CA2602450A1 - Textiles containing at least one layer of polymeric nanofibres and method of production of the layer of polymeric nanofibres from the polymer solution through electrostatic spinning - Google Patents
Textiles containing at least one layer of polymeric nanofibres and method of production of the layer of polymeric nanofibres from the polymer solution through electrostatic spinning Download PDFInfo
- Publication number
- CA2602450A1 CA2602450A1 CA 2602450 CA2602450A CA2602450A1 CA 2602450 A1 CA2602450 A1 CA 2602450A1 CA 2602450 CA2602450 CA 2602450 CA 2602450 A CA2602450 A CA 2602450A CA 2602450 A1 CA2602450 A1 CA 2602450A1
- Authority
- CA
- Canada
- Prior art keywords
- nanofibres
- polymer
- spinning
- low molecular
- created
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 229920000642 polymer Polymers 0.000 title claims abstract description 73
- 238000010041 electrostatic spinning Methods 0.000 title claims abstract description 34
- 239000004753 textile Substances 0.000 title claims abstract description 31
- 238000000034 method Methods 0.000 title claims description 18
- 238000004519 manufacturing process Methods 0.000 title abstract description 9
- 239000000126 substance Substances 0.000 claims abstract description 78
- 239000002245 particle Substances 0.000 claims abstract description 43
- 238000009987 spinning Methods 0.000 claims abstract description 40
- 230000005684 electric field Effects 0.000 claims abstract description 14
- 238000006243 chemical reaction Methods 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 39
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 38
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 25
- 229910052709 silver Inorganic materials 0.000 claims description 25
- 239000004332 silver Substances 0.000 claims description 25
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 19
- 239000013543 active substance Substances 0.000 claims description 15
- 229910052751 metal Inorganic materials 0.000 claims description 14
- 239000002184 metal Substances 0.000 claims description 14
- 150000003839 salts Chemical class 0.000 claims description 14
- 230000009467 reduction Effects 0.000 claims description 13
- 239000000975 dye Substances 0.000 claims description 7
- 150000002739 metals Chemical class 0.000 claims description 7
- 239000002121 nanofiber Substances 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000003054 catalyst Substances 0.000 claims description 4
- 239000002923 metal particle Substances 0.000 claims description 3
- 239000000243 solution Substances 0.000 description 59
- 230000000694 effects Effects 0.000 description 6
- 230000000845 anti-microbial effect Effects 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 241000894006 Bacteria Species 0.000 description 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 4
- 239000002105 nanoparticle Substances 0.000 description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 description 4
- 206010052428 Wound Diseases 0.000 description 3
- 208000027418 Wounds and injury Diseases 0.000 description 3
- 239000003638 chemical reducing agent Substances 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 239000013528 metallic particle Substances 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- 230000002421 anti-septic effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 230000035876 healing Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- ZVNPWFOVUDMGRP-UHFFFAOYSA-N 4-methylaminophenol sulfate Chemical compound OS(O)(=O)=O.CNC1=CC=C(O)C=C1.CNC1=CC=C(O)C=C1 ZVNPWFOVUDMGRP-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241001076388 Fimbria Species 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 230000000721 bacterilogical effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 230000016507 interphase Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 150000001455 metallic ions Chemical class 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920005597 polymer membrane Polymers 0.000 description 1
- 150000003378 silver Chemical class 0.000 description 1
- 229940100890 silver compound Drugs 0.000 description 1
- 150000003379 silver compounds Chemical class 0.000 description 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0015—Electro-spinning characterised by the initial state of the material
- D01D5/003—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion
- D01D5/0038—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion the fibre formed by solvent evaporation, i.e. dry electro-spinning
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/603—Including strand or fiber material precoated with other than free metal or alloy
- Y10T442/607—Strand or fiber material is synthetic polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/608—Including strand or fiber material which is of specific structural definition
- Y10T442/614—Strand or fiber material specified as having microdimensions [i.e., microfiber]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/654—Including a free metal or alloy constituent
- Y10T442/658—Particulate free metal or alloy constituent
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Mechanical Engineering (AREA)
- Nanotechnology (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Artificial Filaments (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Nonwoven Fabrics (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Woven Fabrics (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CZPV2005-225 | 2005-04-11 | ||
| CZ20050225A CZ300797B6 (cs) | 2005-04-11 | 2005-04-11 | Textilie obsahující alespon jednu vrstvu polymerních nanovláken a zpusob výroby vrstvy polymerních nanovláken z roztoku polymeru elektrostatickým zvláknováním |
| PCT/CZ2006/000018 WO2006108364A1 (en) | 2005-04-11 | 2006-04-10 | Textiles containing at least one layer of polymeric nanofibres and method of production of the layer of polymeric nanofibres from the polymer solution through electrostatic spinning |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2602450A1 true CA2602450A1 (en) | 2006-10-19 |
Family
ID=36676579
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA 2602450 Abandoned CA2602450A1 (en) | 2005-04-11 | 2006-04-10 | Textiles containing at least one layer of polymeric nanofibres and method of production of the layer of polymeric nanofibres from the polymer solution through electrostatic spinning |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20080207076A1 (cs) |
| EP (1) | EP1869232A1 (cs) |
| JP (1) | JP2008536022A (cs) |
| KR (1) | KR20080005549A (cs) |
| CN (1) | CN101198728B (cs) |
| AU (1) | AU2006233443A1 (cs) |
| CA (1) | CA2602450A1 (cs) |
| CZ (1) | CZ300797B6 (cs) |
| EA (1) | EA012635B1 (cs) |
| TW (1) | TW200702502A (cs) |
| WO (1) | WO2006108364A1 (cs) |
Families Citing this family (47)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2621652A1 (en) * | 2005-06-07 | 2006-12-14 | The University Of Akron | Nanofiber structures for supporting biological materials |
| US20100292623A1 (en) * | 2006-10-23 | 2010-11-18 | Schoeller Textil Ag | Polyethylenimine nanoparticle-containing microbicidal electrospun polymer fibers for textile applications |
| US8088323B2 (en) * | 2007-02-27 | 2012-01-03 | Ppg Industries Ohio, Inc. | Process of electrospinning organic-inorganic fibers |
| JPWO2008111609A1 (ja) * | 2007-03-14 | 2010-06-24 | 日東紡績株式会社 | シリカ繊維の製造方法 |
| JP2008274512A (ja) * | 2007-04-03 | 2008-11-13 | Nisshinbo Ind Inc | 抗菌性ナノファイバー |
| JP5308435B2 (ja) * | 2007-04-11 | 2013-10-09 | ナショナル ユニヴァーシティー オブ シンガポール | 化学的物質および生物学的物質の除染用の繊維 |
| US20100018641A1 (en) * | 2007-06-08 | 2010-01-28 | Kimberly-Clark Worldwide, Inc. | Methods of Applying Skin Wellness Agents to a Nonwoven Web Through Electrospinning Nanofibers |
| WO2009067365A2 (en) | 2007-11-20 | 2009-05-28 | Clarcor Inc. | Filtration medias, fine fibers under 100 nanofibers, and methods |
| KR20100089852A (ko) * | 2007-11-20 | 2010-08-12 | 다우 코닝 코포레이션 | 물품과 상기 물품을 제조하는 방법 |
| US7815427B2 (en) | 2007-11-20 | 2010-10-19 | Clarcor, Inc. | Apparatus and method for reducing solvent loss for electro-spinning of fine fibers |
| US7967588B2 (en) | 2007-11-20 | 2011-06-28 | Clarcor Inc. | Fine fiber electro-spinning equipment, filter media systems and methods |
| US20090156740A1 (en) | 2007-12-15 | 2009-06-18 | Annette Lechtenboehmer | Tire with component containing polymeric nanofiber |
| JP5004852B2 (ja) * | 2008-04-02 | 2012-08-22 | 日本バイリーン株式会社 | 不織布の製造方法 |
| GB0809499D0 (en) * | 2008-05-23 | 2008-07-02 | Bristol Myers Squibb Co | Polysaccharide nano fibres having antimicrobial properties |
| JP5555702B2 (ja) | 2008-08-29 | 2014-07-23 | ダウ コーニング コーポレーション | 分散体から形成される金属化粒子 |
| CZ2009149A3 (cs) | 2009-03-09 | 2010-09-22 | Elmarco S.R.O. | Zpusob ukládání funkcní vrstvy polymerních nanovláken na povrch podkladu |
| SG174346A1 (en) | 2009-03-19 | 2011-11-28 | Millipore Corp | Removal of microorganisms from fluid samples using nanofiber filtration media |
| JP5600397B2 (ja) * | 2009-04-28 | 2014-10-01 | 北越紀州製紙株式会社 | 静電紡糸ナノ繊維層を有するエアフィルタ用濾材 |
| US20110210061A1 (en) | 2010-02-26 | 2011-09-01 | Clarcor Inc. | Compressed nanofiber composite media |
| CN101857976B (zh) * | 2010-05-19 | 2011-06-08 | 青岛大学 | 一种有序排列和交叉结构纳米纤维的制备装置 |
| JP2012012710A (ja) * | 2010-06-29 | 2012-01-19 | Kao Corp | ナノファイバシート |
| ES2774949T3 (es) | 2010-08-10 | 2020-07-23 | Emd Millipore Corp | Método para la eliminación de retrovirus |
| EP2630287B1 (de) | 2010-10-21 | 2016-02-24 | Hi Tech Textile Holding GmbH | Verfahren und vorrichtung zur herstellung eines verbundvlieses |
| CN101985793B (zh) * | 2010-11-22 | 2012-07-25 | 北京化工大学 | 静电纺丝法连续制备无纺布制品的装置 |
| CZ303299B6 (cs) | 2011-01-17 | 2012-07-18 | Royal Natural Medicine, S.R.O. | Oblicejová rouška a zpusob její výroby |
| CN105413480B (zh) | 2011-04-01 | 2019-03-29 | Emd密理博公司 | 含有纳米纤维的复合材料结构 |
| CZ302901B6 (cs) * | 2011-06-01 | 2012-01-11 | Technická univerzita v Liberci | Zpusob vytvárení funkcní nanovlákenné vrstvy a zarízení k provádení zpusobu |
| CZ303380B6 (cs) * | 2011-06-27 | 2012-08-22 | Contipro Biotech S.R.O. | Zpusob výroby materiálu s anizotropními vlastnostmi složených z nanovláken nebo mikrovláken a zarízení pro provádení tohoto zpusobu |
| CZ2011424A3 (cs) * | 2011-07-14 | 2012-09-19 | Elmarco S.R.O. | Substrát pro kultivaci bunek a zpusob jeho výroby |
| CN108610437A (zh) | 2013-03-14 | 2018-10-02 | 金珂生物医疗公司 | 生物相容的和生物可吸收的衍生的壳聚糖组合物 |
| CZ304660B6 (cs) * | 2013-05-22 | 2014-08-20 | Malm S.R.O. | Způsob a zařízení pro výrobu vrstvy vláken, zejména nanovláken, mikrovláken nebo jejich směsí, s vlákny orientovanými v jednom směru, a kolektor tohoto zařízení pro ukládání vláken |
| KR20190011838A (ko) | 2014-06-26 | 2019-02-07 | 이엠디 밀리포어 코포레이션 | 개선된 먼지 포집 능력을 갖는 필터 구조 |
| CZ2014947A3 (cs) | 2014-12-22 | 2016-06-22 | Technická univerzita v Liberci | Způsob a zařízení pro výrobu textilního kompozitního materiálu obsahujícího polymerní nanovlákna, textilní kompozitní materiál obsahující polymerní nanovlákna |
| CN104562223A (zh) * | 2014-12-29 | 2015-04-29 | 北京化工大学常州先进材料研究院 | 一种负载银的银催化剂纤维膜的制备及其方法 |
| WO2016167871A1 (en) | 2015-04-17 | 2016-10-20 | Emd Millipore Corporation | Method of purifying a biological materia of interest in a sample using nanofiber ultrafiltration membranes operated in tangential flow filtration mode |
| JP6738833B2 (ja) * | 2015-04-28 | 2020-08-12 | コンバテック・テクノロジーズ・インコーポレイテッドＣｏｎｖａｔｅｃ Ｔｅｃｈｎｏｌｏｇｉｅｓ Ｉｎｃ | 抗細菌性ナノファイバー |
| GB201517791D0 (en) * | 2015-10-08 | 2015-11-25 | Univ Leeds | Composite fibre |
| CN105155035B (zh) * | 2015-10-20 | 2017-11-10 | 浙江超凡制衣有限公司 | 一种抗菌保健功能的纤维服装材料及其制备工艺 |
| CN105839294A (zh) * | 2016-05-23 | 2016-08-10 | 浙江理工大学 | 一种通过静电纺丝法制备纳米微晶纤维素-丝素膜的方法 |
| WO2017218692A1 (en) * | 2016-06-14 | 2017-12-21 | California Institute Of Technology | Nanofibers decorated with nanoparticles and methods of their manufacture |
| EP3655142A1 (en) | 2017-07-21 | 2020-05-27 | Merck Millipore Ltd | Non-woven fiber membranes |
| CZ31723U1 (cs) | 2018-01-26 | 2018-04-24 | Technická univerzita v Liberci | Kryt akutní nebo chronické rány |
| CN108962485B (zh) * | 2018-05-30 | 2020-11-10 | 厦门大学 | 一种生物相容的柔性透明导电膜及其制备方法、应用 |
| CN109498271B (zh) * | 2018-12-21 | 2021-09-14 | 振德医疗用品股份有限公司 | 一种定向吸液防粘连纱布及其制造方法 |
| KR102559895B1 (ko) * | 2021-06-24 | 2023-07-27 | 충남대학교산학협력단 | 미립자를 포함하는 나노 섬유의 제조방법 |
| CZ309644B6 (cs) * | 2021-10-14 | 2023-06-07 | Technická univerzita v Liberci | Biokompatibilní a biodegradabilní netkaná vlákenná struktura s obsahem submikronových vláken na bázi oxidu křemičitého, biogenních iontů a funkčním povrchem pro vazbu aktivních látek a způsob její výroby |
| CN116240678B (zh) * | 2023-02-27 | 2025-02-07 | 桂林电子科技大学 | 一种具有多级微结构的柔性传感复合纤维膜及其制备方法与应用 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6753454B1 (en) * | 1999-10-08 | 2004-06-22 | The University Of Akron | Electrospun fibers and an apparatus therefor |
| AU2003290858A1 (en) * | 2002-11-12 | 2004-06-03 | The Regents Of The University Of California | Nano-porous fibers and protein membranes |
| CN1467314A (zh) * | 2003-06-12 | 2004-01-14 | 东南大学 | 抗菌纳米纤维材料及其制备方法 |
| CN1253615C (zh) * | 2003-07-17 | 2006-04-26 | 杨红恩 | 纳米抗菌无纺布滤材及其制备方法 |
| WO2005021845A1 (en) * | 2003-08-28 | 2005-03-10 | Sabanci Universitesi | Metal coated nano fibres |
| CN1283854C (zh) * | 2004-05-31 | 2006-11-08 | 吉林大学 | 金属纳米粒子在高分子纳米纤维中有序排列的电纺丝法 |
-
2005
- 2005-04-11 CZ CZ20050225A patent/CZ300797B6/cs not_active IP Right Cessation
-
2006
- 2006-04-07 TW TW095112418A patent/TW200702502A/zh unknown
- 2006-04-10 CA CA 2602450 patent/CA2602450A1/en not_active Abandoned
- 2006-04-10 JP JP2008505721A patent/JP2008536022A/ja not_active Abandoned
- 2006-04-10 WO PCT/CZ2006/000018 patent/WO2006108364A1/en active Application Filing
- 2006-04-10 US US11/911,134 patent/US20080207076A1/en not_active Abandoned
- 2006-04-10 KR KR1020077026189A patent/KR20080005549A/ko not_active Withdrawn
- 2006-04-10 AU AU2006233443A patent/AU2006233443A1/en not_active Abandoned
- 2006-04-10 EA EA200702132A patent/EA012635B1/ru not_active IP Right Cessation
- 2006-04-10 CN CN2006800210179A patent/CN101198728B/zh not_active Expired - Fee Related
- 2006-04-10 EP EP20060722445 patent/EP1869232A1/en not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| EA012635B1 (ru) | 2009-12-30 |
| EA200702132A1 (ru) | 2008-08-29 |
| WO2006108364A1 (en) | 2006-10-19 |
| KR20080005549A (ko) | 2008-01-14 |
| CN101198728B (zh) | 2010-09-08 |
| US20080207076A1 (en) | 2008-08-28 |
| CN101198728A (zh) | 2008-06-11 |
| HK1118872A1 (en) | 2009-02-20 |
| CZ300797B6 (cs) | 2009-08-12 |
| JP2008536022A (ja) | 2008-09-04 |
| CZ2005225A3 (cs) | 2006-11-15 |
| AU2006233443A1 (en) | 2006-10-19 |
| EP1869232A1 (en) | 2007-12-26 |
| TW200702502A (en) | 2007-01-16 |
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| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Discontinued |