CA2189018C - Improvements relating to antimicrobial cleaning compositions - Google Patents
Improvements relating to antimicrobial cleaning compositions Download PDFInfo
- Publication number
- CA2189018C CA2189018C CA002189018A CA2189018A CA2189018C CA 2189018 C CA2189018 C CA 2189018C CA 002189018 A CA002189018 A CA 002189018A CA 2189018 A CA2189018 A CA 2189018A CA 2189018 C CA2189018 C CA 2189018C
- Authority
- CA
- Canada
- Prior art keywords
- composition according
- ortho
- nonionic surfactant
- acid
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 82
- 230000000845 anti-microbial effect Effects 0.000 title claims description 8
- 238000004140 cleaning Methods 0.000 title claims description 7
- 230000006872 improvement Effects 0.000 title description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical class OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims abstract description 63
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 30
- 229960004889 salicylic acid Drugs 0.000 claims abstract description 24
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims abstract description 23
- 150000001298 alcohols Chemical class 0.000 claims abstract description 19
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 12
- 230000000249 desinfective effect Effects 0.000 claims abstract description 6
- 239000002253 acid Substances 0.000 claims description 27
- 239000003752 hydrotrope Substances 0.000 claims description 18
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims description 13
- 229910052783 alkali metal Inorganic materials 0.000 claims description 8
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 8
- 125000001931 aliphatic group Chemical group 0.000 claims description 7
- 150000001340 alkali metals Chemical class 0.000 claims description 7
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 claims description 7
- 238000007046 ethoxylation reaction Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 125000001424 substituent group Chemical group 0.000 claims description 6
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 5
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims description 5
- 229960003237 betaine Drugs 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 3
- 239000004599 antimicrobial Substances 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 abstract description 24
- 238000009472 formulation Methods 0.000 abstract description 21
- 230000003115 biocidal effect Effects 0.000 abstract description 8
- -1 class of aromatic organic acids Chemical class 0.000 abstract description 8
- 235000005985 organic acids Nutrition 0.000 abstract description 8
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 27
- 239000000047 product Substances 0.000 description 26
- 229920000642 polymer Polymers 0.000 description 22
- 150000007513 acids Chemical class 0.000 description 10
- 125000000217 alkyl group Chemical group 0.000 description 10
- 241000894006 Bacteria Species 0.000 description 9
- 239000003945 anionic surfactant Substances 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 8
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 7
- 229960001860 salicylate Drugs 0.000 description 7
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 6
- 230000008901 benefit Effects 0.000 description 6
- 239000000725 suspension Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- PTHBKNSHSCMKBV-UHFFFAOYSA-N 4,6,8-trihydroxy-3-(2-hydroxyethyl)-2,3-dihydronaphtho[2,3-f][1]benzofuran-5,10-dione Chemical compound O=C1C2=CC(O)=CC(O)=C2C(=O)C2=C1C=C1OCC(CCO)C1=C2O PTHBKNSHSCMKBV-UHFFFAOYSA-N 0.000 description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 150000007524 organic acids Chemical class 0.000 description 5
- 239000002304 perfume Substances 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- PTHBKNSHSCMKBV-ZETCQYMHSA-N versicol Natural products OCC[C@H]1COc2cc3C(=O)c4cc(O)cc(O)c4C(=O)c3c(O)c12 PTHBKNSHSCMKBV-ZETCQYMHSA-N 0.000 description 4
- 229920001817 Agar Polymers 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000008272 agar Substances 0.000 description 3
- 229920006318 anionic polymer Polymers 0.000 description 3
- 230000001580 bacterial effect Effects 0.000 description 3
- 239000003139 biocide Substances 0.000 description 3
- 239000000872 buffer Substances 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- DVEKCXOJTLDBFE-UHFFFAOYSA-O carboxymethyl-dodecyl-dimethylazanium Chemical compound CCCCCCCCCCCC[N+](C)(C)CC(O)=O DVEKCXOJTLDBFE-UHFFFAOYSA-O 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000000645 desinfectant Substances 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- 230000001627 detrimental effect Effects 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 239000012085 test solution Substances 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- JBVOQKNLGSOPNZ-UHFFFAOYSA-N 2-propan-2-ylbenzenesulfonic acid Chemical class CC(C)C1=CC=CC=C1S(O)(=O)=O JBVOQKNLGSOPNZ-UHFFFAOYSA-N 0.000 description 2
- WHSXTWFYRGOBGO-UHFFFAOYSA-N 3-methylsalicylic acid Chemical compound CC1=CC=CC(C(O)=O)=C1O WHSXTWFYRGOBGO-UHFFFAOYSA-N 0.000 description 2
- 208000001840 Dandruff Diseases 0.000 description 2
- 241000194031 Enterococcus faecium Species 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000001888 Peptone Substances 0.000 description 2
- 108010080698 Peptones Proteins 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 230000002779 inactivation Effects 0.000 description 2
- 239000002085 irritant Substances 0.000 description 2
- 231100000021 irritant Toxicity 0.000 description 2
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 2
- 235000015097 nutrients Nutrition 0.000 description 2
- 235000019319 peptone Nutrition 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- SIXNTGDWLSRMIC-UHFFFAOYSA-N sodium;toluene Chemical compound [Na].CC1=CC=CC=C1 SIXNTGDWLSRMIC-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- IOHPVZBSOKLVMN-UHFFFAOYSA-N 2-(2-phenylethyl)benzoic acid Chemical compound OC(=O)C1=CC=CC=C1CCC1=CC=CC=C1 IOHPVZBSOKLVMN-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- LODHFNUFVRVKTH-ZHACJKMWSA-N 2-hydroxy-n'-[(e)-3-phenylprop-2-enoyl]benzohydrazide Chemical compound OC1=CC=CC=C1C(=O)NNC(=O)\C=C\C1=CC=CC=C1 LODHFNUFVRVKTH-ZHACJKMWSA-N 0.000 description 1
- NJESAXZANHETJV-UHFFFAOYSA-N 4-methylsalicylic acid Chemical compound CC1=CC=C(C(O)=O)C(O)=C1 NJESAXZANHETJV-UHFFFAOYSA-N 0.000 description 1
- ZOLACKDSSUBCNN-UHFFFAOYSA-N 5,6-dimethylcyclohexa-2,4-diene-1-carboxylic acid Chemical class CC1C(C(O)=O)C=CC=C1C ZOLACKDSSUBCNN-UHFFFAOYSA-N 0.000 description 1
- 208000002874 Acne Vulgaris Diseases 0.000 description 1
- DHMQDGOQFOQNFH-UHFFFAOYSA-M Aminoacetate Chemical compound NCC([O-])=O DHMQDGOQFOQNFH-UHFFFAOYSA-M 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 241000192125 Firmicutes Species 0.000 description 1
- 101000740205 Homo sapiens Sal-like protein 1 Proteins 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 244000131360 Morinda citrifolia Species 0.000 description 1
- IZWSFJTYBVKZNK-UHFFFAOYSA-O N-dodecyl-N,N-dimethyl-3-ammonio-1-propanesulfonic acid Chemical compound CCCCCCCCCCCC[N+](C)(C)CCCS(O)(=O)=O IZWSFJTYBVKZNK-UHFFFAOYSA-O 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 241001103617 Pseudomonas aeruginosa ATCC 15442 Species 0.000 description 1
- 102100037204 Sal-like protein 1 Human genes 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 206010000496 acne Diseases 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000001857 anti-mycotic effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000000721 bacterilogical effect Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 239000001045 blue dye Substances 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 229940096386 coconut alcohol Drugs 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 231100001010 corrosive Toxicity 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000012258 culturing Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 239000008121 dextrose Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 230000033444 hydroxylation Effects 0.000 description 1
- 238000005805 hydroxylation reaction Methods 0.000 description 1
- 238000011534 incubation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000003410 keratolytic agent Substances 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- GPSDUZXPYCFOSQ-UHFFFAOYSA-N m-toluenecarboxylic acid Natural products CC1=CC=CC(C(O)=O)=C1 GPSDUZXPYCFOSQ-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- ISTASGAHDLTQRU-UHFFFAOYSA-N n-(2-hydroxyethyl)undec-10-enamide Chemical compound OCCNC(=O)CCCCCCCCC=C ISTASGAHDLTQRU-UHFFFAOYSA-N 0.000 description 1
- XKLJHFLUAHKGGU-UHFFFAOYSA-N nitrous amide Chemical compound ON=N XKLJHFLUAHKGGU-UHFFFAOYSA-N 0.000 description 1
- 235000017524 noni Nutrition 0.000 description 1
- 239000006916 nutrient agar Substances 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- NIXKBAZVOQAHGC-UHFFFAOYSA-N phenylmethanesulfonic acid Chemical class OS(=O)(=O)CC1=CC=CC=C1 NIXKBAZVOQAHGC-UHFFFAOYSA-N 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 239000008363 phosphate buffer Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920000141 poly(maleic anhydride) Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 229940058287 salicylic acid derivative anticestodals Drugs 0.000 description 1
- 150000003872 salicylic acid derivatives Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 238000013207 serial dilution Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- GIPRGFRQMWSHAK-UHFFFAOYSA-M sodium;2-propan-2-ylbenzenesulfonate Chemical class [Na+].CC(C)C1=CC=CC=C1S([O-])(=O)=O GIPRGFRQMWSHAK-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- WSWCOQWTEOXDQX-MQQKCMAXSA-N sorbic acid group Chemical group C(\C=C\C=C\C)(=O)O WSWCOQWTEOXDQX-MQQKCMAXSA-N 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Emergency Medicine (AREA)
- Health & Medical Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Detergent Compositions (AREA)
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9412356.9 | 1994-06-20 | ||
| GB9412356A GB9412356D0 (en) | 1994-06-20 | 1994-06-20 | Cleaning composition |
| GB9419379.4 | 1994-09-26 | ||
| GB9419379A GB9419379D0 (en) | 1994-09-26 | 1994-09-26 | Hygiene composition |
| GB9424895.2 | 1994-12-09 | ||
| GBGB9424895.2A GB9424895D0 (en) | 1994-12-09 | 1994-12-09 | Cleaning composition |
| GBGB9504827.8A GB9504827D0 (en) | 1995-03-10 | 1995-03-10 | Disinfecting composition |
| GB9504827.8 | 1995-03-10 | ||
| PCT/EP1995/002090 WO1995035364A1 (en) | 1994-06-20 | 1995-06-01 | Improvements relating to antimicrobial cleaning compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2189018A1 CA2189018A1 (en) | 1995-12-28 |
| CA2189018C true CA2189018C (en) | 2001-01-02 |
Family
ID=27451177
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002189018A Expired - Lifetime CA2189018C (en) | 1994-06-20 | 1995-06-01 | Improvements relating to antimicrobial cleaning compositions |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US5631218A (en, 2012) |
| EP (1) | EP0766729B1 (en, 2012) |
| JP (1) | JP4098358B2 (en, 2012) |
| CN (1) | CN1151180A (en, 2012) |
| AT (1) | ATE186326T1 (en, 2012) |
| AU (1) | AU2673395A (en, 2012) |
| BR (1) | BR9508088A (en, 2012) |
| CA (1) | CA2189018C (en, 2012) |
| DE (1) | DE69513170T2 (en, 2012) |
| ES (1) | ES2139903T3 (en, 2012) |
| GR (1) | GR3032563T3 (en, 2012) |
| HU (1) | HU221137B1 (en, 2012) |
| MY (1) | MY113176A (en, 2012) |
| PL (1) | PL181005B1 (en, 2012) |
| TW (1) | TW304206B (en, 2012) |
| WO (1) | WO1995035364A1 (en, 2012) |
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|---|---|---|---|---|
| DE19525821A1 (de) * | 1995-07-15 | 1997-01-16 | Wella Ag | Haarbehandlungsmittel sowie Verfahren zu dessen Herstellung |
| US6210695B1 (en) | 1997-06-04 | 2001-04-03 | The Procter & Gamble Company | Leave-on antimicrobial compositions |
| US6214363B1 (en) | 1997-11-12 | 2001-04-10 | The Procter & Gamble Company | Liquid antimicrobial cleansing compositions which provide residual benefit versus gram negative bacteria |
| US6183757B1 (en) | 1997-06-04 | 2001-02-06 | Procter & Gamble Company | Mild, rinse-off antimicrobial cleansing compositions which provide improved immediate germ reduction during washing |
| US6190675B1 (en) | 1997-06-04 | 2001-02-20 | Procter & Gamble Company | Mild, rinse-off antimicrobial liquid cleansing compositions which provide improved residual benefit versus gram positive bacteria |
| US6284259B1 (en) | 1997-11-12 | 2001-09-04 | The Procter & Gamble Company | Antimicrobial wipes which provide improved residual benefit versus Gram positive bacteria |
| US6197315B1 (en) | 1997-06-04 | 2001-03-06 | Procter & Gamble Company | Antimicrobial wipes which provide improved residual benefit versus gram negative bacteria |
| US6183763B1 (en) | 1997-06-04 | 2001-02-06 | Procter & Gamble Company | Antimicrobial wipes which provide improved immediate germ reduction |
| US6287577B1 (en) | 1997-11-12 | 2001-09-11 | The Procter & Gamble Company | Leave-on antimicrobial compositions which provide improved residual benefit versus gram positive bacteria |
| US6190674B1 (en) | 1997-06-04 | 2001-02-20 | Procter & Gamble Company | Liquid antimicrobial cleansing compositions |
| US5968539A (en) * | 1997-06-04 | 1999-10-19 | Procter & Gamble Company | Mild, rinse-off antimicrobial liquid cleansing compositions which provide residual benefit versus gram negative bacteria |
| US6287583B1 (en) | 1997-11-12 | 2001-09-11 | The Procter & Gamble Company | Low-pH, acid-containing personal care compositions which exhibit reduced sting |
| DE19753982A1 (de) * | 1997-12-05 | 1999-06-10 | Henkel Kgaa | Geschirrspülmittel mit antibakterieller Wirkung |
| CA2316363C (en) * | 1997-12-23 | 2004-12-21 | Albright & Wilson Uk Limited | Biocidal compositions and treatments |
| US6444710B1 (en) | 1998-10-27 | 2002-09-03 | Alcon Manufacturing, Ltd. | Use of certain fatty acid/amino acid soaps to enhance antimicrobial effectiveness of topically administrable pharmaceutical compositions |
| US6146622A (en) * | 1998-10-27 | 2000-11-14 | Alcon Laboratories, Inc. | Use of certain anionic amino acid based surfactants to enhance antimicrobial effectiveness of topically administrable pharmaceutical compositions |
| CA2340225A1 (en) | 1998-10-27 | 2000-05-04 | Wesley Wehsin Han | Preservative system for topically administrable pharmaceutical compositions containing a fatty acid/amino acid soap |
| DE69913559T2 (de) | 1998-10-27 | 2004-11-11 | Alcon Manufacturing Ltd., Fort Worth | Konservierungssystem für topisch verabreichbare pharmazeutische zusammensetzungen |
| EP1110452A1 (de) * | 1999-12-21 | 2001-06-27 | Chemische Fabrik Dr. Weigert GmbH & Co. KG. | Desinfektionsmittelkonzentrat |
| US6436885B2 (en) | 2000-01-20 | 2002-08-20 | The Procter & Gamble Company | Antimicrobial cleansing compositions containing 2-pyrrolidone-5-carboxylic acid |
| WO2001053444A1 (en) * | 2000-01-20 | 2001-07-26 | The Procter & Gamble Company | Antimicrobial compositions |
| WO2003086332A1 (en) * | 2002-04-11 | 2003-10-23 | Dvm Pharmaceuticals, Inc. | Antimicrobial wash and carrier solutions, and uses thereof |
| GB2417959A (en) * | 2004-09-11 | 2006-03-15 | Reckitt Benckiser Inc | Cleaning and sanitizing compositions |
| EP1931302A1 (en) * | 2005-09-16 | 2008-06-18 | Reckitt Benckiser Inc. | Foaming topical compositions |
| MX2008010359A (es) * | 2006-02-09 | 2009-01-30 | Elevance Renewable Sciences | Composiciones, metodos y sistemas antimicrobianos. |
| US7951232B2 (en) * | 2006-02-09 | 2011-05-31 | Elevance Renewable Sciences, Inc. | Surface coating compositions and methods |
| US7517413B2 (en) * | 2007-03-26 | 2009-04-14 | The Clorox Company | Remediation of microfloral and biofilm development from laundering devices |
| US8888926B2 (en) * | 2010-06-08 | 2014-11-18 | Innovation Services, Inc. | Medical instrument cleaning solution and method of cleaning contaminated surfaces |
| CN102349510A (zh) * | 2011-08-15 | 2012-02-15 | 赣州八维生物科技有限公司 | 一种畜禽用复合消毒剂及使用方法 |
| US8883706B2 (en) | 2012-10-30 | 2014-11-11 | The Clorox Company | Anionic micelles with cationic polymeric counterions systems thereof |
| US8728454B1 (en) | 2012-10-30 | 2014-05-20 | The Clorox Company | Cationic micelles with anionic polymeric counterions compositions thereof |
| US8728530B1 (en) | 2012-10-30 | 2014-05-20 | The Clorox Company | Anionic micelles with cationic polymeric counterions compositions thereof |
| US8883705B2 (en) | 2012-10-30 | 2014-11-11 | The Clorox Company | Cationic micelles with anionic polymeric counterions systems thereof |
| US8765114B2 (en) | 2012-10-30 | 2014-07-01 | The Clorox Company | Anionic micelles with cationic polymeric counterions methods thereof |
| US9578879B1 (en) | 2014-02-07 | 2017-02-28 | Gojo Industries, Inc. | Compositions and methods having improved efficacy against spores and other organisms |
| US9277749B2 (en) | 2014-02-07 | 2016-03-08 | Gojo Industries, Inc. | Compositions and methods with efficacy against spores and other organisms |
| JP6661545B2 (ja) * | 2014-05-12 | 2020-03-11 | ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ | 布地を洗濯する方法 |
| JP6941489B2 (ja) * | 2016-07-13 | 2021-09-29 | 大日本除蟲菊株式会社 | 水性殺菌組成物 |
| EP3681283A1 (en) | 2017-09-15 | 2020-07-22 | GOJO Industries, Inc. | Antimicrobial composition |
| CN116585207B (zh) * | 2023-04-24 | 2024-11-15 | 上海其然生物科技有限公司 | 一种透明均一的水杨酸制剂及其制备方法和应用 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE321753B (en, 2012) * | 1967-01-17 | 1970-03-16 | Helios Kemisk Tekniska Ab | |
| RO64162A2 (fr) * | 1974-12-18 | 1978-07-15 | Miraj Cosmetice | Lotion capillaire antipelliculaire |
| GB1568358A (en) * | 1975-11-18 | 1980-05-29 | Interox Chemicals Ltd | Aromatic peroxyacids and their use in bleaching processes |
| DE2747355A1 (de) * | 1977-10-21 | 1979-04-26 | Edwin Bernard Michaels | Antimikrobielle zubereitungen |
| DE3101011C2 (de) * | 1981-01-15 | 1985-06-05 | Wella Ag, 6100 Darmstadt | Haarbehandlungsmittel |
| JPS57166165A (en) * | 1981-04-07 | 1982-10-13 | Hitachi Ltd | Deodorant |
| GR81844B (en, 2012) * | 1983-03-26 | 1984-12-12 | Procter & Gamble | |
| DE3518929A1 (de) * | 1985-05-25 | 1986-11-27 | Hans-Joachim 3320 Salzgitter Göbel | Mittel zur behandlung von trockenen schuppen und uebermaessiger talgabsonderung der kopfhaut ... |
| DE3619375A1 (de) * | 1986-06-09 | 1987-12-10 | Henkel Kgaa | Verwendung von alkylglycosiden als potenzierungsmittel in alkohol- oder carbonsaeurehaltigen antiseptischen mitteln sowie alkohol- oder carbonsaeurehaltige desinfektions- und reinigungsmittel mit verstaerkter bakterizider wirkung |
| DE3623826A1 (de) * | 1986-07-15 | 1988-01-28 | Wella Ag | Kosmetische mittel mit einem gehalt an wasserstoffperoxid und alpha-bisabolol sowie die verwendung von alpha-bisabolol zur stabilisierung von wasserstoffperoxid |
| US4751015A (en) * | 1987-03-17 | 1988-06-14 | Lever Brothers Company | Quaternary ammonium or phosphonium substituted peroxy carbonic acid precursors and their use in detergent bleach compositions |
| AU619256B2 (en) * | 1988-03-03 | 1992-01-23 | Connetics Australia Pty Ltd | Acne treatment |
| JPH02225404A (ja) * | 1989-02-27 | 1990-09-07 | Shiseido Co Ltd | 抗菌性組成物 |
| JPH0344314A (ja) * | 1989-07-13 | 1991-02-26 | Nippon Petrochem Co Ltd | 酸性染料用染毛助剤 |
| EP0435379A3 (en) * | 1989-12-22 | 1991-07-31 | Akzo N.V. | Suspension, coating, agglomeration and uses of imidoperoxycarboxylic acids |
| GB9003200D0 (en) * | 1990-02-13 | 1990-04-11 | Unilever Plc | Aqueous liquid bleach composition |
| GB9009824D0 (en) * | 1990-04-27 | 1990-06-20 | Procter & Gamble | Cleaning products |
| JPH06145003A (ja) * | 1992-11-10 | 1994-05-24 | Kao Corp | 農園芸用殺生剤効力増強剤 |
-
1995
- 1995-06-01 BR BR9508088A patent/BR9508088A/pt not_active IP Right Cessation
- 1995-06-01 CN CN95193676A patent/CN1151180A/zh active Pending
- 1995-06-01 AU AU26733/95A patent/AU2673395A/en not_active Abandoned
- 1995-06-01 DE DE69513170T patent/DE69513170T2/de not_active Expired - Lifetime
- 1995-06-01 JP JP50155796A patent/JP4098358B2/ja not_active Expired - Lifetime
- 1995-06-01 PL PL95317896A patent/PL181005B1/pl unknown
- 1995-06-01 WO PCT/EP1995/002090 patent/WO1995035364A1/en active IP Right Grant
- 1995-06-01 AT AT95921809T patent/ATE186326T1/de not_active IP Right Cessation
- 1995-06-01 CA CA002189018A patent/CA2189018C/en not_active Expired - Lifetime
- 1995-06-01 ES ES95921809T patent/ES2139903T3/es not_active Expired - Lifetime
- 1995-06-01 HU HU9603518A patent/HU221137B1/hu unknown
- 1995-06-01 EP EP95921809A patent/EP0766729B1/en not_active Expired - Lifetime
- 1995-06-06 US US08/469,946 patent/US5631218A/en not_active Expired - Lifetime
- 1995-06-20 MY MYPI95001671A patent/MY113176A/en unknown
- 1995-06-29 TW TW084106713A patent/TW304206B/zh active
-
2000
- 2000-02-02 GR GR20000400260T patent/GR3032563T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AU2673395A (en) | 1996-01-15 |
| PL181005B1 (pl) | 2001-05-31 |
| GR3032563T3 (en) | 2000-05-31 |
| HU9603518D0 (en) | 1997-02-28 |
| TW304206B (en, 2012) | 1997-05-01 |
| DE69513170D1 (de) | 1999-12-09 |
| JP4098358B2 (ja) | 2008-06-11 |
| CA2189018A1 (en) | 1995-12-28 |
| ES2139903T3 (es) | 2000-02-16 |
| JPH10501832A (ja) | 1998-02-17 |
| CN1151180A (zh) | 1997-06-04 |
| BR9508088A (pt) | 1997-08-12 |
| HUT77302A (hu) | 1998-03-30 |
| ATE186326T1 (de) | 1999-11-15 |
| US5631218A (en) | 1997-05-20 |
| DE69513170T2 (de) | 2000-03-09 |
| EP0766729A1 (en) | 1997-04-09 |
| WO1995035364A1 (en) | 1995-12-28 |
| EP0766729B1 (en) | 1999-11-03 |
| PL317896A1 (en) | 1997-04-28 |
| HU221137B1 (en) | 2002-08-28 |
| MY113176A (en) | 2001-12-31 |
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| EEER | Examination request | ||
| MKEX | Expiry |
Effective date: 20150601 |