CA1070379A - Active material for pressed nickel electrodes - Google Patents
Active material for pressed nickel electrodesInfo
- Publication number
- CA1070379A CA1070379A CA285,597A CA285597A CA1070379A CA 1070379 A CA1070379 A CA 1070379A CA 285597 A CA285597 A CA 285597A CA 1070379 A CA1070379 A CA 1070379A
- Authority
- CA
- Canada
- Prior art keywords
- salt
- solution
- niox
- oxidant
- coox
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract description 88
- 229910052759 nickel Inorganic materials 0.000 title claims abstract description 43
- 239000011149 active material Substances 0.000 title 1
- 229910002451 CoOx Inorganic materials 0.000 claims abstract description 27
- 229910005855 NiOx Inorganic materials 0.000 claims abstract description 23
- 239000007772 electrode material Substances 0.000 claims abstract description 16
- 239000011230 binding agent Substances 0.000 claims abstract description 9
- 239000007800 oxidant agent Substances 0.000 claims description 44
- 239000000243 solution Substances 0.000 claims description 40
- 230000001590 oxidative effect Effects 0.000 claims description 35
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims description 34
- LVIYYTJTOKJJOC-UHFFFAOYSA-N nickel phthalocyanine Chemical class [Ni+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 LVIYYTJTOKJJOC-UHFFFAOYSA-N 0.000 claims description 32
- 150000003839 salts Chemical class 0.000 claims description 23
- 239000002244 precipitate Substances 0.000 claims description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- MPMSMUBQXQALQI-UHFFFAOYSA-N cobalt phthalocyanine Chemical class [Co+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 MPMSMUBQXQALQI-UHFFFAOYSA-N 0.000 claims description 12
- 239000012266 salt solution Substances 0.000 claims description 11
- 229910017052 cobalt Inorganic materials 0.000 claims description 10
- 239000010941 cobalt Substances 0.000 claims description 10
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 10
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 9
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
- 229910052744 lithium Inorganic materials 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 8
- -1 cobaltous nitrates Chemical class 0.000 claims description 5
- 238000003825 pressing Methods 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 3
- QKDGGEBMABOMMW-UHFFFAOYSA-I [OH-].[OH-].[OH-].[OH-].[OH-].[V+5] Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[V+5] QKDGGEBMABOMMW-UHFFFAOYSA-I 0.000 claims description 3
- 229940049676 bismuth hydroxide Drugs 0.000 claims description 3
- TZSXPYWRDWEXHG-UHFFFAOYSA-K bismuth;trihydroxide Chemical compound [OH-].[OH-].[OH-].[Bi+3] TZSXPYWRDWEXHG-UHFFFAOYSA-K 0.000 claims description 3
- SXDBWCPKPHAZSM-UHFFFAOYSA-M bromate Chemical class [O-]Br(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-M 0.000 claims description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052794 bromium Inorganic materials 0.000 claims description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 3
- 150000001805 chlorine compounds Chemical class 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 239000012153 distilled water Substances 0.000 claims description 3
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims description 3
- SATVIFGJTRRDQU-UHFFFAOYSA-N potassium hypochlorite Chemical class [K+].Cl[O-] SATVIFGJTRRDQU-UHFFFAOYSA-N 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 3
- 238000000034 method Methods 0.000 claims 17
- 238000001035 drying Methods 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 abstract description 5
- 150000001868 cobalt Chemical class 0.000 abstract description 3
- 239000000470 constituent Substances 0.000 abstract description 3
- 239000000203 mixture Substances 0.000 description 12
- 229910021503 Cobalt(II) hydroxide Inorganic materials 0.000 description 8
- 239000000126 substance Substances 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 5
- 239000011883 electrode binding agent Substances 0.000 description 4
- ASKVAEGIVYSGNY-UHFFFAOYSA-L cobalt(ii) hydroxide Chemical compound [OH-].[OH-].[Co+2] ASKVAEGIVYSGNY-UHFFFAOYSA-L 0.000 description 3
- 229940058401 polytetrafluoroethylene Drugs 0.000 description 3
- 239000004810 polytetrafluoroethylene Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000005708 Sodium hypochlorite Substances 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000000975 co-precipitation Methods 0.000 description 2
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical class [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 2
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 2
- 238000010325 electrochemical charging Methods 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical class [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- SXDBWCPKPHAZSM-UHFFFAOYSA-N bromic acid Chemical compound OBr(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-N 0.000 description 1
- DKSMCEUSSQTGBK-UHFFFAOYSA-M bromite Chemical class [O-]Br=O DKSMCEUSSQTGBK-UHFFFAOYSA-M 0.000 description 1
- 229910001429 cobalt ion Inorganic materials 0.000 description 1
- XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910001453 nickel ion Inorganic materials 0.000 description 1
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229910052700 potassium Chemical class 0.000 description 1
- 239000011591 potassium Chemical class 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
- Y10T29/49115—Electric battery cell making including coating or impregnating
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/717,860 US4049027A (en) | 1976-08-26 | 1976-08-26 | Active material for pressed nickel electrodes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1070379A true CA1070379A (en) | 1980-01-22 |
Family
ID=24883788
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA285,597A Expired CA1070379A (en) | 1976-08-26 | 1977-08-26 | Active material for pressed nickel electrodes |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US4049027A (forum.php) |
| AR (1) | AR219716A1 (forum.php) |
| AU (1) | AU506821B2 (forum.php) |
| BR (1) | BR7705671A (forum.php) |
| CA (1) | CA1070379A (forum.php) |
| DE (1) | DE2738215A1 (forum.php) |
| FR (1) | FR2363204A1 (forum.php) |
| GB (1) | GB1570422A (forum.php) |
| IL (1) | IL52817A (forum.php) |
| IN (1) | IN146270B (forum.php) |
| IT (1) | IT1079938B (forum.php) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0028072B1 (en) * | 1979-10-03 | 1984-08-01 | LUCAS INDUSTRIES public limited company | A nickel electrode, a method of producing the nickel electrode and an electrochemical cell employing the nickel electrode |
| GB2068925B (en) * | 1980-02-11 | 1984-02-01 | Hibbert D B | Electrocatalyst |
| US4342699A (en) * | 1981-02-23 | 1982-08-03 | Standard Oil Company (Indiana) | Process for production of maleic anhydride |
| US4386019A (en) * | 1981-07-29 | 1983-05-31 | The United States Of America As Represented By The United States Department Of Energy | Method of making electrodes for electrochemical cell |
| US4443526A (en) * | 1982-03-03 | 1984-04-17 | Westinghouse Electric Corp. | NiCO3 Electrode material and electrode |
| US4687598A (en) * | 1983-11-07 | 1987-08-18 | The United States Of America As Represented By The United States Department Of Energy | Electrode-active material for electrochemical batteries and method of preparation |
| DE3854727T2 (de) * | 1987-03-25 | 1996-05-30 | Matsushita Electric Ind Co Ltd | Gasdichte Nickel-Hydridbatterie und Verfahren zur Herstellung. |
| DE3816232C1 (forum.php) * | 1988-05-11 | 1989-07-20 | Deutsche Automobilgesellschaft Mbh, 3000 Hannover, De | |
| EP0419220B1 (en) * | 1989-09-18 | 1994-11-17 | Toshiba Battery Co., Ltd. | Nickel-metal hydride secondary cell |
| FR2670609B1 (fr) * | 1990-12-13 | 1995-07-07 | Sorapec | Electrode positive de nickel. |
| EP0571630B1 (en) * | 1991-10-21 | 2002-01-30 | Yuasa Corporation | Method for production of nickel plate and alkali storage battery |
| JP3438142B2 (ja) * | 1992-09-18 | 2003-08-18 | 松下電器産業株式会社 | 中・大容量密閉式金属酸化物・水素蓄電池 |
| JP3738052B2 (ja) * | 1994-09-20 | 2006-01-25 | 三洋電機株式会社 | ニッケル電極用活物質とこれを用いたニッケル電極及びニッケルアルカリ蓄電池並びにこれらの製造方法 |
| JP3338277B2 (ja) * | 1995-07-04 | 2002-10-28 | 三洋電機株式会社 | アルカリ蓄電池用ニッケル電極活物質の製造方法 |
| DE69805689T2 (de) * | 1997-03-25 | 2003-01-30 | Toda Kogyo Corp., Hiroshima | Verfahren zur Herstellung von Lithium-Kobalt Oxid |
| US7261970B2 (en) * | 2004-04-23 | 2007-08-28 | Ovonic Battery Company Inc. | Nickel metal hydride battery design |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2127807A1 (de) * | 1970-06-23 | 1971-12-30 | Battelle Memorial Institute | Elektrode für die elektrochemische Reduktion von Sauerstoff und Verfahren zu ihrer Herstellung |
| US3961985A (en) * | 1973-03-10 | 1976-06-08 | Tokyo Shibaura Electric Co., Ltd. | Nickel-zinc cell |
| FR2207366A1 (en) * | 1973-11-20 | 1974-06-14 | Westinghouse Electric Corp | Electrode plate with active battery material - contg nickel (II) and nickel (III) hydroxides in 3/1 to 19/1 wt. ratio, for higher specific capacity |
| US3911094A (en) * | 1974-01-28 | 1975-10-07 | Esb Inc | Method of preparing stable NiOOH |
| US3928068A (en) * | 1974-05-20 | 1975-12-23 | Westinghouse Electric Corp | Active electrode composition and electrode |
| US3941614A (en) * | 1975-03-13 | 1976-03-02 | Westinghouse Electric Corporation | Method of preparing high capacity nickel electrode powder |
-
1976
- 1976-08-26 US US05/717,860 patent/US4049027A/en not_active Expired - Lifetime
-
1977
- 1977-08-12 GB GB33942/77A patent/GB1570422A/en not_active Expired
- 1977-08-17 AU AU28003/77A patent/AU506821B2/en not_active Expired
- 1977-08-20 IN IN1302/CAL/77A patent/IN146270B/en unknown
- 1977-08-24 IT IT50768/77A patent/IT1079938B/it active
- 1977-08-24 IL IL52817A patent/IL52817A/xx unknown
- 1977-08-24 DE DE19772738215 patent/DE2738215A1/de not_active Ceased
- 1977-08-25 FR FR7725963A patent/FR2363204A1/fr active Granted
- 1977-08-25 BR BR7705671A patent/BR7705671A/pt unknown
- 1977-08-26 AR AR268959A patent/AR219716A1/es active
- 1977-08-26 CA CA285,597A patent/CA1070379A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB1570422A (en) | 1980-07-02 |
| FR2363204A1 (fr) | 1978-03-24 |
| IN146270B (forum.php) | 1979-04-07 |
| US4049027A (en) | 1977-09-20 |
| AU506821B2 (en) | 1980-01-24 |
| IT1079938B (it) | 1985-05-13 |
| DE2738215A1 (de) | 1978-03-09 |
| AR219716A1 (es) | 1980-09-15 |
| AU2800377A (en) | 1979-03-08 |
| IL52817A (en) | 1980-06-30 |
| FR2363204B1 (forum.php) | 1981-01-09 |
| BR7705671A (pt) | 1978-05-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry | ||
| MKEX | Expiry |
Effective date: 19970122 |