CA2159897C - Composite tire inner-liners and inner tubes - Google Patents
Composite tire inner-liners and inner tubes Download PDFInfo
- Publication number
- CA2159897C CA2159897C CA002159897A CA2159897A CA2159897C CA 2159897 C CA2159897 C CA 2159897C CA 002159897 A CA002159897 A CA 002159897A CA 2159897 A CA2159897 A CA 2159897A CA 2159897 C CA2159897 C CA 2159897C
- Authority
- CA
- Canada
- Prior art keywords
- rubber
- tire
- tire inner
- reactive
- layered silicate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002131 composite material Substances 0.000 title description 6
- 229920001971 elastomer Polymers 0.000 claims abstract description 165
- 239000005060 rubber Substances 0.000 claims abstract description 165
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 75
- 239000000203 mixture Substances 0.000 claims abstract description 47
- 239000004927 clay Substances 0.000 claims abstract description 24
- 239000007787 solid Substances 0.000 claims description 47
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 37
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 31
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 30
- 229920001577 copolymer Polymers 0.000 claims description 27
- 238000009792 diffusion process Methods 0.000 claims description 17
- 150000003839 salts Chemical class 0.000 claims description 15
- 239000010410 layer Substances 0.000 claims description 14
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 12
- 239000007789 gas Substances 0.000 claims description 11
- 239000011229 interlayer Substances 0.000 claims description 10
- 244000043261 Hevea brasiliensis Species 0.000 claims description 9
- 239000005062 Polybutadiene Substances 0.000 claims description 9
- 229920003052 natural elastomer Polymers 0.000 claims description 9
- 229920001194 natural rubber Polymers 0.000 claims description 9
- 229920002857 polybutadiene Polymers 0.000 claims description 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 8
- 239000006229 carbon black Substances 0.000 claims description 8
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- 125000003118 aryl group Chemical group 0.000 claims description 7
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical group O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 239000002243 precursor Substances 0.000 claims description 7
- 239000008896 Opium Substances 0.000 claims description 6
- 229920002367 Polyisobutene Polymers 0.000 claims description 6
- 150000001412 amines Chemical class 0.000 claims description 6
- 229960001027 opium Drugs 0.000 claims description 6
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 6
- 229920001195 polyisoprene Polymers 0.000 claims description 6
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims description 5
- 229920000459 Nitrile rubber Polymers 0.000 claims description 5
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 claims description 5
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 5
- 229910021647 smectite Inorganic materials 0.000 claims description 4
- 229920002725 thermoplastic elastomer Polymers 0.000 claims description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 12
- 239000005864 Sulphur Substances 0.000 claims 6
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims 6
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 6
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims 5
- 125000003277 amino group Chemical group 0.000 claims 3
- 150000001768 cations Chemical class 0.000 claims 3
- 229910052615 phyllosilicate Inorganic materials 0.000 claims 3
- 229920003051 synthetic elastomer Polymers 0.000 claims 3
- 239000005061 synthetic rubber Substances 0.000 claims 3
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims 1
- 230000035699 permeability Effects 0.000 abstract description 11
- 230000002411 adverse Effects 0.000 abstract 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 239000000463 material Substances 0.000 description 10
- 229920003048 styrene butadiene rubber Polymers 0.000 description 8
- 230000004888 barrier function Effects 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 230000005540 biological transmission Effects 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 4
- 229920013646 Hycar Polymers 0.000 description 3
- 229920005549 butyl rubber Polymers 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229920013730 reactive polymer Polymers 0.000 description 3
- 238000004073 vulcanization Methods 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000013032 Hydrocarbon resin Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000006237 Intermediate SAF Substances 0.000 description 1
- 208000007542 Paresis Diseases 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- 238000000333 X-ray scattering Methods 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 239000000370 acceptor Substances 0.000 description 1
- -1 alkyl phthalates Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- VNSBYDPZHCQWNB-UHFFFAOYSA-N calcium;aluminum;dioxido(oxo)silane;sodium;hydrate Chemical compound O.[Na].[Al].[Ca+2].[O-][Si]([O-])=O VNSBYDPZHCQWNB-UHFFFAOYSA-N 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 229920005555 halobutyl Polymers 0.000 description 1
- 125000004968 halobutyl group Chemical group 0.000 description 1
- 229910000271 hectorite Inorganic materials 0.000 description 1
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 229920006270 hydrocarbon resin Polymers 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 150000004010 onium ions Chemical class 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- 208000012318 pareses Diseases 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011085 pressure filtration Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000010734 process oil Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000012783 reinforcing fiber Substances 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 229910000275 saponite Inorganic materials 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000002076 thermal analysis method Methods 0.000 description 1
- 238000003828 vacuum filtration Methods 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 239000004636 vulcanized rubber Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C5/00—Inflatable pneumatic tyres or inner tubes
- B60C5/02—Inflatable pneumatic tyres or inner tubes having separate inflatable inserts, e.g. with inner tubes; Means for lubricating, venting, preventing relative movement between tyre and inner tube
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0008—Compositions of the inner liner
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T152/00—Resilient tires and wheels
- Y10T152/10—Tires, resilient
- Y10T152/10135—Armored
- Y10T152/10234—Interliners
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T152/00—Resilient tires and wheels
- Y10T152/10—Tires, resilient
- Y10T152/10135—Armored
- Y10T152/10234—Interliners
- Y10T152/10243—Cotton, fabric, or rubber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31826—Of natural rubber
- Y10T428/3183—Next to second layer of natural rubber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31826—Of natural rubber
- Y10T428/31833—Next to aldehyde or ketone condensation product or addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31826—Of natural rubber
- Y10T428/31833—Next to aldehyde or ketone condensation product or addition polymer from unsaturated monomers
- Y10T428/31837—Including polyene monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Dispersion Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Tires In General (AREA)
- Laminated Bodies (AREA)
- Tyre Moulding (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US4297293A | 1993-04-05 | 1993-04-05 | |
| US042,972 | 1993-04-05 | ||
| PCT/US1994/003711 WO1994022680A1 (en) | 1993-04-05 | 1994-04-05 | Composite tire inner-liners and inner tubes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2159897A1 CA2159897A1 (en) | 1994-10-13 |
| CA2159897C true CA2159897C (en) | 2004-06-15 |
Family
ID=21924756
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002159897A Expired - Lifetime CA2159897C (en) | 1993-04-05 | 1994-04-05 | Composite tire inner-liners and inner tubes |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US5665183A (OSRAM) |
| EP (1) | EP0695239B1 (OSRAM) |
| JP (1) | JP3240057B2 (OSRAM) |
| KR (1) | KR100275391B1 (OSRAM) |
| CN (1) | CN1043327C (OSRAM) |
| BR (1) | BR9405852A (OSRAM) |
| CA (1) | CA2159897C (OSRAM) |
| CZ (1) | CZ291645B6 (OSRAM) |
| DE (1) | DE69411161T2 (OSRAM) |
| ES (1) | ES2120031T3 (OSRAM) |
| HU (1) | HU212876B (OSRAM) |
| PL (1) | PL310998A1 (OSRAM) |
| RU (1) | RU2124534C1 (OSRAM) |
| TW (1) | TW260639B (OSRAM) |
| WO (1) | WO1994022680A1 (OSRAM) |
Families Citing this family (97)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0763563A1 (en) * | 1995-09-13 | 1997-03-19 | The Goodyear Tire & Rubber Company | Innerliner for pneumatic tires |
| US6034164A (en) * | 1997-02-21 | 2000-03-07 | Exxon Research And Engineering Co. | Nanocomposite materials formed from inorganic layered materials dispersed in a polymer matrix |
| US6087016A (en) * | 1997-06-09 | 2000-07-11 | Inmat, Llc | Barrier coating of an elastomer and a dispersed layered filler in a liquid carrier |
| WO1998056598A1 (en) * | 1997-06-09 | 1998-12-17 | Herberts Gmbh | Barrier coating of an elastomer and a dispersed layered filler in a liquid carrier and coated compositions, particularly tires |
| US6232389B1 (en) | 1997-06-09 | 2001-05-15 | Inmat, Llc | Barrier coating of an elastomer and a dispersed layered filler in a liquid carrier and coated articles |
| CN1079409C (zh) * | 1998-06-04 | 2002-02-20 | 北京化工大学 | 粘土/橡胶纳米复合材料的制备方法 |
| US6454974B1 (en) | 1998-12-21 | 2002-09-24 | Magna International Of America, Inc. | Method for vacuum pressure forming reinforced plastic articles |
| US6977115B1 (en) | 1998-12-21 | 2005-12-20 | Magna International Of America, Inc. | Low pressure compression molded parts having nano-particle reinforced protrusions and method of making the same |
| HU223380B1 (hu) | 1999-05-19 | 2004-06-28 | Exxon Chemical Patents Inc. | Javított szilárdságú, rugalmasságú és csökkentett permeabilitású izobutilénalapú elasztomer blendek, eljárás előállításukra, és alkalmazásuk |
| JP4386504B2 (ja) * | 1999-09-08 | 2009-12-16 | 横浜ゴム株式会社 | タイヤ用ゴム組成物 |
| US6988305B1 (en) | 1999-12-17 | 2006-01-24 | Magna International Of America, Inc. | Method and apparatus for blow molding large reinforced plastic parts |
| US7328733B2 (en) | 1999-12-28 | 2008-02-12 | Exxonmobil Chemical Patents Inc. | Inner tube compositions having improved heat resistance characteristics |
| DE60019806T2 (de) * | 1999-12-28 | 2006-01-19 | Exxonmobil Chemical Patents Inc., Baytown | Innenreifen mit verbesserten hitzeresistenten eigenschaften |
| DE10014664A1 (de) | 2000-03-24 | 2001-09-27 | Sued Chemie Ag | Mit Schwefel vernetzbare Kautschukmischung sowie Verfahren zu Ihrer Herstellung und daraus erhältliche vernetzte Kautschukmischungen und Formkörper |
| JP4588177B2 (ja) * | 2000-06-30 | 2010-11-24 | 株式会社ブリヂストン | 空気入りタイヤおよびその製造方法 |
| GB0020180D0 (en) | 2000-08-17 | 2000-10-04 | Imerys Minerals Ltd | Kaolin products and their production |
| GB0020179D0 (en) * | 2000-08-17 | 2000-10-04 | Imerys Minerals Ltd | Kaolin products and their use |
| US6598645B1 (en) * | 2000-09-27 | 2003-07-29 | The Goodyear Tire & Rubber Company | Tire with at least one of rubber/cord laminate, sidewall insert and apex of a rubber composition which contains oriented intercalated and/or exfoliated clay reinforcement |
| RU2320683C2 (ru) * | 2000-10-13 | 2008-03-27 | Сосьете Де Текнолоджи Мишлен | Эластомерная смесь, содержащая в качестве связывающего агента полифункциональный органосилан |
| US7425591B2 (en) | 2001-10-16 | 2008-09-16 | Exxonmobil Chemical Patents Inc | Elastomeric composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US2795545A (en) * | 1953-04-14 | 1957-06-11 | Monsanto Chemicals | Organic materials |
| DE3806548C2 (de) * | 1987-03-04 | 1996-10-02 | Toyoda Chuo Kenkyusho Kk | Verbundmaterial und Verfahren zu dessen Herstellung |
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| SU1625713A1 (ru) * | 1988-10-04 | 1991-02-07 | Научно-исследовательский институт крупногабаритных шин | Пневматическа шина |
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| WO1993004117A1 (en) * | 1991-08-12 | 1993-03-04 | Allied-Signal Inc. | Melt process formation of polymer nanocomposite of exfoliated layered material |
| WO1993004118A1 (en) * | 1991-08-12 | 1993-03-04 | Allied-Signal Inc. | Melt process formation of polymer nanocomposite of exfoliated layered material |
| WO1993011190A1 (en) * | 1991-11-26 | 1993-06-10 | Allied-Signal Inc. | Polymer nanocomposites formed by melt processing of a polymer and an exfoliated layered material derivatized with reactive organo silanes |
-
1994
- 1994-04-05 CN CN94192043A patent/CN1043327C/zh not_active Expired - Lifetime
- 1994-04-05 CA CA002159897A patent/CA2159897C/en not_active Expired - Lifetime
- 1994-04-05 ES ES94912392T patent/ES2120031T3/es not_active Expired - Lifetime
- 1994-04-05 RU RU95119584A patent/RU2124534C1/ru active
- 1994-04-05 BR BR9405852A patent/BR9405852A/pt not_active IP Right Cessation
- 1994-04-05 CZ CZ19952578A patent/CZ291645B6/cs not_active IP Right Cessation
- 1994-04-05 HU HU9502912A patent/HU212876B/hu not_active IP Right Cessation
- 1994-04-05 JP JP52246794A patent/JP3240057B2/ja not_active Expired - Lifetime
- 1994-04-05 DE DE69411161T patent/DE69411161T2/de not_active Expired - Lifetime
- 1994-04-05 KR KR1019950704339A patent/KR100275391B1/ko not_active Expired - Fee Related
- 1994-04-05 PL PL94310998A patent/PL310998A1/xx unknown
- 1994-04-05 WO PCT/US1994/003711 patent/WO1994022680A1/en not_active Ceased
- 1994-04-05 EP EP94912392A patent/EP0695239B1/en not_active Expired - Lifetime
- 1994-05-05 TW TW083104142A patent/TW260639B/zh active
-
1995
- 1995-06-07 US US08/473,606 patent/US5665183A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| PL310998A1 (en) | 1996-01-22 |
| JPH08510421A (ja) | 1996-11-05 |
| CN1122586A (zh) | 1996-05-15 |
| DE69411161T2 (de) | 1999-02-25 |
| JP3240057B2 (ja) | 2001-12-17 |
| HUT72811A (en) | 1996-05-28 |
| RU2124534C1 (ru) | 1999-01-10 |
| CZ257895A3 (en) | 1996-03-13 |
| WO1994022680A1 (en) | 1994-10-13 |
| HU212876B (en) | 1996-12-30 |
| EP0695239A1 (en) | 1996-02-07 |
| ES2120031T3 (es) | 1998-10-16 |
| CN1043327C (zh) | 1999-05-12 |
| KR960702389A (ko) | 1996-04-27 |
| CA2159897A1 (en) | 1994-10-13 |
| BR9405852A (pt) | 1995-12-05 |
| US5665183A (en) | 1997-09-09 |
| DE69411161D1 (de) | 1998-07-23 |
| EP0695239B1 (en) | 1998-06-17 |
| TW260639B (OSRAM) | 1995-10-21 |
| HU9502912D0 (en) | 1995-12-28 |
| CZ291645B6 (cs) | 2003-04-16 |
| KR100275391B1 (ko) | 2000-12-15 |
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