BR9915085A - Processo de semi-hidrogenação de uma nitrila à aminonitrila correspondente em um meio lìquido - Google Patents

Processo de semi-hidrogenação de uma nitrila à aminonitrila correspondente em um meio lìquido

Info

Publication number
BR9915085A
BR9915085A BR9915085-9A BR9915085A BR9915085A BR 9915085 A BR9915085 A BR 9915085A BR 9915085 A BR9915085 A BR 9915085A BR 9915085 A BR9915085 A BR 9915085A
Authority
BR
Brazil
Prior art keywords
hydrogenation
semi
liquid medium
corresponding aminonitrile
nitrile
Prior art date
Application number
BR9915085-9A
Other languages
English (en)
Other versions
BR9915085B1 (pt
Inventor
Vincent Boschat
Jean-Pierre Brunelle
Original Assignee
Rhodia Polyamide Intermediates
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Polyamide Intermediates filed Critical Rhodia Polyamide Intermediates
Publication of BR9915085A publication Critical patent/BR9915085A/pt
Publication of BR9915085B1 publication Critical patent/BR9915085B1/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00Carboxylic acid nitriles
    • C07C255/01Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/24Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms containing cyano groups and singly-bound nitrogen atoms, not being further bound to other hetero atoms, bound to the same saturated acyclic carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/08Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
    • C08G69/14Lactams
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00Preparation of carboxylic acid nitriles
    • C07C253/30Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D223/00Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom
    • C07D223/02Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C07D223/06Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D223/12Nitrogen atoms not forming part of a nitro radical

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Amplifiers (AREA)
  • Microwave Amplifiers (AREA)

Abstract

"PROCESSO DE SEMI-HIDROGENAçãO DE UMA NITRILA à AMINONITRILA CORRESPONDENTE EM UM MEIO LìQUIDO". A presente invenção refere-se à hidrogenação em função amina de uma função nitrila de uma dinitrila, para se obter a aminonitrila correspondente. Mais precisamente, ela se refere a um processo de semihidrogenação de uma dinitrila à aminonitrila correspondente, em um meio líquido, caracterizado por se operar na presença de um catalisador de níquel ou cobalto de Raney contendo cobre e/ou prata e/ou ouro e na presença de um hidróxido de metal alcalino ou alcalino-terroso. A semi-hidrogenação de adiponitrila fornece a amino-6 capronitrila, composto que é facilmente transformável por hidrólise ciclizadora a caprolactama, produto de saída da síntese da poliamida-6.
BRPI9915085-9A 1998-11-05 1999-11-03 processo de semi-hidrogenação de uma nitrila à aminonitrila correspondente em um meio lìquido. BR9915085B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9814100A FR2785608B1 (fr) 1998-11-05 1998-11-05 Procede d'hemihydrogenation de dinitriles
PCT/FR1999/002677 WO2000027806A1 (fr) 1998-11-05 1999-11-03 Procede d'hemihydrogenation de dinitriles

Publications (2)

Publication Number Publication Date
BR9915085A true BR9915085A (pt) 2001-07-17
BR9915085B1 BR9915085B1 (pt) 2009-08-11

Family

ID=9532553

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI9915085-9A BR9915085B1 (pt) 1998-11-05 1999-11-03 processo de semi-hidrogenação de uma nitrila à aminonitrila correspondente em um meio lìquido.

Country Status (20)

Country Link
US (1) US6521779B1 (pt)
EP (1) EP1127047B1 (pt)
JP (1) JP4040842B2 (pt)
KR (1) KR20010080396A (pt)
CN (1) CN1189450C (pt)
AT (1) ATE249425T1 (pt)
BR (1) BR9915085B1 (pt)
CA (1) CA2349928A1 (pt)
CZ (1) CZ20011562A3 (pt)
DE (1) DE69911231T2 (pt)
ES (1) ES2201795T3 (pt)
FR (1) FR2785608B1 (pt)
ID (1) ID29182A (pt)
MX (1) MXPA01004514A (pt)
PL (1) PL347491A1 (pt)
RU (1) RU2220133C2 (pt)
SK (1) SK6062001A3 (pt)
TW (1) TW464641B (pt)
UA (1) UA59476C2 (pt)
WO (1) WO2000027806A1 (pt)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2826364B1 (fr) * 2001-06-22 2005-01-14 Rhodia Polyamide Intermediates Procede d'hemihydrogenation de dinitriles en aminonitriles
FR2826363B1 (fr) * 2001-06-22 2005-01-14 Rhodia Polyamide Intermediates Procede d'hemihydrogenation de dinitriles en aminonitriles
AU2003215039A1 (en) * 2002-01-16 2003-07-30 Mintek Gold catalysts and methods for their preparation
FR2892118B1 (fr) 2005-10-18 2010-12-10 Rhodia Recherches & Tech Procede de fabrication d'hexamethylene diamine et d'aminocapronitrile.
FR2921922B1 (fr) * 2007-10-04 2009-12-04 Rhodia Operations Procede de fabrication d'amines par hydrogenation de composes nitriles
FR2944791B1 (fr) 2009-04-27 2012-02-10 Rhodia Operations Procede de preparation de lactames.
US8669397B2 (en) 2009-06-13 2014-03-11 Rennovia, Inc. Production of adipic acid and derivatives from carbohydrate-containing materials
CA2763177C (en) 2009-06-13 2017-08-01 Thomas R. Boussie Production of glutaric acid and derivatives from carbohydrate-containing materials
PE20120660A1 (es) 2009-06-13 2012-05-31 Rennovia Inc Produccion de acido adipico y derivados a partir de materiales que contienen carbohidratos
EP2440515B1 (en) 2009-06-13 2018-08-15 Archer-Daniels-Midland Company Production of adipic acid and derivatives from carbohydrate-containing materials
US8669393B2 (en) 2010-03-05 2014-03-11 Rennovia, Inc. Adipic acid compositions
CN102869642A (zh) 2010-03-05 2013-01-09 莱诺维亚公司 己二酸组合物
US9770705B2 (en) 2010-06-11 2017-09-26 Rennovia Inc. Oxidation catalysts
AU2012243157A1 (en) 2011-04-13 2013-10-24 Rennovia, Inc. Production of caprolactam from carbohydrate-containing materials
WO2013090031A2 (en) 2011-12-14 2013-06-20 Rennovia, Inc. Water concentration reduction process
CN104169259B (zh) 2012-02-23 2016-09-21 莱诺维亚公司 从己二酸产生己内酰胺
DE102012006946A1 (de) 2012-04-10 2013-10-10 Stratley Ag Verfahren zur Herstellung von Caprolactam

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4313018A (en) * 1977-04-14 1982-01-26 Western Kentucky University Heterogeneous catalytic hydrogenation
US4601859A (en) * 1984-05-04 1986-07-22 Allied Corporation Selective hydrogenation of aliphatic dinitriles to omega-aminonitriles in ammonia with supported, finely dispersed rhodium-containing catalyst
NL9102112A (nl) * 1991-12-18 1993-07-16 Dsm Nv Werkwijze voor het bereiden van een aminonitril door het partieel hydrogeneren van een nitrilverbinding met twee of meer nitrilgroepen.
US5296628A (en) * 1992-02-13 1994-03-22 E. I. Du Pont De Nemours And Company Preparation of 6-aminocapronitrile
FR2728259B1 (fr) * 1994-12-14 1997-03-14 Rhone Poulenc Chimie Procede d'hemihydrogenation de dinitriles en aminonitriles
DE4446893A1 (de) * 1994-12-27 1996-07-04 Basf Ag Verfahren zur Herstellung von aliphatischen alpha,omega-Aminonitrilen
FR2771091B1 (fr) * 1997-11-20 2000-01-14 Rhone Poulenc Fibres Procede d'hydrogenation de dinitriles

Also Published As

Publication number Publication date
CA2349928A1 (fr) 2000-05-18
CN1189450C (zh) 2005-02-16
WO2000027806A1 (fr) 2000-05-18
US6521779B1 (en) 2003-02-18
EP1127047B1 (fr) 2003-09-10
PL347491A1 (en) 2002-04-08
UA59476C2 (uk) 2003-09-15
DE69911231T2 (de) 2004-04-08
FR2785608A1 (fr) 2000-05-12
DE69911231D1 (de) 2003-10-16
SK6062001A3 (en) 2001-11-06
RU2220133C2 (ru) 2003-12-27
ES2201795T3 (es) 2004-03-16
JP2002539074A (ja) 2002-11-19
CN1331673A (zh) 2002-01-16
CZ20011562A3 (cs) 2001-09-12
EP1127047A1 (fr) 2001-08-29
FR2785608B1 (fr) 2000-12-29
ID29182A (id) 2001-08-09
TW464641B (en) 2001-11-21
BR9915085B1 (pt) 2009-08-11
KR20010080396A (ko) 2001-08-22
JP4040842B2 (ja) 2008-01-30
ATE249425T1 (de) 2003-09-15
MXPA01004514A (es) 2002-09-18

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Legal Events

Date Code Title Description
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 03/11/1999, OBSERVADAS AS CONDICOES LEGAIS.

B24H Lapse because of non-payment of annual fees (definitively: art 78 iv lpi)
B24F Patent annual fee: publication cancelled

Free format text: ANULADA A PUBLICACAO CODIGO 24.8 NA RPI NO 2259 DE 22/04/2014 POR TER SIDO INDEVIDA.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE AS 13A, 14A, 15A, 16A, 17A, 18A, 19A E 20A ANUIDADES.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2607 DE 22-12-2020 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.