CA2428255C - Onium salts and the use therof as latent acids - Google Patents
Onium salts and the use therof as latent acids Download PDFInfo
- Publication number
- CA2428255C CA2428255C CA002428255A CA2428255A CA2428255C CA 2428255 C CA2428255 C CA 2428255C CA 002428255 A CA002428255 A CA 002428255A CA 2428255 A CA2428255 A CA 2428255A CA 2428255 C CA2428255 C CA 2428255C
- Authority
- CA
- Canada
- Prior art keywords
- nr4r5
- substituted
- phenyl
- interrupted
- unsubstituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000002253 acid Substances 0.000 title claims abstract description 158
- 150000003839 salts Chemical class 0.000 title description 30
- 150000007513 acids Chemical class 0.000 title description 10
- -1 anthracyl Chemical group 0.000 claims abstract description 269
- 239000000203 mixture Substances 0.000 claims abstract description 155
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 132
- 150000001875 compounds Chemical class 0.000 claims abstract description 107
- 229920002120 photoresistant polymer Polymers 0.000 claims abstract description 51
- 125000001624 naphthyl group Chemical group 0.000 claims abstract description 45
- 125000001424 substituent group Chemical group 0.000 claims abstract description 45
- 230000009471 action Effects 0.000 claims abstract description 44
- 125000001072 heteroaryl group Chemical group 0.000 claims abstract description 42
- 125000005561 phenanthryl group Chemical group 0.000 claims abstract description 41
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 25
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims abstract description 21
- 125000004957 naphthylene group Chemical group 0.000 claims abstract description 12
- IFVTZJHWGZSXFD-UHFFFAOYSA-N biphenylene Chemical group C1=CC=C2C3=CC=CC=C3C2=C1 IFVTZJHWGZSXFD-UHFFFAOYSA-N 0.000 claims abstract description 11
- 125000006710 (C2-C12) alkenyl group Chemical group 0.000 claims abstract 2
- 150000002367 halogens Chemical group 0.000 claims description 95
- 229910052736 halogen Inorganic materials 0.000 claims description 94
- 229920000642 polymer Polymers 0.000 claims description 68
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- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 34
- 238000000034 method Methods 0.000 claims description 32
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- 238000006243 chemical reaction Methods 0.000 claims description 27
- 125000002088 tosyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1C([H])([H])[H])S(*)(=O)=O 0.000 claims description 27
- 229910052739 hydrogen Inorganic materials 0.000 claims description 25
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- 239000001257 hydrogen Substances 0.000 claims description 22
- 239000000758 substrate Substances 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 18
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- 238000004090 dissolution Methods 0.000 claims description 17
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 claims description 16
- 150000002431 hydrogen Chemical group 0.000 claims description 16
- 125000005146 naphthylsulfonyl group Chemical group C1(=CC=CC2=CC=CC=C12)S(=O)(=O)* 0.000 claims description 14
- 239000011230 binding agent Substances 0.000 claims description 13
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- 125000006527 (C1-C5) alkyl group Chemical group 0.000 claims description 8
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- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims 4
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 23
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 22
- 238000000746 purification Methods 0.000 description 22
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 21
- 238000005160 1H NMR spectroscopy Methods 0.000 description 20
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 20
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- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 description 10
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- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 9
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- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 8
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- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 6
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- FAYMLNNRGCYLSR-UHFFFAOYSA-M triphenylsulfonium triflate Chemical compound [O-]S(=O)(=O)C(F)(F)F.C1=CC=CC=C1[S+](C=1C=CC=CC=1)C1=CC=CC=C1 FAYMLNNRGCYLSR-UHFFFAOYSA-M 0.000 description 1
- WGKLOLBTFWFKOD-UHFFFAOYSA-N tris(2-nonylphenyl) phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC WGKLOLBTFWFKOD-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C07H9/00—Compounds containing a hetero ring sharing at least two hetero atoms with a saccharide radical
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- C07C25/00—Compounds containing at least one halogen atom bound to a six-membered aromatic ring
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- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C305/00—Esters of sulfuric acids
- C07C305/02—Esters of sulfuric acids having oxygen atoms of sulfate groups bound to acyclic carbon atoms of a carbon skeleton
- C07C305/04—Esters of sulfuric acids having oxygen atoms of sulfate groups bound to acyclic carbon atoms of a carbon skeleton being acyclic and saturated
- C07C305/06—Hydrogenosulfates
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- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C305/00—Esters of sulfuric acids
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C305/00—Esters of sulfuric acids
- C07C305/22—Esters of sulfuric acids having oxygen atoms of sulfate groups bound to carbon atoms of six-membered aromatic rings
- C07C305/24—Esters of sulfuric acids having oxygen atoms of sulfate groups bound to carbon atoms of six-membered aromatic rings of non-condensed six-membered aromatic rings
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C381/00—Compounds containing carbon and sulfur and having functional groups not covered by groups C07C301/00 - C07C337/00
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- C07D309/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings
- C07D309/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
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- C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
- C07D333/06—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring carbon atoms
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
- C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
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- G03F7/0045—Photosensitive materials with organic non-macromolecular light-sensitive compounds not otherwise provided for, e.g. dissolution inhibitors
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- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/11—Compounds covalently bound to a solid support
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
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- C40—COMBINATORIAL TECHNOLOGY
- C40B—COMBINATORIAL CHEMISTRY; LIBRARIES, e.g. CHEMICAL LIBRARIES
- C40B40/00—Libraries per se, e.g. arrays, mixtures
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- Y10S430/118—Initiator containing with inhibitor or stabilizer
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Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Physics & Mathematics (AREA)
- Biotechnology (AREA)
- Molecular Biology (AREA)
- Genetics & Genomics (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Materials For Photolithography (AREA)
- Plural Heterocyclic Compounds (AREA)
- Indole Compounds (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP00811147 | 2000-12-04 | ||
| EP00811147.8 | 2000-12-04 | ||
| EP01810551.0 | 2001-06-08 | ||
| EP01810551 | 2001-06-08 | ||
| PCT/EP2001/013725 WO2002046507A2 (en) | 2000-12-04 | 2001-11-26 | Onium salts and the use therof as latent acids |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2428255A1 CA2428255A1 (en) | 2002-06-13 |
| CA2428255C true CA2428255C (en) | 2010-01-05 |
Family
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Family Applications (1)
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|---|---|---|---|
| CA002428255A Expired - Fee Related CA2428255C (en) | 2000-12-04 | 2001-11-26 | Onium salts and the use therof as latent acids |
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| US (1) | US6929896B2 (enExample) |
| EP (1) | EP1344109B1 (enExample) |
| JP (1) | JP4294317B2 (enExample) |
| KR (1) | KR100862281B1 (enExample) |
| CN (1) | CN100383665C (enExample) |
| AT (1) | ATE394707T1 (enExample) |
| AU (1) | AU2002227945A1 (enExample) |
| BR (1) | BR0115944A (enExample) |
| CA (1) | CA2428255C (enExample) |
| DE (1) | DE60133929D1 (enExample) |
| MX (1) | MXPA03004958A (enExample) |
| WO (1) | WO2002046507A2 (enExample) |
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| EP1598704B1 (en) * | 2004-05-17 | 2009-12-02 | FUJIFILM Corporation | Pattern forming method |
| JP2008506826A (ja) * | 2004-07-21 | 2008-03-06 | チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド | 光活性化方法及び逆転した2段階工程による触媒の使用 |
| JP4152928B2 (ja) * | 2004-08-02 | 2008-09-17 | 株式会社シンク・ラボラトリー | ポジ型感光性組成物 |
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| JP4770244B2 (ja) * | 2005-04-11 | 2011-09-14 | Jsr株式会社 | オニウム塩、それを用いた感放射線性酸発生剤及びポジ型感放射線性樹脂組成物 |
| KR20080008354A (ko) * | 2005-05-11 | 2008-01-23 | 도오꾜오까고오교 가부시끼가이샤 | 네거티브형 레지스트 조성물 및 레지스트 패턴 형성 방법 |
| JP2007041200A (ja) * | 2005-08-02 | 2007-02-15 | Fujifilm Corp | ポジ型感光性組成物及びそれを用いたパターン形成方法 |
| JP5546763B2 (ja) | 2005-08-12 | 2014-07-09 | カンブリオス テクノロジーズ コーポレイション | ナノワイヤに基づく透明導電体 |
| US20070077452A1 (en) * | 2005-10-04 | 2007-04-05 | Jie Liu | Organic light emitting devices having latent activated layers and methods of fabricating the same |
| US20070176167A1 (en) * | 2006-01-27 | 2007-08-02 | General Electric Company | Method of making organic light emitting devices |
| GB0607668D0 (en) * | 2006-04-18 | 2006-05-31 | Riso Nat Lab | Use of decomposable vehicles or solvents in printing or coating compositions |
| WO2007124092A2 (en) | 2006-04-21 | 2007-11-01 | Cornell Research Foundation, Inc. | Photoacid generator compounds and compositions |
| US20080014117A1 (en) * | 2006-07-14 | 2008-01-17 | Questel Adhesives | Food sterilization dosage indicator |
| US8018568B2 (en) * | 2006-10-12 | 2011-09-13 | Cambrios Technologies Corporation | Nanowire-based transparent conductors and applications thereof |
| US8094247B2 (en) | 2006-10-12 | 2012-01-10 | Cambrios Technologies Corporation | Nanowire-based transparent conductors and applications thereof |
| GB0623936D0 (en) * | 2006-11-29 | 2007-01-10 | Univ Strathclyde | Polymers with transmission into the ultraviolet |
| WO2008131304A1 (en) | 2007-04-20 | 2008-10-30 | Cambrios Technologies Corporation | Composite transparent conductors and methods of forming the same |
| KR100908601B1 (ko) * | 2007-06-05 | 2009-07-21 | 제일모직주식회사 | 반사방지 하드마스크 조성물 및 이를 이용한 기판상 재료의패턴화 방법 |
| US9034556B2 (en) * | 2007-12-21 | 2015-05-19 | Tokyo Ohka Kogyo Co., Ltd. | Compound and method of producing the same, acid generator, resist composition and method of forming resist pattern |
| JP4703674B2 (ja) * | 2008-03-14 | 2011-06-15 | 富士フイルム株式会社 | レジスト組成物及びそれを用いたパターン形成方法 |
| US8163461B2 (en) * | 2008-04-09 | 2012-04-24 | Cornell Research Foundation, Inc. | Photoacid generator compounds and compositions |
| JP5746829B2 (ja) * | 2009-04-06 | 2015-07-08 | 富士フイルム株式会社 | 感活性光線性または感放射線性樹脂組成物及びそれを用いたパターン形成方法 |
| WO2010140547A1 (ja) * | 2009-06-02 | 2010-12-09 | 山本化成株式会社 | ヨードニウム系光重合開始剤、その製造方法およびこれを含有してなる光硬化性組成物 |
| CN102834936B (zh) | 2010-02-24 | 2015-05-20 | 凯博瑞奥斯技术公司 | 基于纳米线的透明导体及对其进行构图的方法 |
| JP5521996B2 (ja) * | 2010-11-19 | 2014-06-18 | 信越化学工業株式会社 | スルホニウム塩を含む高分子化合物、レジスト材料及びパターン形成方法、並びにスルホニウム塩単量体及びその製造方法 |
| CN103370304A (zh) * | 2011-02-23 | 2013-10-23 | 巴斯夫欧洲公司 | 硫酸锍、其制备及用途 |
| JP2013129649A (ja) * | 2011-11-22 | 2013-07-04 | Central Glass Co Ltd | 珪素化合物、縮合物およびそれを用いたレジスト組成物、ならびにそれを用いるパターン形成方法 |
| JP2013148878A (ja) * | 2011-12-19 | 2013-08-01 | Sumitomo Chemical Co Ltd | レジスト組成物 |
| JP6038284B2 (ja) * | 2012-04-19 | 2016-12-07 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | スルホニウム化合物、それらの製造および使用 |
| WO2016124493A1 (en) | 2015-02-02 | 2016-08-11 | Basf Se | Latent acids and their use |
| EP3590921A4 (en) | 2017-03-31 | 2021-01-13 | Daikin Industries, Ltd. | ALKYL SULPHATE ESTER OR SALT OF THE SAME |
| US11279814B2 (en) | 2017-03-31 | 2022-03-22 | Daikin Industries, Ltd. | Production method for fluoropolymer, surfactant for polymerization, and use of surfactant |
| JP7356282B2 (ja) * | 2018-08-01 | 2023-10-04 | 住友化学株式会社 | レジスト組成物及びレジストパターンの製造方法 |
| WO2025132334A1 (en) | 2023-12-19 | 2025-06-26 | Merck Patent Gmbh | Resists using pfas free pags |
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| BE728755R (fr) | 1968-02-28 | 1969-08-01 | Du Pont | Procédé de préparation de composés organiques non-saturés |
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| JP4262406B2 (ja) * | 1999-12-03 | 2009-05-13 | 東洋合成工業株式会社 | オニウム塩誘導体の製造方法 |
| US6620957B1 (en) * | 1999-12-03 | 2003-09-16 | Toyo Gosei Kogyo Co., Ltd. | Process for producing onium salt derivative and novel onium salt derivative |
| JP4161497B2 (ja) * | 1999-12-24 | 2008-10-08 | Jsr株式会社 | ネガ型感放射線性樹脂組成物 |
-
2001
- 2001-11-26 DE DE60133929T patent/DE60133929D1/de not_active Expired - Lifetime
- 2001-11-26 AT AT01989514T patent/ATE394707T1/de not_active IP Right Cessation
- 2001-11-26 KR KR1020037007500A patent/KR100862281B1/ko not_active Expired - Fee Related
- 2001-11-26 CA CA002428255A patent/CA2428255C/en not_active Expired - Fee Related
- 2001-11-26 AU AU2002227945A patent/AU2002227945A1/en not_active Abandoned
- 2001-11-26 MX MXPA03004958A patent/MXPA03004958A/es not_active Application Discontinuation
- 2001-11-26 US US10/432,263 patent/US6929896B2/en not_active Expired - Fee Related
- 2001-11-26 WO PCT/EP2001/013725 patent/WO2002046507A2/en not_active Ceased
- 2001-11-26 EP EP01989514A patent/EP1344109B1/en not_active Expired - Lifetime
- 2001-11-26 JP JP2002548218A patent/JP4294317B2/ja not_active Expired - Fee Related
- 2001-11-26 BR BR0115944-5A patent/BR0115944A/pt not_active Application Discontinuation
- 2001-11-26 CN CNB018200575A patent/CN100383665C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP1344109A2 (en) | 2003-09-17 |
| AU2002227945A1 (en) | 2002-06-18 |
| JP4294317B2 (ja) | 2009-07-08 |
| BR0115944A (pt) | 2003-12-23 |
| EP1344109B1 (en) | 2008-05-07 |
| CA2428255A1 (en) | 2002-06-13 |
| US6929896B2 (en) | 2005-08-16 |
| JP2004526984A (ja) | 2004-09-02 |
| US20040053158A1 (en) | 2004-03-18 |
| WO2002046507A2 (en) | 2002-06-13 |
| WO2002046507A3 (en) | 2002-09-26 |
| ATE394707T1 (de) | 2008-05-15 |
| KR100862281B1 (ko) | 2008-10-15 |
| CN100383665C (zh) | 2008-04-23 |
| DE60133929D1 (de) | 2008-06-19 |
| MXPA03004958A (es) | 2003-09-05 |
| CN1662853A (zh) | 2005-08-31 |
| KR20040024534A (ko) | 2004-03-20 |
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