CA2151054C - Production of branched polyesters - Google Patents
Production of branched polyesters Download PDFInfo
- Publication number
- CA2151054C CA2151054C CA002151054A CA2151054A CA2151054C CA 2151054 C CA2151054 C CA 2151054C CA 002151054 A CA002151054 A CA 002151054A CA 2151054 A CA2151054 A CA 2151054A CA 2151054 C CA2151054 C CA 2151054C
- Authority
- CA
- Canada
- Prior art keywords
- particles
- process according
- inert gas
- polyester
- vapor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920000728 polyester Polymers 0.000 title claims abstract description 51
- 238000004519 manufacturing process Methods 0.000 title description 2
- 238000000034 method Methods 0.000 claims abstract description 34
- 239000002245 particle Substances 0.000 claims abstract description 34
- 239000007787 solid Substances 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000002243 precursor Substances 0.000 claims abstract description 18
- 150000002894 organic compounds Chemical class 0.000 claims abstract description 13
- 238000002844 melting Methods 0.000 claims abstract description 9
- 230000008018 melting Effects 0.000 claims abstract description 9
- 239000011261 inert gas Substances 0.000 claims description 35
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 30
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 27
- 229910052757 nitrogen Inorganic materials 0.000 claims description 14
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 230000000379 polymerizing effect Effects 0.000 claims description 4
- 229910052786 argon Inorganic materials 0.000 claims description 3
- 239000001307 helium Substances 0.000 claims description 3
- 229910052734 helium Inorganic materials 0.000 claims description 3
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 3
- 239000003570 air Substances 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical class CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract description 9
- 238000006116 polymerization reaction Methods 0.000 description 19
- 239000008188 pellet Substances 0.000 description 14
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 12
- 239000000499 gel Substances 0.000 description 12
- 229920000642 polymer Polymers 0.000 description 11
- 239000006085 branching agent Substances 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 150000002334 glycols Chemical class 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- 229920000139 polyethylene terephthalate Polymers 0.000 description 5
- 239000005020 polyethylene terephthalate Substances 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- -1 polyethylene terephthalate Polymers 0.000 description 4
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 238000010923 batch production Methods 0.000 description 3
- 238000010924 continuous production Methods 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 230000001788 irregular Effects 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 2
- 229920001634 Copolyester Polymers 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 150000003504 terephthalic acids Chemical class 0.000 description 2
- 238000011179 visual inspection Methods 0.000 description 2
- VLDPXPPHXDGHEW-UHFFFAOYSA-N 1-chloro-2-dichlorophosphoryloxybenzene Chemical compound ClC1=CC=CC=C1OP(Cl)(Cl)=O VLDPXPPHXDGHEW-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000010101 extrusion blow moulding Methods 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 230000014509 gene expression Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical class C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- 150000002829 nitrogen Chemical class 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000002040 relaxant effect Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/80—Solid-state polycondensation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/000,315 | 1993-01-04 | ||
| US08/000,315 US5393863A (en) | 1993-01-04 | 1993-01-04 | Production of branched polyesters |
| PCT/US1994/000025 WO1994015990A1 (en) | 1993-01-04 | 1994-01-03 | Production of branched polyesters |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2151054A1 CA2151054A1 (en) | 1994-07-21 |
| CA2151054C true CA2151054C (en) | 2000-07-25 |
Family
ID=21690945
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002151054A Expired - Fee Related CA2151054C (en) | 1993-01-04 | 1994-01-03 | Production of branched polyesters |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US5393863A (https=) |
| EP (1) | EP0677078B1 (https=) |
| JP (1) | JP3241731B2 (https=) |
| KR (1) | KR960700290A (https=) |
| AT (1) | ATE157380T1 (https=) |
| CA (1) | CA2151054C (https=) |
| DE (1) | DE69405210T2 (https=) |
| DK (1) | DK0677078T3 (https=) |
| ES (1) | ES2105636T3 (https=) |
| GR (1) | GR3025423T3 (https=) |
| MX (1) | MX9400009A (https=) |
| TW (1) | TW315377B (https=) |
| WO (1) | WO1994015990A1 (https=) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6495656B1 (en) | 1990-11-30 | 2002-12-17 | Eastman Chemical Company | Copolyesters and fibrous materials formed therefrom |
| DE19519898B4 (de) * | 1995-05-31 | 2006-01-26 | Zimmer Ag | Verfahren zur Verbesserung der Streckfähigkeit von Polyester |
| US6066713A (en) * | 1995-12-21 | 2000-05-23 | Lurgi Zimmer Aktiengesellschaft | Process for improving the drawing ability of polyester |
| US6103774A (en) * | 1997-04-02 | 2000-08-15 | The Coca-Cola Company | Process for removing contaminants from polyesters and controlling polymer molecular weight |
| DE69836223T2 (de) * | 1997-08-28 | 2007-08-30 | Eastman Chemical Co., Kingsport | Verbesserte copolymerbinderfasern |
| US6231976B1 (en) | 1997-08-28 | 2001-05-15 | Eastman Chemical Company | Copolyester binder fibers |
| ATE247183T1 (de) * | 1997-11-06 | 2003-08-15 | Eastman Chem Co | Copolyester-binderfasern |
| US8057666B2 (en) * | 2008-03-11 | 2011-11-15 | Xtrudx Technologies, Inc. | Biomass and waste plastics to neodiesel and valuable chemicals via supercritical water |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3453240A (en) * | 1964-09-24 | 1969-07-01 | Goodyear Tire & Rubber | Polyester resin treatment with ethylene glycol |
| UST887005I4 (en) * | 1970-04-02 | 1971-06-01 | Defensive publication | |
| US3953404A (en) * | 1974-02-07 | 1976-04-27 | General Electric Company | Solid state polymerization of poly(1,4-butylene terephthalate) |
| US4069278A (en) * | 1975-04-01 | 1978-01-17 | General Electric Company | Process of making a high melt viscosity block co-polyester |
| DE2559290B2 (de) * | 1975-12-31 | 1979-08-02 | Davy International Ag, 6000 Frankfurt | Verfahren zur kontinuierlichen Herstellung von hochmolekularem PoIyäthylenterephthalat |
| JPS5513715A (en) * | 1978-07-14 | 1980-01-30 | Nippon Ester Co Ltd | Preparation of polyester pellet |
| CH655938A5 (en) * | 1982-08-25 | 1986-05-30 | Inventa Ag | Process for the preparation of high-molecular-weight polyesters |
| US4591629A (en) * | 1983-04-21 | 1986-05-27 | Ems-Inventa Ag | Process for the purification of high molecular weight polyesters |
| JPS59219328A (ja) * | 1983-05-28 | 1984-12-10 | Toyobo Co Ltd | 高重合度ポリエステルの製造方法 |
| US4532319A (en) * | 1984-09-13 | 1985-07-30 | The Goodyear Tire & Rubber Company | Solid state polymerization of polyester |
| US5149485A (en) * | 1988-08-23 | 1992-09-22 | Sabel Plastechs, Inc. | Method and apparatus for extrusion blow molding polyethylene terephthalate articles |
| US5049647A (en) * | 1988-12-27 | 1991-09-17 | Cobarr S.P.A. | Method for the reduction of impurities in polyester resins |
| CA2012577C (en) * | 1989-03-31 | 1995-12-12 | Shigemi Shiraki | Process for treatment of polyethylene terephthalate, polyethylene terephthalate for molding purposes and process for preparation thereof |
| US5145742A (en) * | 1990-08-03 | 1992-09-08 | Eastman Kodak Company | Polymer pellet configuration for solid-state polymerization |
-
1993
- 1993-01-04 US US08/000,315 patent/US5393863A/en not_active Expired - Lifetime
-
1994
- 1994-01-03 ES ES94905988T patent/ES2105636T3/es not_active Expired - Lifetime
- 1994-01-03 AT AT94905988T patent/ATE157380T1/de active
- 1994-01-03 JP JP51612694A patent/JP3241731B2/ja not_active Expired - Fee Related
- 1994-01-03 KR KR1019950702732A patent/KR960700290A/ko not_active Withdrawn
- 1994-01-03 DK DK94905988.5T patent/DK0677078T3/da active
- 1994-01-03 WO PCT/US1994/000025 patent/WO1994015990A1/en not_active Ceased
- 1994-01-03 MX MX9400009A patent/MX9400009A/es not_active IP Right Cessation
- 1994-01-03 EP EP94905988A patent/EP0677078B1/en not_active Expired - Lifetime
- 1994-01-03 CA CA002151054A patent/CA2151054C/en not_active Expired - Fee Related
- 1994-01-03 DE DE69405210T patent/DE69405210T2/de not_active Expired - Fee Related
- 1994-01-05 TW TW083100047A patent/TW315377B/zh active
-
1997
- 1997-11-19 GR GR970403068T patent/GR3025423T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE69405210D1 (de) | 1997-10-02 |
| KR960700290A (ko) | 1996-01-19 |
| JPH08505419A (ja) | 1996-06-11 |
| GR3025423T3 (en) | 1998-02-27 |
| WO1994015990A1 (en) | 1994-07-21 |
| CA2151054A1 (en) | 1994-07-21 |
| EP0677078B1 (en) | 1997-08-27 |
| JP3241731B2 (ja) | 2001-12-25 |
| TW315377B (https=) | 1997-09-11 |
| DE69405210T2 (de) | 1998-01-02 |
| MX9400009A (es) | 1994-08-31 |
| US5393863A (en) | 1995-02-28 |
| EP0677078A1 (en) | 1995-10-18 |
| ATE157380T1 (de) | 1997-09-15 |
| ES2105636T3 (es) | 1997-10-16 |
| DK0677078T3 (da) | 1998-04-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |