CA2479286A1 - Filled weatherable compositions having a good surface appearance - Google Patents
Filled weatherable compositions having a good surface appearance Download PDFInfo
- Publication number
- CA2479286A1 CA2479286A1 CA002479286A CA2479286A CA2479286A1 CA 2479286 A1 CA2479286 A1 CA 2479286A1 CA 002479286 A CA002479286 A CA 002479286A CA 2479286 A CA2479286 A CA 2479286A CA 2479286 A1 CA2479286 A1 CA 2479286A1
- Authority
- CA
- Canada
- Prior art keywords
- percent
- weight
- molding composition
- styrene
- units derived
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 71
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 37
- 239000003365 glass fiber Substances 0.000 claims abstract description 25
- 229920001577 copolymer Polymers 0.000 claims abstract description 24
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000000945 filler Substances 0.000 claims abstract description 15
- 239000004952 Polyamide Substances 0.000 claims abstract description 13
- 229920001971 elastomer Polymers 0.000 claims abstract description 13
- 238000000465 moulding Methods 0.000 claims abstract description 13
- 229920002647 polyamide Polymers 0.000 claims abstract description 13
- 229910052882 wollastonite Inorganic materials 0.000 claims abstract description 12
- 239000010456 wollastonite Substances 0.000 claims abstract description 12
- 238000009757 thermoplastic moulding Methods 0.000 claims abstract description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 10
- 239000005060 rubber Substances 0.000 claims abstract description 8
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract 3
- 239000002245 particle Substances 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 abstract description 5
- 229920001778 nylon Polymers 0.000 description 10
- 229920005989 resin Polymers 0.000 description 10
- 239000011347 resin Substances 0.000 description 10
- 239000004677 Nylon Substances 0.000 description 9
- -1 vinyl compounds Chemical class 0.000 description 6
- 150000008064 anhydrides Chemical class 0.000 description 5
- 239000000806 elastomer Substances 0.000 description 5
- 229920006122 polyamide resin Polymers 0.000 description 5
- 229920000638 styrene acrylonitrile Polymers 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 229920002292 Nylon 6 Polymers 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 150000004985 diamines Chemical class 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229920000305 Nylon 6,10 Polymers 0.000 description 2
- 229920002302 Nylon 6,6 Polymers 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 150000003951 lactams Chemical class 0.000 description 2
- 239000004611 light stabiliser Substances 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- BPILDHPJSYVNAF-UHFFFAOYSA-M sodium;diiodomethanesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C(I)I BPILDHPJSYVNAF-UHFFFAOYSA-M 0.000 description 2
- 150000003440 styrenes Chemical class 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- GUOSQNAUYHMCRU-UHFFFAOYSA-N 11-Aminoundecanoic acid Chemical compound NCCCCCCCCCCC(O)=O GUOSQNAUYHMCRU-UHFFFAOYSA-N 0.000 description 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- ZMWRRFHBXARRRT-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2-methylbutan-2-yl)phenol Chemical compound CCC(C)(C)C1=CC(C(C)(C)CC)=CC(N2N=C3C=CC=CC3=N2)=C1O ZMWRRFHBXARRRT-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- PPKRHKAXRRVXBQ-UHFFFAOYSA-N 4-[(4-aminocyclohexyl)methyl]cyclohexan-1-amine;dodecanamide Chemical compound CCCCCCCCCCCC(N)=O.C1CC(N)CCC1CC1CCC(N)CC1 PPKRHKAXRRVXBQ-UHFFFAOYSA-N 0.000 description 1
- ACYXOHNDKRVKLH-UHFFFAOYSA-N 5-phenylpenta-2,4-dienenitrile prop-2-enoic acid Chemical compound OC(=O)C=C.N#CC=CC=CC1=CC=CC=C1 ACYXOHNDKRVKLH-UHFFFAOYSA-N 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- 229920000571 Nylon 11 Polymers 0.000 description 1
- 229920000299 Nylon 12 Polymers 0.000 description 1
- 229920001007 Nylon 4 Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical group 0.000 description 1
- 229920006127 amorphous resin Polymers 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000002902 bimodal effect Effects 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 150000001990 dicarboxylic acid derivatives Chemical class 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexamethylene diamine Natural products NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 238000010191 image analysis Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000005395 methacrylic acid group Chemical class 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- FJXWKBZRTWEWBJ-UHFFFAOYSA-N nonanediamide Chemical compound NC(=O)CCCCCCCC(N)=O FJXWKBZRTWEWBJ-UHFFFAOYSA-N 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001485 poly(butyl acrylate) polymer Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 description 1
- 229940080818 propionamide Drugs 0.000 description 1
- 239000003340 retarding agent Substances 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920006163 vinyl copolymer Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/103,028 | 2002-03-21 | ||
| US10/103,028 US6756439B2 (en) | 2002-03-21 | 2002-03-21 | Filled weatherable compositions having a good surface appearance |
| PCT/US2003/008502 WO2003080725A1 (en) | 2002-03-21 | 2003-03-18 | Filled weatherable compositions having a good surface appearance |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2479286A1 true CA2479286A1 (en) | 2003-10-02 |
Family
ID=28040295
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002479286A Abandoned CA2479286A1 (en) | 2002-03-21 | 2003-03-18 | Filled weatherable compositions having a good surface appearance |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6756439B2 (enExample) |
| EP (1) | EP1490433A1 (enExample) |
| JP (1) | JP2005520904A (enExample) |
| KR (1) | KR20050002874A (enExample) |
| CN (1) | CN1330703C (enExample) |
| AU (1) | AU2003225886A1 (enExample) |
| CA (1) | CA2479286A1 (enExample) |
| MX (1) | MXPA04009044A (enExample) |
| TW (1) | TW200401005A (enExample) |
| WO (1) | WO2003080725A1 (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7185468B2 (en) | 2002-10-31 | 2007-03-06 | Jeld-Wen, Inc. | Multi-layered fire door and method for making the same |
| JP2007534865A (ja) * | 2004-04-21 | 2007-11-29 | ジェルドウィン インコーポレイテッド | 繊維強化複合体、及び繊維強化複合体を含む建築用構造物 |
| DE102005040620A1 (de) * | 2004-10-11 | 2006-04-13 | Bayer Materialscience Ag | Glasfaserverstärkte Polymer-Zusammensetzungen |
| DE102004059238A1 (de) * | 2004-12-08 | 2006-06-14 | Basf Ag | Füllstoffhaltige Formmassen auf Basis von Styrolcopolymeren |
| EP1927630A4 (en) | 2005-09-22 | 2013-05-01 | Fujitsu Ltd | RESIN COMPOSITION AND RESIN OF PLANT BASE CONTAINING RESIN BODY RESIN, USING THE SUBSTANCE |
| KR100756349B1 (ko) * | 2006-12-18 | 2007-09-10 | 제일모직주식회사 | 나일론계 수지 복합재 |
| EP3039071B1 (en) * | 2013-08-28 | 2019-04-10 | SABIC Global Technologies B.V. | Soft touch compositions and articles thereof |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2653146A1 (de) | 1976-11-23 | 1978-05-24 | Bayer Ag | Thermoplastische formmassen |
| NL8603246A (nl) * | 1986-12-20 | 1988-07-18 | Stamicarbon | Thermoplastische polymeermengsels. |
| JPH0345640A (ja) | 1989-07-14 | 1991-02-27 | Mitsubishi Monsanto Chem Co | ガラス繊維強化熱可塑性樹脂組成物 |
| JP2876226B2 (ja) | 1989-11-10 | 1999-03-31 | 三菱レイヨン株式会社 | 耐衝撃性、耐熱安定性に優れた樹脂組成物 |
| JPH0481460A (ja) | 1990-07-24 | 1992-03-16 | Mitsubishi Rayon Co Ltd | 耐衝撃性、耐熱安定性に優れた樹脂組成物 |
| DE4114248A1 (de) | 1991-05-02 | 1992-11-05 | Basf Ag | Glasfaserverstaerkte styrol-copolymerisate |
| EP0587907B1 (en) | 1992-03-31 | 1997-06-04 | Sumitomo Dow Limited | Thermoplastic resin composition containing glass fiber |
-
2002
- 2002-03-21 US US10/103,028 patent/US6756439B2/en not_active Expired - Fee Related
-
2003
- 2003-03-18 AU AU2003225886A patent/AU2003225886A1/en not_active Abandoned
- 2003-03-18 JP JP2003578464A patent/JP2005520904A/ja active Pending
- 2003-03-18 WO PCT/US2003/008502 patent/WO2003080725A1/en not_active Ceased
- 2003-03-18 EP EP03745149A patent/EP1490433A1/en not_active Withdrawn
- 2003-03-18 MX MXPA04009044A patent/MXPA04009044A/es active IP Right Grant
- 2003-03-18 CN CNB038065789A patent/CN1330703C/zh not_active Expired - Fee Related
- 2003-03-18 CA CA002479286A patent/CA2479286A1/en not_active Abandoned
- 2003-03-18 KR KR10-2004-7014774A patent/KR20050002874A/ko not_active Withdrawn
- 2003-03-20 TW TW092106115A patent/TW200401005A/zh unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US6756439B2 (en) | 2004-06-29 |
| WO2003080725A1 (en) | 2003-10-02 |
| TW200401005A (en) | 2004-01-16 |
| US20030181581A1 (en) | 2003-09-25 |
| EP1490433A1 (en) | 2004-12-29 |
| CN1330703C (zh) | 2007-08-08 |
| MXPA04009044A (es) | 2005-01-25 |
| JP2005520904A (ja) | 2005-07-14 |
| AU2003225886A1 (en) | 2003-10-08 |
| KR20050002874A (ko) | 2005-01-10 |
| CN1643056A (zh) | 2005-07-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued |