CA2590779C - Ultraporous sol gel monoliths - Google Patents

Ultraporous sol gel monoliths Download PDF

Info

Publication number
CA2590779C
CA2590779C CA2590779A CA2590779A CA2590779C CA 2590779 C CA2590779 C CA 2590779C CA 2590779 A CA2590779 A CA 2590779A CA 2590779 A CA2590779 A CA 2590779A CA 2590779 C CA2590779 C CA 2590779C
Authority
CA
Canada
Prior art keywords
sol gel
chromatography
monolith
ultraporous
sol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA2590779A
Other languages
English (en)
French (fr)
Other versions
CA2590779A1 (en
Inventor
Dengfeng Xu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Agilent Technologies Inc
Original Assignee
Agilent Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agilent Technologies Inc filed Critical Agilent Technologies Inc
Publication of CA2590779A1 publication Critical patent/CA2590779A1/en
Application granted granted Critical
Publication of CA2590779C publication Critical patent/CA2590779C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/281—Sorbents specially adapted for preparative, analytical or investigative chromatography
    • B01J20/282—Porous sorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28042—Shaped bodies; Monolithic structures
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28047—Gels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28069—Pore volume, e.g. total pore volume, mesopore volume, micropore volume
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/281—Sorbents specially adapted for preparative, analytical or investigative chromatography
    • B01J20/286—Phases chemically bonded to a substrate, e.g. to silica or to polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/281—Sorbents specially adapted for preparative, analytical or investigative chromatography
    • B01J20/291—Gel sorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional [3D] monoliths
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/553—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on fluorides
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/0045—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by a process involving the formation of a sol or a gel, e.g. sol-gel or precipitation processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08—Selective adsorption, e.g. chromatography
    • B01D15/26—Selective adsorption, e.g. chromatography characterised by the separation mechanism
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/50—Aspects relating to the use of sorbent or filter aid materials
    • B01J2220/54—Sorbents specially adapted for analytical or investigative chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/80—Aspects related to sorbents specially adapted for preparative, analytical or investigative chromatography
    • B01J2220/82—Shaped bodies, e.g. monoliths, plugs, tubes, continuous beds
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00793—Uses not provided for elsewhere in C04B2111/00 as filters or diaphragms
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0081—Uses not provided for elsewhere in C04B2111/00 as catalysts or catalyst carriers
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00836—Uses not provided for elsewhere in C04B2111/00 for medical or dental applications
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00844—Uses not provided for elsewhere in C04B2111/00 for electronic applications

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Structural Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Silicon Compounds (AREA)
CA2590779A 2004-12-20 2005-12-01 Ultraporous sol gel monoliths Expired - Fee Related CA2590779C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/018,168 US7439272B2 (en) 2004-12-20 2004-12-20 Ultraporous sol gel monoliths
US11/018,168 2004-12-20
PCT/US2005/043429 WO2006068797A1 (en) 2004-12-20 2005-12-01 Ultraporous sol gel monoliths

Publications (2)

Publication Number Publication Date
CA2590779A1 CA2590779A1 (en) 2006-06-29
CA2590779C true CA2590779C (en) 2011-04-19

Family

ID=36177825

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2590779A Expired - Fee Related CA2590779C (en) 2004-12-20 2005-12-01 Ultraporous sol gel monoliths

Country Status (7)

Country Link
US (2) US7439272B2 (https=)
EP (1) EP1827679A1 (https=)
JP (1) JP5288804B2 (https=)
AU (1) AU2005319513B2 (https=)
CA (1) CA2590779C (https=)
TW (1) TWI315997B (https=)
WO (1) WO2006068797A1 (https=)

Families Citing this family (90)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6686035B2 (en) * 1999-02-05 2004-02-03 Waters Investments Limited Porous inorganic/organic hybrid particles for chromatographic separations and process for their preparation
US7250214B2 (en) 2001-08-09 2007-07-31 Waters Investments Limited Porous inorganic/organic hybrid monolith materials for chromatographic separations and process for their preparation
DE10393599T5 (de) 2002-10-30 2005-10-27 Waters Investments Ltd., New Castle Poröse anorganische/organische Homogene copolymerische Hybridmaterialien für chromatographische Auftrennungen und Verfahren für deren Herstellung
US20100324155A1 (en) * 2003-07-08 2010-12-23 Los Alamos National Security, Llc Preparation of inorganic foam
US8658277B2 (en) * 2004-07-30 2014-02-25 Waters Technologies Corporation Porous inorganic/organic hybrid materials with ordered domains for chromatographic separations and processes for their preparation
US10773186B2 (en) 2004-07-30 2020-09-15 Waters Technologies Corporation Porous inorganic/organic hybrid materials with ordered domains for chromatographic separations and processes for their preparation
US20060079736A1 (en) 2004-10-13 2006-04-13 Sing-Fatt Chin Method and device for percutaneous left ventricular reconstruction
US7766816B2 (en) * 2005-06-09 2010-08-03 Chf Technologies, Inc. Method and apparatus for closing off a portion of a heart ventricle
US8506474B2 (en) 2005-08-19 2013-08-13 Bioventrix, Inc. Method and device for treating dysfunctional cardiac tissue
US20070089604A1 (en) * 2005-10-20 2007-04-26 Wu Chen Novel chromatographic stationary phase
DE102005062606A1 (de) * 2005-12-23 2007-07-05 Deutsche Institute Für Textil- Und Faserforschung Denkendorf Nanoskalige Teilchen auf der Basis von SiO2 und Mischoxiden hiervon, deren Herstellung und Verwendung zur Behandlung textiler Materialien
EP2069239A4 (en) * 2006-09-08 2013-04-10 Cornell Res Foundation Inc SOL GEL PRE-RUNNER AND PRODUCTS FROM IT
WO2008034256A1 (en) * 2006-09-22 2008-03-27 Mcmaster University Methods and compounds for forming monolithic titania, optionally biomolecule doped, with controlled morphology using biocompatible sol-gel processes
US9211115B2 (en) 2006-09-28 2015-12-15 Bioventrix, Inc. Location, time, and/or pressure determining devices, systems, and methods for deployment of lesion-excluding heart implants for treatment of cardiac heart failure and other disease states
US20100059442A1 (en) * 2006-11-17 2010-03-11 The Regents Of The University Of California Method and system for separating analytes
US7628915B2 (en) 2006-12-08 2009-12-08 Varian, Inc. Metal cyano bonded phases
WO2008085435A1 (en) 2007-01-12 2008-07-17 Waters Investments Limited Porous carbon-heteroatom-silicon hybrid inorganic/organic materials for chromatographic separations and process for the preparation thereof
US20080223585A1 (en) * 2007-03-13 2008-09-18 Schlumberger Technology Corporation Providing a removable electrical pump in a completion system
US7651762B2 (en) * 2007-03-13 2010-01-26 Varian, Inc. Methods and devices using a shrinkable support for porous monolithic materials
WO2008150766A1 (en) * 2007-05-29 2008-12-11 Waters Investments Limited Chromatography column
EP2161573B1 (en) * 2007-06-18 2014-10-01 GL Sciences Incorporated Monolith adsorbent and method and apparatus for adsorbing samples with the same
WO2009046343A1 (en) 2007-10-03 2009-04-09 Bioventrix (A Chf Technologies, Inc.) Treating dysfunctional cardiac tissue
FR2929622B1 (fr) * 2008-04-04 2011-03-04 Eads Europ Aeronautic Defence Revetements mesostructures comprenant un agent texturant particulier, pour application en aeronautique et aerospatiale
US20090306769A1 (en) * 2008-06-06 2009-12-10 Boston Scientific Scimed, Inc. Medical balloon made with hybrid polymer-ceramic material and method of making and using the same
TW201004869A (en) 2008-06-10 2010-02-01 Nanotune Technologies Corp Nanoporous materials and related methods
FR2933703B1 (fr) * 2008-07-11 2012-08-17 Commissariat Energie Atomique Detecteurs nanoporeux de composes aromatiques monocycliques et autres polluants
US11439977B2 (en) 2009-06-01 2022-09-13 Waters Technologies Corporation Hybrid material for chromatographic separations comprising a superficially porous core and a surrounding material
JP6151021B2 (ja) 2009-06-01 2017-06-21 ウオーターズ・テクノロジーズ・コーポレイシヨン クロマトグラフ分離用ハイブリッド材料
US9272260B2 (en) * 2009-08-14 2016-03-01 University Of Louisville Research Foundation, Inc. Methods of synthesis and purification by use of a solid support
CA2786412C (en) * 2010-01-08 2018-02-06 University Of Tasmania Porous polymer monoliths, processes for preparation and use thereof
US9138308B2 (en) 2010-02-03 2015-09-22 Apollo Endosurgery, Inc. Mucosal tissue adhesion via textured surface
WO2011130737A2 (en) * 2010-04-16 2011-10-20 University Of South Florida Materials and methods for capillary microextraction in combination with high-performance liquid chromatography
JP5852640B2 (ja) 2010-05-11 2016-02-03 アラーガン、インコーポレイテッドＡｌｌｅｒｇａｎ，Ｉｎｃｏｒｐｏｒａｔｅｄ ポロゲン組成物、製造方法、および使用
US8603833B2 (en) * 2010-06-03 2013-12-10 University Of South Florida Germania-silica-based sol-gel monolith and uses thereof
JP5856162B2 (ja) 2010-07-26 2016-02-09 ウオーターズ・テクノロジーズ・コーポレイシヨン 粒度分布の狭い実質的に非多孔質のハイブリッドコアを含む表面多孔質材料
US20120237676A1 (en) * 2011-03-14 2012-09-20 Intermolecular, Inc. Sol-gel based formulations and methods for preparation of hydrophobic ultra low refractive index anti-reflective coatings on glass
WO2013006904A1 (en) 2011-07-12 2013-01-17 University Of Tasmania Use of porous polymer materials for storage of biological samples
EP3175797B1 (en) 2011-09-30 2020-02-12 Bioventrix, Inc. Trans-catheter ventricular reconstruction structures and systems for treatment of congestive heart failure and other conditions
US9278857B2 (en) * 2012-01-31 2016-03-08 Seagate Technology Inc. Method of surface tension control to reduce trapped gas bubbles
KR101407624B1 (ko) 2012-07-03 2014-06-16 한국기계연구원 메조-메크로 기공을 포함하는 다공질 입자의 제조 방법
WO2014022657A1 (en) 2012-08-02 2014-02-06 Allergan, Inc. Mucosal tissue adhesion via textured surface
EP2900289A1 (en) 2012-09-28 2015-08-05 Allergan, Inc. Porogen compositions, methods of making and uses
AU2014268717A1 (en) 2013-05-24 2015-12-03 Bioventrix, Inc. Cardiac tissue penetrating devices, methods, and systems for treatment of congestive heart failure and other conditions
FR3009384B1 (fr) * 2013-07-31 2017-03-10 Commissariat Energie Atomique Procede de fabrication d'une colonne de chromatographie en phase gazeuse et colonne obtenue par un tel procede
TWI707038B (zh) 2013-08-05 2020-10-11 美商扭轉生物科技有限公司 重新合成之基因庫
EP3038540B1 (en) 2013-08-30 2019-11-06 Bioventrix, Inc. Cardiac tissue anchoring devices and systems for treatment of congestive heart failure and other conditions
EP3038539B1 (en) 2013-08-30 2021-08-18 Bioventrix, Inc. Heart anchor positioning devices for treatment of congestive heart failure and other conditions
KR101578395B1 (ko) 2014-03-21 2015-12-17 고려대학교 산학협력단 이산화탄소 건식 흡착용 아민 개질 실리카겔 지지체의 제조방법
US20160097073A1 (en) * 2014-10-06 2016-04-07 Therapeutic Proteins International, LLC Purification and separation treatment assembly (pasta) for biological products
WO2016126882A1 (en) 2015-02-04 2016-08-11 Twist Bioscience Corporation Methods and devices for de novo oligonucleic acid assembly
CA2975855C (en) 2015-02-04 2025-09-23 Twist Bioscience Corporation SYNTHETIC GENE COMPOSITIONS AND ASSEMBLY METHODS
US9981239B2 (en) 2015-04-21 2018-05-29 Twist Bioscience Corporation Devices and methods for oligonucleic acid library synthesis
WO2017044518A1 (en) 2015-09-10 2017-03-16 Bioventrix, Inc. Systems and methods for deploying a cardiac anchor
KR20180050411A (ko) 2015-09-18 2018-05-14 트위스트 바이오사이언스 코포레이션 올리고핵산 변이체 라이브러리 및 그의 합성
KR102794025B1 (ko) 2015-09-22 2025-04-09 트위스트 바이오사이언스 코포레이션 핵산 합성을 위한 가요성 기판
CN115920796A (zh) 2015-12-01 2023-04-07 特韦斯特生物科学公司 功能化表面及其制备
CN105504186A (zh) * 2016-01-04 2016-04-20 山东大学 一种3,4-二（4-氰基苯基）-2,5-二苯基苯基接枝聚硅氧烷的制备方法及应用
US11478353B2 (en) 2016-01-29 2022-10-25 Bioventrix, Inc. Percutaneous arterial access to position trans-myocardial implant devices and methods
US20190134604A1 (en) 2016-03-06 2019-05-09 Waters Technologies Corporation Porous materials with controlled porosity; process for the preparation thereof; and use thereof for chromatographic separations
US9700872B1 (en) * 2016-07-01 2017-07-11 The Florida International University Board Of Trustees Superpolar chromatographic stationary phases and extraction sorbents and their methods of synthesis
CN106198793A (zh) * 2016-07-06 2016-12-07 云南中烟工业有限责任公司 一种超临界流体色谱‑气相色谱‑质谱测定卷烟主流烟气中酚类化合物的方法
CN106018619A (zh) * 2016-07-06 2016-10-12 云南中烟工业有限责任公司 一种超临界流体色谱-气相色谱-质谱测定卷烟主流烟气中醛酮类化合物的方法
JP6854340B2 (ja) 2016-08-22 2021-04-07 ツイスト バイオサイエンス コーポレーション デノボ合成された核酸ライブラリ
US10417457B2 (en) 2016-09-21 2019-09-17 Twist Bioscience Corporation Nucleic acid based data storage
KR102514213B1 (ko) 2016-12-16 2023-03-27 트위스트 바이오사이언스 코포레이션 면역 시냅스의 변이체 라이브러리 및 그의 합성
AU2018219908B2 (en) * 2017-02-10 2025-06-26 Albert Einstein College Of Medicine Sol-gel/hydrogel therapeutic delivery system and methods thereof
CN110892485B (zh) 2017-02-22 2024-03-22 特韦斯特生物科学公司 基于核酸的数据存储
WO2018170169A1 (en) 2017-03-15 2018-09-20 Twist Bioscience Corporation Variant libraries of the immunological synapse and synthesis thereof
US10020199B1 (en) 2017-05-15 2018-07-10 International Business Machines Corporation Porous tin oxide films
WO2018231864A1 (en) 2017-06-12 2018-12-20 Twist Bioscience Corporation Methods for seamless nucleic acid assembly
US10696965B2 (en) 2017-06-12 2020-06-30 Twist Bioscience Corporation Methods for seamless nucleic acid assembly
CN111566125A (zh) 2017-09-11 2020-08-21 特韦斯特生物科学公司 Gpcr结合蛋白及其合成
CN111565834B (zh) 2017-10-20 2022-08-26 特韦斯特生物科学公司 用于多核苷酸合成的加热的纳米孔
KR102804057B1 (ko) 2018-01-04 2025-05-07 트위스트 바이오사이언스 코포레이션 Dna 기반 디지털 정보 저장
CA3100739A1 (en) 2018-05-18 2019-11-21 Twist Bioscience Corporation Polynucleotides, reagents, and methods for nucleic acid hybridization
CN109613150B (zh) * 2018-11-09 2021-05-28 兰州中科安泰分析科技有限责任公司 PLOT-Al2O3色谱柱高压动态法涂覆工艺
US12357959B2 (en) 2018-12-26 2025-07-15 Twist Bioscience Corporation Highly accurate de novo polynucleotide synthesis
US11630089B2 (en) * 2019-01-23 2023-04-18 King Fahd University Of Petroleum And Minerals Yttrium-containing sol-gel coating, its use, and manufacture
CN109734325A (zh) * 2019-02-20 2019-05-10 邹玉 一种超疏水防雾玻璃的制备方法
CA3131691A1 (en) 2019-02-26 2020-09-03 Twist Bioscience Corporation Variant nucleic acid libraries for antibody optimization
CN113766930B (zh) 2019-02-26 2025-07-22 特韦斯特生物科学公司 Glp1受体的变异核酸文库
AU2020298294A1 (en) 2019-06-21 2022-02-17 Twist Bioscience Corporation Barcode-based nucleic acid sequence assembly
WO2021061842A1 (en) 2019-09-23 2021-04-01 Twist Bioscience Corporation Variant nucleic acid libraries for single domain antibodies
JP2022548309A (ja) 2019-09-23 2022-11-17 ツイスト バイオサイエンス コーポレーション Ｃｒｔｈ２のバリアント核酸ライブラリー
IL293670A (en) 2019-12-09 2022-08-01 Twist Bioscience Corp Variable nucleic acid libraries for adenosine receptors
CN111234253A (zh) * 2020-02-27 2020-06-05 吉林师范大学 一种纳米金属有机骨架材料的制备方法
CN111589384B (zh) * 2020-05-14 2022-02-25 大连工业大学 一种CsxWO3-SiO2复合气凝胶的原位合成方法
US12085744B1 (en) * 2021-11-10 2024-09-10 Meta Platforms Technologies, Llc Superconformal recessed feature fill sol-gels
US12187906B2 (en) 2022-04-20 2025-01-07 Meta Platforms Technologies, Llc Variable refractive index thin films
KR20260039665A (ko) 2023-07-07 2026-03-20 후류게루즈 가부시키가이샤 화합물의 처리 방법, 화합물 또는 그 반응물의 제조 방법, 화합물의 처리 시스템 및 교환용 처리 칼럼

Family Cites Families (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL145278B (nl) 1966-04-06 1975-03-17 Nebraska State Werkwijze ter uitvoering van een heresteringsreactie tussen een vloeibare polyhydrische alcohol en een hydrofobe ester van een vetzuur met lange keten.
US4778909A (en) * 1984-05-11 1988-10-18 Northeastern University Stable silica-based ether bonded phases for biopolymer separations
US5108595A (en) 1985-11-01 1992-04-28 E. I. Du Pont De Nemours And Company Porous silica microspheres having silanol-enriched and silanized surfaces
US5023208A (en) 1989-12-19 1991-06-11 Orion Laboratories, Inc. Sol-gel process for glass and ceramic articles
US5264197A (en) 1991-12-20 1993-11-23 Yazaki Corporation Sol-gel process for providing a tailored gel microstructure
US5374755A (en) 1992-07-17 1994-12-20 Millipore Corporation Liquid chromatography stationary phases with reduced silanol interactions
CZ286859B6 (en) 1993-02-26 2000-07-12 Merck Patent Gmbh Stationary phase for chromatography
EP0710219B1 (en) * 1993-07-19 1997-12-10 MERCK PATENT GmbH Inorganic porous material and process for making same
US6207098B1 (en) 1996-12-26 2001-03-27 Merck Patent Gmbh Method for producing porous inorganic materials
JP3985171B2 (ja) * 1996-12-26 2007-10-03 直弘 曽我 無機系多孔質体の製造方法
EP0991940B1 (de) 1997-06-18 2010-08-25 Merck Patent GmbH Verwendung monolithischer sorbentien für präparative chromatographische trennverfahren
DE69841079D1 (de) 1998-01-23 2009-10-01 Merck Patent Gmbh Verfahren zur herstellung von inorganischem material in einer kapillare
JPH11287791A (ja) 1998-04-01 1999-10-19 Naohiro Soga キャピラリーカラム
US6210570B1 (en) 1998-08-21 2001-04-03 Agilent Technologies, Inc. Monolithic silica column
US6071410A (en) 1998-11-16 2000-06-06 Varian, Inc. Recovery of organic solutes from aqueous solutions
ATE464118T1 (de) 1999-02-05 2010-04-15 Waters Technologies Corp Poröse hybridpartikel zur chromatographischen trennung
JP2001026664A (ja) * 1999-05-13 2001-01-30 Matsushita Electric Ind Co Ltd 多孔体の製造方法
WO2001058562A1 (en) 2000-02-09 2001-08-16 University Of South Florida Sol-gel monolithic column with optical window and method of making
US7052532B1 (en) * 2000-03-09 2006-05-30 3M Innovative Properties Company High temperature nanofilter, system and method
EP1134189A1 (de) 2000-03-16 2001-09-19 Degussa AG Formkörper amorpher, poröser (Metall-)Silikate
US6346140B2 (en) 2000-03-31 2002-02-12 Kabushiki Kaisha Toyota Chuo Kenkyusho Porous solid for gas adsorption separation and gas adsorption separation process employing it
DE10034076C1 (de) 2000-07-13 2002-01-24 Merck Patent Gmbh Anschlußsystem für Kunststoffsäulen
US6620368B1 (en) 2000-07-13 2003-09-16 Simax Technologies, Inc. Sol-gel process for production of oxide-based glass and ceramic articles
US6528167B2 (en) 2001-01-31 2003-03-04 Waters Investments Limited Porous hybrid particles with organic groups removed from the surface
US7250214B2 (en) 2001-08-09 2007-07-31 Waters Investments Limited Porous inorganic/organic hybrid monolith materials for chromatographic separations and process for their preparation
US7125912B2 (en) 2001-10-09 2006-10-24 Simax Technologies, Inc. Doped sol-gel materials and method of manufacture utilizing reduced mixing temperatures
US7026362B2 (en) 2001-10-09 2006-04-11 Simax Technologies, Inc. Sol-gel process utilizing reduced mixing temperatures
US7235142B2 (en) * 2002-01-04 2007-06-26 University Of Dayton Non-toxic corrosion-protection rinses and seals based on cobalt
US7000885B2 (en) 2002-02-01 2006-02-21 Simax Technologies, Inc. Apparatus and method for forming a sol-gel monolith utilizing multiple casting
US6645378B1 (en) 2002-03-05 2003-11-11 Dionex Corporation Polar silanes and their use on silica supports
US20030230524A1 (en) 2002-06-18 2003-12-18 Naohiro Soga Chromatographic chip and method of fabrication thereof
JP4362752B2 (ja) * 2002-09-13 2009-11-11 直弘 曽我 一体型多孔質材料の製造方法

Also Published As

Publication number Publication date
US20090008327A1 (en) 2009-01-08
US20060131238A1 (en) 2006-06-22
JP2008525535A (ja) 2008-07-17
WO2006068797B1 (en) 2006-08-17
US7439272B2 (en) 2008-10-21
EP1827679A1 (en) 2007-09-05
WO2006068797A1 (en) 2006-06-29
AU2005319513B2 (en) 2010-05-13
AU2005319513A1 (en) 2006-06-29
US7595350B2 (en) 2009-09-29
TWI315997B (en) 2009-10-21
TW200633772A (en) 2006-10-01
CA2590779A1 (en) 2006-06-29
JP5288804B2 (ja) 2013-09-11

Similar Documents

Publication Publication Date Title
CA2590779C (en) Ultraporous sol gel monoliths
US7651762B2 (en) Methods and devices using a shrinkable support for porous monolithic materials
Nakanishi Sol–gel process of oxides accompanied by phase separation
Siouffi Silica gel-based monoliths prepared by the sol–gel method: facts and figures
Boissiere et al. Spherical MSU‐1 mesoporous silica particles tuned for HPLC
Unger et al. Monolithic silicas in separation science: concepts, syntheses, characterization, modeling and applications
Aggarwal et al. Monolithic bed structure for capillary liquid chromatography
US4874518A (en) Porous silica microspheres having a silanol enriched surface
US8404346B2 (en) Porous inorganic/organic hybrid monolith materials for chromatographic separations and process for their preparation
US5108595A (en) Porous silica microspheres having silanol-enriched and silanized surfaces
US9289747B2 (en) Nanocomposites and their application as monolith columns
EP1049929B1 (en) Process for producing inorganic porous material in a capillary
US5032266A (en) Porous silica microspheres having silanol-enriched and silanized surfaces
Ahmed et al. Investigation on synthesis of spheres-on-sphere silica particles and their assessment for high performance liquid chromatography applications
Tian et al. Large‐pore mesoporous SBA‐15 silica particles with submicrometer size as stationary phases for high‐speed CEC separation
US20210170304A1 (en) Porous inorganic/organic hybrid materials with ordered domains for chromatographic separations and processes for their preparation
EP0221780B1 (en) Porous silica microspheres having silanol-enriched and silanized surfaces
WO2005091972A2 (en) Group iv metal oxide monolithic columns
RU2847997C1 (ru) Способ получения сорбента на основе сферических частиц алюминия и металлоорганического каркасного полимера MIL-53(Al)
HK1140714A (en) Methods and devices using a shrinkable support for porous monolithic materials
Dark et al. Monolithic Silicas in Separation Science E-Book

Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed

Effective date: 20161201