CA2399975A1 - Process for purifying a liquid hydrocarbon fuel - Google Patents
Process for purifying a liquid hydrocarbon fuel Download PDFInfo
- Publication number
- CA2399975A1 CA2399975A1 CA002399975A CA2399975A CA2399975A1 CA 2399975 A1 CA2399975 A1 CA 2399975A1 CA 002399975 A CA002399975 A CA 002399975A CA 2399975 A CA2399975 A CA 2399975A CA 2399975 A1 CA2399975 A1 CA 2399975A1
- Authority
- CA
- Canada
- Prior art keywords
- membrane
- porous
- molecular weight
- fuel
- liquid hydrocarbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000446 fuel Substances 0.000 title claims abstract description 33
- 238000000034 method Methods 0.000 title claims abstract description 24
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 22
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 21
- 230000008569 process Effects 0.000 title claims abstract description 21
- 239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 20
- 239000007788 liquid Substances 0.000 title claims abstract description 17
- 239000012528 membrane Substances 0.000 claims abstract description 101
- 239000012466 permeate Substances 0.000 claims abstract description 20
- 239000013542 high molecular weight contaminant Substances 0.000 claims abstract description 15
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 15
- 238000001728 nano-filtration Methods 0.000 claims abstract description 14
- 239000012264 purified product Substances 0.000 claims abstract description 4
- -1 polysiloxane Polymers 0.000 claims description 20
- 229920001296 polysiloxane Polymers 0.000 claims description 14
- 238000000926 separation method Methods 0.000 claims description 12
- 239000000356 contaminant Substances 0.000 claims description 11
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 5
- 230000008901 benefit Effects 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 239000010949 copper Substances 0.000 claims description 5
- 230000004907 flux Effects 0.000 claims description 5
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 3
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 239000000758 substrate Substances 0.000 description 13
- 229920000642 polymer Polymers 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 239000002131 composite material Substances 0.000 description 7
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 6
- 238000004132 cross linking Methods 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- 239000004697 Polyetherimide Substances 0.000 description 4
- 150000001336 alkenes Chemical class 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229920001601 polyetherimide Polymers 0.000 description 4
- 238000000108 ultra-filtration Methods 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 239000003431 cross linking reagent Substances 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 125000001183 hydrocarbyl group Chemical group 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000003350 kerosene Substances 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 229920002239 polyacrylonitrile Polymers 0.000 description 3
- 239000012465 retentate Substances 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 239000002033 PVDF binder Substances 0.000 description 2
- 239000004962 Polyamide-imide Substances 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000002877 alkyl aryl group Chemical group 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 125000003710 aryl alkyl group Chemical group 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 238000001471 micro-filtration Methods 0.000 description 2
- 229920002492 poly(sulfone) Polymers 0.000 description 2
- 229920002312 polyamide-imide Polymers 0.000 description 2
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- 230000001012 protector Effects 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical class [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 150000002431 hydrogen Chemical group 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000004447 silicone coating Substances 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G31/00—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for
- C10G31/11—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for by dialysis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/144—Purification; Separation; Use of additives using membranes, e.g. selective permeation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP00200548 | 2000-02-17 | ||
| EP00200548.6 | 2000-02-17 | ||
| PCT/EP2001/001807 WO2001060949A1 (en) | 2000-02-17 | 2001-02-16 | Process for purifying a liquid hydrocarbon fuel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2399975A1 true CA2399975A1 (en) | 2001-08-23 |
Family
ID=8171035
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002399975A Abandoned CA2399975A1 (en) | 2000-02-17 | 2001-02-16 | Process for purifying a liquid hydrocarbon fuel |
| CA002399798A Abandoned CA2399798A1 (en) | 2000-02-17 | 2001-02-16 | Process for purifying a liquid hydrocarbon product |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002399798A Abandoned CA2399798A1 (en) | 2000-02-17 | 2001-02-16 | Process for purifying a liquid hydrocarbon product |
Country Status (15)
| Country | Link |
|---|---|
| US (2) | US20020007587A1 (enExample) |
| EP (2) | EP1255803A1 (enExample) |
| JP (2) | JP2003523449A (enExample) |
| KR (1) | KR100760719B1 (enExample) |
| CN (2) | CN1235844C (enExample) |
| AT (1) | ATE286495T1 (enExample) |
| AU (2) | AU764342B2 (enExample) |
| BR (2) | BR0107866B1 (enExample) |
| CA (2) | CA2399975A1 (enExample) |
| DE (1) | DE60108224T2 (enExample) |
| ES (1) | ES2231442T3 (enExample) |
| PL (1) | PL200197B1 (enExample) |
| RU (1) | RU2236394C2 (enExample) |
| WO (2) | WO2001060771A1 (enExample) |
| ZA (1) | ZA200206614B (enExample) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10260036B3 (de) * | 2002-12-19 | 2004-06-03 | Philipps-Universität Marburg | Verfahren zur Trennung von Polymersystemen und darin verwendete porenfreie Polymerfilme |
| MXPA05010976A (es) * | 2003-04-17 | 2005-11-28 | Shell Int Research | Proceso para separar cuerpos coloreados y/o contaminantes asfaltenicos de una mezcla de hidrocarburos. |
| AU2004285085A1 (en) * | 2003-11-04 | 2005-05-12 | Shell Internationale Research Maatschappij B.V. | Process for upgrading a liquid hydrocarbon stream with a non-porous or nano-filtration membrane |
| US8070859B2 (en) | 2004-02-25 | 2011-12-06 | Membrane Technology And Research, Inc. | Method for producing a non-porous membrane |
| CA2583393A1 (en) * | 2004-10-11 | 2006-04-20 | Shell Internationale Research Maatschappij B.V. | Process for separating colour bodies and/or asphalthenic contaminants from a hydrocarbon mixture |
| EP1812537A1 (en) * | 2004-10-11 | 2007-08-01 | Shell Internationale Research Maatschappij B.V. | Process to prepare a haze free oil |
| JP2009530072A (ja) * | 2006-03-16 | 2009-08-27 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 液体流から金属硫化物粒子を除去する方法及び装置 |
| US20080200696A1 (en) * | 2006-07-06 | 2008-08-21 | Miller Jeffrey T | Separation process using aromatic-selective polymeric membranes |
| WO2008074791A1 (en) * | 2006-12-20 | 2008-06-26 | Shell Internationale Research Maatschappij B.V. | Process for removing poly(propylene oxide) from propylene oxide by membrane separation |
| DE102007014603A1 (de) * | 2007-03-23 | 2008-09-25 | Basf Se | Verfahren des Transports einer aus einem Lagerbehälter entnommenen flüssigen Monomerenphase im Tank eines Tankwagens oder eines Tankschiffs |
| DE102007014606A1 (de) * | 2007-03-23 | 2008-09-25 | Basf Se | Verfahren zur Lagerung einer unter den Bedingungen der Lagerung flüssigen Monomerenphase |
| US8864996B2 (en) | 2007-08-28 | 2014-10-21 | Exxonmobil Research And Engineering Company | Reduction of conradson carbon residue and average boiling points utilizing high pressure ultrafiltration |
| US7736493B2 (en) | 2007-08-28 | 2010-06-15 | Exxonmobil Research And Engineering Company | Deasphalter unit throughput increase via resid membrane feed preparation |
| US8177965B2 (en) | 2007-08-28 | 2012-05-15 | Exxonmobil Research And Engineering Company | Enhancement of saturates content in heavy hydrocarbons utilizing ultrafiltration |
| US7815790B2 (en) | 2007-08-28 | 2010-10-19 | Exxonmobil Research And Engineering Company | Upgrade of visbroken residua products by ultrafiltration |
| US7867379B2 (en) | 2007-08-28 | 2011-01-11 | Exxonmobil Research And Engineering Company | Production of an upgraded stream from steam cracker tar by ultrafiltration |
| US7897828B2 (en) | 2007-08-28 | 2011-03-01 | Exxonmobile Research And Engineering Company | Process for separating a heavy oil feedstream into improved products |
| US7871510B2 (en) | 2007-08-28 | 2011-01-18 | Exxonmobil Research & Engineering Co. | Production of an enhanced resid coker feed using ultrafiltration |
| WO2012076532A1 (en) | 2010-12-08 | 2012-06-14 | Shell Internationale Research Maatschappij B.V. | Process for purifying aryl group containing carbonates |
| WO2012076519A1 (en) | 2010-12-08 | 2012-06-14 | Shell Internationale Research Maatschappij B.V. | Process for purifying dialkyl carbonate |
| CN102625397A (zh) * | 2011-01-31 | 2012-08-01 | 中兴通讯股份有限公司 | 切换方法及系统 |
| US20140187835A1 (en) * | 2012-12-28 | 2014-07-03 | Shell Oil Company | Process for the preparation of an olefinic product from an oxygenate |
| EP2938591A1 (en) * | 2012-12-28 | 2015-11-04 | Shell Internationale Research Maatschappij B.V. | Process for the preparation of an olefinic product comprising ethylene and/or propylene |
| EP2938590A1 (en) * | 2012-12-28 | 2015-11-04 | Shell Internationale Research Maatschappij B.V. | Process for the preparation of an olefinic product from an oxygenate |
| US20140282786A1 (en) | 2013-03-12 | 2014-09-18 | Time Warner Cable Enterprises Llc | Methods and apparatus for providing and uploading content to personalized network storage |
| TWI669317B (zh) * | 2014-09-22 | 2019-08-21 | 德商贏創德固賽有限責任公司 | 反應性單體的改良製造方法 |
| RU2622404C1 (ru) * | 2016-01-19 | 2017-06-15 | Публичное акционерное общество "СИБУР Холдинг" | Способ очистки жидких углеводородов от высокомолекулярных примесей |
| KR20210062642A (ko) * | 2018-10-01 | 2021-05-31 | 쉘 인터내셔날 리써취 마트샤피지 비.브이. | 나노여과에 의해 촉매 미립자를 제거하는 방법 |
| JP7609855B2 (ja) * | 2019-09-25 | 2025-01-07 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 噴射器堆積物を低減するためのプロセス |
| AU2021399910B2 (en) | 2020-12-17 | 2024-07-04 | Shell Internationale Research Maatschappij B.V. | Process for pre-treating renewable feedstocks |
| WO2023144294A1 (en) | 2022-01-28 | 2023-08-03 | Shell Internationale Research Maatschappij B.V. | Processes for polyether polyol purification and preparation |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1263845A (en) * | 1985-08-28 | 1989-12-12 | Oleh Kutowy | Method of removing substances from fossil derived, hydrocarbon liquids |
| CA2040798A1 (en) * | 1990-05-25 | 1991-11-26 | Dean T. Tsou | Facilitated liquid membranes for olefin/paraffin gas separations and related process |
| US5151182A (en) * | 1991-08-30 | 1992-09-29 | Membrane Products Kiryat Weizmann Ltd. | Polyphenylene oxide-derived membranes for separation in organic solvents |
| US5205934A (en) * | 1991-08-30 | 1993-04-27 | Membrane Products Kiryat Weitzman Ltd. | Silicone-derived solvent stable membranes |
| US5265734A (en) * | 1991-08-30 | 1993-11-30 | Membrane Products Kiryat Weitzman Ltd. | Silicon-derived solvent stable membranes |
| CA2198212A1 (en) * | 1994-09-28 | 1996-04-04 | John Scott Buchanan | Hydrocarbon conversion |
| US5785860A (en) * | 1996-09-13 | 1998-07-28 | University Of British Columbia | Upgrading heavy oil by ultrafiltration using ceramic membrane |
| JP3827818B2 (ja) * | 1997-07-03 | 2006-09-27 | ボッシュ・レックスロス株式会社 | 可変容量ピストンポンプの吐出量制御装置 |
| US6013852A (en) * | 1997-11-21 | 2000-01-11 | Shell Oil Company | Producing light olefins from a contaminated liquid hydrocarbon stream by means of thermal cracking |
| US5965015A (en) * | 1998-11-09 | 1999-10-12 | Whatman Inc. | Oil-water separator system with oleophobic fibrous filter |
-
2001
- 2001-02-16 ES ES01905792T patent/ES2231442T3/es not_active Expired - Lifetime
- 2001-02-16 AT AT01905792T patent/ATE286495T1/de not_active IP Right Cessation
- 2001-02-16 JP JP2001560321A patent/JP2003523449A/ja active Pending
- 2001-02-16 CA CA002399975A patent/CA2399975A1/en not_active Abandoned
- 2001-02-16 KR KR1020027010603A patent/KR100760719B1/ko not_active Expired - Fee Related
- 2001-02-16 WO PCT/EP2001/001808 patent/WO2001060771A1/en not_active Ceased
- 2001-02-16 EP EP01903781A patent/EP1255803A1/en not_active Withdrawn
- 2001-02-16 CN CNB018052177A patent/CN1235844C/zh not_active Expired - Fee Related
- 2001-02-16 PL PL357562A patent/PL200197B1/pl unknown
- 2001-02-16 AU AU33778/01A patent/AU764342B2/en not_active Ceased
- 2001-02-16 WO PCT/EP2001/001807 patent/WO2001060949A1/en not_active Ceased
- 2001-02-16 JP JP2001559826A patent/JP2004500381A/ja not_active Withdrawn
- 2001-02-16 CN CN01807966A patent/CN1422326A/zh active Pending
- 2001-02-16 DE DE60108224T patent/DE60108224T2/de not_active Expired - Lifetime
- 2001-02-16 CA CA002399798A patent/CA2399798A1/en not_active Abandoned
- 2001-02-16 AU AU31760/01A patent/AU3176001A/en not_active Abandoned
- 2001-02-16 BR BRPI0107866-6A patent/BR0107866B1/pt not_active IP Right Cessation
- 2001-02-16 BR BR0108466-6A patent/BR0108466A/pt not_active Application Discontinuation
- 2001-02-16 US US09/785,908 patent/US20020007587A1/en not_active Abandoned
- 2001-02-16 EP EP01905792A patent/EP1255717B1/en not_active Expired - Lifetime
- 2001-02-16 RU RU2002124871/04A patent/RU2236394C2/ru active
- 2001-10-09 US US09/785,125 patent/US6488856B2/en not_active Expired - Fee Related
-
2002
- 2002-08-19 ZA ZA200206614A patent/ZA200206614B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ES2231442T3 (es) | 2005-05-16 |
| AU3377801A (en) | 2001-08-27 |
| DE60108224D1 (de) | 2005-02-10 |
| WO2001060771A1 (en) | 2001-08-23 |
| RU2236394C2 (ru) | 2004-09-20 |
| CN1404464A (zh) | 2003-03-19 |
| CN1235844C (zh) | 2006-01-11 |
| ATE286495T1 (de) | 2005-01-15 |
| WO2001060771A8 (en) | 2003-04-24 |
| BR0107866A (pt) | 2002-11-05 |
| EP1255803A1 (en) | 2002-11-13 |
| PL200197B1 (pl) | 2008-12-31 |
| KR100760719B1 (ko) | 2007-10-04 |
| ZA200206614B (en) | 2003-03-13 |
| PL357562A1 (en) | 2004-07-26 |
| JP2003523449A (ja) | 2003-08-05 |
| AU764342B2 (en) | 2003-08-14 |
| KR20020075427A (ko) | 2002-10-04 |
| RU2002124871A (ru) | 2004-01-10 |
| US20020007587A1 (en) | 2002-01-24 |
| CA2399798A1 (en) | 2001-08-23 |
| AU3176001A (en) | 2001-08-27 |
| WO2001060949A1 (en) | 2001-08-23 |
| DE60108224T2 (de) | 2005-12-29 |
| EP1255717B1 (en) | 2005-01-05 |
| BR0107866B1 (pt) | 2011-11-29 |
| EP1255717A1 (en) | 2002-11-13 |
| US6488856B2 (en) | 2002-12-03 |
| US20020017490A1 (en) | 2002-02-14 |
| BR0108466A (pt) | 2002-12-03 |
| JP2004500381A (ja) | 2004-01-08 |
| CN1422326A (zh) | 2003-06-04 |
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