CA2860121C - Hydrogen quality monitor - Google Patents

Hydrogen quality monitor Download PDF

Info

Publication number
CA2860121C
CA2860121C CA2860121A CA2860121A CA2860121C CA 2860121 C CA2860121 C CA 2860121C CA 2860121 A CA2860121 A CA 2860121A CA 2860121 A CA2860121 A CA 2860121A CA 2860121 C CA2860121 C CA 2860121C
Authority
CA
Canada
Prior art keywords
hydrogen
fuel cell
fuel
purity
source
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CA2860121A
Other languages
English (en)
French (fr)
Other versions
CA2860121A1 (en
Inventor
Christopher James KIRK
Simon Edward Foster
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Intelligent Energy Ltd
Original Assignee
Intelligent Energy Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Intelligent Energy Ltd filed Critical Intelligent Energy Ltd
Publication of CA2860121A1 publication Critical patent/CA2860121A1/en
Application granted granted Critical
Publication of CA2860121C publication Critical patent/CA2860121C/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/416—Systems
    • G01N27/417—Systems using cells, i.e. more than one cell and probes with solid electrolytes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/501—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
    • C01B3/503—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion characterised by the membrane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • C01B3/58—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
    • H01M8/0444—Concentration; Density
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
    • H01M8/04537—Electric variables
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
    • H01M8/04537—Electric variables
    • H01M8/04544—Voltage
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
    • H01M8/04537—Electric variables
    • H01M8/04574—Current
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
    • H01M8/04537—Electric variables
    • H01M8/04604—Power, energy, capacity or load
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
    • H01M8/04858—Electric variables
    • H01M8/04925—Power, energy, capacity or load
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H01M8/0687—Reactant purification by the use of membranes or filters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/16—Hydrogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Manufacturing & Machinery (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • Molecular Biology (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Fuel Cell (AREA)
  • Hydrogen, Water And Hydrids (AREA)
CA2860121A 2011-12-21 2012-12-19 Hydrogen quality monitor Active CA2860121C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB1122035.7 2011-12-21
GB1122035.7A GB2497787B (en) 2011-12-21 2011-12-21 Hydrogen quality monitor
PCT/GB2012/053189 WO2013093461A1 (en) 2011-12-21 2012-12-19 Hydrogen quality monitor

Publications (2)

Publication Number Publication Date
CA2860121A1 CA2860121A1 (en) 2013-06-27
CA2860121C true CA2860121C (en) 2020-04-07

Family

ID=45572813

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2860121A Active CA2860121C (en) 2011-12-21 2012-12-19 Hydrogen quality monitor

Country Status (18)

Country Link
US (1) US9726635B2 (enExample)
EP (1) EP2795706B1 (enExample)
JP (1) JP6139560B2 (enExample)
KR (1) KR102024108B1 (enExample)
CN (1) CN104115320B (enExample)
AR (1) AR089432A1 (enExample)
AU (1) AU2012356446B2 (enExample)
BR (1) BR112014015251A2 (enExample)
CA (1) CA2860121C (enExample)
DK (1) DK2795706T3 (enExample)
GB (1) GB2497787B (enExample)
MX (1) MX2014007738A (enExample)
PH (1) PH12014501433A1 (enExample)
RU (1) RU2014129811A (enExample)
SG (1) SG11201403461VA (enExample)
TW (1) TWI581491B (enExample)
WO (1) WO2013093461A1 (enExample)
ZA (1) ZA201404979B (enExample)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2526287C (en) * 2014-05-19 2023-02-08 Intelligent Energy Ltd Apparatus for determining reactant purity
US9809454B2 (en) * 2014-10-24 2017-11-07 Japan Pionics Co., Ltd. Method for refining hydrogen
WO2018226660A1 (en) 2017-06-06 2018-12-13 Skyre, Inc. Hydrogen monitoring and delivery components and methods
US10329150B2 (en) * 2017-06-29 2019-06-25 GM Global Technology Operations LLC Fuel cell system and method for determining purity level of hydrogen gas provided to an anode side of the fuel cell
JP7351607B2 (ja) 2018-09-03 2023-09-27 トヨタ自動車株式会社 燃料電池システムおよび燃料ガス品質の判定方法
GB2580061A (en) * 2018-12-20 2020-07-15 Nanosun Ip Ltd Method and apparatus for assessing the suitability of a fuel for use in a fuel cell
CN110459787A (zh) * 2019-08-26 2019-11-15 广东国鸿氢能科技有限公司 一种氢燃料电池消氢装置
CN111896602B (zh) * 2020-09-02 2024-12-24 天津新氢动力科技有限公司 一种氢气品质检测装置及检测方法
DE102020214583A1 (de) 2020-11-19 2022-05-19 Siemens Energy Global GmbH & Co. KG Wasserstoffreinheit
CN112858391B (zh) * 2021-01-26 2022-09-20 山东大学 一种代偿式氢气纯度检测系统与检测方法
CN114792828A (zh) * 2022-05-14 2022-07-26 北京亿华通科技股份有限公司 一种燃料电池氢系统氢气纯度的监测方法
CN118152762B (zh) * 2024-05-11 2024-08-20 之江实验室 基于深度学习的中性氢源识别与分割方法、装置和介质

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5647710A (en) 1979-09-27 1981-04-30 Toshiba Corp Monitor device for purity of gas
US5763113A (en) * 1996-08-26 1998-06-09 General Motors Corporation PEM fuel cell monitoring system
US6063516A (en) * 1997-10-24 2000-05-16 General Motors Corporation Method of monitoring CO concentrations in hydrogen feed to a PEM fuel cell
US6783882B2 (en) 2001-02-14 2004-08-31 Ball Aerospace & Technologies Corp. Method and apparatus for maintenance of fuel cell cathode air quality with breathable hydrophobic membrane air filter
US6638416B2 (en) * 2001-09-24 2003-10-28 Delphi Technologies, Inc. Hydrogen sensing process
JP3807668B2 (ja) * 2001-10-24 2006-08-09 本田技研工業株式会社 燃料電池用の水素供給装置
JP2003197235A (ja) * 2001-12-27 2003-07-11 Aisin Seiki Co Ltd 燃料改質装置を備えた燃料電池システムの制御装置
JP3972675B2 (ja) * 2002-02-15 2007-09-05 日産自動車株式会社 燃料電池システム
US20030175566A1 (en) 2002-03-12 2003-09-18 Fisher John M. Fuel cell power systems and methods of operating fuel cell power systems
US20040005494A1 (en) * 2002-07-05 2004-01-08 Drake Javit A. Chemical sensing in fuel cell systems
US6881507B2 (en) * 2003-06-04 2005-04-19 Milos Milacic Method and apparatus for measuring the mass flow of hydrogen in a fuel cell
JP2005201639A (ja) * 2004-01-13 2005-07-28 Nissan Motor Co Ltd 水素濃度検出器及びこれを用いた燃料電池システム
EP1750836A4 (en) * 2004-05-28 2008-04-02 Hyradix Inc METHOD FOR PRODUCING HYDROGEN BY PARTIAL OXIDATION / STEAM REFORMING
JP4659410B2 (ja) * 2004-08-23 2011-03-30 岩谷産業株式会社 水素燃料電池のセル電圧モニター装置及びその利用方法
US20060057727A1 (en) * 2004-09-16 2006-03-16 Speranza A J System for monitoring the health of electrical generators and method thereof
US7550113B2 (en) * 2004-09-16 2009-06-23 Proton Energy Systems, Inc. System for maintaining hydrogen purity in electrical generators and method thereof
TWI237922B (en) 2004-10-13 2005-08-11 Delta Electronics Inc Power supply system
JP4791757B2 (ja) * 2005-05-09 2011-10-12 株式会社東芝 燃料電池用液体燃料、燃料電池用燃料カートリッジ及び燃料電池
US20070243624A1 (en) * 2006-04-12 2007-10-18 Proton Energy Systems Inc. Hydrogen emission reporting system and method thereof
US7887958B2 (en) * 2006-05-15 2011-02-15 Idatech, Llc Hydrogen-producing fuel cell systems with load-responsive feedstock delivery systems
JP2008243430A (ja) * 2007-03-26 2008-10-09 Tokyo Gas Co Ltd 燃料電池の保護方法及び保護システム
US20090263581A1 (en) 2008-04-16 2009-10-22 Northeast Maritime Institute, Inc. Method and apparatus to coat objects with parylene and boron nitride
TWM339092U (en) 2007-11-12 2008-08-21 Syspotek Corp Fuel cell with temperature sensing device
KR20100108761A (ko) * 2009-03-30 2010-10-08 삼성에스디아이 주식회사 연료 전지 시스템 및 복수 개의 연료 전지들의 작동을 제어하는 방법
TW201037495A (en) 2009-04-02 2010-10-16 Pegatron Corp Motherboard with fan
WO2010128555A1 (ja) 2009-05-08 2010-11-11 トヨタ自動車株式会社 燃料電池の水素濃度推定装置、燃料電池システム
MX2011013358A (es) * 2009-06-12 2012-01-20 Ida Tech Llc Sistemas y metodos para controlar independientemente la operacion de pilas de celulas energeticas y sistemas de celulas energeticas que incorporan los mismos.
US8128875B2 (en) 2010-02-26 2012-03-06 General Electric Company Hydrogen control system for electric generator
US8547553B2 (en) * 2010-03-17 2013-10-01 General Electric Company Fiber optic hydrogen purity sensor and system
JP5597004B2 (ja) * 2010-03-24 2014-10-01 東京瓦斯株式会社 センサー運転方法
JP2011249171A (ja) * 2010-05-27 2011-12-08 Toyota Motor Corp 燃料電池システム、燃料電池システムの制御方法、および、燃料電池スタックの劣化判定方法

Also Published As

Publication number Publication date
TW201338258A (zh) 2013-09-16
JP6139560B2 (ja) 2017-05-31
EP2795706B1 (en) 2016-10-19
US20150346140A1 (en) 2015-12-03
AU2012356446A1 (en) 2014-07-17
CN104115320B (zh) 2018-06-05
BR112014015251A2 (pt) 2017-06-13
AU2012356446B2 (en) 2017-06-15
MX2014007738A (es) 2015-01-12
TWI581491B (zh) 2017-05-01
GB2497787B (en) 2019-06-26
GB2497787A (en) 2013-06-26
KR102024108B1 (ko) 2019-09-23
CA2860121A1 (en) 2013-06-27
KR20140112037A (ko) 2014-09-22
ZA201404979B (en) 2022-03-30
WO2013093461A1 (en) 2013-06-27
PH12014501433A1 (en) 2014-09-22
CN104115320A (zh) 2014-10-22
EP2795706A1 (en) 2014-10-29
RU2014129811A (ru) 2016-02-10
US9726635B2 (en) 2017-08-08
JP2015507326A (ja) 2015-03-05
SG11201403461VA (en) 2014-07-30
AR089432A1 (es) 2014-08-20
DK2795706T3 (en) 2017-02-06
GB201122035D0 (en) 2012-02-01

Similar Documents

Publication Publication Date Title
CA2860121C (en) Hydrogen quality monitor
JP2015507326A5 (enExample)
CA2662830C (en) In-line gas purity monitoring and control system
US9574275B2 (en) Methods of producing and providing purified gas using an electrochemical cell
US6733661B2 (en) Ultrapure water producing apparatus
US20090071819A1 (en) Electrolyzer cell stack system
JP3807668B2 (ja) 燃料電池用の水素供給装置
US8076037B2 (en) Hydrogen sensor cell for detecting contaminants
US20240337036A1 (en) Method for operating an electrolysis plant, and electrolysis plant
US20220069323A1 (en) Method and apparatus for assessing the suitability of a fuel for use in a fuel cell

Legal Events

Date Code Title Description
EEER Examination request

Effective date: 20171120