CA2725738C - Carbon catalyst, method for producing carbon catalyst, fuel cell, electricity storage device, and use of carbon catalyst - Google Patents
Carbon catalyst, method for producing carbon catalyst, fuel cell, electricity storage device, and use of carbon catalyst Download PDFInfo
- Publication number
- CA2725738C CA2725738C CA2725738A CA2725738A CA2725738C CA 2725738 C CA2725738 C CA 2725738C CA 2725738 A CA2725738 A CA 2725738A CA 2725738 A CA2725738 A CA 2725738A CA 2725738 C CA2725738 C CA 2725738C
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- Prior art keywords
- carbon
- carbon catalyst
- nitrogen
- nitrogen atom
- catalyst
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- 239000003054 catalyst Substances 0.000 title claims abstract description 201
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 154
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 153
- 239000000446 fuel Substances 0.000 title claims description 37
- 238000004519 manufacturing process Methods 0.000 title claims description 16
- 230000005611 electricity Effects 0.000 title claims description 13
- 238000003860 storage Methods 0.000 title claims description 13
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 131
- 125000004433 nitrogen atom Chemical group N* 0.000 claims abstract description 120
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 96
- 230000003197 catalytic effect Effects 0.000 claims abstract description 15
- 239000007833 carbon precursor Substances 0.000 claims description 52
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- 238000000034 method Methods 0.000 claims description 36
- 125000004432 carbon atom Chemical group C* 0.000 claims description 20
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 19
- 229910052760 oxygen Inorganic materials 0.000 claims description 19
- 239000001301 oxygen Substances 0.000 claims description 19
- 150000001875 compounds Chemical class 0.000 claims description 16
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 15
- 229910052723 transition metal Inorganic materials 0.000 claims description 15
- 150000003624 transition metals Chemical class 0.000 claims description 15
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- 239000010936 titanium Substances 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 8
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- 238000010000 carbonizing Methods 0.000 claims description 5
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- 229910017052 cobalt Inorganic materials 0.000 claims description 5
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- VSZWPYCFIRKVQL-UHFFFAOYSA-N selanylidenegallium;selenium Chemical compound [Se].[Se]=[Ga].[Se]=[Ga] VSZWPYCFIRKVQL-UHFFFAOYSA-N 0.000 claims description 5
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Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8647—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
- H01M4/8652—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites as mixture
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/05—Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/32—Carbon-based
- H01G11/34—Carbon-based characterised by carbonisation or activation of carbon
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/32—Carbon-based
- H01G11/38—Carbon pastes or blends; Binders or additives therein
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
- H01M4/8882—Heat treatment, e.g. drying, baking
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9075—Catalytic material supported on carriers, e.g. powder carriers
- H01M4/9083—Catalytic material supported on carriers, e.g. powder carriers on carbon or graphite
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/96—Carbon-based electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M2008/1095—Fuel cells with polymeric electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
- H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
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- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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Applications Claiming Priority (3)
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| JP2008-147399 | 2008-06-04 | ||
| JP2008147399A JP5481646B2 (ja) | 2008-06-04 | 2008-06-04 | 炭素触媒、燃料電池、蓄電装置 |
| PCT/JP2009/060245 WO2009148115A1 (ja) | 2008-06-04 | 2009-06-04 | 炭素触媒及び炭素触媒の製造方法、燃料電池、蓄電装置、炭素触媒の使用方法 |
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| WO (1) | WO2009148115A1 (enExample) |
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| US8791043B2 (en) * | 2008-12-31 | 2014-07-29 | Samsung Electronics Co., Ltd. | Ordered mesoporous carbon composite catalyst, method of manufacturing the same, and fuel cell using the same |
| JP5403799B2 (ja) * | 2009-06-26 | 2014-01-29 | 帝人株式会社 | 炭素材料及びその製造方法 |
| WO2011055739A1 (ja) * | 2009-11-05 | 2011-05-12 | 国立大学法人群馬大学 | 炭素触媒並びにその製造方法及びこれを用いた電極並びに電池 |
| EP2523903A4 (en) * | 2010-01-12 | 2013-05-01 | Nat Nanomaterials Inc | METHOD AND SYSTEM FOR PRODUCING GRAPHENE AND GRAPHENOL |
| CA2796644C (en) * | 2010-04-20 | 2018-10-02 | Nisshinbo Holdings Inc. | Carbon catalyst for direct fuel cell cathode, and direct fuel cell cathode and direct fuel cell using same |
| JP5586337B2 (ja) * | 2010-06-11 | 2014-09-10 | 旭化成ケミカルズ株式会社 | 窒素含有炭素材料 |
| JP5837364B2 (ja) * | 2010-08-30 | 2015-12-24 | 住友化学株式会社 | ポリマーコンポジット変性物の製造方法 |
| JP2012072052A (ja) * | 2010-09-02 | 2012-04-12 | Sumitomo Chemical Co Ltd | 変性物および窒素含有導電性カーボン |
| JP5149364B2 (ja) * | 2010-11-08 | 2013-02-20 | 国立大学法人群馬大学 | 炭素触媒及びその製造方法並びにこれを用いた電極及び電池 |
| JP5193274B2 (ja) | 2010-11-29 | 2013-05-08 | 国立大学法人群馬大学 | 水素生成用炭素触媒及びその製造方法並びにこれを用いて水素を生成する方法 |
| EP2665119B1 (en) * | 2011-01-14 | 2018-10-24 | Showa Denko K.K. | Method for producing fuel cell electrode catalyst, fuel cell electrode catalyst, and uses thereof |
| JP5957793B2 (ja) * | 2011-01-19 | 2016-07-27 | マツダ株式会社 | 炭素材の製造方法 |
| JP2012221735A (ja) * | 2011-04-08 | 2012-11-12 | Kumamoto Univ | 燃料電池用電極触媒 |
| WO2012161335A1 (ja) | 2011-05-23 | 2012-11-29 | 帝人株式会社 | 粒子状炭素触媒およびその製造方法 |
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| CN103747872B (zh) * | 2011-08-08 | 2016-06-08 | 昭和电工株式会社 | 氧还原催化剂的制造方法以及其用途 |
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| JP5655161B2 (ja) * | 2011-12-09 | 2015-01-14 | パナソニック株式会社 | 硝酸還元方法、硝酸還元触媒、硝酸還元電極、燃料電池、及び水処理装置 |
| JP5677589B2 (ja) * | 2011-12-12 | 2015-02-25 | パナソニック株式会社 | 炭素系材料、電極触媒、酸素還元電極触媒、ガス拡散電極、水溶液電解装置、並びに炭素系材料の製造方法 |
| JP5743945B2 (ja) * | 2012-03-30 | 2015-07-01 | 株式会社東芝 | 酸素還元触媒と酸素還元触媒を用いた電気化学セル |
| CA2877053A1 (en) * | 2012-06-28 | 2014-01-03 | The Royal Institution For The Advancement Of Learning/Mcgill University | Fabrication and functionalization of a pure non-noble metal catalyst structure showing time stability for large scale applications |
| JP5942277B2 (ja) * | 2012-07-06 | 2016-06-29 | パナソニックＩｐマネジメント株式会社 | 炭素系材料、電極触媒、電極、ガス拡散電極、電気化学装置、燃料電池、並びに炭素系材料の製造方法 |
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| JP6266203B2 (ja) * | 2012-11-14 | 2018-01-24 | 旭化成株式会社 | 窒素含有炭素材料、その製造方法及び燃料電池用電極 |
| JP6244936B2 (ja) * | 2013-01-30 | 2017-12-13 | 東洋インキＳｃホールディングス株式会社 | 炭素触媒及びその製造方法、及び該炭素触媒を用いた触媒インキ並びに燃料電池 |
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| US9899687B2 (en) * | 2013-09-02 | 2018-02-20 | Council Of Scientific And Industrial Research | Process for the synthesis of nitrogen-doped carbon electro-catalyst |
| KR20160093699A (ko) * | 2013-12-03 | 2016-08-08 | 가부시키가이샤 알박 | 리튬 유황 이차전지 |
| JP6153485B2 (ja) * | 2014-02-26 | 2017-06-28 | 帝人株式会社 | カソード電極構造体及び膜・電極接合体 |
| US10727495B2 (en) | 2014-03-11 | 2020-07-28 | Asahi Kasei Kabushiki Kaisha | Nitrogen-containing carbon material and process for producing nitrogen-containing carbon material, and slurry, ink, and electrode for fuel cell |
| JP5779267B2 (ja) * | 2014-04-02 | 2015-09-16 | 旭化成ケミカルズ株式会社 | 窒素含有炭素材料 |
| JP6543531B2 (ja) * | 2015-08-24 | 2019-07-10 | 旭化成株式会社 | 窒素含有炭素材料及びその製造方法、含窒素炭素材料用前駆体組成物、並びに燃料電池用電極 |
| JP6800608B2 (ja) * | 2016-05-17 | 2020-12-16 | 日清紡ホールディングス株式会社 | 電池電極、電池電極触媒層用組成物及び電池 |
| JP6921485B2 (ja) | 2016-05-27 | 2021-08-18 | 日清紡ホールディングス株式会社 | 電池カソード、電池カソード触媒層用組成物及び電池 |
| WO2018038764A1 (en) * | 2016-08-22 | 2018-03-01 | Nanotek Instruments, Inc. | Humic acid-bonded metal foil film current collector and battery and supercapacitor containing same |
| US11344867B2 (en) | 2017-07-13 | 2022-05-31 | Nisshinbo Holdings Inc. | Carbon catalyst, battery electrode and battery |
| US10953386B2 (en) | 2017-12-29 | 2021-03-23 | Mannon Water (Singapore) PTE. LTD. | Filtration media for removing chloramine, chlorine, and ammonia, and method of making the same |
| JP7205209B2 (ja) * | 2018-12-18 | 2023-01-17 | 東洋インキＳｃホールディングス株式会社 | バイオ燃料電池アノード用触媒インキ材料、バイオ燃料電池アノード用触媒インキ組成物、バイオ燃料電池アノード、バイオ燃料電池デバイス |
| EP3975322B1 (en) * | 2019-05-23 | 2024-11-13 | National Institute for Materials Science | Porous carbon structure, manufacturing method therefor, positive electrode material using same, and battery using same |
| KR102881918B1 (ko) * | 2019-08-13 | 2025-11-05 | 현대자동차주식회사 | 촉매 전극을 위한 전이금속 지지체 및 이의 제조방법 |
| JP7442133B2 (ja) * | 2020-04-03 | 2024-03-04 | 国立大学法人千葉大学 | ベーサル窒素を選択的に導入した含窒素炭素材料およびその製造方法 |
| CN112023945B (zh) * | 2020-09-01 | 2022-07-05 | 广州大学 | 一种介孔碳基电催化剂的制备方法 |
| CN114574897B (zh) * | 2022-03-23 | 2024-06-11 | 中国科学院宁波材料技术与工程研究所 | 锌氧比可调的碳基催化剂、其制备方法及应用 |
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| DE2108417C3 (de) * | 1971-02-22 | 1978-05-11 | Siemens Ag, 1000 Berlin Und 8000 Muenchen | Verfahren zur Herstellung stickstoffhaltiger, pulverförmiger Kohle als Elektrodenmaterial für elektrochemische Zellen |
| JPS5124710Y2 (enExample) * | 1971-02-25 | 1976-06-24 | ||
| US4816289A (en) * | 1984-04-25 | 1989-03-28 | Asahi Kasei Kogyo Kabushiki Kaisha | Process for production of a carbon filament |
| JPH0721388A (ja) | 1993-06-23 | 1995-01-24 | Toshiba Corp | 画像認識装置 |
| US6689711B2 (en) * | 2001-10-09 | 2004-02-10 | Metallic Power, Inc. | Methods of producing oxygen reduction catalyst |
| US20060263674A1 (en) * | 2003-04-17 | 2006-11-23 | Mamoru Hosoya | Catalyst and process for producing the same, catalytic electrode and process for producing the same, membrane/electrode union, and electrochemical device |
| JP4529494B2 (ja) * | 2003-04-17 | 2010-08-25 | ソニー株式会社 | 酸素還元触媒の製造方法 |
| JP4041429B2 (ja) * | 2003-06-02 | 2008-01-30 | 独立行政法人科学技術振興機構 | 燃料電池用電極およびその製造方法 |
| JP3740578B2 (ja) | 2003-06-11 | 2006-02-01 | 松下電器産業株式会社 | 酸素還元用電極の製造方法ならびに酸素還元用電極及びそれを用いた電気化学素子 |
| JP2006331846A (ja) | 2005-05-26 | 2006-12-07 | Asahi Kasei Corp | 燃料電池用電極触媒 |
| KR100805104B1 (ko) * | 2005-08-31 | 2008-02-21 | 삼성에스디아이 주식회사 | 높은 비표면적과 전도성을 갖는 탄소 재료 및 이의 제조방법 |
| JP4452889B2 (ja) * | 2006-02-03 | 2010-04-21 | 国立大学法人群馬大学 | 燃料電池用電極触媒及びその製造方法並びに該触媒を用いた燃料電池 |
| TWI314169B (en) * | 2007-05-16 | 2009-09-01 | Ind Tech Res Inst | Activated carbon fibers and precursor material thereof |
| JP2009208061A (ja) * | 2008-02-06 | 2009-09-17 | Gunma Univ | 炭素触媒及びこの炭素触媒を含むスラリー、炭素触媒の製造方法、ならびに、炭素触媒を用いた燃料電池、蓄電装置及び環境触媒 |
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| US9373849B2 (en) | 2016-06-21 |
| EP2298443A4 (en) | 2014-05-07 |
| JP2009291706A (ja) | 2009-12-17 |
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| EP2298443A1 (en) | 2011-03-23 |
| US20110136036A1 (en) | 2011-06-09 |
| JP5481646B2 (ja) | 2014-04-23 |
| EP2298443B1 (en) | 2018-09-12 |
| WO2009148115A1 (ja) | 2009-12-10 |
| CA2725738A1 (en) | 2009-12-10 |
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