CA1312094C - Transition metal complex catalyzed reactions - Google Patents

Transition metal complex catalyzed reactions

Info

Publication number
CA1312094C
CA1312094C CA000537549A CA537549A CA1312094C CA 1312094 C CA1312094 C CA 1312094C CA 000537549 A CA000537549 A CA 000537549A CA 537549 A CA537549 A CA 537549A CA 1312094 C CA1312094 C CA 1312094C
Authority
CA
Canada
Prior art keywords
rhodium
hydroformylation
organic polymer
aldehyde
phosphite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CA000537549A
Other languages
English (en)
French (fr)
Inventor
David Robert Bryant
John Michael Maher
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US06/865,061 external-priority patent/US4717775A/en
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Application granted granted Critical
Publication of CA1312094C publication Critical patent/CA1312094C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CA000537549A 1986-05-20 1987-05-20 Transition metal complex catalyzed reactions Expired - Lifetime CA1312094C (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US046,821 1986-05-11
US06/865,061 US4717775A (en) 1984-12-28 1986-05-20 Transition metal complex catalyzed reactions
US865,061 1986-05-20
US07/046,821 US4774361A (en) 1986-05-20 1987-05-11 Transition metal complex catalyzed reactions

Publications (1)

Publication Number Publication Date
CA1312094C true CA1312094C (en) 1992-12-29

Family

ID=26724327

Family Applications (1)

Application Number Title Priority Date Filing Date
CA000537549A Expired - Lifetime CA1312094C (en) 1986-05-20 1987-05-20 Transition metal complex catalyzed reactions

Country Status (12)

Country Link
US (1) US4774361A (https=)
EP (1) EP0276231B1 (https=)
JP (1) JPS63503385A (https=)
CN (1) CN1010011B (https=)
AU (1) AU613312B2 (https=)
CA (1) CA1312094C (https=)
DE (1) DE3773890D1 (https=)
ES (1) ES2004935A6 (https=)
IN (1) IN169727B (https=)
MX (1) MX166107B (https=)
NO (1) NO166583C (https=)
WO (1) WO1987007261A2 (https=)

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CN1290814C (zh) 2002-08-31 2006-12-20 奥克森诺奥勒芬化学股份有限公司 通过烯属不饱和化合物的加氢甲酰基化制备醛的方法，该方法在环状碳酸酯存在的条件下由未改性的金属配合物催化
KR20050092414A (ko) * 2003-01-16 2005-09-21 데이진 화이바 가부시키가이샤 폴리에스테르 이수축 혼섬사
CN101654462B (zh) * 2003-07-03 2013-05-29 陶氏技术投资有限责任公司 配体降解产物的最小化,或其向有用的膦配体的转化
DE10349343A1 (de) * 2003-10-23 2005-06-02 Basf Ag Stabilisierung von Hydroformylierungskatalysatoren auf Basis von Phosphoramiditliganden
CA2575122C (en) 2004-08-02 2013-06-25 Union Carbide Chemicals & Plastics Technology Corporation Stabilization of a hydroformylation process
RU2458906C2 (ru) * 2007-03-20 2012-08-20 Дау Текнолоджи Инвестментс Ллс Способ гидроформилирования с усовершенствованным контролем над изомерами продуктов
KR100964098B1 (ko) * 2007-04-09 2010-06-16 주식회사 엘지화학 포스파이트 리간드를 포함하는 촉매 조성물 및 이를 이용한히드로포르밀화 방법
CA2729643C (en) 2008-07-03 2016-08-16 Dow Technology Investments Llc Process of controlling heavies in a recycle catalyst stream
JP5670909B2 (ja) 2008-11-14 2015-02-18 ユニバーシティ・オブ・カンザス ポリマーに担持された遷移金属触媒錯体、及びその使用方法
WO2010117391A1 (en) 2009-03-31 2010-10-14 Dow Technology Investment Llc Hydroformylation process with a doubly open-ended bisphosphite ligand
US7928267B1 (en) * 2009-06-22 2011-04-19 Eastman Chemical Company Phosphite containing catalysts for hydroformylation processes
CN102574878A (zh) 2009-10-16 2012-07-11 陶氏技术投资有限责任公司 气相加氢甲酰化方法
EP2516371B2 (en) 2009-12-22 2022-08-17 Dow Technology Investments LLC Controlling the normal:iso aldehyde ratio in a mixed ligand hydroformylation process by controlling the olefin partial pressure
EP2942343B1 (en) 2009-12-22 2019-09-04 Dow Technology Investments LLC Controlling the normal : iso aldehyde ratio in a mixed ligand hydroformylation process
CA2784943C (en) 2009-12-22 2016-09-06 Dow Technology Investments Llc Controlling the normal:iso aldehyde ratio in a mixed ligand hydroformylation process by controlling the syngas partial pressure
EP2624953B1 (en) 2010-10-05 2018-10-24 Dow Technology Investments LLC Hydroformylation process
RU2601416C2 (ru) 2010-11-12 2016-11-10 Дау Текнолоджи Инвестментс Ллс Снижение загрязнения в процессах гидроформилирования посредством добавления воды
SA112330271B1 (ar) 2011-04-18 2015-02-09 داو تكنولوجى انفستمنتس ال ال سى تخفيف التلوث في عمليات هيدروفورملة عن طريق إضافة الماء
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SG11201405863QA (en) 2012-04-12 2014-11-27 Basf Se Method for replenishing the catalyst in continuous hydroformylation
US8889917B2 (en) 2012-04-12 2014-11-18 Basf Se Method of supplementing the catalyst in continuous hydroformylation
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MX360063B (es) * 2012-08-29 2018-10-22 Dow Technology Investments Llc Proceso de preparacion de catalizador.
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CN104045532B (zh) 2013-03-15 2018-05-25 陶氏技术投资有限责任公司 加氢甲酰化方法
WO2015094781A1 (en) 2013-12-19 2015-06-25 Dow Technology Investments Llc Hydroformylation process
CN104725170B (zh) 2013-12-19 2019-08-23 陶氏技术投资有限责任公司 加氢甲酰化方法
RU2674698C1 (ru) 2014-03-31 2018-12-12 Дау Текнолоджи Инвестментс Ллк Способ гидроформилирования
WO2015175158A1 (en) 2014-05-14 2015-11-19 Dow Technology Investments Llc Stabilized organophosphorous compounds
MY184826A (en) * 2014-12-04 2021-04-24 Dow Technology Investments Llc Hydroformylation process
TWI709568B (zh) 2015-09-30 2020-11-11 美商陶氏科技投資公司 用於製造有機磷化合物的方法
TWI709566B (zh) 2015-09-30 2020-11-11 美商陶氏科技投資公司 用於製造有機磷化合物的方法
PL3374340T3 (pl) 2015-11-10 2022-04-11 Dow Technology Investments Llc Sposób wytwarzania aldehydów
ES2901236T3 (es) 2016-02-11 2022-03-21 Dow Technology Investments Llc Procesos para convertir olefinas en alcoholes, éteres o combinaciones de los mismos
CA3018072C (en) 2016-03-18 2024-10-29 Dow Technology Investments Llc HYDROFORMYLATION PROCESS
TW201840362A (zh) 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
TW201840363A (zh) 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 處理氫甲醯化催化劑溶液之方法
TWI758353B (zh) 2016-11-08 2022-03-21 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
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EP3710161B1 (en) 2017-11-13 2024-10-16 Dow Technology Investments LLC Processes for recovery of rhodium from a hydroformylation process
TWI793216B (zh) * 2017-12-07 2023-02-21 美商陶氏科技投資公司 氫甲醯化方法
CN112055614A (zh) 2018-05-30 2020-12-08 陶氏技术投资有限责任公司 包括单膦、四膦配位体的组合的催化剂组合物和使用其的加氢甲酰化过程
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TWI874467B (zh) 2019-11-05 2025-03-01 美商陶氏科技投資有限公司 用於自ｃ６或更高碳數烯烴氫甲醯化製程之催化劑淨化流回收銠之方法
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CN114478214B (zh) * 2020-10-23 2024-05-17 中国石油化工股份有限公司 一种氢甲酰化方法和一种氢甲酰化产物的分离方法
JP7796748B2 (ja) 2020-12-14 2026-01-09 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化プロセスにおける触媒金属の責務を改善するためのプロセス
EP4430218A1 (en) 2021-11-11 2024-09-18 Dow Technology Investments LLC Processes for recovering rhodium from hydroformylation processes
US20240399349A1 (en) 2021-12-16 2024-12-05 Dow Technology Investments Llc Transition metal complex hydroformylation catalyst precuror compositions comprising such compounds, and hydroformylation processes
CN118317834A (zh) 2021-12-16 2024-07-09 陶氏技术投资有限责任公司 化合物、包含此类化合物的过渡金属络合物加氢甲酰化催化剂前体组合物和加氢甲酰化方法
EP4634148A1 (en) 2022-12-13 2025-10-22 Dow Technology Investments LLC Process to minimize polyphosphine usage by making use of degradation products
EP4705270A1 (en) 2023-05-04 2026-03-11 Dow Technology Investments LLC Hydroformylation process
GB202307175D0 (en) 2023-05-15 2023-06-28 Johnson Matthey Davy Technologies Ltd Process for hydrogenating a substrate
KR20260028059A (ko) 2023-06-26 2026-03-03 다우 테크놀로지 인베스트먼츠 엘엘씨. 하이드로포르밀화 공정을 제어하는 방법
CN121532373A (zh) 2023-08-03 2026-02-13 陶氏技术投资有限责任公司 用于改善基于铑/亚磷酸酯的均相加氢甲酰化催化剂活性的方法
KR20260045840A (ko) 2023-08-03 2026-04-03 다우 테크놀로지 인베스트먼츠 엘엘씨. 하이드로포르밀화 공정
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Also Published As

Publication number Publication date
EP0276231A1 (en) 1988-08-03
NO880207L (no) 1988-01-19
EP0276231B1 (en) 1991-10-16
ES2004935A6 (es) 1989-02-16
WO1987007261A3 (en) 1988-04-07
NO166583B (no) 1991-05-06
IN169727B (https=) 1991-12-14
MX166107B (es) 1992-12-21
AU7489887A (en) 1987-12-22
DE3773890D1 (de) 1991-11-21
AU613312B2 (en) 1991-08-01
NO166583C (no) 1991-08-14
NO880207D0 (no) 1988-01-19
CN87104311A (zh) 1988-06-08
JPS63503385A (ja) 1988-12-08
US4774361A (en) 1988-09-27
WO1987007261A2 (en) 1987-12-03
JPH0548215B2 (https=) 1993-07-20
CN1010011B (zh) 1990-10-17

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