CA2448447A1 - Method for producing a plasma-polymerized polymer electrolyte membrane and a polyazol membrane coated by plasma-polymerization - Google Patents

Method for producing a plasma-polymerized polymer electrolyte membrane and a polyazol membrane coated by plasma-polymerization Download PDF

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Publication number
CA2448447A1
CA2448447A1 CA002448447A CA2448447A CA2448447A1 CA 2448447 A1 CA2448447 A1 CA 2448447A1 CA 002448447 A CA002448447 A CA 002448447A CA 2448447 A CA2448447 A CA 2448447A CA 2448447 A1 CA2448447 A1 CA 2448447A1
Authority
CA
Canada
Prior art keywords
plasma
membrane
acid
polyazole
aromatic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002448447A
Other languages
English (en)
French (fr)
Inventor
Jorg Mueller
Laurent Mex
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2448447A1 publication Critical patent/CA2448447A1/en
Abandoned legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12—Composite membranes; Ultra-thin membranes
    • B01D69/125—In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction
    • B01D69/127—In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction using electrical discharge or plasma-polymerisation
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1027—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having carbon, oxygen and other atoms, e.g. sulfonated polyethersulfones [S-PES]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/103—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having nitrogen, e.g. sulfonated polybenzimidazoles [S-PBI], polybenzimidazoles with phosphoric acid, sulfonated polyamides [S-PA] or sulfonated polyphosphazenes [S-PPh]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1072—Polymeric electrolyte materials characterised by the manufacturing processes by chemical reactions, e.g. insitu polymerisation or insitu crosslinking
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1086—After-treatment of the membrane other than by polymerisation
    • H01M8/1088—Chemical modification, e.g. sulfonation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Sustainable Energy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Electrochemistry (AREA)
  • Sustainable Development (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Fuel Cell (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
  • Physical Vapour Deposition (AREA)
CA002448447A 2001-07-11 2002-07-11 Method for producing a plasma-polymerized polymer electrolyte membrane and a polyazol membrane coated by plasma-polymerization Abandoned CA2448447A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10133738A DE10133738A1 (de) 2001-07-11 2001-07-11 Verfahren zur Herstellung einer plasmapolymerisierten Polymer-Elektrolytmembran
DE10133738.8 2001-07-11
PCT/EP2002/007734 WO2003007411A2 (de) 2001-07-11 2002-07-11 Verfahren zur herstellung einer plasmapolymerisierten polymer-elektrolytmembran sowie eine plasmabeschichtete polyazol-membran

Publications (1)

Publication Number Publication Date
CA2448447A1 true CA2448447A1 (en) 2003-01-23

Family

ID=7691424

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002448447A Abandoned CA2448447A1 (en) 2001-07-11 2002-07-11 Method for producing a plasma-polymerized polymer electrolyte membrane and a polyazol membrane coated by plasma-polymerization

Country Status (8)

Country Link
EP (1) EP1497882A2 (zh)
JP (1) JP2005520001A (zh)
KR (1) KR20040014572A (zh)
CN (1) CN1610984A (zh)
AU (1) AU2002328339A1 (zh)
CA (1) CA2448447A1 (zh)
DE (1) DE10133738A1 (zh)
WO (1) WO2003007411A2 (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006003943A1 (ja) * 2004-06-30 2006-01-12 Tdk Corporation 直接アルコール型燃料電池及びその製造方法
US8277983B2 (en) 2002-09-13 2012-10-02 Basf Fuel Cell Gmbh Proton-conducting membrane and its use

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10209419A1 (de) 2002-03-05 2003-09-25 Celanese Ventures Gmbh Verfahren zur Herstellung einer Polymerelektrolytmembran und deren Anwendung in Brennstoffzellen
US7846982B2 (en) 2002-03-06 2010-12-07 Pemeas Gmbh Proton conducting electrolyte membrane having reduced methanol permeability and the use thereof in fuel cells
JP4638220B2 (ja) 2002-04-25 2011-02-23 ビーエーエスエフ フューエル セル ゲゼルシャフト ミット ベシュレンクテル ハフツング 多層電解質膜
DE10230477A1 (de) 2002-07-06 2004-01-15 Celanese Ventures Gmbh Funktionalisierte Polyazole, Verfahren zu ihrer Herstellung sowie ihre Verwendung
DE50302082D1 (de) 2002-08-02 2006-02-02 Pemeas Gmbh Protonenleitende polymembran, welche sulfonsäuregruppen enthaltende polymere umfasst, und deren anwendung in brennstoffzellen
WO2004024796A1 (de) * 2002-08-29 2004-03-25 Pemeas Gmbh Verfahren zur herstellung von protonenleitenden polymermembranen, verbesserte polymermembranen und deren anwendung in brennstoffzellen
DE10239701A1 (de) 2002-08-29 2004-03-11 Celanese Ventures Gmbh Polymerfolie auf Basis von Polyazolen und deren Verwendung
DE10246459A1 (de) 2002-10-04 2004-04-15 Celanese Ventures Gmbh Protonenleitende Polymermembran umfassend Phosphonsäuregruppen enthaltende Polyazole und deren Anwendung in Brennstoffzellen
DE10246372A1 (de) 2002-10-04 2004-04-15 Celanese Ventures Gmbh Mit einer Katalysatorschicht beschichtete protonenleitende Polymermembran enthaltend Polyazole und deren Anwendung in Brennstoffzellen
DE10246373A1 (de) 2002-10-04 2004-04-15 Celanese Ventures Gmbh Protonenleitende Polymermembran umfassend Sulfonsäuregruppen enthaltende Polyazole und deren Anwendung in Brennstoffzellen
JP4875489B2 (ja) 2003-07-27 2012-02-15 ベーアーエスエフ フューエル セル ゲーエムベーハー プロトン伝導性膜およびその使用
KR100727216B1 (ko) * 2004-11-19 2007-06-13 주식회사 엘지화학 신규한 술폰화 공중합체 및 이를 이용한 전해질막
KR100706067B1 (ko) * 2005-01-25 2007-04-11 한양대학교 산학협력단 산 또는 염기 도핑된 미세다공성을 갖는 수소이온 전도성 고분자, 그 제조방법, 상기 고분자를 이용한 고분자막, 및 그 고분자막을 채용한 연료전지
DE102006040749A1 (de) 2006-08-31 2008-03-06 Daimler Ag Oxidationsstabilisierte Polymer-Elektrolyt-Membranen für Brennstoffzellen
FR2908558B1 (fr) * 2006-11-13 2008-12-19 Commissariat Energie Atomique Materiau d'electrolyte silicie pour pile a combustible, procede pour sa realisation et pile a combustible mettant en oeuvre un tel materiau.
FR2928227B1 (fr) * 2008-02-29 2010-04-02 Commissariat Energie Atomique Procede de fabrication d'une membrane polymerique a conduction ionique pour pile a combustible.
WO2012015071A1 (ja) * 2010-07-28 2012-02-02 住友化学株式会社 高分子電解質、高分子電解質膜およびポリアリーレン系化合物
WO2012015072A1 (ja) * 2010-07-28 2012-02-02 住友化学株式会社 高分子電解質組成物、高分子電解質および含硫黄複素環芳香族化合物
WO2017217628A1 (ko) * 2016-06-14 2017-12-21 충남대학교산학협력단 금속 나노입자-고분자 복합체 박막의 제조방법
CN111621208B (zh) * 2020-05-18 2021-11-05 江苏菲沃泰纳米科技股份有限公司 防水膜层及其制备方法、应用和产品

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4032440A (en) * 1975-11-18 1977-06-28 The United States Of America As Represented By The Secretary Of The Interior Semipermeable membrane
US4806246A (en) * 1986-04-11 1989-02-21 Applied Membrane Technology, Inc. Pore size control using plasma polymerization techniques
DE4234521C1 (de) * 1992-10-13 1994-02-24 Carbone Ag Verfahren zur Herstellung einer Komposit-Plasmamembran und ihre Verwendung
DE19901378A1 (de) * 1999-01-15 2000-07-20 Fraunhofer Ges Forschung Verfahren zur Herstellung einer Polymermembran, insbesondere einer Polymerelektrolytmembran für Methanol-Brennstoffzellen und eine solche Membran
DE19914571C2 (de) * 1999-03-31 2002-10-24 Joerg Mueller Verfahren zur Herstellung einer plasmapolymerisierten ionenleitenden Sperrschicht für Polymer-Elektrolytmembranen

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8277983B2 (en) 2002-09-13 2012-10-02 Basf Fuel Cell Gmbh Proton-conducting membrane and its use
US8716356B2 (en) 2002-09-13 2014-05-06 Basf Fuel Cell Gmbh Proton-conducting membrane and its use
WO2006003943A1 (ja) * 2004-06-30 2006-01-12 Tdk Corporation 直接アルコール型燃料電池及びその製造方法
US8652704B2 (en) 2004-06-30 2014-02-18 Tdk Corporation Direct alcohol fuel cell with cathode catalyst layer containing silver and method for producing the same

Also Published As

Publication number Publication date
EP1497882A2 (de) 2005-01-19
WO2003007411A3 (de) 2004-11-04
AU2002328339A1 (en) 2003-01-29
CN1610984A (zh) 2005-04-27
JP2005520001A (ja) 2005-07-07
WO2003007411A2 (de) 2003-01-23
DE10133738A1 (de) 2003-02-06
KR20040014572A (ko) 2004-02-14

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