CA2895186C - Esterification of 2,5-furan-dicarboxylic acid - Google Patents

Esterification of 2,5-furan-dicarboxylic acid Download PDF

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Publication number
CA2895186C
CA2895186C CA2895186A CA2895186A CA2895186C CA 2895186 C CA2895186 C CA 2895186C CA 2895186 A CA2895186 A CA 2895186A CA 2895186 A CA2895186 A CA 2895186A CA 2895186 C CA2895186 C CA 2895186C
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Prior art keywords
alcohol
reaction
fdca
furan
psi
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CA2895186A
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English (en)
French (fr)
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CA2895186A1 (en
Inventor
Kenneth STENSRUD
Padmesh Venkitasubramanian
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Archer Daniels Midland Co
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Archer Daniels Midland Co
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/56—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/68—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P17/00—Preparation of heterocyclic carbon compounds with only O, N, S, Se or Te as ring hetero atoms
    • C12P17/02—Oxygen as only ring hetero atoms
    • C12P17/04—Oxygen as only ring hetero atoms containing a five-membered hetero ring, e.g. griseofulvin, vitamin C
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Health & Medical Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biotechnology (AREA)
  • Biochemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Microbiology (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Furan Compounds (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
CA2895186A 2012-12-20 2013-12-09 Esterification of 2,5-furan-dicarboxylic acid Active CA2895186C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261739761P 2012-12-20 2012-12-20
US61/739,761 2012-12-20
PCT/US2013/073821 WO2014099438A2 (en) 2012-12-20 2013-12-09 Esterification of 2,5-furan-dicarboxylic acid

Publications (2)

Publication Number Publication Date
CA2895186A1 CA2895186A1 (en) 2014-06-26
CA2895186C true CA2895186C (en) 2019-10-22

Family

ID=50979377

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2895186A Active CA2895186C (en) 2012-12-20 2013-12-09 Esterification of 2,5-furan-dicarboxylic acid

Country Status (12)

Country Link
US (2) US9765045B2 (https=)
EP (1) EP2935229B1 (https=)
JP (1) JP6370307B2 (https=)
KR (1) KR101963478B1 (https=)
CN (1) CN105246958B (https=)
AU (1) AU2013363501B2 (https=)
BR (1) BR112015014183B1 (https=)
CA (1) CA2895186C (https=)
ES (1) ES2642005T3 (https=)
MX (1) MX362292B (https=)
SG (1) SG11201503646TA (https=)
WO (1) WO2014099438A2 (https=)

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AU2013338397B2 (en) * 2012-10-29 2017-11-16 Archer Daniels Midland Company Alcohol-mediated esterification of carboxylic acids with carbonates
CA2921489C (en) * 2013-08-30 2021-06-29 Furanix Technologies B.V. Process for purifying an acid composition comprising 2-formyl-furan-5-carboxylic acid and 2,5-furandicarboxylic acid
US9944615B2 (en) 2014-05-08 2018-04-17 Eastman Chemical Company Purifying crude furan 2,5-dicarboxylic acid by hydrogenation and a purge zone
US9604202B2 (en) 2014-05-08 2017-03-28 Eastman Chemical Company Furan-2,5-dicarboxylic acid purge process
US10010812B2 (en) 2014-05-08 2018-07-03 Eastman Chemical Company Furan-2,5-dicarboxylic acid purge process
JP6452428B2 (ja) * 2014-12-18 2019-01-16 花王株式会社 ハロゲン系樹脂用可塑剤
US10160740B2 (en) 2015-03-20 2018-12-25 The Board Of Trustees Of The Leland Stanford Junior University Carbonate-promoted carboxylation reactions for the synthesis of valuable organic compounds
PL3283470T3 (pl) 2015-04-14 2024-05-06 E I Du Pont De Nemours Sposoby wytwarzania kwasu 2,5-furanodikarboksylowego i jego pochodnych
US20190084952A1 (en) * 2015-07-24 2019-03-21 E I Du Pont De Nemours And Company Process for producing 2,5-furandicarboxylic acid dialkyl ester
EP3434672B1 (en) * 2015-07-24 2020-02-19 DuPont Industrial Biosciences USA, LLC Processes for preparing 2,5-furandicarboxylic acid
WO2017091437A1 (en) * 2015-11-24 2017-06-01 Archer Daniels Midland Company Organotin catalysts in esterification processes of furan-2,5-dicarboxylic acid (fdca)
EP3402787A4 (en) 2016-01-13 2019-11-27 Stora Enso Oyj PROCESS FOR THE PREPARATION OF 2,5-FURANDIC ACETIC ACID AND INTERMEDIATES AND DERIVATIVES THEREOF
WO2018187031A1 (en) * 2017-04-05 2018-10-11 Archer Daniels Midland Company Novel esterification catalyst and uses thereof
EP4071142B1 (en) * 2017-06-22 2023-10-04 Archer Daniels Midland Company Process for making esters of 2,5-furandicarboxylic acid
EP3652161A1 (en) 2017-07-12 2020-05-20 Stora Enso Oyj Purified 2,5-furandicarboxylic acid pathway products
US20190023837A1 (en) 2017-07-20 2019-01-24 Eastman Chemical Company Production of polyethylene furanoate in a retrofitted polyester plant
WO2019214576A1 (zh) * 2018-05-10 2019-11-14 中国科学院长春应用化学研究所 2，5-呋喃二甲酸的制备方法
US11236199B2 (en) * 2018-06-25 2022-02-01 Eastman Chemical Company Oxidation process to produce 5-(alkoxycarbonyl)furan-2-carboxylic acids (ACFC)
US20190389820A1 (en) * 2018-06-25 2019-12-26 Eastman Chemical Company Process for producing 5-(alkoxycarbonyl)furan-2-carboxylic acids and compositions containing same
US11440895B2 (en) 2018-06-25 2022-09-13 Eastman Chemical Company Oxidation process to produce 5-(alkoxycarbonyl)furan-2-carboxylic acids (ACFC)
JP7163659B2 (ja) * 2018-08-06 2022-11-01 三菱ケミカル株式会社 グルカル酸生産能を有する高耐酸性微生物、及びそれを用いたグルカル酸の製造方法
CN112585123A (zh) * 2018-08-31 2021-03-30 伊士曼化工公司 在改造的dmt设备中生产纯化呋喃-2,5-二甲酸二烷基酯（dafd）
US10526301B1 (en) * 2018-10-18 2020-01-07 Eastman Chemical Company Production of purified dialkyl-furan-2,5-dicarboxylate (DAFD) in a retrofitted DMT plant
US11787774B2 (en) 2019-09-05 2023-10-17 Eastman Chemical Company Efficient process for producing 5-(alkoxycarbonyl)-furan-2-carboxylic acids
CA3187611A1 (en) * 2020-08-12 2022-02-17 Iman TABER Purification of 2,5-furandicarboxylic acid, dimethyl ester and other esterified products
WO2022049384A1 (en) 2020-09-03 2022-03-10 Imperial College Innovations Limited Surfactants
KR102640902B1 (ko) * 2021-11-08 2024-02-27 한국생산기술연구원 테트라히드로퓨란-2,5-디카르복실산을 이용한 테트라히드로퓨란-2,5-디에스터의 제조 및 분리 정제 방법
CN115286598B (zh) * 2022-07-01 2024-04-26 中国石油化工股份有限公司 一种2,5-呋喃二甲酸二酯类化合物的合成方法
CN117362252B (zh) * 2023-10-08 2024-09-10 华东师范大学 一种从呋喃制备2,5-呋喃二甲酸二甲酯的方法
CN117624093A (zh) * 2023-12-06 2024-03-01 中科国生(杭州)科技有限公司 一种5-十二烷氧羰基呋喃-2-羧酸钠的制备方法

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US5071754A (en) * 1990-01-23 1991-12-10 Battelle Memorial Institute Production of esters of lactic acid, esters of acrylic acid, lactic acid, and acrylic acid
CN100594220C (zh) * 2003-03-05 2010-03-17 伊士曼化工公司 聚合物共混物
CN1938257A (zh) * 2004-01-29 2007-03-28 齐凯姆公司 有机酸的回收
DE102004008042A1 (de) * 2004-02-19 2005-09-01 Goldschmidt Gmbh Verfahren zur Herstellung von Aminosäureestern und deren Säure-Additions-Salzen
DE102004047869A1 (de) * 2004-10-01 2006-04-06 Goldschmidt Gmbh Verfahren zur enzymatischen Synthese von Pyroglutaminsäureestern
WO2007038496A2 (en) * 2005-09-27 2007-04-05 Chemic Laboratories, Inc. Synthesis of fatty alcohol esters of hydroxy carboxylic acids, the use of the same as percutaneous permeation enhancers
US7772414B1 (en) * 2006-11-14 2010-08-10 Aerophase, Inc. Process for producing biodiesel fuel products
CA2625511A1 (en) * 2008-03-13 2009-09-13 Dilum Dunuwila Process for the direct production of esters of carboxylic acids from fermentation broths
US8105809B2 (en) * 2008-07-03 2012-01-31 Accera, Inc. Enzymatic synthesis of acetoacetate esters and derivatives
US8188305B2 (en) * 2009-02-03 2012-05-29 David Miller Method of producing biodiesel with supercritical alcohol and apparatus for same
DE102009028975A1 (de) * 2009-08-28 2011-03-03 Evonik Oxeno Gmbh Esterderivate der 2,5-Furandicarbonsäure und ihre Verwendung als Weichmacher
KR101769455B1 (ko) * 2009-10-07 2017-08-18 퓨라닉스 테크놀러지스 비.브이. 2,5-퓨란다이카르복시산 및 2,5-퓨란다이카르복시산의 다이알킬 에스테르의 제조방법
EP2486027B2 (en) * 2009-10-07 2022-01-19 Furanix Technologies B.V. Method for the preparation of 2,5-furandicarboxylic acid and esters thereof
EP2481733A1 (en) * 2011-01-28 2012-08-01 Süd-Chemie AG Process for manufacturing esters of 2,5-furandicarboxylic acid
US8859788B2 (en) * 2012-06-22 2014-10-14 Eastman Chemical Company Esterification of furan-2,5-dicarboxylic acid to a dialkyl-furan-2,5-dicarboxylate vapor with rectification
US8658810B2 (en) * 2012-06-22 2014-02-25 Eastman Chemical Company Method for producing purified dialkyl-furan-2,5-dicarboxylate vapor

Also Published As

Publication number Publication date
JP6370307B2 (ja) 2018-08-08
EP2935229B1 (en) 2017-06-28
AU2013363501A1 (en) 2015-05-28
BR112015014183A2 (pt) 2017-07-11
US9765045B2 (en) 2017-09-19
CA2895186A1 (en) 2014-06-26
EP2935229A4 (en) 2016-01-27
WO2014099438A2 (en) 2014-06-26
SG11201503646TA (en) 2015-07-30
US10155736B2 (en) 2018-12-18
MX2015007903A (es) 2015-10-05
KR20150095931A (ko) 2015-08-21
AU2013363501B2 (en) 2016-12-01
CN105246958A (zh) 2016-01-13
BR112015014183B1 (pt) 2021-03-16
ES2642005T3 (es) 2017-11-14
CN105246958B (zh) 2018-02-02
EP2935229A2 (en) 2015-10-28
MX362292B (es) 2019-01-10
US20170369463A1 (en) 2017-12-28
WO2014099438A3 (en) 2015-07-16
JP2016506407A (ja) 2016-03-03
US20150315166A1 (en) 2015-11-05
KR101963478B1 (ko) 2019-03-28

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