BRPI0509808A - processo para converter alcanos gasosos em hidrocarbonetos lìquidos - Google Patents

processo para converter alcanos gasosos em hidrocarbonetos lìquidos

Info

Publication number
BRPI0509808A
BRPI0509808A BRPI0509808-4A BRPI0509808A BRPI0509808A BR PI0509808 A BRPI0509808 A BR PI0509808A BR PI0509808 A BRPI0509808 A BR PI0509808A BR PI0509808 A BRPI0509808 A BR PI0509808A
Authority
BR
Brazil
Prior art keywords
hydrobromic acid
vapor
hydrocarbons
liquid hydrocarbons
gaseous alkanes
Prior art date
Application number
BRPI0509808-4A
Other languages
English (en)
Inventor
John J Waycuilis
Original Assignee
Marathon Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US10/826,885 external-priority patent/US7244867B2/en
Application filed by Marathon Oil Co filed Critical Marathon Oil Co
Publication of BRPI0509808A publication Critical patent/BRPI0509808A/pt
Publication of BRPI0509808B1 publication Critical patent/BRPI0509808B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/09—Bromine; Hydrogen bromide
    • C01B7/093—Hydrogen bromide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/09—Bromine; Hydrogen bromide
    • C01B7/096—Bromine
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B9/00—General methods of preparing halides
    • C01B9/04—Bromides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1025—Natural gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PROCESSO PARA CONVERTER ALCANOS GASOSOS EM HIDROCARBONETOS LìQUIDOS. Processo para converter alcanos gasosos em hidrocarbonetos líquidos, onde uma alimentação gasosa contendo alcanos é reagida com um vapor seco de bromo para formar brometos de alquila e vapor de ácido hidrobromídrico. A mistura de brometos de alquila e ácido hidrobromídrico é, então, reagida sobre um catalisador de silicato de alumínio cristalina sintético, tal como um zeólito ZSM-5, a uma temperatura de cerca de 150<198>C a cerca de 45O<198> C, a fim de formar hidrocarbonetos com maior peso molecular e vapor e ácido hidrobromídrico. Propano e butano, que contêm uma porção dos produtos, podem ser recuperados ou reciclados de volta através do processo, para tomar hidrocarbonetos C5+ adicionais. Vários métodos são divulgados para remover o vapor de ácido hidrobromídrico dos hidrocarbonetos de maior peso molecular e para gerar bromo a partir do ácido hidrobromídrico para uso no processo.
BRPI0509808-4A 2004-04-16 2005-04-15 Processo para converter alcanos gasosos em hidrocarbonetos líquidos BRPI0509808B1 (pt)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US10/826,885 2004-04-16
US10/826,885 US7244867B2 (en) 2004-04-16 2004-04-16 Process for converting gaseous alkanes to liquid hydrocarbons
US11/101,886 US7348464B2 (en) 2004-04-16 2005-04-08 Process for converting gaseous alkanes to liquid hydrocarbons
US11/101,886 2005-04-08
PCT/US2005/012655 WO2005104689A2 (en) 2004-04-16 2005-04-15 Process for converting gaseous alkanes to liquid hydrocarbons

Publications (2)

Publication Number Publication Date
BRPI0509808A true BRPI0509808A (pt) 2007-09-18
BRPI0509808B1 BRPI0509808B1 (pt) 2015-04-07

Family

ID=35242120

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0509808-4A BRPI0509808B1 (pt) 2004-04-16 2005-04-15 Processo para converter alcanos gasosos em hidrocarbonetos líquidos

Country Status (10)

Country Link
EP (1) EP1735255A4 (pt)
JP (1) JP5150249B2 (pt)
KR (1) KR101170773B1 (pt)
AR (1) AR051257A1 (pt)
AU (1) AU2005237458B2 (pt)
BR (1) BRPI0509808B1 (pt)
CA (1) CA2561133C (pt)
MX (1) MXPA06011655A (pt)
NO (1) NO20065250L (pt)
WO (1) WO2005104689A2 (pt)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8173851B2 (en) * 2004-04-16 2012-05-08 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US20060100469A1 (en) 2004-04-16 2006-05-11 Waycuilis John J Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US8642822B2 (en) 2004-04-16 2014-02-04 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
US7244867B2 (en) 2004-04-16 2007-07-17 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US20080275284A1 (en) 2004-04-16 2008-11-06 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
CN101312784B (zh) 2005-11-23 2011-06-22 国际壳牌研究有限公司 通过矿物碳酸盐化隔离二氧化碳的方法
EP1993979A4 (en) * 2006-02-03 2011-07-06 Grt Inc CONTINUOUS PROCESS FOR CONVERTING NATURAL GAS TO LIQUID HYDROCARBONS
EP1837320A1 (en) 2006-03-23 2007-09-26 ETH Zürich Production of saturated C2 to C5 hydrocarbons
EP2039044A2 (en) 2006-06-21 2009-03-25 Qualcomm Incorporated Methods and apparatus for measuring, communicating and/or using interference information
CA2653602A1 (en) 2006-06-21 2007-12-27 Qualcomm Incorporated Wireless resource allocation methods and apparatus
TWI372539B (en) 2006-06-23 2012-09-11 Qualcomm Inc Methods and systems for processing overhead reduction for control channel packets
CN101284232B (zh) * 2007-04-13 2013-01-16 微宏动力系统（湖州）有限公司 甲烷溴氧化制溴甲烷及其转化制碳氢化合物的催化剂
EP2148942A4 (en) * 2007-05-14 2011-11-09 Grt Inc PROCESS FOR THE CONVERSION OF HYDROCARBON RAW MATERIALS WITH HALOGEN ELECTROLYTIC RECOVERY
US8282810B2 (en) 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
AP2828A (en) * 2008-07-18 2014-01-31 Grt Inc Continuous process for converting natural gas to liquid hydrocarbons
US8367884B2 (en) 2010-03-02 2013-02-05 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8198495B2 (en) 2010-03-02 2012-06-12 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8815050B2 (en) 2011-03-22 2014-08-26 Marathon Gtf Technology, Ltd. Processes and systems for drying liquid bromine
US8436220B2 (en) 2011-06-10 2013-05-07 Marathon Gtf Technology, Ltd. Processes and systems for demethanization of brominated hydrocarbons
US8829256B2 (en) 2011-06-30 2014-09-09 Gtc Technology Us, Llc Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons
US8802908B2 (en) 2011-10-21 2014-08-12 Marathon Gtf Technology, Ltd. Processes and systems for separate, parallel methane and higher alkanes' bromination
US9193641B2 (en) 2011-12-16 2015-11-24 Gtc Technology Us, Llc Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5573619A (en) * 1978-11-30 1980-06-03 Mitsubishi Heavy Ind Ltd Condensation of methyl chloride through dehydrochlorination
DE3069081D1 (en) * 1979-12-13 1984-10-04 Ici Plc Method of recovering bromine from methyl bromide
US4373109A (en) * 1981-08-05 1983-02-08 Olah George A Bifunctional acid-base catalyzed conversion of hetero-substituted methanes into olefins
US4523040A (en) * 1981-09-01 1985-06-11 Olah George A Methyl halides and methyl alcohol from methane
GB8333613D0 (en) * 1983-12-16 1984-01-25 British Petroleum Co Plc Production of hydrocarbons from c1 to c4 alkyl monohalides
GB8410479D0 (en) * 1984-04-24 1984-05-31 British Petroleum Co Plc Conversion process
US4795843A (en) * 1985-08-26 1989-01-03 Uop Inc. Conversion of methane into larger organic hydrocarbons
US5087786A (en) * 1990-04-25 1992-02-11 Amoco Corporation Halogen-assisted conversion of lower alkanes
US5276240A (en) * 1991-10-18 1994-01-04 Board Of Regents, The University Of Texas System Catalytic hydrodehalogenation of polyhalogenated hydrocarbons
RU2366642C2 (ru) * 2003-07-15 2009-09-10 Джи Ар Ти, Инк. Синтез углеводородов

Also Published As

Publication number Publication date
AU2005237458A1 (en) 2005-11-10
AU2005237458B2 (en) 2011-10-13
BRPI0509808B1 (pt) 2015-04-07
CA2561133C (en) 2014-07-08
KR20070029159A (ko) 2007-03-13
AR051257A1 (es) 2007-01-03
NO20065250L (no) 2007-01-08
EP1735255A2 (en) 2006-12-27
JP5150249B2 (ja) 2013-02-20
CA2561133A1 (en) 2005-11-10
KR101170773B1 (ko) 2012-08-03
JP2007532760A (ja) 2007-11-15
WO2005104689A3 (en) 2006-05-04
WO2005104689A2 (en) 2005-11-10
MXPA06011655A (es) 2007-01-23
EP1735255A4 (en) 2012-01-04

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Legal Events

Date Code Title Description
B25A Requested transfer of rights approved

Owner name: MARATHON GTF TECHNOLOGY, LTD. (US)

Free format text: TRANSFERIDO DE: MARATHON OIL COMPANY

B07A Technical examination (opinion): publication of technical examination (opinion) [chapter 7.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 15/04/2005, OBSERVADAS AS CONDICOES LEGAIS.

B25A Requested transfer of rights approved
B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time
B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)