CA1036615A - Copper base metallorganic compounds and process for the preparation thereof - Google Patents
Copper base metallorganic compounds and process for the preparation thereofInfo
- Publication number
- CA1036615A CA1036615A CA214,089A CA214089A CA1036615A CA 1036615 A CA1036615 A CA 1036615A CA 214089 A CA214089 A CA 214089A CA 1036615 A CA1036615 A CA 1036615A
- Authority
- CA
- Canada
- Prior art keywords
- formula
- reacting
- monovalent
- copper
- carried out
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000010949 copper Substances 0.000 title claims abstract description 37
- 150000001875 compounds Chemical class 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 title claims abstract description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 9
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 9
- 238000002360 preparation method Methods 0.000 title description 3
- 238000006243 chemical reaction Methods 0.000 claims abstract description 12
- 150000002825 nitriles Chemical class 0.000 claims abstract description 12
- 239000002184 metal Substances 0.000 claims abstract description 11
- 229910052751 metal Inorganic materials 0.000 claims abstract description 11
- 150000004703 alkoxides Chemical class 0.000 claims abstract description 8
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 7
- 150000001450 anions Chemical class 0.000 claims abstract description 7
- 150000001879 copper Chemical class 0.000 claims abstract description 7
- 150000004820 halides Chemical class 0.000 claims abstract description 7
- 150000005840 aryl radicals Chemical class 0.000 claims abstract description 6
- 239000012442 inert solvent Substances 0.000 claims abstract description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims abstract description 4
- 239000001257 hydrogen Substances 0.000 claims abstract description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 3
- 230000003647 oxidation Effects 0.000 claims abstract description 3
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 6
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 150000002430 hydrocarbons Chemical class 0.000 claims description 2
- 239000011261 inert gas Substances 0.000 claims description 2
- 230000009466 transformation Effects 0.000 abstract description 3
- 150000001336 alkenes Chemical class 0.000 abstract description 2
- 150000001408 amides Chemical class 0.000 abstract description 2
- 238000006460 hydrolysis reaction Methods 0.000 abstract description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
- 239000000047 product Substances 0.000 description 15
- 238000003756 stirring Methods 0.000 description 8
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 5
- 241000786363 Rhampholeon spectrum Species 0.000 description 5
- 229910021589 Copper(I) bromide Inorganic materials 0.000 description 2
- 239000013067 intermediate product Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- SUSQOBVLVYHIEX-UHFFFAOYSA-N phenylacetonitrile Chemical compound N#CCC1=CC=CC=C1 SUSQOBVLVYHIEX-UHFFFAOYSA-N 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- UUFQTNFCRMXOAE-UHFFFAOYSA-N 1-methylmethylene Chemical compound C[CH] UUFQTNFCRMXOAE-UHFFFAOYSA-N 0.000 description 1
- 239000005749 Copper compound Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000012295 chemical reaction liquid Substances 0.000 description 1
- 150000001880 copper compounds Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- FVSKHRXBFJPNKK-UHFFFAOYSA-N propionitrile Chemical compound CCC#N FVSKHRXBFJPNKK-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- C07F1/08—Copper compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT31501/73A IT1006641B (it) | 1973-11-21 | 1973-11-21 | Composti metallorganici a base di rame e processo per la loro pre parazione |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1036615A true CA1036615A (en) | 1978-08-15 |
Family
ID=11233702
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA214,089A Expired CA1036615A (en) | 1973-11-21 | 1974-11-19 | Copper base metallorganic compounds and process for the preparation thereof |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US3966782A (no) |
| JP (1) | JPS535655B2 (no) |
| BE (1) | BE822402A (no) |
| CA (1) | CA1036615A (no) |
| CH (1) | CH606034A5 (no) |
| DK (1) | DK140102B (no) |
| ES (1) | ES432366A1 (no) |
| FR (1) | FR2251566B1 (no) |
| GB (1) | GB1444855A (no) |
| IE (1) | IE41827B1 (no) |
| IT (1) | IT1006641B (no) |
| LU (1) | LU71321A1 (no) |
| NL (1) | NL169077C (no) |
| NO (1) | NO143745C (no) |
| ZA (1) | ZA747358B (no) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS608862B2 (ja) * | 1976-04-15 | 1985-03-06 | 住友化学工業株式会社 | ケタジン製造用高分子触媒およびその製造方法および該触媒を用いるケタジンの製造方法 |
| US4749802A (en) * | 1984-09-17 | 1988-06-07 | University Of Iowa Research Foundation, Inc. | Method of preparation of trifluoromethyl copper and trifluoromethyl aromatics |
| IT1245393B (it) * | 1991-03-22 | 1994-09-20 | Eniricerche Spa | Bistema catalitico e procedimento per la produzione di metanolo da gas di sintesi in fase liquida |
| JP3186643B2 (ja) * | 1997-05-08 | 2001-07-11 | 日本電気株式会社 | 充電器および充電器と携帯無線機とからなる無線装置 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3221026A (en) * | 1962-02-13 | 1965-11-30 | Du Pont | Salts of 1,1-dicyano-2,2,2-trialkoxyethanes |
| BE760081A (fr) * | 1969-12-11 | 1971-06-09 | Halcon International Inc | Nouveaux complexes de bromure cuivreux ou de chlorure cuivreux et d'adiponitrile, ainsi que leurs procedes de preparation |
-
1973
- 1973-11-21 IT IT31501/73A patent/IT1006641B/it active
-
1974
- 1974-11-07 GB GB4827074A patent/GB1444855A/en not_active Expired
- 1974-11-11 IE IE2313/74A patent/IE41827B1/en unknown
- 1974-11-15 US US05/524,311 patent/US3966782A/en not_active Expired - Lifetime
- 1974-11-18 ZA ZA00747358A patent/ZA747358B/xx unknown
- 1974-11-18 FR FR7437905A patent/FR2251566B1/fr not_active Expired
- 1974-11-18 CH CH1531574A patent/CH606034A5/xx not_active IP Right Cessation
- 1974-11-19 CA CA214,089A patent/CA1036615A/en not_active Expired
- 1974-11-20 NO NO744177A patent/NO143745C/no unknown
- 1974-11-20 JP JP13283874A patent/JPS535655B2/ja not_active Expired
- 1974-11-20 LU LU71321A patent/LU71321A1/xx unknown
- 1974-11-20 DK DK603674AA patent/DK140102B/da not_active IP Right Cessation
- 1974-11-20 BE BE150687A patent/BE822402A/xx unknown
- 1974-11-21 NL NLAANVRAGE7415230,A patent/NL169077C/xx not_active IP Right Cessation
- 1974-11-21 ES ES432366A patent/ES432366A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| IE41827L (en) | 1975-05-21 |
| JPS5083333A (no) | 1975-07-05 |
| DK140102C (no) | 1979-11-26 |
| GB1444855A (en) | 1976-08-04 |
| ES432366A1 (es) | 1977-01-01 |
| LU71321A1 (no) | 1975-05-28 |
| NL169077B (nl) | 1982-01-04 |
| NO744177L (no) | 1975-06-16 |
| DK603674A (no) | 1975-07-21 |
| ZA747358B (en) | 1975-11-26 |
| IT1006641B (it) | 1976-10-20 |
| JPS535655B2 (no) | 1978-03-01 |
| DE2455217A1 (de) | 1975-06-26 |
| US3966782A (en) | 1976-06-29 |
| NL169077C (nl) | 1982-06-01 |
| DE2455217B2 (de) | 1976-05-13 |
| DK140102B (da) | 1979-06-18 |
| IE41827B1 (en) | 1980-04-09 |
| BE822402A (fr) | 1975-03-14 |
| NO143745B (no) | 1980-12-29 |
| NO143745C (no) | 1981-04-08 |
| AU7521074A (en) | 1976-05-13 |
| CH606034A5 (no) | 1978-10-13 |
| NL7415230A (nl) | 1975-05-23 |
| FR2251566A1 (no) | 1975-06-13 |
| FR2251566B1 (no) | 1976-12-31 |
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