CA2789843A1 - Process for preparing high-reactivity isobutene homo- or copolymers - Google Patents

Process for preparing high-reactivity isobutene homo- or copolymers Download PDF

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Publication number
CA2789843A1
CA2789843A1 CA2789843A CA2789843A CA2789843A1 CA 2789843 A1 CA2789843 A1 CA 2789843A1 CA 2789843 A CA2789843 A CA 2789843A CA 2789843 A CA2789843 A CA 2789843A CA 2789843 A1 CA2789843 A1 CA 2789843A1
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CA
Canada
Prior art keywords
isobutene
complex
donor
phenyl
polymerization
Prior art date
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Granted
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CA2789843A
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English (en)
French (fr)
Other versions
CA2789843C (en
Inventor
Hannah Maria Koenig
Klaus Muhlbach
Matthias Kiefer
Sergei V. Kostjuk
Irina Vasilenko
Alexander Frolov
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BASF SE
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BASF SE
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Publication date
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Publication of CA2789843A1 publication Critical patent/CA2789843A1/en
Application granted granted Critical
Publication of CA2789843C publication Critical patent/CA2789843C/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C08F10/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C08F210/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/12—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of boron, aluminium, gallium, indium, thallium or rare earths
    • C08F4/14—Boron halides or aluminium halides; Complexes thereof with organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
CA2789843A 2010-02-17 2011-02-10 Process for preparing high-reactivity isobutene homo- or copolymers Active CA2789843C (en)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
EP10153847 2010-02-17
EP10153847.8 2010-02-17
EP10157068 2010-03-19
EP10157068.7 2010-03-19
EP10193047 2010-11-30
EP10193047.7 2010-11-30
PCT/EP2011/051929 WO2011101281A1 (de) 2010-02-17 2011-02-10 Verfahren zur herstellung von hochreaktiven isobutenhomo- oder -copolymeren

Publications (2)

Publication Number Publication Date
CA2789843A1 true CA2789843A1 (en) 2011-08-25
CA2789843C CA2789843C (en) 2018-07-10

Family

ID=43928027

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2789843A Active CA2789843C (en) 2010-02-17 2011-02-10 Process for preparing high-reactivity isobutene homo- or copolymers

Country Status (11)

Country Link
EP (1) EP2536768B1 (pt-pt)
JP (2) JP5798130B2 (pt-pt)
KR (1) KR101797789B1 (pt-pt)
CN (2) CN107033265A (pt-pt)
AR (1) AR080195A1 (pt-pt)
BR (1) BR112012020302B1 (pt-pt)
CA (1) CA2789843C (pt-pt)
MY (1) MY156799A (pt-pt)
RU (1) RU2555400C2 (pt-pt)
SG (2) SG10201500721PA (pt-pt)
WO (1) WO2011101281A1 (pt-pt)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160168282A1 (en) * 2010-11-30 2016-06-16 Basf Se Preparation of isobutene homo- or copolymer derivatives
US10975175B2 (en) * 2016-07-22 2021-04-13 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
US11718632B2 (en) 2020-04-08 2023-08-08 Lg Chem, Ltd. Catalyst composition and method for preparing isobutene-based oligomer using the same

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG10201500721PA (en) * 2010-02-17 2015-04-29 Basf Se Method for producing highly reactive isobutene homo or copolymers
US9562117B2 (en) 2010-11-30 2017-02-07 Basf Se Preparation of derivatives of isobutene copolymers
US8697820B2 (en) 2011-08-11 2014-04-15 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
KR20140090634A (ko) * 2011-10-21 2014-07-17 바스프 에스이 이소부텐 단일중합체 또는 공중합체 제조 방법
US9458262B2 (en) 2011-10-21 2016-10-04 Basf Se Process for preparing isobutene homopolymers or copolymers
US9156924B2 (en) * 2013-03-12 2015-10-13 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US9631038B2 (en) * 2013-10-11 2017-04-25 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
CN105149005B (zh) * 2015-10-08 2017-05-31 山东鸿瑞新材料科技有限公司 一种三氯化铝催化剂体系及其用于生产低分子量聚异丁烯的方法
CN106928390B (zh) * 2015-12-30 2020-01-07 中国石油天然气股份有限公司 一种制备异丁烯与烷基苯乙烯聚合物的方法
BR112018016567B1 (pt) * 2016-02-16 2022-07-05 Basf Se Processo para preparar homo- ou copolímeros de isobuteno de alta reatividade
MY193220A (en) * 2016-02-16 2022-09-26 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
CN106905453A (zh) * 2017-03-20 2017-06-30 山东成泰化工有限公司 一种用于合成中高分子量聚异丁烯的复合催化剂、制备方法及聚合工艺
JP6839004B2 (ja) * 2017-03-21 2021-03-03 株式会社カネカ イソブチレン系重合体の製造方法
US10167352B1 (en) * 2017-06-28 2019-01-01 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US10047174B1 (en) * 2017-06-28 2018-08-14 Infineum International Limited Polymerization initiating system and method to produce highly reactive olefin functional polymers
EP3444283B1 (en) 2017-08-17 2020-02-26 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
CN111171197B (zh) * 2020-02-11 2022-08-02 北京石油化工学院 一种利用双官能团引发剂制备高活性聚异丁烯的方法及应用
EP3943518A1 (en) * 2020-07-22 2022-01-26 Indian Oil Corporation Limited Polymerization catalyst system and process to produce highly reactive polyisobutylene
KR20220037612A (ko) * 2020-09-18 2022-03-25 주식회사 엘지화학 촉매 조성물 및 이를 이용한 이소부텐-이소프렌 공중합체의 제조방법
EP4001321A1 (en) 2020-11-17 2022-05-25 Basf Se Process for preparation of polyisobutene derivatives

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2702604C2 (de) 1977-01-22 1984-08-30 Basf Ag, 6700 Ludwigshafen Polyisobutene
GB8329082D0 (en) 1983-11-01 1983-12-07 Bp Chem Int Ltd Low molecular weight polymers of 1-olefins
CA1326322C (en) * 1988-05-03 1994-01-18 Gabor Kaszas Uniform molecular weight polymers
US5169914A (en) * 1988-05-03 1992-12-08 Edison Polymer Innovation Corporation Uniform molecular weight polymers
US5286823A (en) 1991-06-22 1994-02-15 Basf Aktiengesellschaft Preparation of highly reactive polyisobutenes
US5340881A (en) 1992-11-16 1994-08-23 The University Of Akron Aldehyde-telechelic polyisobutylenes, catalytic method for preparing the same with high conversion and selectivity, and block copolymers made thereform
DE19825334A1 (de) * 1998-06-05 1999-12-09 Basf Ag Verfahren zur Herstellung hochreaktiver Polyisobutene
CN1128162C (zh) * 2000-07-17 2003-11-19 北京化工大学 可控碳阳离子聚合方法
DE10211418A1 (de) * 2002-03-15 2003-09-25 Bayer Ag Verfahren zur Herstellung hochreaktiver Polyisobutene
CN101613423B (zh) * 2008-06-27 2011-05-18 北京化工大学 一种用于合成高反应活性聚异丁烯的引发体系
KR101691127B1 (ko) * 2009-09-25 2016-12-29 차이나 페트로리움 앤드 케미컬 코포레이션 이소올레핀 폴리머 및 그의 제조 방법
SG10201500721PA (en) * 2010-02-17 2015-04-29 Basf Se Method for producing highly reactive isobutene homo or copolymers

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160168282A1 (en) * 2010-11-30 2016-06-16 Basf Se Preparation of isobutene homo- or copolymer derivatives
US10745496B2 (en) * 2010-11-30 2020-08-18 Basf Se Preparation of isobutene homo- or copolymer derivatives
US11306161B2 (en) * 2010-11-30 2022-04-19 Basf Se Preparation of isobutene homo- or copolymer derivatives
US10975175B2 (en) * 2016-07-22 2021-04-13 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
US11718632B2 (en) 2020-04-08 2023-08-08 Lg Chem, Ltd. Catalyst composition and method for preparing isobutene-based oligomer using the same

Also Published As

Publication number Publication date
AR080195A1 (es) 2012-03-21
WO2011101281A1 (de) 2011-08-25
JP5798130B2 (ja) 2015-10-21
KR101797789B1 (ko) 2017-11-15
JP6099708B2 (ja) 2017-03-22
RU2012139361A (ru) 2014-03-27
SG182759A1 (en) 2012-09-27
KR20130008551A (ko) 2013-01-22
BR112012020302A2 (pt) 2020-07-28
CA2789843C (en) 2018-07-10
JP2015206058A (ja) 2015-11-19
RU2555400C2 (ru) 2015-07-10
JP2013519766A (ja) 2013-05-30
EP2536768A1 (de) 2012-12-26
CN107033265A (zh) 2017-08-11
BR112012020302B1 (pt) 2021-08-17
MY156799A (en) 2016-03-31
CN102762610A (zh) 2012-10-31
EP2536768B1 (de) 2015-04-08
SG10201500721PA (en) 2015-04-29

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