CA2489457A1 - Glass fibre reinforced plastics - Google Patents

Glass fibre reinforced plastics Download PDF

Info

Publication number
CA2489457A1
CA2489457A1 CA002489457A CA2489457A CA2489457A1 CA 2489457 A1 CA2489457 A1 CA 2489457A1 CA 002489457 A CA002489457 A CA 002489457A CA 2489457 A CA2489457 A CA 2489457A CA 2489457 A1 CA2489457 A1 CA 2489457A1
Authority
CA
Canada
Prior art keywords
groups
water
glass fibre
weight
minutes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002489457A
Other languages
English (en)
French (fr)
Inventor
Thorsten Rische
Jan Weikard
Thomas Feller
Erhard Luehmann
Karin Naujoks
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Covestro Deutschland AG
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2489457A1 publication Critical patent/CA2489457A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
    • C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
    • C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
    • C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/26—Macromolecular compounds or prepolymers
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/26—Macromolecular compounds or prepolymers
    • C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C03C25/326—Polyureas; Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0828—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing sulfonate groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/68—Unsaturated polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/703—Isocyanates or isothiocyanates transformed in a latent form by physical means
    • C08G18/705—Dispersions of isocyanates or isothiocyanates in a liquid medium
    • C08G18/706—Dispersions of isocyanates or isothiocyanates in a liquid medium the liquid medium being water
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/7806—Nitrogen containing -N-C=0 groups
    • C08G18/7818—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
    • C08G18/7831—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing biuret groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
    • C08G18/807—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with nitrogen containing compounds
    • C08G18/8074—Lactams
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/81—Unsaturated isocyanates or isothiocyanates
    • C08G18/8141—Unsaturated isocyanates or isothiocyanates masked
    • C08G18/815—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen
    • C08G18/8158—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen
    • C08G18/8175—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen with esters of acrylic or alkylacrylic acid having only one group containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
    • C08J5/08—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials glass fibres
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Dispersion Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Reinforced Plastic Materials (AREA)
  • Laminated Bodies (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Surface Treatment Of Glass Fibres Or Filaments (AREA)
CA002489457A 2002-06-17 2003-06-04 Glass fibre reinforced plastics Abandoned CA2489457A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10226933.5 2002-06-17
DE10226933A DE10226933A1 (de) 2002-06-17 2002-06-17 Glasfaserverstärkte Kunststoffe
PCT/EP2003/005828 WO2003106542A1 (de) 2002-06-17 2003-06-04 Glasfaserverstärkte kunststoffe

Publications (1)

Publication Number Publication Date
CA2489457A1 true CA2489457A1 (en) 2003-12-24

Family

ID=29594582

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002489457A Abandoned CA2489457A1 (en) 2002-06-17 2003-06-04 Glass fibre reinforced plastics

Country Status (18)

Country Link
US (1) US20040195731A1 (enExample)
EP (1) EP1516012B1 (enExample)
JP (1) JP4384032B2 (enExample)
KR (1) KR101012534B1 (enExample)
CN (1) CN1326918C (enExample)
AT (1) ATE452929T1 (enExample)
AU (1) AU2003276904A1 (enExample)
BR (1) BRPI0311924A2 (enExample)
CA (1) CA2489457A1 (enExample)
DE (2) DE10226933A1 (enExample)
DK (1) DK1516012T3 (enExample)
ES (1) ES2337039T3 (enExample)
MX (1) MXPA04012738A (enExample)
PT (1) PT1516012E (enExample)
RU (1) RU2005100955A (enExample)
SI (1) SI1516012T1 (enExample)
TW (1) TWI311141B (enExample)
WO (1) WO2003106542A1 (enExample)

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* Cited by examiner, † Cited by third party
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WO2008043722A1 (de) * 2006-10-09 2008-04-17 Basf Se Strahlungshärtbare verbindungen
DE102007006492A1 (de) * 2007-02-09 2008-08-14 Bayer Materialscience Ag UV-härtbare Dispersionen auf Basis von Polyisocyanaten
CN101855183B (zh) * 2007-11-08 2016-05-04 Ppg工业俄亥俄公司 用于玻璃纤维的施胶组合物、施胶的玻璃纤维、和包含其的增强制品
US20110230615A1 (en) * 2007-11-08 2011-09-22 Van Der Woude Jacobus Hendricus Antonius Fiber Glass Strands And Reinforced Products Comprising The Same
DE102008001855A1 (de) * 2008-05-19 2009-11-26 Evonik Degussa Gmbh Zweikomponenten-Zusammensetzung zur Herstellung von flexiblen Polyurethan-Gelcoats
US9388270B2 (en) * 2009-02-11 2016-07-12 Ppg Industries Ohio, Inc. Fiber reinforced polymeric composites and methods of making the same
JP5664545B2 (ja) * 2009-02-26 2015-02-04 宇部興産株式会社 水性ポリウレタン樹脂分散体及びその製造方法
JP5242749B2 (ja) * 2010-08-30 2013-07-24 北広ケミカル株式会社 水溶性または水分散性ポリイソシアネート架橋剤およびこれを用いた撥水撥油剤組成物並びにその撥水撥油剤組成物を用いた繊維の撥水撥油加工方法
US8647471B2 (en) * 2010-12-22 2014-02-11 Bayer Materialscience Llc Process for the production of sized and/or wet-strength papers, paperboards and cardboards
JP2012149178A (ja) * 2011-01-19 2012-08-09 Hitachi Chemical Co Ltd ウレタンオリゴマー及び樹脂組成物、並びにこれらを用いた硬化物
DE102011102135B3 (de) 2011-05-20 2012-08-30 Impreg Gmbh Einlegeschlauch zum Auskleiden und Sanieren von Rohrleitungen und Kanälen, insbesondere von Abwasserkanälen
JP5869893B2 (ja) * 2012-01-24 2016-02-24 株式会社Adeka 水系ポリウレタン樹脂組成物を含有するガラス繊維集束剤、繊維強化樹脂用ガラス繊維及び繊維強化合成樹脂組成物
US9574056B2 (en) 2014-02-05 2017-02-21 Johns Manville Fiber reinforced thermoplastic composites and methods of making
US9725563B2 (en) 2014-02-05 2017-08-08 Johns Manville Fiber reinforced thermoset composites and methods of making
DE102014210098A1 (de) * 2014-05-27 2015-12-03 Bayerische Motoren Werke Aktiengesellschaft Geschlichtete Faser und diese enthaltendes Faserverbundmaterial, Verfahren zum Schlichten einer Faser sowie zum Herstellen eines Faserverbundmaterials
CN107098602A (zh) * 2017-04-01 2017-08-29 长兴微羽智能科技有限公司 一种风力发电机叶片用玻纤增强材料的制备方法
JP7084157B2 (ja) 2018-02-21 2022-06-14 帝人株式会社 サイジング剤組成物、炭素繊維の製造方法及びサイジング剤付着炭素繊維
EP4112669A1 (de) 2021-07-01 2023-01-04 Covestro Deutschland AG Nicht-ionisch hydrophilierte polyurethan-dispersionen mit methacrylat-doppelbindungen
EP4112670A1 (de) 2021-07-01 2023-01-04 Covestro Deutschland AG Nicht-ionisch hydrophilierte polyurethan-dispersionen mit acrylat-doppelbindungen
CN113929850B (zh) * 2021-11-30 2023-07-28 上海华峰新材料研发科技有限公司 一种水性聚氨酯上浆剂及其制备方法和应用
CN116082814B (zh) * 2022-12-08 2024-12-24 上海锦湖日丽塑料有限公司 高透光率低浮纤玻璃纤维增强pc组合物及其制备方法

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US4005244A (en) * 1974-09-30 1977-01-25 Ppg Industries, Inc. Ultraviolet light curable opacifying compositions
CN85106980A (zh) * 1984-07-13 1987-04-01 B·F·谷德里奇公司 玻璃纤维增强的氯乙烯聚合物产品及其制备工艺
US5059947A (en) * 1990-03-19 1991-10-22 Chen Shih Chiang Vehicle brake warning device
ZA93819B (en) * 1992-02-24 1993-10-15 Cook Composites & Polymers Process of making a rigid multi-layer preform
DE59709939D1 (de) * 1996-03-01 2003-06-05 Bayer Ag In Wasser lösliche oder dispergierbare Polyurethanharnstoffe, ein Verfahren zu deren Herstellung und ihre Verwendung zur Beschichtung beliebiger Substrate
DE19611850A1 (de) * 1996-03-26 1997-10-02 Bayer Ag Verwendung von ionischen und nichtionischen wäßrigen Polyurethandispersionen auf Basis von 1-Methyl-2,4- und/oder -2,6-diisocyanatocyclohexan als Bindemittel für Glasfaserschlichten sowie spezielle ionische und nichtionische wäßrige Polyurethandispersionen auf Basis von 1-Methyl-2,4- und/oder -2,6-diisocyanatocyclohexan
JP3783283B2 (ja) * 1996-05-14 2006-06-07 日東紡績株式会社 ガラス繊維用集束剤
DE19914896A1 (de) * 1999-04-01 2000-10-05 Basf Coatings Ag Thermisch und/oder mit aktinischer Strahlung härtbarer wäßriger Beschichtungsstoff und seine Verwendung
DE19914882A1 (de) * 1999-04-01 2000-10-05 Bayer Ag Selbstvernetzende Polyurethan-, Polyurethan-Polyharnstoff- bzw. Polyharnstoff-Dispersionen für Schlichten
BR0014422A (pt) * 1999-09-30 2002-06-11 Basf Ag Dispersão aquosa de poliuretano curável por u.v. e calor, e, uso da dispersão de poliuretano
DE10054933A1 (de) * 2000-11-06 2002-05-08 Bayer Ag Verfahren zur Beschichtung von Substraten

Also Published As

Publication number Publication date
ES2337039T3 (es) 2010-04-20
EP1516012B1 (de) 2009-12-23
US20040195731A1 (en) 2004-10-07
CN1326918C (zh) 2007-07-18
BRPI0311924A2 (pt) 2016-06-28
DE10226933A1 (de) 2003-12-24
MXPA04012738A (es) 2005-03-23
CN1675291A (zh) 2005-09-28
EP1516012A1 (de) 2005-03-23
SI1516012T1 (sl) 2010-04-30
AU2003276904A1 (en) 2003-12-31
TWI311141B (en) 2009-06-21
PT1516012E (pt) 2010-02-25
RU2005100955A (ru) 2006-01-20
ATE452929T1 (de) 2010-01-15
KR101012534B1 (ko) 2011-02-07
JP4384032B2 (ja) 2009-12-16
WO2003106542A1 (de) 2003-12-24
KR20050012290A (ko) 2005-01-31
DE50312259D1 (de) 2010-02-04
TW200413430A (en) 2004-08-01
JP2005530878A (ja) 2005-10-13
DK1516012T3 (da) 2010-04-19

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Legal Events

Date Code Title Description
FZDE Discontinued