, Inc. | Thermosetting adhesive films including a fibrous carrier |
| JP5692347B2 (ja) * | 2013-12-17 | 2015-04-01 | デクセリアルズ株式会社 | 導電接着剤 |
| JP6460365B2 (ja) * | 2014-03-14 | 2019-01-30 | Dic株式会社 | 樹脂組成物、熱伝導性接着剤及び積層体 |
| CN106164168A (zh) | 2014-04-10 | 2016-11-23 | 赫克塞尔合成有限公司 | 复合材料的改进 |
| CA2957758A1 (en) | 2014-08-12 | 2016-02-18 | 3M Innovative Properties Company | Film adhesive |
| BR112017016240A2 (pt) | 2015-01-30 | 2018-03-27 | Zephyros Inc | composição |
-
2015
- 2015-11-19 EP EP15195469.0A patent/EP3170877B1/en not_active Revoked
-
2016
- 2016-11-17 EP EP16806385.7A patent/EP3377588B1/en active Active
- 2016-11-17 BR BR112018010315A patent/BR112018010315A2/pt not_active Application Discontinuation
- 2016-11-17 CN CN201680066995.9A patent/CN108291130B/zh active Active
- 2016-11-17 CA CA3005870A patent/CA3005870A1/en not_active Abandoned
- 2016-11-17 MX MX2018006138A patent/MX2018006138A/es unknown
- 2016-11-17 KR KR1020187017183A patent/KR20180083413A/ko not_active Ceased
- 2016-11-17 JP JP2018526102A patent/JP2019503406A/ja active Pending
- 2016-11-17 WO PCT/US2016/062498 patent/WO2017087651A1/en not_active Ceased
- 2016-11-17 US US15/775,178 patent/US20180273811A1/en active Pending
-
2022
- 2022-02-18 JP JP2022023342A patent/JP2022065120A/ja active Pending
-
2024
- 2024-02-13 JP JP2024019129A patent/JP2024056831A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JP2019503406A (ja) | 2019-02-07 |
| MX2018006138A (es) | 2018-08-15 |
| WO2017087651A1 (en) | 2017-05-26 |
| EP3170877A1 (en) | 2017-05-24 |
| US20180273811A1 (en) | 2018-09-27 |
| JP2024056831A (ja) | 2024-04-23 |
| JP2022065120A (ja) | 2022-04-26 |
| CN108291130A (zh) | 2018-07-17 |
| KR20180083413A (ko) | 2018-07-20 |
| EP3377588B1 (en) | 2023-05-03 |
| BR112018010315A2 (pt) | 2018-12-04 |
| CN108291130B (zh) | 2021-02-05 |
| EP3377588A1 (en) | 2018-09-26 |
| EP3170877B1 (en) | 2020-11-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP3377588B1 (en) | Structural adhesive with improved failure mode | |
| US11377576B2 (en) | Structural adhesive with improved corrosion resistance | |
| EP2700683B1 (en) | Structural adhesive film | |
| EP2529856B1 (en) | Metal Part Assembly And Method For Making Same | |
| EP2727664B1 (en) | Method for making a hemmed structure of metal panels | |
| EP2781277A1 (en) | Panel assembly and method for making the same | |
| EP4019602A1 (en) | Low tack structural adhesive for shear bonding of magnets in electrical motors |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Discontinued |
Effective date: 20210831 |
|
| FZDE | Discontinued |
Effective date: 20210831 |