BRPI1009577B1 - processo para preparar uma mistura de gás rica em hidrogênio - Google Patents

processo para preparar uma mistura de gás rica em hidrogênio Download PDF

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Publication number
BRPI1009577B1
BRPI1009577B1 BRPI1009577A BRPI1009577A BRPI1009577B1 BR PI1009577 B1 BRPI1009577 B1 BR PI1009577B1 BR PI1009577 A BRPI1009577 A BR PI1009577A BR PI1009577 A BRPI1009577 A BR PI1009577A BR PI1009577 B1 BRPI1009577 B1 BR PI1009577B1
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BR
Brazil
Prior art keywords
mixture
gas
gas mixture
halogen
hydrogen rich
Prior art date
Application number
BRPI1009577A
Other languages
English (en)
Inventor
Jan Prins Mark
Simon Henri Fleys Matthieu
Van Den Berg Robert
Original Assignee
Air Prod & Chem
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=40912110&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=BRPI1009577(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Air Prod & Chem, Shell Int Research filed Critical Air Prod & Chem
Publication of BRPI1009577A2 publication Critical patent/BRPI1009577A2/pt
Publication of BRPI1009577B1 publication Critical patent/BRPI1009577B1/pt

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/52—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with liquids; Regeneration of used liquids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/466—Entrained flow processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/002—Removal of contaminants
    • C10K1/003—Removal of contaminants of acid contaminants, e.g. acid gas removal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/10—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
    • C10K1/101—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids with water only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C01B2203/0288—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step containing two CO-shift steps
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0415—Purification by absorption in liquids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

processo para preparar uma mistura de gás rica em hidrogênio processo para preparar uma mistura de gás rica em hidrogênio a partir de uma mistura de gás contendo halogênio compreendendo hidrogênio e pelo menos 50% em volume de monóxido de carbono, em uma base seca, contatando a mistura de gás contendo halogênio com água tendo uma temperatura de entre 150 e 250 °c para obter uma mistura de gás pobre em halogênio e tendo uma relação molar de monóxido de carbono para vapor de entre 0,2:1 e 0,9:1 e submetendo dita mistura de gás pobre em halogênio a uma reação de deslocamento do gás de água em que parte todo o monóxido de carbono é convertido com o vapor em hidrogênio e dióxido de carbono na presença de um catalisador como presente em um reator de leito fixo ou em uma série de mais que um reator de leito fixo e em que a temperatura da mistura de gás conforme ela entra no reator ou reatores está entre 190 e 230 °c.
BRPI1009577A 2009-03-19 2010-03-18 processo para preparar uma mistura de gás rica em hidrogênio BRPI1009577B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP09155616 2009-03-19
PCT/EP2010/053560 WO2010106148A1 (en) 2009-03-19 2010-03-18 Process to prepare a hydrogen rich gas mixture

Publications (2)

Publication Number Publication Date
BRPI1009577A2 BRPI1009577A2 (pt) 2016-03-08
BRPI1009577B1 true BRPI1009577B1 (pt) 2020-04-28

Family

ID=40912110

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI1009577A BRPI1009577B1 (pt) 2009-03-19 2010-03-18 processo para preparar uma mistura de gás rica em hidrogênio

Country Status (12)

Country Link
US (1) US8679450B2 (pt)
EP (1) EP2408709B2 (pt)
JP (1) JP2012520819A (pt)
KR (1) KR101751076B1 (pt)
AU (1) AU2010224845B2 (pt)
BR (1) BRPI1009577B1 (pt)
CA (1) CA2755325C (pt)
MY (1) MY154030A (pt)
PL (1) PL215440B1 (pt)
RU (1) RU2515967C2 (pt)
UA (1) UA103079C2 (pt)
WO (1) WO2010106148A1 (pt)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8703094B2 (en) * 2009-06-30 2014-04-22 Shell Oil Company Process to prepare a hydrogen rich gas mixture
GB201119957D0 (en) 2011-11-18 2012-01-04 Johnson Matthey Plc Process
GB201119962D0 (en) 2011-11-18 2012-01-04 Johnson Matthey Plc Process
GB201119960D0 (en) 2011-11-18 2012-01-04 Johnson Matthey Plc Process
US9023243B2 (en) * 2012-08-27 2015-05-05 Proton Power, Inc. Methods, systems, and devices for synthesis gas recapture
US9458014B2 (en) * 2012-12-28 2016-10-04 General Electronic Company Sytems and method for CO2 capture and H2 separation with three water-gas shift reactions and warm desulfurization
RU2755470C1 (ru) * 2020-08-04 2021-09-16 Федеральное государственное автономное образовательное учреждение высшего образования "Сибирский федеральный университет" Способ получения газа, обогащенного водородом, из газообразного углеводородного сырья

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1964810C3 (de) * 1969-12-24 1979-04-05 Siemens Ag, 1000 Berlin Und 8000 Muenchen Vorrichtung zur Gewinnung von Wasserstoff
US4021366A (en) * 1975-06-30 1977-05-03 Texaco Inc. Production of hydrogen-rich gas
GB1578365A (en) * 1977-05-09 1980-11-05 Ici Ltd Hydrogen
JPS60156553A (ja) * 1984-01-26 1985-08-16 Nippon Shokubai Kagaku Kogyo Co Ltd 一酸化炭素転化反応用触媒
US4704137A (en) * 1987-02-09 1987-11-03 Texaco Inc. Process for upgrading water used in cooling and cleaning of raw synthesis gas
NL185225C (nl) * 1988-01-13 1992-03-16 Comprimo Bv Werkwijze voor het omzetten en verwijderen van zwavelverbindingen uit een co-bevattend gas.
CN1039099C (zh) 1992-01-16 1998-07-15 国际壳牌研究有限公司 从流体中过滤固体颗粒的设备
JPH10204448A (ja) * 1997-01-28 1998-08-04 Ishikawajima Harima Heavy Ind Co Ltd ガス化発電装置
US6033456A (en) * 1998-02-06 2000-03-07 Texaco Inc. Integration of partial oxidation process and direct reduction reaction process
NO319681B1 (no) * 1998-09-16 2005-09-05 Statoil Asa Fremgangsmate for fremstilling av en H2-rik gass og en CO2-rik gass ved hoyt trykk
EP1195353A4 (en) * 1999-04-02 2003-01-22 Ebara Corp PROCESS AND APPARATUS FOR PRODUCING HYDROGEN BY GASIFICATION OF FUEL
US6211254B1 (en) * 1999-06-07 2001-04-03 John P. Whitney Process for recycling heterogeneous waste
GB9920871D0 (en) * 1999-09-06 1999-11-10 Ici Plc Catalysts
EP1499418B1 (en) 2002-03-26 2006-01-11 Shell Internationale Researchmaatschappij B.V. Filter assembly comprising filter elements and a filter grid
GB0218785D0 (en) * 2002-08-13 2002-09-18 Ici Plc Catalyst bed combination
JP2004189993A (ja) * 2002-12-13 2004-07-08 Sumitomo Heavy Ind Ltd ガス精製方法、ガス精製装置及びこれを用いた石炭ガス化発電システム
JP4745219B2 (ja) * 2003-03-18 2011-08-10 ケロッグ ブラウン アンド ルート，インコーポレイテッド 水素製造用の自己熱改質装置−改質交換器の配置
US20070225382A1 (en) * 2005-10-14 2007-09-27 Van Den Berg Robert E Method for producing synthesis gas or a hydrocarbon product
EP1939138A1 (en) 2006-12-08 2008-07-02 Shell Internationale Researchmaatschappij B.V. A process of increasing the hydrogen/carbon monoxide molar ratio in a synthesis gas
DE102007015245A1 (de) * 2007-03-29 2008-10-02 Linde Ag Verfahren und Vorrichtung zur Erzeugung von Synthesegas
CN101050391B (zh) † 2007-03-30 2011-04-13 青岛联信化学有限公司 一种粉煤气化低水/气耐硫变换工艺

Also Published As

Publication number Publication date
AU2010224845B2 (en) 2013-08-22
RU2515967C2 (ru) 2014-05-20
JP2012520819A (ja) 2012-09-10
BRPI1009577A2 (pt) 2016-03-08
AU2010224845A1 (en) 2011-09-22
KR20110139746A (ko) 2011-12-29
PL396441A1 (pl) 2012-04-23
PL215440B1 (pl) 2013-12-31
EP2408709B1 (en) 2013-01-30
MY154030A (en) 2015-04-30
CA2755325A1 (en) 2010-09-23
RU2011142140A (ru) 2013-04-27
US8679450B2 (en) 2014-03-25
CA2755325C (en) 2019-05-28
KR101751076B1 (ko) 2017-06-26
UA103079C2 (uk) 2013-09-10
EP2408709A1 (en) 2012-01-25
EP2408709B2 (en) 2017-11-01
US20120001126A1 (en) 2012-01-05
WO2010106148A1 (en) 2010-09-23

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B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B25A Requested transfer of rights approved

Owner name: AIR PRODUCTS AND CHEMICALS, INC. (US)

B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 28/04/2020, OBSERVADAS AS CONDICOES LEGAIS.