CA1074775A - Process for the manufacture of a catalyst - Google Patents
Process for the manufacture of a catalystInfo
- Publication number
- CA1074775A CA1074775A CA221,176A CA221176A CA1074775A CA 1074775 A CA1074775 A CA 1074775A CA 221176 A CA221176 A CA 221176A CA 1074775 A CA1074775 A CA 1074775A
- Authority
- CA
- Canada
- Prior art keywords
- aluminum
- alkyl
- product
- catalyst
- dialkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 53
- 238000000034 method Methods 0.000 title claims abstract description 24
- 238000004519 manufacturing process Methods 0.000 title abstract description 4
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 69
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 61
- -1 aluminum alkyl halides Chemical class 0.000 claims abstract description 33
- 238000007669 thermal treatment Methods 0.000 claims abstract description 19
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims abstract description 14
- 150000001336 alkenes Chemical class 0.000 claims abstract description 13
- 150000001983 dialkylethers Chemical class 0.000 claims abstract description 11
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 claims abstract description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 41
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 39
- 239000000725 suspension Substances 0.000 claims description 38
- 229920000642 polymer Polymers 0.000 claims description 36
- 239000007795 chemical reaction product Substances 0.000 claims description 35
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 34
- 239000000203 mixture Substances 0.000 claims description 25
- 239000002904 solvent Substances 0.000 claims description 19
- 229930195733 hydrocarbon Natural products 0.000 claims description 18
- 150000002430 hydrocarbons Chemical class 0.000 claims description 18
- 239000000047 product Substances 0.000 claims description 17
- 239000004215 Carbon black (E152) Substances 0.000 claims description 16
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 15
- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- 150000004820 halides Chemical class 0.000 claims description 7
- 230000001955 cumulated effect Effects 0.000 claims description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 5
- 239000005977 Ethylene Substances 0.000 claims description 5
- 239000000178 monomer Substances 0.000 claims description 5
- BRXCPUJQSHQGEU-UHFFFAOYSA-N bicyclo[4.1.0]hepta-3,5-diene Chemical compound C1C=CC=C2CC21 BRXCPUJQSHQGEU-UHFFFAOYSA-N 0.000 claims description 3
- 239000012442 inert solvent Substances 0.000 claims description 3
- 150000001805 chlorine compounds Chemical class 0.000 claims 2
- 229920001577 copolymer Polymers 0.000 claims 2
- 125000005843 halogen group Chemical group 0.000 claims 1
- 150000005673 monoalkenes Chemical class 0.000 claims 1
- 238000011282 treatment Methods 0.000 abstract description 20
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 4
- 235000010210 aluminium Nutrition 0.000 description 47
- 239000000306 component Substances 0.000 description 40
- 229940095050 propylene Drugs 0.000 description 38
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 26
- 229910010061 TiC13 Inorganic materials 0.000 description 22
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 20
- 230000007717 exclusion Effects 0.000 description 20
- 239000007787 solid Substances 0.000 description 18
- 239000000243 solution Substances 0.000 description 18
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 17
- 239000007788 liquid Substances 0.000 description 16
- 239000012452 mother liquor Substances 0.000 description 14
- 229910052757 nitrogen Inorganic materials 0.000 description 13
- 239000004743 Polypropylene Substances 0.000 description 12
- 238000007373 indentation Methods 0.000 description 12
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 10
- 239000002612 dispersion medium Substances 0.000 description 10
- 229920001155 polypropylene Polymers 0.000 description 10
- 229910052719 titanium Inorganic materials 0.000 description 10
- 239000010936 titanium Substances 0.000 description 10
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 8
- 239000007789 gas Substances 0.000 description 8
- 239000001257 hydrogen Substances 0.000 description 8
- 229910052739 hydrogen Inorganic materials 0.000 description 8
- 238000001816 cooling Methods 0.000 description 7
- 238000001035 drying Methods 0.000 description 7
- 239000002244 precipitate Substances 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- 238000007792 addition Methods 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000011521 glass Substances 0.000 description 6
- 229910010066 TiC14 Inorganic materials 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 229920006395 saturated elastomer Polymers 0.000 description 5
- 238000004448 titration Methods 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 240000007817 Olea europaea Species 0.000 description 4
- 239000012190 activator Substances 0.000 description 4
- 229910052786 argon Inorganic materials 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000010908 decantation Methods 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 239000007792 gaseous phase Substances 0.000 description 3
- UWNADWZGEHDQAB-UHFFFAOYSA-N i-Pr2C2H4i-Pr2 Natural products CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 238000010557 suspension polymerization reaction Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 2
- WWUVJRULCWHUSA-UHFFFAOYSA-N 2-methyl-1-pentene Chemical compound CCCC(C)=C WWUVJRULCWHUSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical class C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- 101100328463 Mus musculus Cmya5 gene Proteins 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 229910003074 TiCl4 Inorganic materials 0.000 description 2
- 101150050280 alsD gene Proteins 0.000 description 2
- 229920001585 atactic polymer Polymers 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- CHVJITGCYZJHLR-UHFFFAOYSA-N cyclohepta-1,3,5-triene Chemical compound C1C=CC=CC=C1 CHVJITGCYZJHLR-UHFFFAOYSA-N 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 1
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 description 1
- LDTAOIUHUHHCMU-UHFFFAOYSA-N 3-methylpent-1-ene Chemical compound CCC(C)C=C LDTAOIUHUHHCMU-UHFFFAOYSA-N 0.000 description 1
- 241001630921 Chlorida Species 0.000 description 1
- 235000008247 Echinochloa frumentacea Nutrition 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 240000004072 Panicum sumatrense Species 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 229940000425 combination drug Drugs 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 235000019628 coolness Nutrition 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- KDUIUFJBNGTBMD-VXMYFEMYSA-N cyclooctatetraene Chemical compound C1=C\C=C/C=C\C=C1 KDUIUFJBNGTBMD-VXMYFEMYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000000727 fraction Substances 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- HCTVWSOKIJULET-LQDWTQKMSA-M phenoxymethylpenicillin potassium Chemical compound [K+].N([C@H]1[C@H]2SC([C@@H](N2C1=O)C([O-])=O)(C)C)C(=O)COC1=CC=CC=C1 HCTVWSOKIJULET-LQDWTQKMSA-M 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WHFQAROQMWLMEY-UHFFFAOYSA-N propylene dimer Chemical group CC=C.CC=C WHFQAROQMWLMEY-UHFFFAOYSA-N 0.000 description 1
- 230000036647 reaction Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000002226 simultaneous effect Effects 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 235000012976 tarts Nutrition 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2413261A DE2413261A1 (de) | 1974-03-20 | 1974-03-20 | Verfahren zur herstellung eines katalysators |
| DE19752503718 DE2503718A1 (de) | 1975-01-30 | 1975-01-30 | Verfahren zur herstellung eines katalysators |
| DE19752503708 DE2503708A1 (de) | 1975-01-30 | 1975-01-30 | Verfahren zur herstellung eines katalysators |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1074775A true CA1074775A (en) | 1980-04-01 |
Family
ID=27185839
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA221,176A Expired CA1074775A (en) | 1974-03-20 | 1975-02-28 | Process for the manufacture of a catalyst |
Country Status (18)
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51123796A (en) * | 1975-04-23 | 1976-10-28 | Mitsubishi Chem Ind Ltd | Preparation process of solid titanium trichloride catalyst |
| IT1040379B (it) * | 1975-08-08 | 1979-12-20 | Montedison Spa | Componenti catalitici e catalizzatori per la polimerizzazione delle olefine |
| JPS60184510A (ja) * | 1984-03-01 | 1985-09-20 | Mitsubishi Chem Ind Ltd | 高分子量３メチルブテン−１重合体の製造方法 |
| CN116333193B (zh) * | 2023-05-22 | 2024-02-02 | 上海优铖工逸技术有限公司 | 一种齐格勒纳塔催化剂及其制备方法、应用 |
-
1975
- 1975-02-22 ES ES435000A patent/ES435000A1/es not_active Expired
- 1975-02-24 IN IN351/CAL/1975A patent/IN142675B/en unknown
- 1975-02-27 IT IT20753/75A patent/IT1033280B/it active
- 1975-02-27 FI FI750570A patent/FI750570A7/fi not_active Application Discontinuation
- 1975-02-27 LU LU71936A patent/LU71936A1/xx unknown
- 1975-02-28 IE IE430/75A patent/IE40702B1/xx unknown
- 1975-02-28 DK DK81275*#A patent/DK81275A/da unknown
- 1975-02-28 NO NO750687A patent/NO750687L/no unknown
- 1975-02-28 DD DD184497A patent/DD117813A5/xx unknown
- 1975-02-28 SE SE7502295A patent/SE7502295L/xx unknown
- 1975-02-28 GB GB8563/75A patent/GB1492132A/en not_active Expired
- 1975-02-28 BR BR1226/75A patent/BR7501226A/pt unknown
- 1975-02-28 JP JP50024113A patent/JPS50125986A/ja active Pending
- 1975-02-28 AT AT155575A patent/AT338514B/de not_active IP Right Cessation
- 1975-02-28 CA CA221,176A patent/CA1074775A/en not_active Expired
- 1975-03-01 RO RO7581720A patent/RO68474A/ro unknown
- 1975-03-03 FR FR7506527A patent/FR2272738B1/fr not_active Expired
- 1975-03-20 HU HU75HO00001777A patent/HU171909B/hu unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RO68474A (ro) | 1980-07-15 |
| FI750570A7 (enrdf_load_stackoverflow) | 1975-09-21 |
| FR2272738B1 (enrdf_load_stackoverflow) | 1978-06-23 |
| ES435000A1 (es) | 1977-03-01 |
| HU171909B (hu) | 1978-04-28 |
| AU7863675A (en) | 1976-09-02 |
| AT338514B (de) | 1977-08-25 |
| NO750687L (enrdf_load_stackoverflow) | 1975-09-23 |
| JPS50125986A (enrdf_load_stackoverflow) | 1975-10-03 |
| SE7502295L (enrdf_load_stackoverflow) | 1975-09-22 |
| BR7501226A (pt) | 1975-12-16 |
| DD117813A5 (enrdf_load_stackoverflow) | 1976-02-05 |
| IT1033280B (it) | 1979-07-10 |
| IE40702B1 (en) | 1979-08-01 |
| GB1492132A (en) | 1977-11-16 |
| IE40702L (en) | 1975-09-20 |
| DK81275A (enrdf_load_stackoverflow) | 1975-09-21 |
| IN142675B (enrdf_load_stackoverflow) | 1977-08-13 |
| ATA155575A (de) | 1976-12-15 |
| FR2272738A1 (enrdf_load_stackoverflow) | 1975-12-26 |
| LU71936A1 (enrdf_load_stackoverflow) | 1977-01-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |