CA1205347A - Mild liquid detergent compositions - Google Patents
Mild liquid detergent compositionsInfo
- Publication number
- CA1205347A CA1205347A CA000421891A CA421891A CA1205347A CA 1205347 A CA1205347 A CA 1205347A CA 000421891 A CA000421891 A CA 000421891A CA 421891 A CA421891 A CA 421891A CA 1205347 A CA1205347 A CA 1205347A
- Authority
- CA
- Canada
- Prior art keywords
- alkyl
- detergent
- group
- sulfate
- supplementary
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 118
- 239000000203 mixture Substances 0.000 title claims abstract description 110
- 239000007788 liquid Substances 0.000 title claims abstract description 58
- -1 alkyl ether ethylenoxy sulfate salt Chemical class 0.000 claims abstract description 57
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 38
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 27
- 239000002253 acid Substances 0.000 claims abstract description 20
- 238000005187 foaming Methods 0.000 claims abstract description 20
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 18
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 13
- 239000002904 solvent Substances 0.000 claims abstract description 12
- 206010040880 Skin irritation Diseases 0.000 claims abstract description 11
- 230000036556 skin irritation Effects 0.000 claims abstract description 11
- 231100000475 skin irritation Toxicity 0.000 claims abstract description 11
- 125000002252 acyl group Chemical group 0.000 claims abstract description 10
- 239000000344 soap Substances 0.000 claims abstract description 8
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 7
- 150000007942 carboxylates Chemical group 0.000 claims abstract description 7
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 6
- 239000012736 aqueous medium Substances 0.000 claims abstract description 5
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 claims abstract 3
- 230000000576 supplementary effect Effects 0.000 claims description 29
- 229910052708 sodium Inorganic materials 0.000 claims description 28
- 239000011734 sodium Substances 0.000 claims description 28
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 26
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 17
- 125000004432 carbon atom Chemical group C* 0.000 claims description 13
- 239000004280 Sodium formate Substances 0.000 claims description 10
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 10
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical group [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 claims description 10
- 235000019254 sodium formate Nutrition 0.000 claims description 10
- 229960003237 betaine Drugs 0.000 claims description 9
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 8
- 150000001768 cations Chemical class 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 7
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 7
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 5
- 229910052700 potassium Inorganic materials 0.000 claims description 5
- 239000011591 potassium Substances 0.000 claims description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical class NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 4
- 239000004202 carbamide Chemical class 0.000 claims description 4
- YNDGLMYLSGEDHX-UHFFFAOYSA-N 1,2,4,3-trioxathiane 3,3-dioxide Chemical class O=S1(=O)OCCOO1 YNDGLMYLSGEDHX-UHFFFAOYSA-N 0.000 claims description 3
- WFIZEGIEIOHZCP-UHFFFAOYSA-M potassium formate Chemical compound [K+].[O-]C=O WFIZEGIEIOHZCP-UHFFFAOYSA-M 0.000 claims description 3
- 150000005846 sugar alcohols Polymers 0.000 claims description 2
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical class OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 claims 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 29
- 239000006260 foam Substances 0.000 abstract description 20
- 238000004851 dishwashing Methods 0.000 abstract description 15
- 230000000694 effects Effects 0.000 abstract description 10
- 239000002453 shampoo Substances 0.000 abstract description 6
- 239000003349 gelling agent Substances 0.000 abstract description 5
- 239000004519 grease Substances 0.000 abstract description 5
- 229910052799 carbon Inorganic materials 0.000 abstract description 4
- 238000004140 cleaning Methods 0.000 abstract description 4
- 238000004945 emulsification Methods 0.000 abstract description 4
- 150000001298 alcohols Chemical class 0.000 abstract description 3
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 abstract description 2
- 239000003752 hydrotrope Substances 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 39
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N EtOH Substances CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 29
- 239000000047 product Substances 0.000 description 20
- 230000007794 irritation Effects 0.000 description 11
- 239000000243 solution Substances 0.000 description 11
- 239000004615 ingredient Substances 0.000 description 10
- 239000002304 perfume Substances 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 150000005215 alkyl ethers Chemical class 0.000 description 9
- 238000001727 in vivo Methods 0.000 description 9
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 8
- 125000000129 anionic group Chemical group 0.000 description 8
- 230000000622 irritating effect Effects 0.000 description 8
- 229940048842 sodium xylenesulfonate Drugs 0.000 description 8
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 8
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 description 7
- 229940063953 ammonium lauryl sulfate Drugs 0.000 description 7
- 238000007792 addition Methods 0.000 description 6
- 238000013019 agitation Methods 0.000 description 6
- 239000002689 soil Substances 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 5
- 239000007795 chemical reaction product Substances 0.000 description 5
- 239000000499 gel Substances 0.000 description 5
- 231100000400 irritating Toxicity 0.000 description 5
- 230000003472 neutralizing effect Effects 0.000 description 5
- 235000015067 sauces Nutrition 0.000 description 5
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
- 150000004996 alkyl benzenes Chemical class 0.000 description 4
- 235000019864 coconut oil Nutrition 0.000 description 4
- 239000003240 coconut oil Substances 0.000 description 4
- 230000005484 gravity Effects 0.000 description 4
- 230000001180 sulfating effect Effects 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000008096 xylene Substances 0.000 description 4
- URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 241001465754 Metazoa Species 0.000 description 3
- JHIXEZNTXMFXEK-UHFFFAOYSA-N N-(tetradecanoyl)ethanolamine Chemical compound CCCCCCCCCCCCCC(=O)NCCO JHIXEZNTXMFXEK-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- 210000001015 abdomen Anatomy 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 108010009736 Protein Hydrolysates Proteins 0.000 description 2
- 244000299461 Theobroma cacao Species 0.000 description 2
- 235000009470 Theobroma cacao Nutrition 0.000 description 2
- 239000011149 active material Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 125000003368 amide group Chemical group 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 229940079886 disodium lauryl sulfosuccinate Drugs 0.000 description 2
- KHIQYZGEUSTKSB-UHFFFAOYSA-L disodium;4-dodecoxy-4-oxo-3-sulfobutanoate Chemical compound [Na+].[Na+].CCCCCCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O.CCCCCCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O KHIQYZGEUSTKSB-UHFFFAOYSA-L 0.000 description 2
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 2
- 229940043264 dodecyl sulfate Drugs 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- SKDZEPBJPGSFHS-UHFFFAOYSA-N n,n-bis(2-hydroxyethyl)tetradecanamide Chemical compound CCCCCCCCCCCCCC(=O)N(CCO)CCO SKDZEPBJPGSFHS-UHFFFAOYSA-N 0.000 description 2
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 2
- 239000003531 protein hydrolysate Substances 0.000 description 2
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 2
- 238000007619 statistical method Methods 0.000 description 2
- 229940117986 sulfobetaine Drugs 0.000 description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
- 239000012085 test solution Substances 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 125000005270 trialkylamine group Chemical group 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
- MARCAKLHFUYDJE-UHFFFAOYSA-N 1,2-xylene;hydrate Chemical compound O.CC1=CC=CC=C1C MARCAKLHFUYDJE-UHFFFAOYSA-N 0.000 description 1
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 1
- ZZNDQCACFUJAKJ-UHFFFAOYSA-N 1-phenyltridecan-1-one Chemical compound CCCCCCCCCCCCC(=O)C1=CC=CC=C1 ZZNDQCACFUJAKJ-UHFFFAOYSA-N 0.000 description 1
- JJPWJEGNCRGGGA-UHFFFAOYSA-N 4-[[2-[5-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-1,3,4-oxadiazol-2-yl]acetyl]amino]benzoic acid Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1=NN=C(O1)CC(=O)NC1=CC=C(C(=O)O)C=C1 JJPWJEGNCRGGGA-UHFFFAOYSA-N 0.000 description 1
- OCKGFTQIICXDQW-ZEQRLZLVSA-N 5-[(1r)-1-hydroxy-2-[4-[(2r)-2-hydroxy-2-(4-methyl-1-oxo-3h-2-benzofuran-5-yl)ethyl]piperazin-1-yl]ethyl]-4-methyl-3h-2-benzofuran-1-one Chemical compound C1=C2C(=O)OCC2=C(C)C([C@@H](O)CN2CCN(CC2)C[C@H](O)C2=CC=C3C(=O)OCC3=C2C)=C1 OCKGFTQIICXDQW-ZEQRLZLVSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 229910015900 BF3 Inorganic materials 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 101100087530 Caenorhabditis elegans rom-1 gene Proteins 0.000 description 1
- 241000700199 Cavia porcellus Species 0.000 description 1
- VGCXGMAHQTYDJK-UHFFFAOYSA-N Chloroacetyl chloride Chemical compound ClCC(Cl)=O VGCXGMAHQTYDJK-UHFFFAOYSA-N 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 1
- 241001435619 Lile Species 0.000 description 1
- 101100305983 Mus musculus Rom1 gene Proteins 0.000 description 1
- MMBILEWCGWTAOV-UHFFFAOYSA-N N-(2-Hydroxypropyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)NCC(C)O MMBILEWCGWTAOV-UHFFFAOYSA-N 0.000 description 1
- 241001585714 Nola Species 0.000 description 1
- 235000003166 Opuntia robusta Nutrition 0.000 description 1
- 244000218514 Opuntia robusta Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 108010077895 Sarcosine Proteins 0.000 description 1
- 241000282887 Suidae Species 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- LHIJANUOQQMGNT-UHFFFAOYSA-N aminoethylethanolamine Chemical compound NCCNCCO LHIJANUOQQMGNT-UHFFFAOYSA-N 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 1
- 229940106681 chloroacetic acid Drugs 0.000 description 1
- XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 238000012217 deletion Methods 0.000 description 1
- 230000037430 deletion Effects 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- UKHVLWKBNNSRRR-ODZAUARKSA-M dowicil 200 Chemical compound [Cl-].C1N(C2)CN3CN2C[N+]1(C\C=C/Cl)C3 UKHVLWKBNNSRRR-ODZAUARKSA-M 0.000 description 1
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 230000003165 hydrotropic effect Effects 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- WRUGWIBCXHJTDG-UHFFFAOYSA-L magnesium sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Mg+2].[O-]S([O-])(=O)=O WRUGWIBCXHJTDG-UHFFFAOYSA-L 0.000 description 1
- 229940061634 magnesium sulfate heptahydrate Drugs 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- APVPOHHVBBYQAV-UHFFFAOYSA-N n-(4-aminophenyl)sulfonyloctadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NS(=O)(=O)C1=CC=C(N)C=C1 APVPOHHVBBYQAV-UHFFFAOYSA-N 0.000 description 1
- 150000004005 nitrosamines Chemical class 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- DJEHXEMURTVAOE-UHFFFAOYSA-M potassium bisulfite Chemical compound [K+].OS([O-])=O DJEHXEMURTVAOE-UHFFFAOYSA-M 0.000 description 1
- 229940099427 potassium bisulfite Drugs 0.000 description 1
- 235000010259 potassium hydrogen sulphite Nutrition 0.000 description 1
- GHKGUEZUGFJUEJ-UHFFFAOYSA-M potassium;4-methylbenzenesulfonate Chemical compound [K+].CC1=CC=C(S([O-])(=O)=O)C=C1 GHKGUEZUGFJUEJ-UHFFFAOYSA-M 0.000 description 1
- 230000000063 preceeding effect Effects 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 108700004121 sarkosyl Proteins 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 1
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- GIPRGFRQMWSHAK-UHFFFAOYSA-M sodium;2-propan-2-ylbenzenesulfonate Chemical compound [Na+].CC(C)C1=CC=CC=C1S([O-])(=O)=O GIPRGFRQMWSHAK-UHFFFAOYSA-M 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000019635 sulfation Effects 0.000 description 1
- 238000005670 sulfation reaction Methods 0.000 description 1
- AGGIJOLULBJGTQ-UHFFFAOYSA-N sulfoacetic acid Chemical class OC(=O)CS(O)(=O)=O AGGIJOLULBJGTQ-UHFFFAOYSA-N 0.000 description 1
- 150000008054 sulfonate salts Chemical class 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 150000004026 tertiary sulfonium compounds Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0094—High foaming compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/126—Acylisethionates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US350,497 | 1982-02-19 | ||
| US06/350,497 US4554098A (en) | 1982-02-19 | 1982-02-19 | Mild liquid detergent compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1205347A true CA1205347A (en) | 1986-06-03 |
Family
ID=23376979
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000421891A Expired CA1205347A (en) | 1982-02-19 | 1983-02-18 | Mild liquid detergent compositions |
Country Status (19)
Families Citing this family (67)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NZ206213A (en) * | 1982-11-16 | 1985-12-13 | Unilever Plc | Foaming liquid detergent compositions containing alkylbenzenesulphonates and alkyl ether sulphates |
| JPS60132912A (ja) * | 1983-12-21 | 1985-07-16 | Kao Corp | シヤンプ−組成物 |
| GB8420945D0 (en) * | 1984-08-17 | 1984-09-19 | Unilever Plc | Detergents compositions |
| GB8428149D0 (en) * | 1984-11-07 | 1984-12-12 | Procter & Gamble Ltd | Liquid detergent compositions |
| EP0193386A3 (en) * | 1985-02-28 | 1989-05-24 | The Procter & Gamble Company | Mild detergent compositions |
| EP0203660B1 (en) * | 1985-05-28 | 1989-01-04 | Unilever N.V. | Liquid cleaning and softening compositions |
| US5167872A (en) * | 1985-10-31 | 1992-12-01 | The Procter & Gamble Company | Comprising anionic surfactant polymeric nonionic surfactant and betaine surfactant |
| US4772425A (en) * | 1985-12-23 | 1988-09-20 | Colgate-Palmolive Company | Light duty liquid dishwashing composition containing abrasive |
| US4772424A (en) * | 1986-01-08 | 1988-09-20 | The Proctor & Gamble Company | Shampoo containing mixtures of sulfate and/or sulfonate, sarcosinate and betaine surfactants |
| GB8602589D0 (en) * | 1986-02-03 | 1986-03-12 | Unilever Plc | Detergent compositions |
| US4692275A (en) * | 1986-04-23 | 1987-09-08 | Lever Brothers Company | Detergent compositions containing an alkylbenzene sulfonate and alcohol ethoxysulfate surfactant system |
| FR2601960B1 (fr) * | 1986-07-25 | 1989-05-26 | Lesieur Cotelle | Composition detergente, visqueuse, diluable et son procede d'obtention |
| US4731201A (en) * | 1986-08-12 | 1988-03-15 | Colgate-Palmolive Company | Shampoo method and composition |
| LU86839A1 (fr) * | 1987-04-10 | 1988-12-13 | Oreal | Composition cosmetique detergente et moussante,retardant le regraissage des cheveux |
| US4917842A (en) * | 1988-02-12 | 1990-04-17 | The Standard Oil Company | Process of making ceramics |
| GB8810820D0 (en) | 1988-05-06 | 1988-06-08 | Unilever Plc | Detergent compositions |
| US4931204A (en) * | 1988-11-14 | 1990-06-05 | Imaginative Research Associates, Inc. | Self-foaming oil compositions and process for making and using same |
| US5186857A (en) * | 1988-11-14 | 1993-02-16 | Imaginative Research Associates, Inc. | Self-foaming oil compositions and process for making and using same |
| US5336446A (en) * | 1989-02-21 | 1994-08-09 | Goodman Robert M | Compositions and process for non-irritating dense foaming of bath water and peri-vaginal cleaning |
| WO1990011343A1 (en) * | 1989-03-21 | 1990-10-04 | Imaginative Research Associates, Inc. | Self-foaming oil compositions and process for making and using same |
| US5066743A (en) * | 1989-03-27 | 1991-11-19 | Loctite Corporation | Two-part composition comprising a cyanoacrylate adhesive and a primer comprising a tertiary ammonium carboxylate compound |
| US4979993A (en) * | 1989-03-27 | 1990-12-25 | Loctite Corporation | Trialkylammonium alkyl carboxylate primer for cyanoacrylate bonding of polymeric substrates |
| US5075042A (en) * | 1989-05-01 | 1991-12-24 | Ppg Industries, Inc. | Surfactant blend containing an alkyl poly(ethyleneoxy)sulfonate to reduce dermal irritation |
| US5726137A (en) * | 1989-06-21 | 1998-03-10 | Colgate-Palmolive Company | Low silicone hair conditioning shampoo and non-silicone hair conditioning/style control shampoo |
| US4992213A (en) * | 1989-06-23 | 1991-02-12 | Mallett G Troy | Cleaning composition, oil dispersant and use thereof |
| JPH05503547A (ja) * | 1990-01-29 | 1993-06-10 | ザ、プロクター、エンド、ギャンブル、カンパニー | 双性洗剤界面活性剤とモノエタノールアミンおよび／またはβ―アミノアルカノールとを含有する液体硬質表面用洗剤組成物 |
| US5342549A (en) * | 1990-01-29 | 1994-08-30 | The Procter & Gamble Company | Hard surface liquid detergent compositions containing hydrocarbyl-amidoalkylenebetaine |
| US5540865A (en) * | 1990-01-29 | 1996-07-30 | The Procter & Gamble Company | Hard surface liquid detergent compositions containing hydrocarbylamidoalkylenebetaine |
| DE4003098A1 (de) * | 1990-02-02 | 1991-08-08 | Henkel Kgaa | Waessriges fluessiges reinigungsmittel |
| DE4007638A1 (de) * | 1990-03-10 | 1991-09-12 | Beiersdorf Ag | Kosmetische reinigungsmittel |
| US5336445A (en) * | 1990-03-27 | 1994-08-09 | The Procter & Gamble Company | Liquid hard surface detergent compositions containing beta-aminoalkanols |
| GB9024162D0 (en) * | 1990-11-07 | 1990-12-19 | Unilever Plc | Detergent composition |
| DE4040887C2 (de) * | 1990-12-20 | 1994-05-19 | Goldschmidt Ag Th | Verfahren zur Herstellung fließfähiger wäßriger Dispersionen von Betainen |
| US5540864A (en) * | 1990-12-21 | 1996-07-30 | The Procter & Gamble Company | Liquid hard surfce detergent compositions containing zwitterionic detergent surfactant and monoethanolamine and/or beta-aminoalkanol |
| MY109460A (en) * | 1991-10-03 | 1997-01-31 | Kao Corp | Liquid detergent composition. |
| GB9123422D0 (en) * | 1991-11-05 | 1991-12-18 | Unilever Plc | Detergent composition |
| CA2082474C (en) * | 1991-11-12 | 1998-12-29 | Karla J. Rys-Cicciari | Skin cleansing composition |
| WO1993015173A1 (en) * | 1992-01-23 | 1993-08-05 | The Procter & Gamble Company | Liquid hard surface detergent compositions containing zwitterionic and cationic detergent surfactants and monoethanolamine and/or beta-aminoalkanol |
| US5298195A (en) * | 1992-03-09 | 1994-03-29 | Amway Corporation | Liquid dishwashing detergent |
| US5310508A (en) * | 1992-07-15 | 1994-05-10 | Colgate-Palmolive Company | Mild personal cleansing compositions containing sodium alcohol ethoxy glyceryl sulfonate |
| US5536451A (en) * | 1992-10-26 | 1996-07-16 | The Procter & Gamble Company | Liquid hard surface detergent compositions containing short chain amphocarboxylate detergent surfactant |
| JPH08505424A (ja) * | 1993-01-12 | 1996-06-11 | ヘンケル・コーポレイション | 皿洗い洗剤 |
| CA2173437C (en) * | 1993-11-12 | 1999-08-31 | Ronald Anthony Masters | Liquid hard surface detergent compositions containing amphoteric detergent surfactant and perfume |
| ZA948477B (en) * | 1993-11-16 | 1996-04-29 | Colgate Palmolive Co | Gelled light duty liquid detergent |
| US5518647A (en) * | 1993-12-20 | 1996-05-21 | Colgate-Palmolive Company | Foaming liquid emulsion composition |
| US5531933A (en) * | 1993-12-30 | 1996-07-02 | The Procter & Gamble Company | Liquid hard surface detergent compositions containing specific polycarboxylate detergent builders |
| US5415805A (en) * | 1994-02-25 | 1995-05-16 | Betz Laboratories, Inc. | Corrosion inhibitor composition and method of use |
| US5602087A (en) * | 1994-08-02 | 1997-02-11 | Colgate-Palmolive Company | Composition |
| US5534198A (en) * | 1994-08-02 | 1996-07-09 | The Procter & Gamble Company | Glass cleaner compositions having good filming/streaking characteristics and substantive modifier to provide long lasting hydrophilicity |
| ES2179108T3 (es) * | 1994-08-10 | 2003-01-16 | Kao Corp | Composicion detergente. |
| WO1996014378A1 (en) * | 1994-11-08 | 1996-05-17 | Colgate-Palmolive Company | Light duty liquid cleaning compositions |
| US6524390B1 (en) * | 1995-05-16 | 2003-02-25 | C. Kerry Jones | Handwashing technique analysis |
| MX9708784A (es) * | 1995-06-01 | 1998-02-28 | Henkel Corp | Composicion de agentes tensoactivos. |
| JP2001525870A (ja) * | 1997-05-16 | 2001-12-11 | ザ、プロクター、エンド、ギャンブル、カンパニー | 調節されたｐＨ、および所望の食物汚れ除去及び泡立ち性を有する軽質液状又はゲル状皿洗い洗剤組成物 |
| US5929024A (en) * | 1997-11-20 | 1999-07-27 | Colgate Palmolive Company | Cleaning compositions |
| DE10003567A1 (de) * | 2000-01-27 | 2001-08-09 | Henkel Kgaa | Tensidkombination |
| WO2004061071A1 (ja) * | 2002-12-27 | 2004-07-22 | Kao Corporation | 洗浄剤組成物 |
| KR100604976B1 (ko) | 2004-09-03 | 2006-07-28 | 학교법인연세대학교 | 다작용기 리간드로 안정화된 수용성 나노입자 |
| KR100713745B1 (ko) * | 2006-02-27 | 2007-05-07 | 연세대학교 산학협력단 | 상전이 리간드로 코팅된 수용성 자성 또는 금속 산화물나노입자 및 이의 제조방법 |
| US20070267444A1 (en) * | 2006-05-05 | 2007-11-22 | De Buzzaccarini Francesco | Concentrated compositions contained in bottom dispensing containers |
| DE102007005942A1 (de) * | 2007-02-01 | 2008-08-07 | Henkel Ag & Co. Kgaa | Handgeschirrspülmittel mit nativer Tensidkombination |
| PL3026099T3 (pl) * | 2014-11-26 | 2021-06-14 | The Procter & Gamble Company | Saszetka czyszcząca |
| ES2714084T3 (es) * | 2014-11-26 | 2019-05-27 | Procter & Gamble | Bolsa limpiadora |
| WO2018075841A1 (en) * | 2016-10-21 | 2018-04-26 | The Procter & Gamble Company | Concentrated shampoo dosage of foam for providing hair care benefits |
| US12226505B2 (en) | 2018-10-25 | 2025-02-18 | The Procter & Gamble Company | Compositions having enhanced deposition of surfactant-soluble anti-dandruff agents |
| EP4194533B1 (en) * | 2021-12-08 | 2024-06-05 | The Procter & Gamble Company | Liquid hand dishwashing detergent composition |
| EP4253510A1 (en) | 2022-03-31 | 2023-10-04 | The Procter & Gamble Company | Liquid hand dishwashing detergent composition |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE546094A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1955-03-23 | |||
| GB1084739A (en) * | 1963-06-25 | 1967-09-27 | Marchon Products Ltd | Surface-active compositions |
| CA787878A (en) * | 1965-01-04 | 1968-06-18 | F. Pflaumer Phillip | Detergent composition |
| GB1128836A (en) * | 1966-06-10 | 1968-10-02 | Procter & Gamble Ltd | Detergent composition |
| BE759280A (fr) * | 1969-11-24 | 1971-05-24 | Procter & Gamble | Compositions detergentes liquides |
| FR2082249A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1970-03-09 | 1971-12-10 | Colgate Palmolive Co | |
| AU464487B2 (en) * | 1971-06-16 | 1975-08-11 | Colgate-Palmolive Pty. Ltd. | Light duty detergent formulations |
| GB1429637A (en) * | 1972-04-06 | 1976-03-24 | Unilever Ltd | Dishwashing compositions |
| US3898186A (en) * | 1973-04-09 | 1975-08-05 | Procter & Gamble | Dishwashing compositions containing gel forming gelatin |
| US4092273A (en) * | 1974-10-03 | 1978-05-30 | Colgate-Palmolive Company | Liquid detergent of controlled viscosity |
| US3950417A (en) * | 1975-02-28 | 1976-04-13 | Johnson & Johnson | High-lathering non-irritating detergent compositions |
| GB1547361A (en) * | 1975-03-24 | 1979-06-13 | Unilever Ltd | Hair shampoos |
| JPS5238507A (en) * | 1975-09-22 | 1977-03-25 | Kao Corp | Detergent composition |
| GB1545311A (en) * | 1976-03-16 | 1979-05-10 | Procter & Gamble Ltd | Detergent compositions |
| DE2750731C3 (de) * | 1977-11-12 | 1983-05-11 | Rewo Chemische Werke Gmbh, 6497 Steinau | Betaine und diese Verbindungen enthaltende Reinigungs-,Bade- und Desinfektionsmittel |
| US4186113A (en) * | 1978-04-03 | 1980-01-29 | Johnson & Johnson | Low irritating detergent compositions |
| DE3011549A1 (de) * | 1980-03-26 | 1981-10-01 | Henkel KGaA, 4000 Düsseldorf | Haarwasch- und koerperreinigungsmittel |
-
1982
- 1982-02-19 US US06/350,497 patent/US4554098A/en not_active Expired - Lifetime
-
1983
- 1983-02-04 NZ NZ203198A patent/NZ203198A/en unknown
- 1983-02-04 GR GR70411A patent/GR77411B/el unknown
- 1983-02-09 ZA ZA83890A patent/ZA83890B/xx unknown
- 1983-02-10 MX MX196230A patent/MX158900A/es unknown
- 1983-02-14 DK DK062683A patent/DK159068C/da not_active IP Right Cessation
- 1983-02-14 PH PH28511A patent/PH20487A/en unknown
- 1983-02-15 SE SE8300807A patent/SE456425B/sv not_active IP Right Cessation
- 1983-02-16 FR FR8302511A patent/FR2522012B1/fr not_active Expired
- 1983-02-16 DE DE3305197A patent/DE3305197C2/de not_active Expired - Lifetime
- 1983-02-17 CH CH889/83A patent/CH654590A5/de not_active IP Right Cessation
- 1983-02-18 BE BE0/210141A patent/BE895941A/fr not_active IP Right Cessation
- 1983-02-18 BR BR8300800A patent/BR8300800A/pt unknown
- 1983-02-18 CA CA000421891A patent/CA1205347A/en not_active Expired
- 1983-02-18 AU AU11643/83A patent/AU559168B2/en not_active Expired
- 1983-02-18 IT IT47741/83A patent/IT1169058B/it active
- 1983-02-18 PT PT76258A patent/PT76258B/pt not_active IP Right Cessation
- 1983-02-21 GB GB08304767A patent/GB2114996B/en not_active Expired
-
1987
- 1987-12-30 MY MY914/87A patent/MY8700914A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BR8300800A (pt) | 1983-11-16 |
| SE8300807D0 (sv) | 1983-02-15 |
| MX158900A (es) | 1989-03-29 |
| MY8700914A (en) | 1987-12-31 |
| DK62683D0 (da) | 1983-02-14 |
| AU559168B2 (en) | 1987-02-26 |
| IT8347741A0 (it) | 1983-02-18 |
| IT1169058B (it) | 1987-05-27 |
| US4554098A (en) | 1985-11-19 |
| GB2114996B (en) | 1985-11-27 |
| AU1164383A (en) | 1983-08-25 |
| FR2522012B1 (fr) | 1986-07-11 |
| SE8300807L (sv) | 1983-08-20 |
| GB8304767D0 (en) | 1983-03-23 |
| DK159068C (da) | 1991-01-28 |
| NZ203198A (en) | 1985-10-11 |
| SE456425B (sv) | 1988-10-03 |
| DK159068B (da) | 1990-08-27 |
| PT76258A (en) | 1983-03-01 |
| BE895941A (fr) | 1983-08-18 |
| DK62683A (da) | 1983-08-20 |
| GR77411B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1984-09-13 |
| DE3305197A1 (de) | 1983-09-01 |
| CH654590A5 (de) | 1986-02-28 |
| PT76258B (en) | 1986-02-04 |
| GB2114996A (en) | 1983-09-01 |
| FR2522012A1 (fr) | 1983-08-26 |
| DE3305197C2 (de) | 1994-10-27 |
| PH20487A (en) | 1987-01-16 |
| ZA83890B (en) | 1984-09-26 |
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