BR9915085A - Processo de semi-hidrogenação de uma nitrila à aminonitrila correspondente em um meio lìquido - Google Patents
Processo de semi-hidrogenação de uma nitrila à aminonitrila correspondente em um meio lìquidoInfo
- Publication number
- BR9915085A BR9915085A BR9915085-9A BR9915085A BR9915085A BR 9915085 A BR9915085 A BR 9915085A BR 9915085 A BR9915085 A BR 9915085A BR 9915085 A BR9915085 A BR 9915085A
- Authority
- BR
- Brazil
- Prior art keywords
- hydrogenation
- semi
- liquid medium
- corresponding aminonitrile
- nitrile
- Prior art date
Links
- 238000005984 hydrogenation reaction Methods 0.000 title abstract 5
- 125000005219 aminonitrile group Chemical group 0.000 title abstract 3
- 239000007788 liquid Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 150000002825 nitriles Chemical class 0.000 title abstract 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 abstract 2
- LUMNWCHHXDUKFI-UHFFFAOYSA-N 5-bicyclo[2.2.1]hept-2-enylmethanol Chemical compound C1C2C(CO)CC1C=C2 LUMNWCHHXDUKFI-UHFFFAOYSA-N 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- 229920002292 Nylon 6 Polymers 0.000 abstract 1
- 239000007868 Raney catalyst Substances 0.000 abstract 1
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 abstract 1
- 229910000564 Raney nickel Inorganic materials 0.000 abstract 1
- BTGRAWJCKBQKAO-UHFFFAOYSA-N adiponitrile Chemical compound N#CCCCCC#N BTGRAWJCKBQKAO-UHFFFAOYSA-N 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 abstract 1
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 abstract 1
- 150000001412 amines Chemical group 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052737 gold Inorganic materials 0.000 abstract 1
- 239000010931 gold Substances 0.000 abstract 1
- AILKHAQXUAOOFU-UHFFFAOYSA-N hexanenitrile Chemical compound CCCCCC#N AILKHAQXUAOOFU-UHFFFAOYSA-N 0.000 abstract 1
- 230000007062 hydrolysis Effects 0.000 abstract 1
- 238000006460 hydrolysis reaction Methods 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 239000004332 silver Substances 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
- C07C255/24—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms containing cyano groups and singly-bound nitrogen atoms, not being further bound to other hetero atoms, bound to the same saturated acyclic carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D223/00—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom
- C07D223/02—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings
- C07D223/06—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D223/12—Nitrogen atoms not forming part of a nitro radical
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Amplifiers (AREA)
- Microwave Amplifiers (AREA)
Abstract
"PROCESSO DE SEMI-HIDROGENAçãO DE UMA NITRILA à AMINONITRILA CORRESPONDENTE EM UM MEIO LìQUIDO". A presente invenção refere-se à hidrogenação em função amina de uma função nitrila de uma dinitrila, para se obter a aminonitrila correspondente. Mais precisamente, ela se refere a um processo de semihidrogenação de uma dinitrila à aminonitrila correspondente, em um meio líquido, caracterizado por se operar na presença de um catalisador de níquel ou cobalto de Raney contendo cobre e/ou prata e/ou ouro e na presença de um hidróxido de metal alcalino ou alcalino-terroso. A semi-hidrogenação de adiponitrila fornece a amino-6 capronitrila, composto que é facilmente transformável por hidrólise ciclizadora a caprolactama, produto de saída da síntese da poliamida-6.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9814100A FR2785608B1 (fr) | 1998-11-05 | 1998-11-05 | Procede d'hemihydrogenation de dinitriles |
PCT/FR1999/002677 WO2000027806A1 (fr) | 1998-11-05 | 1999-11-03 | Procede d'hemihydrogenation de dinitriles |
Publications (2)
Publication Number | Publication Date |
---|---|
BR9915085A true BR9915085A (pt) | 2001-07-17 |
BR9915085B1 BR9915085B1 (pt) | 2009-08-11 |
Family
ID=9532553
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI9915085-9A BR9915085B1 (pt) | 1998-11-05 | 1999-11-03 | processo de semi-hidrogenação de uma nitrila à aminonitrila correspondente em um meio lìquido. |
Country Status (20)
Country | Link |
---|---|
US (1) | US6521779B1 (pt) |
EP (1) | EP1127047B1 (pt) |
JP (1) | JP4040842B2 (pt) |
KR (1) | KR20010080396A (pt) |
CN (1) | CN1189450C (pt) |
AT (1) | ATE249425T1 (pt) |
BR (1) | BR9915085B1 (pt) |
CA (1) | CA2349928A1 (pt) |
CZ (1) | CZ20011562A3 (pt) |
DE (1) | DE69911231T2 (pt) |
ES (1) | ES2201795T3 (pt) |
FR (1) | FR2785608B1 (pt) |
ID (1) | ID29182A (pt) |
MX (1) | MXPA01004514A (pt) |
PL (1) | PL347491A1 (pt) |
RU (1) | RU2220133C2 (pt) |
SK (1) | SK6062001A3 (pt) |
TW (1) | TW464641B (pt) |
UA (1) | UA59476C2 (pt) |
WO (1) | WO2000027806A1 (pt) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2826364B1 (fr) * | 2001-06-22 | 2005-01-14 | Rhodia Polyamide Intermediates | Procede d'hemihydrogenation de dinitriles en aminonitriles |
FR2826363B1 (fr) * | 2001-06-22 | 2005-01-14 | Rhodia Polyamide Intermediates | Procede d'hemihydrogenation de dinitriles en aminonitriles |
AU2003215039A1 (en) * | 2002-01-16 | 2003-07-30 | Mintek | Gold catalysts and methods for their preparation |
FR2892118B1 (fr) | 2005-10-18 | 2010-12-10 | Rhodia Recherches & Tech | Procede de fabrication d'hexamethylene diamine et d'aminocapronitrile. |
FR2921922B1 (fr) * | 2007-10-04 | 2009-12-04 | Rhodia Operations | Procede de fabrication d'amines par hydrogenation de composes nitriles |
FR2944791B1 (fr) | 2009-04-27 | 2012-02-10 | Rhodia Operations | Procede de preparation de lactames. |
US8669397B2 (en) | 2009-06-13 | 2014-03-11 | Rennovia, Inc. | Production of adipic acid and derivatives from carbohydrate-containing materials |
CA2763177C (en) | 2009-06-13 | 2017-08-01 | Thomas R. Boussie | Production of glutaric acid and derivatives from carbohydrate-containing materials |
PE20120660A1 (es) | 2009-06-13 | 2012-05-31 | Rennovia Inc | Produccion de acido adipico y derivados a partir de materiales que contienen carbohidratos |
EP2440515B1 (en) | 2009-06-13 | 2018-08-15 | Archer-Daniels-Midland Company | Production of adipic acid and derivatives from carbohydrate-containing materials |
US8669393B2 (en) | 2010-03-05 | 2014-03-11 | Rennovia, Inc. | Adipic acid compositions |
CN102869642A (zh) | 2010-03-05 | 2013-01-09 | 莱诺维亚公司 | 己二酸组合物 |
US9770705B2 (en) | 2010-06-11 | 2017-09-26 | Rennovia Inc. | Oxidation catalysts |
AU2012243157A1 (en) | 2011-04-13 | 2013-10-24 | Rennovia, Inc. | Production of caprolactam from carbohydrate-containing materials |
WO2013090031A2 (en) | 2011-12-14 | 2013-06-20 | Rennovia, Inc. | Water concentration reduction process |
CN104169259B (zh) | 2012-02-23 | 2016-09-21 | 莱诺维亚公司 | 从己二酸产生己内酰胺 |
DE102012006946A1 (de) | 2012-04-10 | 2013-10-10 | Stratley Ag | Verfahren zur Herstellung von Caprolactam |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4313018A (en) * | 1977-04-14 | 1982-01-26 | Western Kentucky University | Heterogeneous catalytic hydrogenation |
US4601859A (en) * | 1984-05-04 | 1986-07-22 | Allied Corporation | Selective hydrogenation of aliphatic dinitriles to omega-aminonitriles in ammonia with supported, finely dispersed rhodium-containing catalyst |
NL9102112A (nl) * | 1991-12-18 | 1993-07-16 | Dsm Nv | Werkwijze voor het bereiden van een aminonitril door het partieel hydrogeneren van een nitrilverbinding met twee of meer nitrilgroepen. |
US5296628A (en) * | 1992-02-13 | 1994-03-22 | E. I. Du Pont De Nemours And Company | Preparation of 6-aminocapronitrile |
FR2728259B1 (fr) * | 1994-12-14 | 1997-03-14 | Rhone Poulenc Chimie | Procede d'hemihydrogenation de dinitriles en aminonitriles |
DE4446893A1 (de) * | 1994-12-27 | 1996-07-04 | Basf Ag | Verfahren zur Herstellung von aliphatischen alpha,omega-Aminonitrilen |
FR2771091B1 (fr) * | 1997-11-20 | 2000-01-14 | Rhone Poulenc Fibres | Procede d'hydrogenation de dinitriles |
-
1998
- 1998-11-05 FR FR9814100A patent/FR2785608B1/fr not_active Expired - Fee Related
-
1999
- 1999-03-11 UA UA2001063753A patent/UA59476C2/uk unknown
- 1999-11-03 AT AT99954042T patent/ATE249425T1/de not_active IP Right Cessation
- 1999-11-03 PL PL99347491A patent/PL347491A1/xx not_active IP Right Cessation
- 1999-11-03 CZ CZ20011562A patent/CZ20011562A3/cs unknown
- 1999-11-03 JP JP2000580986A patent/JP4040842B2/ja not_active Expired - Fee Related
- 1999-11-03 RU RU2001115092/04A patent/RU2220133C2/ru not_active IP Right Cessation
- 1999-11-03 CA CA002349928A patent/CA2349928A1/fr not_active Abandoned
- 1999-11-03 WO PCT/FR1999/002677 patent/WO2000027806A1/fr not_active Application Discontinuation
- 1999-11-03 ES ES99954042T patent/ES2201795T3/es not_active Expired - Lifetime
- 1999-11-03 US US09/831,148 patent/US6521779B1/en not_active Expired - Fee Related
- 1999-11-03 SK SK606-2001A patent/SK6062001A3/sk unknown
- 1999-11-03 KR KR1020017005696A patent/KR20010080396A/ko not_active Application Discontinuation
- 1999-11-03 MX MXPA01004514A patent/MXPA01004514A/es not_active IP Right Cessation
- 1999-11-03 ID IDW00200101205A patent/ID29182A/id unknown
- 1999-11-03 CN CNB998147508A patent/CN1189450C/zh not_active Expired - Fee Related
- 1999-11-03 EP EP99954042A patent/EP1127047B1/fr not_active Expired - Lifetime
- 1999-11-03 BR BRPI9915085-9A patent/BR9915085B1/pt not_active IP Right Cessation
- 1999-11-03 DE DE69911231T patent/DE69911231T2/de not_active Expired - Lifetime
-
2001
- 2001-10-09 TW TW088119218A patent/TW464641B/zh not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CA2349928A1 (fr) | 2000-05-18 |
CN1189450C (zh) | 2005-02-16 |
WO2000027806A1 (fr) | 2000-05-18 |
US6521779B1 (en) | 2003-02-18 |
EP1127047B1 (fr) | 2003-09-10 |
PL347491A1 (en) | 2002-04-08 |
UA59476C2 (uk) | 2003-09-15 |
DE69911231T2 (de) | 2004-04-08 |
FR2785608A1 (fr) | 2000-05-12 |
DE69911231D1 (de) | 2003-10-16 |
SK6062001A3 (en) | 2001-11-06 |
RU2220133C2 (ru) | 2003-12-27 |
ES2201795T3 (es) | 2004-03-16 |
JP2002539074A (ja) | 2002-11-19 |
CN1331673A (zh) | 2002-01-16 |
CZ20011562A3 (cs) | 2001-09-12 |
EP1127047A1 (fr) | 2001-08-29 |
FR2785608B1 (fr) | 2000-12-29 |
ID29182A (id) | 2001-08-09 |
TW464641B (en) | 2001-11-21 |
BR9915085B1 (pt) | 2009-08-11 |
KR20010080396A (ko) | 2001-08-22 |
JP4040842B2 (ja) | 2008-01-30 |
ATE249425T1 (de) | 2003-09-15 |
MXPA01004514A (es) | 2002-09-18 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 03/11/1999, OBSERVADAS AS CONDICOES LEGAIS. |
|
B24H | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi) | ||
B24F | Patent annual fee: publication cancelled |
Free format text: ANULADA A PUBLICACAO CODIGO 24.8 NA RPI NO 2259 DE 22/04/2014 POR TER SIDO INDEVIDA. |
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B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time |
Free format text: REFERENTE AS 13A, 14A, 15A, 16A, 17A, 18A, 19A E 20A ANUIDADES. |
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B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |
Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2607 DE 22-12-2020 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |