UST887005I4 - Defensive publication - Google Patents

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Publication number
UST887005I4
UST887005I4 US887005DH UST887005I4 US T887005 I4 UST887005 I4 US T887005I4 US 887005D H US887005D H US 887005DH US T887005 I4 UST887005 I4 US T887005I4
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United States
Prior art keywords
prepolymer
glycol
fluidized bed
molecular weight
defensive publication
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Publication of UST887005I4 publication Critical patent/UST887005I4/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • C08G63/80Solid-state polycondensation

Abstract

PROCESS OF MAUNFACTURING A POLYESTER BY INITIALLY FORMING A MOLTEN PREPOLYMER FROM A GLYCOL, SUCH AS ETHYLENE GLYCOL AND A DIFUNCTIONAL COMPOUND SUCH AS TEREPHTHALIC ACID OR A LOWER DIALKYL DIESTER THEREOF, SOLIDIFYING THE RESULTING PREPOLYMER, CRYSTALLIZING THE PREPOLYMER, PULVERIZING THE CRYSTALLIZED PREPOLYMER, POLYMERIZING THE PULVERIZED PREPOLYMER IN A HEATED FLUIDIZED BED IN THE PRESENCE OF A CONTINUOUSLY INTRODUCED STREAM OF PREHEATED INERT GAS, WHEREIN AN IMPROVEMENT RESIDES IN MAINTAINING WITHIN THE FLUIDIZED BED A CONTROLLED CONCENTRATION OF GLYCOL VAPOR, WHEREBY THE MOLECULAR WEIGHT OF THE POLYMER IS CAUSED TO ATTAIN A PREDETERMINED VALUE.

Description

DEFENSIVE PUBLlCATlUN UNITED STATES PATENT OFFICE Published at the request of the applicant or owner in accordance with the Notice of Dec. 16, 1969, 869 0.G. 687. The abstracts of Defensive Publication applications are identified by distinctly numbered series and are arranged chronologically. The heading of each abstract indicates the number of pages of specification, including claims and sheets of drawings contained in the application as originally filed. The files of these applications are available to the public for inspection and reproduction may be purchased for 30 cents a sheet.
Defensive Publication applications have not been examined as to the merits of alleged invention. The Patent Oflice makes no assertion as to the novelty of the disclosed subject matter.
PUBLISHED JUNE 1, 1971 T887,005 CONTROL OF MOLECULAR WEIGHT 0F POLY (ETHYLENE TEREPHTHALATE) DURING SOLID PHASE POLYCONDENSATION Charles J. Kibler, 620 Dogwood Drive 37663; David L. Nealy, 908 Afton St. 37660; and Thomas G. Davis, 1368 Garden Drive, 37664, all of Kingsport, Tenn.
Filed Apr. 2, 1970, Ser. No. 25,270 Int. Cl. C08g 17/03 US. Cl. 260-75 No Drawing. 15 Pages Specification Process of manufacturing a polyester by initially forming a molten prepolymer from a glycol, such as ethylene glycol and a difunctional compound such as terephthalic acid or a lower dialkyl diester thereof, solidifying the resulting prepolymer, crystallizing the prepolymer, pulverizing the crystallized prepolyrner, polymerizing the pulverized prepolyrner in a heated fluidized bed in the presence of a continuously introduced stream of preheated inert gas, wherein an improvement resides in maintaining within the fluidized bed a controlled concentration of glycol vapor, whereby the molecular Weight of the polymer is caused to attain a predetermined value.
US887005D 1970-04-02 1970-04-02 Defensive publication Pending UST887005I4 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US2527070A 1970-04-02 1970-04-02

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UST887005I4 true UST887005I4 (en) 1971-06-01

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US887005D Pending UST887005I4 (en) 1970-04-02 1970-04-02 Defensive publication

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4379912A (en) 1982-08-12 1983-04-12 Eastman Kodak Company Method of making polyester prepolymers
EP0085643A2 (en) * 1982-02-02 1983-08-10 The Goodyear Tire & Rubber Company Process for the production of high molecular weight polyester
WO1994015991A1 (en) * 1993-01-04 1994-07-21 Eastman Chemical Company Production of polyesters and polyester articles having good clarity
WO1994015990A1 (en) * 1993-01-04 1994-07-21 Eastman Chemical Company Production of branched polyesters

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0085643A2 (en) * 1982-02-02 1983-08-10 The Goodyear Tire & Rubber Company Process for the production of high molecular weight polyester
EP0085643A3 (en) * 1982-02-02 1983-08-17 The Goodyear Tire & Rubber Company Process for the production of high molecular weight polyester
US4379912A (en) 1982-08-12 1983-04-12 Eastman Kodak Company Method of making polyester prepolymers
WO1994015991A1 (en) * 1993-01-04 1994-07-21 Eastman Chemical Company Production of polyesters and polyester articles having good clarity
WO1994015990A1 (en) * 1993-01-04 1994-07-21 Eastman Chemical Company Production of branched polyesters
US5393871A (en) * 1993-01-04 1995-02-28 Eastman Chemical Company Production of polyesters and polyester articles having good clarity

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