BRPI0916797B1 - vaso de reação, e processo para preparação de sulfeto de hidrogênio - Google Patents
vaso de reação, e processo para preparação de sulfeto de hidrogênio Download PDFInfo
- Publication number
- BRPI0916797B1 BRPI0916797B1 BRPI0916797A BRPI0916797A BRPI0916797B1 BR PI0916797 B1 BRPI0916797 B1 BR PI0916797B1 BR PI0916797 A BRPI0916797 A BR PI0916797A BR PI0916797 A BRPI0916797 A BR PI0916797A BR PI0916797 B1 BRPI0916797 B1 BR PI0916797B1
- Authority
- BR
- Brazil
- Prior art keywords
- sulfur
- reaction vessel
- reaction
- pressure
- gas
- Prior art date
Links
- 238000006243 chemical reaction Methods 0.000 title claims description 60
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title claims description 34
- 229910000037 hydrogen sulfide Inorganic materials 0.000 title claims description 33
- 238000004519 manufacturing process Methods 0.000 title claims 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 78
- 229910052717 sulfur Inorganic materials 0.000 claims description 77
- 239000011593 sulfur Substances 0.000 claims description 77
- 239000007788 liquid Substances 0.000 claims description 54
- 239000007789 gas Substances 0.000 claims description 51
- 229910052739 hydrogen Inorganic materials 0.000 claims description 33
- 239000001257 hydrogen Substances 0.000 claims description 33
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 32
- 239000003153 chemical reaction reagent Substances 0.000 claims description 20
- 239000003054 catalyst Substances 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 13
- 239000000376 reactant Substances 0.000 claims description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- 239000007795 chemical reaction product Substances 0.000 claims description 5
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims description 3
- 229910052787 antimony Inorganic materials 0.000 claims description 3
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 3
- 229910052785 arsenic Inorganic materials 0.000 claims description 3
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 3
- 229910052797 bismuth Inorganic materials 0.000 claims description 3
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 3
- 229910017052 cobalt Inorganic materials 0.000 claims description 3
- 239000010941 cobalt Substances 0.000 claims description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
- 238000005984 hydrogenation reaction Methods 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 239000011574 phosphorus Substances 0.000 claims description 3
- 229910052711 selenium Inorganic materials 0.000 claims description 3
- 239000011669 selenium Substances 0.000 claims description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052721 tungsten Inorganic materials 0.000 claims description 3
- 239000010937 tungsten Substances 0.000 claims description 3
- 229910052720 vanadium Inorganic materials 0.000 claims description 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 3
- 230000003068 static effect Effects 0.000 claims description 2
- 230000001174 ascending effect Effects 0.000 claims 1
- 230000007797 corrosion Effects 0.000 description 17
- 238000005260 corrosion Methods 0.000 description 17
- 238000003786 synthesis reaction Methods 0.000 description 12
- 230000015572 biosynthetic process Effects 0.000 description 11
- 239000012071 phase Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 7
- 229910000831 Steel Inorganic materials 0.000 description 6
- 239000010959 steel Substances 0.000 description 6
- 238000001816 cooling Methods 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- LSDPWZHWYPCBBB-UHFFFAOYSA-N methyl mercaptane Natural products SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- HHVIBTZHLRERCL-UHFFFAOYSA-N sulfonyldimethane Chemical compound CS(C)(=O)=O HHVIBTZHLRERCL-UHFFFAOYSA-N 0.000 description 2
- 230000008016 vaporization Effects 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910020599 Co 3 O 4 Inorganic materials 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 235000019994 cava Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000010574 gas phase reaction Methods 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 239000002638 heterogeneous catalyst Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- -1 saturated sulfur hydrogen Chemical class 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 230000019086 sulfide ion homeostasis Effects 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 231100000925 very toxic Toxicity 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910001868 water Inorganic materials 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
- B01J8/025—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical shaped bed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J10/00—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor
- B01J10/005—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor carried out at high temperatures in the presence of a molten material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2455—Stationary reactors without moving elements inside provoking a loop type movement of the reactants
- B01J19/246—Stationary reactors without moving elements inside provoking a loop type movement of the reactants internally, i.e. the mixture circulating inside the vessel such that the upward stream is separated physically from the downward stream(s)
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/16—Hydrogen sulfides
- C01B17/161—Preparation from elemental sulfur
- C01B17/162—Preparation from elemental sulfur from elemental sulfur and hydrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Catalysts (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102008040544A DE102008040544A1 (de) | 2008-07-18 | 2008-07-18 | Reaktionsbehälter und Verfahren zur Verwendung |
| PCT/EP2009/058388 WO2010006932A1 (de) | 2008-07-18 | 2009-07-03 | Reaktionsbehälter und verfahren zur verwendung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0916797A2 BRPI0916797A2 (pt) | 2018-02-20 |
| BRPI0916797B1 true BRPI0916797B1 (pt) | 2018-09-18 |
Family
ID=41165616
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0916797A BRPI0916797B1 (pt) | 2008-07-18 | 2009-07-03 | vaso de reação, e processo para preparação de sulfeto de hidrogênio |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US7833508B2 (enExample) |
| EP (2) | EP2300144A1 (enExample) |
| JP (1) | JP5886045B2 (enExample) |
| KR (1) | KR101633140B1 (enExample) |
| CN (1) | CN102099103B (enExample) |
| BR (1) | BRPI0916797B1 (enExample) |
| DE (1) | DE102008040544A1 (enExample) |
| ES (1) | ES2709122T3 (enExample) |
| MX (1) | MX2010013441A (enExample) |
| MY (1) | MY179997A (enExample) |
| RU (1) | RU2517510C2 (enExample) |
| WO (1) | WO2010006932A1 (enExample) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101911563B1 (ko) | 2011-02-23 | 2018-10-24 | 에보니크 데구사 게엠베하 | 3-(메틸티오)프로판알 및 시안화수소로부터 2-히드록시-4-(메틸티오)부탄니트릴을 제조하는 방법 |
| DE102011081828A1 (de) | 2011-08-30 | 2013-02-28 | Evonik Degussa Gmbh | Verfahren zur Umsetzung von Methylmercaptopropionaldehyd aus Roh-Acrolein und Roh-Methylmercaptan |
| BR112014003602B1 (pt) | 2011-08-30 | 2021-05-18 | Evonik Operations Gmbh | sistema de reação e método para produção contínua de um sal de metionina |
| CN102500285B (zh) * | 2011-11-03 | 2014-04-23 | 烟台大学 | 一种硫化氢合成装置 |
| EP2676928A1 (de) | 2012-06-22 | 2013-12-25 | Evonik Industries AG | Reaktor und Verfahren zur Herstellung von Schwefelwasserstoff |
| EP2676925A1 (de) | 2012-06-22 | 2013-12-25 | Evonik Industries AG | Reaktor und Verfahren zur Herstellung von Schwefelwasserstoff |
| EP2676927A1 (de) * | 2012-06-22 | 2013-12-25 | Evonik Industries AG | Reaktor und Verfahren zur Herstellung von Schwefelwasserstoff |
| EP2676926A1 (de) * | 2012-06-22 | 2013-12-25 | Evonik Industries AG | Reaktor und Verfahren zur Herstellung von Schwefelwasserstoff |
| CN103272538A (zh) * | 2013-04-26 | 2013-09-04 | 中昊光明化工研究设计院有限公司 | 液埋气室式反应塔 |
| US20180346667A1 (en) | 2015-11-24 | 2018-12-06 | Carlsberg A/S | Plant based material for injection molding |
| WO2017099783A1 (en) | 2015-12-10 | 2017-06-15 | Hasenberg Daniel M | Hydrogen sulfide production process and related reactor vessels |
| AU2017275468A1 (en) | 2016-05-31 | 2018-11-08 | Novus International Inc. | Process for producing methyl mercaptan from dimethyl sulfide |
| CN112770834B (zh) * | 2018-09-05 | 2023-07-21 | 巴斯夫欧洲公司 | 进行气/液两相高压反应的方法 |
| JP7674157B2 (ja) * | 2021-05-31 | 2025-05-09 | 古河機械金属株式会社 | 硫化水素製造装置および硫化水素の製造方法 |
| KR102623738B1 (ko) * | 2021-08-11 | 2024-01-11 | 주식회사 레이크테크놀로지 | 황화수소 반응기 및 황화수소 제조방법 |
| JP7729109B2 (ja) * | 2021-08-17 | 2025-08-26 | 住友金属鉱山株式会社 | 硫化水素反応装置 |
| KR102674768B1 (ko) * | 2021-10-28 | 2024-06-13 | 주식회사 레이크테크놀로지 | 황화수소 반응기 |
| KR102720624B1 (ko) * | 2021-10-28 | 2024-10-23 | 주식회사 레이크테크놀로지 | 황화수소 반응기 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE558432C (de) * | 1930-09-27 | 1932-09-07 | I G Farbenindustrie Akt Ges | Verfahren zur Herstellung von Schwefelwasserstoff |
| US2876070A (en) * | 1955-03-28 | 1959-03-03 | Chemetron Corp | Method for producing hydrogen sulfide by synthesis |
| US2876071A (en) * | 1955-05-31 | 1959-03-03 | Chemetron Corp | Method for producing hydrogen sulfide by synthesis |
| US2877099A (en) * | 1956-08-15 | 1959-03-10 | Socony Mobil Oil Co | Multistage concurrent-countercurrent liquid gas contact and apparatus therefor |
| DE1193040B (de) | 1960-03-10 | 1965-05-20 | Inventa A G Fuer Forschung | Verfahren zur Herstellung von Cyclohexanon |
| FR1593276A (enExample) | 1967-12-19 | 1970-05-25 | ||
| US4094961A (en) | 1974-11-07 | 1978-06-13 | Ralph M. Parsons Company | Hydrogen sulfide production |
| CA1088276A (en) * | 1976-08-02 | 1980-10-28 | Paul T. Pendergraft | Process for removal of hydrogen sulfide and hydrogen polysulfide from liquid sulfur |
| CS190793B1 (en) | 1976-11-25 | 1979-06-29 | Pavol Klucovsky | Process for preparing hydrogen sulphide from gaseous hydrogen and sulphide vapours |
| CS190792B1 (en) | 1976-11-25 | 1979-06-29 | Milan Karvas | Process for preparing hydrogen sulphide |
| SU833479A1 (ru) * | 1979-10-29 | 1981-05-30 | Институт Газа Академии Наук Усср | Способ получени восстановительногогАзА, СОдЕРжАщЕгО СЕРОВОдОРОд и ОКиСьуглЕРОдА |
| DE68920358T2 (de) * | 1988-04-07 | 1995-06-29 | Jgc Corp | Verfahren zur Herstellung von Schwefelwasserstoff. |
| JPH01257109A (ja) * | 1988-04-07 | 1989-10-13 | Jgc Corp | 硫化水素の製造方法 |
| JPH03103311A (ja) * | 1989-09-14 | 1991-04-30 | Jgc Corp | 硫化水素の製造方法およびその製造装置 |
| US5130102A (en) * | 1990-06-11 | 1992-07-14 | Chemical Research & Licensing Company | Catalytic distillation reactor |
| US5686056A (en) * | 1996-02-05 | 1997-11-11 | Bechtel Group, Inc. | Methods and apparatus for purifying hydrogen sulfide |
| JPH10192692A (ja) * | 1997-01-13 | 1998-07-28 | Jgc Corp | 気液接触反応器 |
| DE102006019590A1 (de) * | 2006-04-27 | 2007-10-31 | Degussa Gmbh | Reaktionsbehälter für die Herstellung von Schwefelwasserstoff |
-
2008
- 2008-07-18 DE DE102008040544A patent/DE102008040544A1/de not_active Ceased
-
2009
- 2009-07-03 MY MYPI2011000223A patent/MY179997A/en unknown
- 2009-07-03 RU RU2011105738/05A patent/RU2517510C2/ru not_active IP Right Cessation
- 2009-07-03 KR KR1020117001163A patent/KR101633140B1/ko not_active Expired - Fee Related
- 2009-07-03 EP EP09780121A patent/EP2300144A1/de not_active Withdrawn
- 2009-07-03 WO PCT/EP2009/058388 patent/WO2010006932A1/de not_active Ceased
- 2009-07-03 BR BRPI0916797A patent/BRPI0916797B1/pt not_active IP Right Cessation
- 2009-07-03 JP JP2011517849A patent/JP5886045B2/ja not_active Expired - Fee Related
- 2009-07-03 CN CN200980128187.0A patent/CN102099103B/zh not_active Expired - Fee Related
- 2009-07-03 MX MX2010013441A patent/MX2010013441A/es active IP Right Grant
- 2009-07-03 EP EP16165339.9A patent/EP3067115B1/de not_active Not-in-force
- 2009-07-03 ES ES16165339T patent/ES2709122T3/es active Active
- 2009-07-10 US US12/501,114 patent/US7833508B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN102099103A (zh) | 2011-06-15 |
| RU2517510C2 (ru) | 2014-05-27 |
| JP5886045B2 (ja) | 2016-03-16 |
| EP3067115B1 (de) | 2018-10-31 |
| US20100015037A1 (en) | 2010-01-21 |
| US7833508B2 (en) | 2010-11-16 |
| ES2709122T3 (es) | 2019-04-15 |
| MX2010013441A (es) | 2011-01-21 |
| KR101633140B1 (ko) | 2016-06-23 |
| RU2011105738A (ru) | 2012-08-27 |
| KR20110044205A (ko) | 2011-04-28 |
| EP2300144A1 (de) | 2011-03-30 |
| WO2010006932A1 (de) | 2010-01-21 |
| CN102099103B (zh) | 2015-06-03 |
| BRPI0916797A2 (pt) | 2018-02-20 |
| EP3067115A1 (de) | 2016-09-14 |
| DE102008040544A1 (de) | 2010-01-21 |
| JP2011528277A (ja) | 2011-11-17 |
| MY179997A (en) | 2020-11-19 |
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