CA2387877C - Systemes catalyseurs et leur utilisation dans un procede de polymerisation - Google Patents
Systemes catalyseurs et leur utilisation dans un procede de polymerisation Download PDFInfo
- Publication number
- CA2387877C CA2387877C CA002387877A CA2387877A CA2387877C CA 2387877 C CA2387877 C CA 2387877C CA 002387877 A CA002387877 A CA 002387877A CA 2387877 A CA2387877 A CA 2387877A CA 2387877 C CA2387877 C CA 2387877C
- Authority
- CA
- Canada
- Prior art keywords
- group
- catalyst
- compound
- reactor
- polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/02—Anti-static agent incorporated into the catalyst
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
Abstract
La présente invention concerne des compositions de catalyseur comprenant un composé catalyseur de hafnium contenant le groupe 15, des compositions de catalyseur mélangées comprenant le composé catalyseur de hafnium contenant le groupe 15 et un composé catalyseur métallocène contenant un ligand volumineux, et les systèmes catalyseurs non supportés et supportés correspondants. L'invention concerne également un procédé de polymérisation d'oléfine(s) dans lequel sont utilisés ces systèmes, et les polymères obtenus.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/425,390 US6300438B1 (en) | 1999-10-22 | 1999-10-22 | Hafnium transition metal catalyst compounds, catalyst systems and their use in a polymerization process |
US09/425,390 | 1999-10-22 | ||
US09/428,576 | 1999-10-28 | ||
US09/428,576 US6271323B1 (en) | 1999-10-28 | 1999-10-28 | Mixed catalyst compounds, catalyst systems and their use in a polymerization process |
PCT/US2000/013310 WO2001030860A1 (fr) | 1999-10-22 | 2000-05-15 | Systemes catalyseurs et leur utilisation dans un procede de polymerisation |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2387877A1 CA2387877A1 (fr) | 2001-05-03 |
CA2387877C true CA2387877C (fr) | 2006-12-19 |
Family
ID=27026667
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002387877A Expired - Fee Related CA2387877C (fr) | 1999-10-22 | 2000-05-15 | Systemes catalyseurs et leur utilisation dans un procede de polymerisation |
Country Status (23)
Country | Link |
---|---|
EP (1) | EP1226191B1 (fr) |
JP (1) | JP3746234B2 (fr) |
KR (1) | KR100567304B1 (fr) |
CN (1) | CN1184242C (fr) |
AR (1) | AR025163A1 (fr) |
AT (1) | ATE299898T1 (fr) |
AU (1) | AU764962B2 (fr) |
BR (1) | BR0015241B1 (fr) |
CA (1) | CA2387877C (fr) |
CZ (1) | CZ20021401A3 (fr) |
DE (1) | DE60021405T2 (fr) |
EG (1) | EG22573A (fr) |
IL (1) | IL149174A0 (fr) |
MX (1) | MXPA02004000A (fr) |
MY (1) | MY126752A (fr) |
NO (1) | NO20021863L (fr) |
PL (1) | PL354578A1 (fr) |
RU (1) | RU2241717C2 (fr) |
SA (1) | SA00210261B1 (fr) |
SK (1) | SK5482002A3 (fr) |
TR (1) | TR200201083T2 (fr) |
TW (1) | TW538051B (fr) |
WO (1) | WO2001030860A1 (fr) |
Families Citing this family (61)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6281306B1 (en) * | 1999-12-16 | 2001-08-28 | Univation Technologies, Llc | Method of polymerization |
AU2002217907B2 (en) | 2000-12-04 | 2005-11-10 | Univation Technologies, Llc | Polimerization process |
US6605675B2 (en) * | 2000-12-04 | 2003-08-12 | Univation Technologies, Llc | Polymerization process |
AU2002246517A1 (en) | 2001-01-16 | 2002-08-12 | Exxonmobil Chemical Patents Inc. | Catalysts with at least two transition metal compounds and polymerization processes using them |
US6960635B2 (en) * | 2001-11-06 | 2005-11-01 | Dow Global Technologies Inc. | Isotactic propylene copolymers, their preparation and use |
US7094848B2 (en) | 2003-05-13 | 2006-08-22 | Exxonmobil Chemical Patents Inc. | Olefin polymerization catalyst system |
US7045583B2 (en) | 2003-12-22 | 2006-05-16 | Exxon Mobil Chemical Patents Inc. | Olefin polymerization catalyst system |
EP1805226A1 (fr) | 2004-10-29 | 2007-07-11 | Exxonmobil Chemical Patents Inc. | Compose catalytique contenant un ligand tridente divalent |
US7323526B2 (en) * | 2005-07-29 | 2008-01-29 | Univation Technologies, Llc | Supported metallocene-alkyl catalyst composition |
EP1803747A1 (fr) * | 2005-12-30 | 2007-07-04 | Borealis Technology Oy | Catalyseur de polymérisation à surface modifiée pour réduire la formation de gels dans des films |
JP5676106B2 (ja) * | 2006-11-14 | 2015-02-25 | ユニベーション・テクノロジーズ・エルエルシー | 触媒系及び重合方法 |
KR20100015391A (ko) | 2007-03-07 | 2010-02-12 | 다우 글로벌 테크놀로지스 인크. | 테더링된 담지 전이 금속 착체 |
TW200936619A (en) | 2007-11-15 | 2009-09-01 | Univation Tech Llc | Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom |
CN102712701A (zh) | 2009-12-07 | 2012-10-03 | 尤尼威蒂恩技术有限责任公司 | 减少催化剂的静电荷的方法和使用该催化剂生产聚烯烃的方法 |
CN102803308B (zh) | 2010-02-18 | 2015-04-01 | 尤尼威蒂恩技术有限公司 | 用于操作聚合反应器的方法 |
MY162328A (en) | 2010-02-22 | 2017-05-31 | Univation Tech Llc | Catalyst systems and methods for using same to produce polyolefin products |
EP2558531B1 (fr) | 2010-04-13 | 2017-02-15 | Univation Technologies, LLC | Mélanges de polymères et des films réalisés |
EP2593217B1 (fr) | 2010-07-16 | 2014-07-02 | Univation Technologies, LLC | Systèmes et procédés de mesure d'accumulation de particules sur les surfaces d'un réacteur |
WO2012009215A1 (fr) | 2010-07-16 | 2012-01-19 | Univation Technologies, Llc | Systèmes et procédés pour mesurer la charge statique portée par des particules |
WO2012015898A1 (fr) | 2010-07-28 | 2012-02-02 | Univation Technologies, Llc | Systèmes et procédés pour mesurer la vitesse d'un mélange particule/fluide |
EP2646480B1 (fr) | 2010-11-30 | 2016-04-13 | Univation Technologies, LLC | Procédés pour la polymérisation d'oléfines avec des sels carboxylate de métal extraits |
BR112013012545B1 (pt) | 2010-11-30 | 2020-04-14 | Univation Tech Llc | composição catalisadora, processo de produção de uma composição catalisadora e processo de polimerização |
RU2589055C2 (ru) | 2010-12-17 | 2016-07-10 | Юнивейшн Текнолоджиз, Ллк | Системы и способы выделения углеводородов из содержащего полиолефины газообразного продукта продувки |
CN103347905B (zh) | 2010-12-22 | 2015-12-16 | 尤尼威蒂恩技术有限责任公司 | 用于聚烯烃聚合方法的添加剂 |
RU2598023C2 (ru) | 2011-05-13 | 2016-09-20 | Юнивейшн Текнолоджиз, Ллк | Полученные распылительной сушкой каталитические композиции и способы полимеризации, в которых они применяются |
WO2013028283A1 (fr) | 2011-08-19 | 2013-02-28 | Univation Technologies, Llc | Systèmes de catalyseur et leurs procédés d'utilisation pour la production de produits de polyoléfine |
EP2750797B1 (fr) | 2011-11-08 | 2020-04-01 | Univation Technologies, LLC | Procédés de préparation d'un système catalyseur |
WO2013070602A1 (fr) | 2011-11-08 | 2013-05-16 | Univation Technologies, Llc | Procédés pour la production de polyoléfines avec des systèmes de catalyseur |
US10280283B2 (en) | 2012-12-28 | 2019-05-07 | Univation Technologies, Llc | Supported catalyst with improved flowability |
CN105189566A (zh) | 2013-01-30 | 2015-12-23 | 尤尼威蒂恩技术有限责任公司 | 制造具有改进的流动的催化剂组合物的方法 |
ES2949819T3 (es) | 2013-02-07 | 2023-10-03 | Univation Tech Llc | Preparación de poliolefina |
ES2644669T3 (es) | 2013-03-15 | 2017-11-29 | Univation Technologies, Llc | Ligandos para catalizadores |
US9644053B2 (en) | 2013-03-15 | 2017-05-09 | Univation Technologies, Llc | Tridentate nitrogen based ligands for olefin polymerisation catalysts |
WO2014149360A1 (fr) | 2013-03-15 | 2014-09-25 | Univation Technologies, Llc | Système de catalyseur multiple comprenant des métallocènes et des complexes de ligand à base d'azote tridentate pour la polymérisation des oléfines |
BR112015029498B1 (pt) | 2013-06-05 | 2020-10-27 | Univation Technologies, Llc | método para proteger um grupo fenol em um composto precursor e método para gerar um polímero de polietileno |
EP3663323B1 (fr) * | 2014-02-11 | 2024-03-20 | Univation Technologies, LLC | Production de produits de polyoléfines |
CA2943378C (fr) | 2014-04-02 | 2023-09-12 | Univation Technologies, Llc | Compositions de continuite et leurs procedes de fabrication et d'utilisation |
SG11201701265UA (en) | 2014-08-19 | 2017-03-30 | Univation Tech Llc | Fluorinated catalyst supports and catalyst systems |
BR112017003170B1 (pt) | 2014-08-19 | 2022-02-15 | Univation Technologies, Llc | Método para fazer um suporte de catalisador de alumina-sílica fluorado e sistema de catalisador de alumina-sílica fluorado |
CN106794455B (zh) | 2014-08-19 | 2020-09-04 | 尤尼威蒂恩技术有限责任公司 | 氟化催化剂载体和催化剂系统 |
US10471641B2 (en) | 2015-01-21 | 2019-11-12 | Univation Technologies, Llc | Methods for controlling polymer chain scission |
CN107107433B (zh) | 2015-01-21 | 2019-09-13 | 尤尼威蒂恩技术有限责任公司 | 用于聚烯烃中的凝胶减少的方法 |
SG11201707037TA (en) | 2015-03-10 | 2017-09-28 | Univation Tech Llc | Spray dried catalyst compositions, methods for preparation and use in olefin polymerization processes |
US10221254B2 (en) | 2015-04-08 | 2019-03-05 | Univation Technologies, Llc | Closed reactor transitions between metallocene catalysts |
CA2982569A1 (fr) | 2015-04-17 | 2016-10-20 | Univation Technologies, Llc | Procedes et systemes permettant la polymerisation d'olefines |
SG11201708341WA (en) | 2015-04-17 | 2017-11-29 | Univation Tech Llc | Producing polyolefin products |
US10533063B2 (en) | 2015-04-20 | 2020-01-14 | Exxonmobil Chemical Patents Inc. | Supported catalyst systems and processes for use thereof |
US10519256B2 (en) | 2015-04-27 | 2019-12-31 | Univation Technologies, Llc | Supported catalyst compositions having improved flow properties and preparation thereof |
WO2018151903A1 (fr) | 2017-02-20 | 2018-08-23 | Exxonmobil Chemical Patents Inc. | Systèmes catalytiques supportés et leurs procédés d'utilisation |
CN111094366B (zh) | 2017-08-04 | 2022-06-24 | 埃克森美孚化学专利公司 | 聚乙烯组合物和由其制备的膜 |
US11414436B2 (en) | 2018-04-26 | 2022-08-16 | Exxonmobil Chemical Patents Inc. | Non-coordinating anion type activators containing cation having large alkyl groups |
WO2019246069A1 (fr) | 2018-06-19 | 2019-12-26 | Exxonmobil Chemical Patents Inc. | Compositions de polyéthylène et films préparés à partir de celles-ci |
CN109174190B (zh) * | 2018-09-17 | 2021-06-08 | 天津科技大学 | 用于乙烯选择性齐聚的催化剂体系 |
KR102547229B1 (ko) * | 2019-10-16 | 2023-06-26 | 한화솔루션 주식회사 | 올레핀 중합용 혼성 촉매의 제조방법, 올레핀 중합용 혼성 촉매 및 올레핀계 중합체 |
WO2021119089A1 (fr) | 2019-12-11 | 2021-06-17 | Exxonmobil Chemical Patents Inc. | Procédés d'introduction d'activateurs liquides dans des réactions de polymérisation d'oléfines |
WO2021126523A1 (fr) | 2019-12-19 | 2021-06-24 | Exxonmobil Chemical Patents Inc. | Production d'un copolymère de polypropylène résistant aux chocs à l'aide de catalyseurs métallocène et ziegler-natta dans des réacteurs parallèles |
WO2021194831A1 (fr) | 2020-03-25 | 2021-09-30 | Exxonmobil Chemical Patents Inc. | Alkylation de complexes de catalyseurs de coordination de métal de transition |
WO2021262838A1 (fr) | 2020-06-26 | 2021-12-30 | Exxonmobil Chemical Patents Inc. | Copolymères constitués d'éthylène, d'alpha-oléfine, de diène non conjugué et de styrène substitué et articles fabriqués à partir de ceux-ci |
WO2021262842A1 (fr) | 2020-06-26 | 2021-12-30 | Exxonmobil Chemical Patents Inc. | COPOLYMERS D'ÉTHYLÈNE, α-OLÉFINE, DIÈNE NON CONJUGUÉ, ET CYCLOALCÈNE ARYL-SUBSTITUÉ, PROCÉDÉ DE PRODUCTION, MÉLANGES ET ARTICLES OBTENUS À PARTIR DE CEUX-CI |
CN116209683A (zh) | 2020-08-10 | 2023-06-02 | 埃克森美孚化学专利公司 | 向聚合反应器递送非芳族溶液的方法 |
CN113816981B (zh) * | 2021-09-15 | 2023-06-02 | 惠生(中国)投资有限公司 | 一种双核含氮配体ivb过渡金属配合物及其在烯烃高温聚合中的用途 |
Family Cites Families (5)
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EP0569388B1 (fr) * | 1990-12-27 | 1996-03-13 | Exxon Chemical Patents Inc. | Compose amido de metal de transition et systeme catalytique de production de polypropylene isotactique |
US6451938B1 (en) * | 1997-02-25 | 2002-09-17 | Exxon Mobil Chemical Patents Inc. | Polymerization catalyst system comprising heterocyclic fused cyclopentadienide ligands |
TWI246520B (en) * | 1997-04-25 | 2006-01-01 | Mitsui Chemicals Inc | Processes for olefin polymerization |
US6242545B1 (en) * | 1997-12-08 | 2001-06-05 | Univation Technologies | Polymerization catalyst systems comprising substituted hafinocenes |
US6291609B1 (en) * | 1998-03-04 | 2001-09-18 | Exxonmobil Chemical Patents Inc. | High temperature olefin polymerization process |
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2000
- 2000-05-15 TW TW089109283A patent/TW538051B/zh not_active IP Right Cessation
- 2000-05-15 SK SK548-2002A patent/SK5482002A3/sk unknown
- 2000-05-15 AT AT00935968T patent/ATE299898T1/de not_active IP Right Cessation
- 2000-05-15 AR ARP000102337A patent/AR025163A1/es not_active Application Discontinuation
- 2000-05-15 MX MXPA02004000A patent/MXPA02004000A/es active IP Right Grant
- 2000-05-15 RU RU2002112853/04A patent/RU2241717C2/ru active
- 2000-05-15 TR TR2002/01083T patent/TR200201083T2/xx unknown
- 2000-05-15 KR KR1020027005179A patent/KR100567304B1/ko not_active IP Right Cessation
- 2000-05-15 CA CA002387877A patent/CA2387877C/fr not_active Expired - Fee Related
- 2000-05-15 IL IL14917400A patent/IL149174A0/xx unknown
- 2000-05-15 PL PL00354578A patent/PL354578A1/xx not_active Application Discontinuation
- 2000-05-15 MY MYPI20002112A patent/MY126752A/en unknown
- 2000-05-15 CZ CZ20021401A patent/CZ20021401A3/cs unknown
- 2000-05-15 CN CNB008145288A patent/CN1184242C/zh not_active Expired - Fee Related
- 2000-05-15 JP JP2001533856A patent/JP3746234B2/ja not_active Expired - Fee Related
- 2000-05-15 AU AU51348/00A patent/AU764962B2/en not_active Ceased
- 2000-05-15 EG EG20000625A patent/EG22573A/xx active
- 2000-05-15 BR BRPI0015241-2A patent/BR0015241B1/pt not_active IP Right Cessation
- 2000-05-15 DE DE60021405T patent/DE60021405T2/de not_active Expired - Lifetime
- 2000-05-15 WO PCT/US2000/013310 patent/WO2001030860A1/fr active IP Right Grant
- 2000-05-15 EP EP00935968A patent/EP1226191B1/fr not_active Expired - Lifetime
- 2000-07-25 SA SA00210261A patent/SA00210261B1/ar unknown
-
2002
- 2002-04-19 NO NO20021863A patent/NO20021863L/no not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
AU5134800A (en) | 2001-05-08 |
AR025163A1 (es) | 2002-11-13 |
EP1226191A1 (fr) | 2002-07-31 |
BR0015241B1 (pt) | 2010-10-05 |
CA2387877A1 (fr) | 2001-05-03 |
ATE299898T1 (de) | 2005-08-15 |
CZ20021401A3 (cs) | 2002-10-16 |
WO2001030860A1 (fr) | 2001-05-03 |
TR200201083T2 (tr) | 2002-10-21 |
SK5482002A3 (en) | 2003-02-04 |
RU2241717C2 (ru) | 2004-12-10 |
KR20020081207A (ko) | 2002-10-26 |
DE60021405T2 (de) | 2006-05-18 |
MXPA02004000A (es) | 2002-10-23 |
SA00210261B1 (ar) | 2005-11-23 |
MY126752A (en) | 2006-10-31 |
NO20021863L (no) | 2002-06-21 |
CN1382162A (zh) | 2002-11-27 |
TW538051B (en) | 2003-06-21 |
BR0015241A (pt) | 2002-12-24 |
IL149174A0 (en) | 2002-11-10 |
JP2003513113A (ja) | 2003-04-08 |
DE60021405D1 (de) | 2005-08-25 |
EP1226191B1 (fr) | 2005-07-20 |
NO20021863D0 (no) | 2002-04-19 |
PL354578A1 (en) | 2004-01-26 |
RU2002112853A (ru) | 2004-01-20 |
CN1184242C (zh) | 2005-01-12 |
KR100567304B1 (ko) | 2006-04-04 |
JP3746234B2 (ja) | 2006-02-15 |
EG22573A (en) | 2003-04-30 |
AU764962B2 (en) | 2003-09-04 |
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