CA1214453A - Electrolytic cell cathode - Google Patents
Electrolytic cell cathodeInfo
- Publication number
- CA1214453A CA1214453A CA000431802A CA431802A CA1214453A CA 1214453 A CA1214453 A CA 1214453A CA 000431802 A CA000431802 A CA 000431802A CA 431802 A CA431802 A CA 431802A CA 1214453 A CA1214453 A CA 1214453A
- Authority
- CA
- Canada
- Prior art keywords
- host matrix
- modifier
- catalytic
- cathode
- materials
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000463 material Substances 0.000 claims abstract description 189
- 230000003197 catalytic effect Effects 0.000 claims abstract description 73
- 239000003607 modifier Substances 0.000 claims abstract description 46
- 239000011159 matrix material Substances 0.000 claims abstract description 42
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 37
- 238000000034 method Methods 0.000 claims abstract description 33
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000001257 hydrogen Substances 0.000 claims abstract description 27
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 27
- 239000000758 substrate Substances 0.000 claims abstract description 22
- 239000000126 substance Substances 0.000 claims abstract description 21
- 239000003054 catalyst Substances 0.000 claims abstract description 19
- 239000003792 electrolyte Substances 0.000 claims abstract description 16
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 15
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 14
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 14
- 230000007704 transition Effects 0.000 claims abstract description 11
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 8
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 7
- 238000001771 vacuum deposition Methods 0.000 claims abstract description 6
- 229910052712 strontium Inorganic materials 0.000 claims abstract description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 76
- 229910052751 metal Inorganic materials 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 13
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 6
- 229910052720 vanadium Inorganic materials 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 229910052758 niobium Inorganic materials 0.000 claims description 5
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 229910052707 ruthenium Inorganic materials 0.000 claims description 4
- 238000000151 deposition Methods 0.000 claims description 3
- 239000011149 active material Substances 0.000 claims description 2
- 230000000051 modifying effect Effects 0.000 claims 3
- 229910052723 transition metal Inorganic materials 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 abstract description 10
- 230000004048 modification Effects 0.000 abstract description 7
- 238000012986 modification Methods 0.000 abstract description 7
- 239000012633 leachable Substances 0.000 abstract description 2
- 229910052684 Cerium Inorganic materials 0.000 abstract 1
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 28
- 239000000306 component Substances 0.000 description 19
- 239000000203 mixture Substances 0.000 description 15
- 239000010936 titanium Substances 0.000 description 11
- 239000010406 cathode material Substances 0.000 description 10
- 229910000564 Raney nickel Inorganic materials 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 230000008569 process Effects 0.000 description 9
- 239000007868 Raney catalyst Substances 0.000 description 8
- 239000003513 alkali Substances 0.000 description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 8
- 235000010210 aluminium Nutrition 0.000 description 8
- 230000015556 catabolic process Effects 0.000 description 8
- 238000006731 degradation reaction Methods 0.000 description 8
- 239000002178 crystalline material Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 7
- 231100000572 poisoning Toxicity 0.000 description 7
- 230000000607 poisoning effect Effects 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 238000005868 electrolysis reaction Methods 0.000 description 6
- 238000002386 leaching Methods 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 229910000510 noble metal Inorganic materials 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- 238000004544 sputter deposition Methods 0.000 description 5
- 238000012546 transfer Methods 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000003518 caustics Substances 0.000 description 4
- 229910052697 platinum Inorganic materials 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 239000003570 air Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000008151 electrolyte solution Substances 0.000 description 2
- 238000009713 electroplating Methods 0.000 description 2
- 238000010285 flame spraying Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000011872 intimate mixture Substances 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 230000036961 partial effect Effects 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 230000007096 poisonous effect Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- -1 so-dium hydroxide Chemical class 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 229910052715 tantalum Inorganic materials 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 241000286904 Leptothecata Species 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 229910003296 Ni-Mo Inorganic materials 0.000 description 1
- 229910003294 NiMo Inorganic materials 0.000 description 1
- 229910005807 NiMoSi Inorganic materials 0.000 description 1
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 239000002156 adsorbate Substances 0.000 description 1
- 229910001514 alkali metal chloride Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- 230000002101 lytic effect Effects 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000001755 magnetron sputter deposition Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000010310 metallurgical process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000013080 microcrystalline material Substances 0.000 description 1
- 230000003278 mimic effect Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- DDTIGTPWGISMKL-UHFFFAOYSA-N molybdenum nickel Chemical compound [Ni].[Mo] DDTIGTPWGISMKL-UHFFFAOYSA-N 0.000 description 1
- 229910001000 nickel titanium Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000007750 plasma spraying Methods 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 229960002816 potassium chloride Drugs 0.000 description 1
- 239000012254 powdered material Substances 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000682 scanning probe acoustic microscopy Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000010944 silver (metal) Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000005477 sputtering target Methods 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/20—Carbon compounds
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
- C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Metallurgy (AREA)
- Catalysts (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/399,892 US4545883A (en) | 1982-07-19 | 1982-07-19 | Electrolytic cell cathode |
| US399,892 | 1982-07-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1214453A true CA1214453A (en) | 1986-11-25 |
Family
ID=23581382
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000431802A Expired CA1214453A (en) | 1982-07-19 | 1983-07-05 | Electrolytic cell cathode |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4545883A (cg-RX-API-DMAC10.html) |
| EP (1) | EP0099867A1 (cg-RX-API-DMAC10.html) |
| JP (1) | JPH0733597B2 (cg-RX-API-DMAC10.html) |
| AU (1) | AU563946B2 (cg-RX-API-DMAC10.html) |
| CA (1) | CA1214453A (cg-RX-API-DMAC10.html) |
| IN (1) | IN161512B (cg-RX-API-DMAC10.html) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1240363A (en) * | 1983-10-28 | 1988-08-09 | John E. Keem | Electrodes made with disordered active material and method of making the same |
| WO1986006107A1 (fr) * | 1985-04-10 | 1986-10-23 | Asahi Glass Company Ltd. | Cathode de surtension a faible teneur en hydrogene de longue duree et son procede de production |
| US4746584A (en) * | 1985-06-24 | 1988-05-24 | The Standard Oil Company | Novel amorphous metal alloys as electrodes for hydrogen formation and oxidation |
| CA2126136C (en) * | 1994-06-17 | 2007-06-05 | Steven J. Thorpe | Amorphous metal/metallic glass electrodes for electrochemical processes |
| GB9502665D0 (en) * | 1995-02-11 | 1995-03-29 | Ici Plc | Cathode for use in electrolytic cell |
| EP0769576B1 (en) * | 1995-10-18 | 2000-09-20 | Tosoh Corporation | Low hydrogen overvoltage cathode and process for production thereof |
| DE19624923C1 (de) * | 1996-06-21 | 1998-03-12 | Siemens Ag | Verfahren zur Herstellung eines Katalysators sowie danach hergestellter Katalysator |
| FR2843896A1 (fr) * | 2002-12-09 | 2004-03-05 | Commissariat Energie Atomique | Substrat poreux contenant une phase metallique a gradient de concentration et procede de fabrication de ce substrat |
| US7175751B2 (en) * | 2003-05-01 | 2007-02-13 | Ovonic Fuel Cell Company Llc | Method and apparatus for electrorefining impure hydrogen |
| US7052587B2 (en) * | 2003-06-27 | 2006-05-30 | General Motors Corporation | Photoelectrochemical device and electrode |
| US20050059186A1 (en) * | 2003-09-15 | 2005-03-17 | Kelly Nelson A. | Photoelectrochemical device and method of making |
| WO2007004553A1 (ja) * | 2005-06-30 | 2007-01-11 | Showa Denko K. K. | 固体電解コンデンサの製造方法 |
| KR100684767B1 (ko) * | 2005-07-29 | 2007-02-20 | 삼성에스디아이 주식회사 | 연료 전지 캐소드용 촉매, 이를 포함하는 막-전극 어셈블리및 연료 전지 시스템 |
| KR100766976B1 (ko) * | 2006-04-28 | 2007-10-12 | 삼성에스디아이 주식회사 | 연료 전지용 캐소드 촉매, 이의 제조방법, 이를 포함하는연료 전지용 막-전극 어셈블리 및 연료전지 시스템 |
| DE102006057386A1 (de) * | 2006-12-04 | 2008-06-05 | Uhde Gmbh | Verfahren zum Beschichten von Substraten |
| US20100094070A1 (en) * | 2008-10-15 | 2010-04-15 | Headwaters Technology Innovation, Llc | Ethylene trimerization using a supported chromium-tantalum catalyst |
| JP5429789B2 (ja) * | 2009-04-21 | 2014-02-26 | 国立大学法人東北大学 | 電気透析装置 |
| ITMI20091719A1 (it) * | 2009-10-08 | 2011-04-09 | Industrie De Nora Spa | Catodo per processi elettrolitici |
| WO2011156825A2 (en) * | 2010-06-08 | 2011-12-15 | Yale University | Bulk metallic glass nanowires for use in energy conversion and storage devices |
| CN104399496B (zh) * | 2014-11-27 | 2017-07-28 | 中国科学技术大学 | 一种二硒化钴修饰碳纤维复合材料及其制备方法和应用 |
| JP6614660B2 (ja) * | 2016-02-05 | 2019-12-04 | 国立大学法人秋田大学 | 多孔質ニッケルの製造方法 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1542552B1 (de) * | 1965-10-09 | 1970-06-18 | Varta Ag | Verfahren zur Herstellung eines poroesen,Metall enthaltenden und geformten Katalysators |
| DE1917642A1 (de) * | 1969-04-05 | 1971-01-14 | Messerschmitt Boelkow Blohm | Katalysator,insbesondere zum Zersetzen von Hydrazin und dessen Derivaten |
| DE1923920C3 (de) * | 1969-05-10 | 1980-07-17 | Siemens Ag, 1000 Berlin Und 8000 Muenchen | Raney-Mischkatalysator |
| DE1928929C3 (de) * | 1969-06-07 | 1979-04-12 | Siemens Ag, 1000 Berlin Und 8000 Muenchen | Raney-Mischkatalysator |
| GB1352995A (en) * | 1970-04-22 | 1974-05-15 | Nat Res Dev | Catalytic processes |
| DE2113676C2 (de) * | 1971-03-20 | 1985-09-12 | Conradty GmbH & Co Metallelektroden KG, 8505 Röthenbach | Elektrode für elektrochemische Prozesse |
| US3957692A (en) * | 1973-12-10 | 1976-05-18 | United Kingdom Atomic Energy Authority | Method of preparing a catalyst |
| FR2350406A2 (fr) * | 1976-05-04 | 1977-12-02 | Rhone Poulenc Ind | Cathode pour cellule d'electrolyse |
| GB1504110A (en) * | 1975-07-08 | 1978-03-15 | Rhone Poulenc Ind | Cathode |
| US4115322A (en) * | 1976-01-07 | 1978-09-19 | Hydro-Quebec | Method for obtaining high activity electrocatalysts on pyrolytic graphite |
| US4033837A (en) * | 1976-02-24 | 1977-07-05 | Olin Corporation | Plated metallic cathode |
| US4116804A (en) * | 1976-11-17 | 1978-09-26 | E. I. Du Pont De Nemours And Company | Catalytically active porous nickel electrodes |
| US4275126A (en) * | 1978-04-12 | 1981-06-23 | Battelle Memorial Institute | Fuel cell electrode on solid electrolyte substrate |
| DE2829901A1 (de) * | 1978-07-07 | 1980-01-24 | Metallgesellschaft Ag | Verfahren zur herstellung eines bleches oder bandes mit oberflaechiger katalysatorstruktur |
| JPS5927215B2 (ja) * | 1978-12-27 | 1984-07-04 | 日産自動車株式会社 | 表面活性化処理を施した機能材料とその製造方法 |
| US4289650A (en) * | 1979-03-29 | 1981-09-15 | Olin Corporation | Cathode for chlor-alkali cells |
| US4244798A (en) * | 1979-10-29 | 1981-01-13 | General Motors Corporation | Exhaust electrode process for exhaust gas oxygen sensor |
| US4279709A (en) * | 1979-05-08 | 1981-07-21 | The Dow Chemical Company | Preparation of porous electrodes |
| US4544473A (en) * | 1980-05-12 | 1985-10-01 | Energy Conversion Devices, Inc. | Catalytic electrolytic electrode |
| US4342792A (en) * | 1980-05-13 | 1982-08-03 | The British Petroleum Company Limited | Electrodes and method of preparation thereof for use in electrochemical cells |
| US4328080A (en) * | 1980-10-24 | 1982-05-04 | General Electric Company | Method of making a catalytic electrode |
| JPS58130742A (ja) * | 1982-01-26 | 1983-08-04 | Matsushita Electric Ind Co Ltd | 携帯用水車発電機 |
-
1982
- 1982-07-19 US US06/399,892 patent/US4545883A/en not_active Expired - Lifetime
-
1983
- 1983-07-05 CA CA000431802A patent/CA1214453A/en not_active Expired
- 1983-07-08 EP EP83850196A patent/EP0099867A1/en not_active Ceased
- 1983-07-13 IN IN866/CAL/83A patent/IN161512B/en unknown
- 1983-07-13 AU AU16799/83A patent/AU563946B2/en not_active Expired
- 1983-07-18 JP JP58130743A patent/JPH0733597B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US4545883A (en) | 1985-10-08 |
| AU1679983A (en) | 1984-01-26 |
| IN161512B (cg-RX-API-DMAC10.html) | 1987-12-19 |
| JPH0733597B2 (ja) | 1995-04-12 |
| EP0099867A1 (en) | 1984-02-01 |
| AU563946B2 (en) | 1987-07-30 |
| JPS5947391A (ja) | 1984-03-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |