CA1289421C - Procede de fabrication de moules en metal a haut point de fusion parpulverisation dudit metal sur une forme en elastomere silicone charge - Google Patents
Procede de fabrication de moules en metal a haut point de fusion parpulverisation dudit metal sur une forme en elastomere silicone chargeInfo
- Publication number
- CA1289421C CA1289421C CA000494681A CA494681A CA1289421C CA 1289421 C CA1289421 C CA 1289421C CA 000494681 A CA000494681 A CA 000494681A CA 494681 A CA494681 A CA 494681A CA 1289421 C CA1289421 C CA 1289421C
- Authority
- CA
- Canada
- Prior art keywords
- metal
- melting point
- refractory
- molten metal
- high melting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 67
- 239000002184 metal Substances 0.000 title claims abstract description 67
- 229920001296 polysiloxane Polymers 0.000 title claims abstract description 34
- 238000004519 manufacturing process Methods 0.000 title claims description 14
- 230000004927 fusion Effects 0.000 title claims description 5
- 238000004544 sputter deposition Methods 0.000 title 1
- 238000002844 melting Methods 0.000 claims abstract description 28
- 230000008018 melting Effects 0.000 claims abstract description 23
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 11
- 239000010959 steel Substances 0.000 claims abstract description 11
- 239000000945 filler Substances 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims description 42
- 238000000034 method Methods 0.000 claims description 41
- 229920002379 silicone rubber Polymers 0.000 claims description 22
- -1 alkyl silicate Chemical compound 0.000 claims description 21
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 15
- 229910045601 alloy Inorganic materials 0.000 claims description 15
- 239000000956 alloy Substances 0.000 claims description 15
- 238000005507 spraying Methods 0.000 claims description 15
- 238000004132 cross linking Methods 0.000 claims description 14
- 239000003921 oil Substances 0.000 claims description 14
- 229910052718 tin Inorganic materials 0.000 claims description 13
- 239000002245 particle Substances 0.000 claims description 12
- 239000011701 zinc Substances 0.000 claims description 12
- 229920001971 elastomer Polymers 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 11
- 239000000806 elastomer Substances 0.000 claims description 10
- 229910052782 aluminium Inorganic materials 0.000 claims description 9
- 229910000077 silane Inorganic materials 0.000 claims description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- 239000003431 cross linking reagent Substances 0.000 claims description 8
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 6
- 239000010409 thin film Substances 0.000 claims description 6
- 229910052725 zinc Inorganic materials 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 239000003054 catalyst Substances 0.000 claims description 5
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 5
- 239000011819 refractory material Substances 0.000 claims description 5
- 239000000454 talc Substances 0.000 claims description 5
- 229910052623 talc Inorganic materials 0.000 claims description 5
- 229910021626 Tin(II) chloride Inorganic materials 0.000 claims description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- 125000000962 organic group Chemical group 0.000 claims description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 4
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- 239000010936 titanium Substances 0.000 claims description 4
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- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
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- 229910052797 bismuth Inorganic materials 0.000 claims description 2
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- 239000002131 composite material Substances 0.000 claims description 2
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 2
- 229910052697 platinum Inorganic materials 0.000 claims description 2
- 238000010298 pulverizing process Methods 0.000 claims description 2
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- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 2
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- 125000005375 organosiloxane group Chemical group 0.000 claims 2
- 241000206761 Bacillariophyta Species 0.000 claims 1
- 229920000914 Metallic fiber Polymers 0.000 claims 1
- 229910000611 Zinc aluminium Inorganic materials 0.000 claims 1
- HXFVOUUOTHJFPX-UHFFFAOYSA-N alumane;zinc Chemical compound [AlH3].[Zn] HXFVOUUOTHJFPX-UHFFFAOYSA-N 0.000 claims 1
- UOUJSJZBMCDAEU-UHFFFAOYSA-N chromium(3+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[Cr+3].[Cr+3] UOUJSJZBMCDAEU-UHFFFAOYSA-N 0.000 claims 1
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- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 1
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- 238000000151 deposition Methods 0.000 abstract 1
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- 239000000155 melt Substances 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 15
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- 125000004432 carbon atom Chemical group C* 0.000 description 9
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
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- 239000008096 xylene Substances 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical group [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
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- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 3
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- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 2
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- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 2
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- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
- B29C33/38—Moulds or cores; Details thereof or accessories therefor characterised by the material or the manufacturing process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
- B29C33/56—Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2705/00—Use of metals, their alloys or their compounds, for preformed parts, e.g. for inserts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2883/00—Use of polymers having silicon, with or without sulfur, nitrogen, oxygen, or carbon only, in the main chain, as mould material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S29/00—Metal working
- Y10S29/039—Spraying with other step
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Coating By Spraying Or Casting (AREA)
- Laminated Bodies (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Adornments (AREA)
- Push-Button Switches (AREA)
- Golf Clubs (AREA)
- Mold Materials And Core Materials (AREA)
- Molds, Cores, And Manufacturing Methods Thereof (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR84/16929 | 1984-11-07 | ||
| FR8416929A FR2572673B1 (fr) | 1984-11-07 | 1984-11-07 | Procede de fabrication de moules en metal a haut point de fusion par pulverisation dudit metal sur une forme en elastomere silicone charge |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1289421C true CA1289421C (fr) | 1991-09-24 |
Family
ID=9309337
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000494681A Expired - Fee Related CA1289421C (fr) | 1984-11-07 | 1985-11-06 | Procede de fabrication de moules en metal a haut point de fusion parpulverisation dudit metal sur une forme en elastomere silicone charge |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US4726412A (enExample) |
| EP (1) | EP0184522B1 (enExample) |
| JP (1) | JPS61165249A (enExample) |
| KR (1) | KR910005174B1 (enExample) |
| AT (1) | ATE32505T1 (enExample) |
| AU (1) | AU576270B2 (enExample) |
| BR (1) | BR8505439A (enExample) |
| CA (1) | CA1289421C (enExample) |
| DE (1) | DE3561617D1 (enExample) |
| ES (1) | ES8704379A1 (enExample) |
| FR (1) | FR2572673B1 (enExample) |
| ZA (1) | ZA858485B (enExample) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2631861A1 (fr) * | 1988-05-27 | 1989-12-01 | Staphane Sa | Procede de fabrication d'un moule d'injection pour thermoplastique |
| US5189781A (en) * | 1990-08-03 | 1993-03-02 | Carnegie Mellon University | Rapid tool manufacturing |
| JP2916593B2 (ja) * | 1991-07-01 | 1999-07-05 | 東芝モノフラックス株式会社 | 鋳造用鋳型 |
| JP3141454B2 (ja) * | 1991-10-29 | 2001-03-05 | 株式会社日立製作所 | 樹脂型の製作方法、並びに樹脂型を用いた減圧鋳造方法 |
| IT1250214B (it) * | 1991-11-22 | 1995-04-03 | Rivestimento al nitruro di titanio per conchiglie per pistoni. | |
| US5518060A (en) * | 1994-01-25 | 1996-05-21 | Brunswick Corporation | Method of producing polymeric patterns for use in evaporable foam casting |
| US5449483A (en) * | 1994-02-04 | 1995-09-12 | The Goodyear Tire & Rubber Company | Method and apparatus for making a tire mold |
| GB9402471D0 (en) * | 1994-02-09 | 1994-03-30 | Weber Manufacturing Limited | Nickel shell molds |
| US5937265A (en) * | 1997-04-24 | 1999-08-10 | Motorola, Inc. | Tooling die insert and rapid method for fabricating same |
| GB2338666B (en) | 1998-06-26 | 2002-08-07 | Sprayform Holdings Ltd | Tooling production |
| US5967218A (en) * | 1998-07-06 | 1999-10-19 | Ford Motor Company | Method of integrating detailed features into a spray formed rapid tool |
| US6060117A (en) * | 1998-08-31 | 2000-05-09 | Ford Global Technologies, Inc. | Making and using thermal spray masks carrying thermoset epoxy coating |
| US6638460B1 (en) * | 1998-12-15 | 2003-10-28 | David M. Wahl | Method for preparing a thermal cooled vacuum form |
| US6550742B1 (en) | 1999-12-15 | 2003-04-22 | David M. Wahl | Thermal cooled vacuum form |
| US6447704B1 (en) * | 2000-05-23 | 2002-09-10 | Gmic, Corp. | Thermal-sprayed tooling |
| DE10025588A1 (de) * | 2000-05-24 | 2001-11-29 | Mold Masters Ltd | Einrichtung zur Verarbeitung von geschmolzenem Material, Verfahren und Vorrichtung zur Herstellung derselben |
| US6492589B1 (en) * | 2000-08-31 | 2002-12-10 | Ericsson Inc. | Electronics enclosure utilizing thermal insulating ceramic coating |
| US20040151611A1 (en) * | 2003-01-30 | 2004-08-05 | Kline Kerry J. | Method for producing powder metal tooling, mold cavity member |
| DE102006021477A1 (de) * | 2006-05-09 | 2007-11-15 | K1 Gmbh | Verfahren zum Abformen mikrostrukturierter dreidimensionaler Freiformflächen |
| US8241581B2 (en) * | 2006-09-27 | 2012-08-14 | Minimus Spine, Inc. | Apparatus, method and system for delivering ozone |
| US20100102478A1 (en) * | 2008-10-23 | 2010-04-29 | Flavio Maschera | Method of fabricating bath-models for nickel shells |
| GB201001179D0 (en) * | 2010-01-26 | 2010-03-10 | Rolls Royce Plc | Method of producing an integral self supporting coating test piece from a coating material |
| ES2368237B1 (es) * | 2010-01-26 | 2012-09-14 | María Del Mar Hernández Molina | Procedimiento para la fabricación de maquetas o moldes de piezas para el calzado y dispositivo con dos soportes porta-moldes. |
| JP6046505B2 (ja) | 2013-01-29 | 2016-12-14 | 株式会社ダイセル | シート状モールド及びその製造方法並びにその用途 |
| KR101851371B1 (ko) * | 2016-03-04 | 2018-06-07 | (주)엘켐 | 패턴 형성 방법 |
| KR102212839B1 (ko) * | 2018-10-26 | 2021-02-05 | 배철호 | 대형 입체조형물 제작을 위한 실리콘 몰드 제조방법 및 실리콘 몰드 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE704732C (de) * | 1938-01-11 | 1941-04-05 | Max Stoessel | Verfahren zur Herstellung von Guss- oder Pressformen, insbesondere fuer die Kunstharzindustrie |
| US2479598A (en) * | 1944-04-10 | 1949-08-23 | Hiram L Barber | Method of making metal molds |
| US3161919A (en) * | 1959-02-12 | 1964-12-22 | Ren Plastics Inc | Resin-bonded molds, dies, fixtures and the like |
| US3638299A (en) * | 1968-12-30 | 1972-02-01 | Ici Ltd | Process for the production of molds |
| FR2044266A5 (enExample) * | 1969-05-14 | 1971-02-19 | Wendel Sidelor | |
| FR2062106A5 (en) * | 1969-10-10 | 1971-06-25 | Bachi Arturo | Roduction process |
| FR2098629A5 (fr) * | 1970-07-22 | 1972-03-10 | Rhone Poulenc Sa | Moules pour le moulage de metaux et alliages non ferreux |
| US3784152A (en) * | 1972-04-24 | 1974-01-08 | Ici Ltd | Process of producing a composite mold having cooling pipes embedded therein |
| GB1541445A (en) * | 1976-01-17 | 1979-02-28 | Hrb Tooling Ab | Forming tools and a method of producing such tools |
| JPS5530340A (en) * | 1978-08-25 | 1980-03-04 | Komatsu Ltd | Molding method of casting mold |
| JPS55121010A (en) * | 1979-03-09 | 1980-09-17 | Mitsubishi Electric Corp | Providing method of mold for high molecular constituent |
| FR2498123A1 (fr) * | 1981-01-19 | 1982-07-23 | Matra | Procede de fabrication de pieces metalliques de forme par projection sur un modele destructible |
| JPS6059064B2 (ja) * | 1981-03-17 | 1985-12-23 | 株式会社小松製作所 | マイクロ波加熱硬化鋳型用模型の製造方法 |
| JPS58215240A (ja) * | 1982-06-08 | 1983-12-14 | Akira Shimazu | 鋳型用模型の製造方法 |
-
1984
- 1984-11-07 FR FR8416929A patent/FR2572673B1/fr not_active Expired
-
1985
- 1985-10-23 DE DE8585420192T patent/DE3561617D1/de not_active Expired
- 1985-10-23 EP EP85420192A patent/EP0184522B1/fr not_active Expired
- 1985-10-23 AT AT85420192T patent/ATE32505T1/de not_active IP Right Cessation
- 1985-10-31 BR BR8505439A patent/BR8505439A/pt unknown
- 1985-11-04 AU AU49323/85A patent/AU576270B2/en not_active Ceased
- 1985-11-05 ZA ZA858485A patent/ZA858485B/xx unknown
- 1985-11-06 CA CA000494681A patent/CA1289421C/fr not_active Expired - Fee Related
- 1985-11-06 JP JP60247302A patent/JPS61165249A/ja active Granted
- 1985-11-06 ES ES548589A patent/ES8704379A1/es not_active Expired
- 1985-11-06 KR KR1019850008280A patent/KR910005174B1/ko not_active Expired
- 1985-11-07 US US06/795,881 patent/US4726412A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| ZA858485B (en) | 1986-06-25 |
| US4726412A (en) | 1988-02-23 |
| BR8505439A (pt) | 1986-08-05 |
| ES8704379A1 (es) | 1987-04-01 |
| AU576270B2 (en) | 1988-08-18 |
| KR910005174B1 (ko) | 1991-07-23 |
| FR2572673B1 (fr) | 1987-01-09 |
| KR860003890A (ko) | 1986-06-13 |
| FR2572673A1 (fr) | 1986-05-09 |
| ATE32505T1 (de) | 1988-03-15 |
| ES548589A0 (es) | 1987-04-01 |
| DE3561617D1 (en) | 1988-03-24 |
| EP0184522A1 (fr) | 1986-06-11 |
| EP0184522B1 (fr) | 1988-02-17 |
| JPS61165249A (ja) | 1986-07-25 |
| AU4932385A (en) | 1986-05-15 |
| JPH0223331B2 (enExample) | 1990-05-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKLA | Lapsed |