BR9914924A - Método para preparar um sistema catalisador de hidrogenação, e, processo para a hidrogenação de um composto olefinicamente insaturado com hidrogênio. - Google Patents
Método para preparar um sistema catalisador de hidrogenação, e, processo para a hidrogenação de um composto olefinicamente insaturado com hidrogênio.Info
- Publication number
- BR9914924A BR9914924A BR9914924-9A BR9914924A BR9914924A BR 9914924 A BR9914924 A BR 9914924A BR 9914924 A BR9914924 A BR 9914924A BR 9914924 A BR9914924 A BR 9914924A
- Authority
- BR
- Brazil
- Prior art keywords
- hydrogenation
- hydrogen
- catalyst system
- preparing
- olefinically unsaturated
- Prior art date
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/04—Reduction, e.g. hydrogenation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/121—Metal hydrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/122—Metal aryl or alkyl compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/02—Hydrogenation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/46—Titanium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/48—Zirconium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/49—Hafnium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
"MéTODO PARA PREPARAR UM SISTEMA CATALISADOR DE HIDROGENAçãO, E, PROCESSO PARA A HIDROGENAçãO DE UM COMPOSTO OLEFINICAMENTE INSATURADO COM HIDROGêNIO" Esta invenção refere-se a um método para preparar um processo de sistema catalisador de hidrogenação envolvendo a reação de um metaloceno do grupo 4 (A) com um hidreto metálico ou um composto organometálico (B) em uma relação molar (B)/(A) que é maior do que 10, seguido pela ativação da mistura catalisadora resultante com hidrogênio, em uma pressão de hidrogênio p (em MPa) e em uma temperatura T (em °C), em que um agente de neutralização (C), que é capaz de reagir com o composto (B), é adicionado à mistura catalisadora: (a) antes da ativação; (b) dentro do t horas a partir da ativação em que t é igual a x dividido por (p * T * (B)/(A)) e x corresponde a 10.000, e a um processo para a hidrogenação de um composto olefinicamente insaturado com hidrogênio, na presença de um sistema catalisador de hidrogenação, obtido pelo método da invenção.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP98308932 | 1998-10-30 | ||
PCT/EP1999/008311 WO2000025915A2 (en) | 1998-10-30 | 1999-10-28 | A method for preparing a hydrogenation catalyst system |
Publications (1)
Publication Number | Publication Date |
---|---|
BR9914924A true BR9914924A (pt) | 2001-07-10 |
Family
ID=8235140
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR9914924-9A BR9914924A (pt) | 1998-10-30 | 1999-10-28 | Método para preparar um sistema catalisador de hidrogenação, e, processo para a hidrogenação de um composto olefinicamente insaturado com hidrogênio. |
Country Status (12)
Country | Link |
---|---|
US (2) | US6461993B1 (pt) |
EP (1) | EP1131156B1 (pt) |
JP (1) | JP5166658B2 (pt) |
KR (1) | KR100600458B1 (pt) |
AT (1) | ATE224230T1 (pt) |
AU (1) | AU2659500A (pt) |
BR (1) | BR9914924A (pt) |
DE (1) | DE69903058T2 (pt) |
ES (1) | ES2184520T3 (pt) |
TW (1) | TW583027B (pt) |
WO (1) | WO2000025915A2 (pt) |
ZA (1) | ZA200103702B (pt) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1311561B1 (en) * | 2000-07-28 | 2005-06-08 | KRATON Polymers Research B.V. | Process for preparing partially hydrogenated butadiene polymers |
ITMI20022055A1 (it) | 2002-09-27 | 2004-03-28 | Enitecnologie Spa | Procedimento per la idrogenazione di omopolimeri e copolimeri di dieni coniugati. |
WO2005030821A1 (en) * | 2003-09-24 | 2005-04-07 | Kraton Polymers Research B.V. | Conjugated diene polymers and copolymer blocks having high vinyl content prepared using mixed microstructure control agents and process for preparing same |
US20110119993A1 (en) * | 2009-11-24 | 2011-05-26 | Exxonmobil Research And Engineering Company | High severity hydroprocessing interstitial metal hydride catalysts and associated processes |
US8618010B2 (en) * | 2009-11-24 | 2013-12-31 | Exxonmobil Research And Engineering Company | Interstitial metal hydride catalyst activity regeneration process |
US20110119992A1 (en) * | 2009-11-24 | 2011-05-26 | Exxonmobil Research And Engineering Company | Oxidation resistant interstitial metal hydride catalysts and associated processes |
US20110119990A1 (en) | 2009-11-24 | 2011-05-26 | Exxonmobil Research And Engineering Companhy | Group 13-15 interstitial metal hydride catalysts and associated processes |
US8598067B2 (en) | 2010-11-09 | 2013-12-03 | Exxonmobil Research And Engineering Company | Interstitial metal hydride catalyst systems and associated processes |
US8765628B2 (en) | 2010-11-09 | 2014-07-01 | Exxonmobil Research And Engineering Company | Poison resistant catalyst systems and associated processes |
US8637424B2 (en) | 2010-11-09 | 2014-01-28 | Exxonmobil Research And Engineering Company | Integrated interstitial metal hydride catalyst support systems and associated processes |
JP6215214B2 (ja) * | 2012-09-21 | 2017-10-18 | 旭化成株式会社 | 水素添加用触媒組成物及び当該水素添加用触媒組成物を用いた水素添加方法 |
ES2673316T3 (es) | 2012-09-21 | 2018-06-21 | Asahi Kasei Kabushiki Kaisha | Composición de catalizador de hidrogenación y procedimiento de hidrogenación que utiliza dicha composición de catalizador de hidrogenación |
TWI586693B (zh) | 2013-07-23 | 2017-06-11 | 財團法人工業技術研究院 | 選擇性氫化共聚物的方法 |
CA2960005C (en) | 2014-09-04 | 2023-02-14 | Kuraray Co., Ltd. | Method for producing anionic polymer |
Family Cites Families (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3401983A (en) * | 1967-01-24 | 1968-09-17 | Henriette L Williams | Vehicle brake control |
BE737574A (pt) | 1968-09-05 | 1970-02-02 | ||
DE2722221A1 (de) * | 1977-05-17 | 1978-11-23 | Studiengesellschaft Kohle Mbh | Alkalimetallkomplexverbindungen, verfahren zu ihrer herstellung und ihre verwendung zur hydrierung und nitridierung von alkalimetallen |
GB2134909B (en) | 1983-01-20 | 1986-08-20 | Asahi Chemical Ind | Catalytic hydrogenation of conjugated diene polymer |
US4656230A (en) * | 1985-07-12 | 1987-04-07 | Phillips Petroleum Company | Hydrogenation process |
JP2718059B2 (ja) | 1988-04-28 | 1998-02-25 | 日本合成ゴム株式会社 | 重合体の水素添加方法および触媒 |
JP2969771B2 (ja) | 1989-12-22 | 1999-11-02 | ジェイエスアール株式会社 | オレフィン性不飽和重合体の水素添加方法および水素添加用触媒組成物 |
US5039755A (en) | 1990-05-29 | 1991-08-13 | Shell Oil Company | Selective hydrogenation of conjugated diolefin polymers |
US5141997A (en) * | 1990-08-15 | 1992-08-25 | Shell Oil Company | Selective hydrogenation of conjugated diolefin polymers |
US5132372A (en) | 1991-09-09 | 1992-07-21 | Shell Oil Company | Process for selective hydrogenation of conjugated diolefin polymers |
US5206307A (en) * | 1991-09-09 | 1993-04-27 | Shell Oil Company | Process for selective hydrogenation of conjugated diolefin polymers |
US5270274A (en) | 1991-11-28 | 1993-12-14 | Japan Synthetic Rubber Co., Ltd. | Catalyst composition for hydrogenating olefinically unsaturated polymers |
US5173537A (en) | 1991-12-20 | 1992-12-22 | Shell Oil Company | Selective hydrogenation of conjugated diolefin poylmers |
US5242961A (en) * | 1992-05-28 | 1993-09-07 | Shell Oil Company | Color prevention in titanium catalyzed hydrogenated diene polymers |
JP3282166B2 (ja) * | 1992-09-01 | 2002-05-13 | ジェイエスアール株式会社 | オレフィン性不飽和重合体の水素化方法および水素添加触媒 |
US5583185A (en) * | 1992-11-03 | 1996-12-10 | Repsol Quimica S.A. | Process for hydrogenation in solution of the double bonds of conjugated dienes, and hydrogenated block copolymer produced |
US5244980A (en) * | 1992-12-07 | 1993-09-14 | Shell Oil Company | Selective hydrogenation of conjugated diolefin polymers with Tebbe's reagent |
JP3326773B2 (ja) * | 1993-01-26 | 2002-09-24 | ジェイエスアール株式会社 | オレフィン性不飽和結合を含有する重合体の水素化方法および水素添加触媒 |
FI97141C (fi) | 1994-03-14 | 1996-10-25 | Neste Oy | Menetelmä tyydyttämättömien polymeerien selektiiviseksi hydrogenoimiseksi |
JP3617553B2 (ja) | 1994-05-18 | 2005-02-09 | 旭化成ケミカルズ株式会社 | オレフィン水添複合触媒及び水添共役ジエン系重合体の製造方法 |
JPH09121783A (ja) | 1995-09-01 | 1997-05-13 | Res Inst For Prod Dev | 魚介類用餌料 |
BR9701276A (pt) * | 1996-03-15 | 1998-11-10 | Shell Int Research | Composição catalizadora processo para a hidrogenação de polímeros contendo insaturação etiléncia e composto de titánio |
US5705571A (en) * | 1996-05-17 | 1998-01-06 | Taiwan Synthetic Rubber Corporation | Process for selective hydrogenation of conjugated diene polymer |
JPH1053614A (ja) * | 1996-05-29 | 1998-02-24 | Shell Internatl Res Maatschappij Bv | 共役ジエンポリマーの水素化のためのプロセスとこのプロセスで使用するのに適した触媒組成物 |
IT1284105B1 (it) * | 1996-07-04 | 1998-05-08 | Enichem Elastomers | Procedimento per la preparazione di un catalizzatore utile per la idrogenazione di copolimeri stirene-butadiene |
JPH10101727A (ja) * | 1996-09-24 | 1998-04-21 | Shell Internatl Res Maatschappij Bv | オレフィン又はポリマーを水素化するための触媒及び方法 |
IT1295266B1 (it) * | 1997-10-03 | 1999-05-04 | Enichem Spa | Procedimento e catalizzatore per l'idrogenazione di composti olefinicamente insaturi |
JP3777810B2 (ja) | 1998-07-24 | 2006-05-24 | Jsr株式会社 | オレフイン性不飽和化合物の水素添加触媒および水素添加方法 |
KR100348761B1 (ko) * | 1999-11-26 | 2002-08-13 | 금호석유화학 주식회사 | 공액디엔을 포함하는 중합체의 선택적 수소화 방법 |
-
1999
- 1999-10-05 TW TW088117150A patent/TW583027B/zh not_active IP Right Cessation
- 1999-10-08 US US09/416,218 patent/US6461993B1/en not_active Expired - Lifetime
- 1999-10-28 WO PCT/EP1999/008311 patent/WO2000025915A2/en active IP Right Grant
- 1999-10-28 ES ES99968770T patent/ES2184520T3/es not_active Expired - Lifetime
- 1999-10-28 BR BR9914924-9A patent/BR9914924A/pt not_active IP Right Cessation
- 1999-10-28 JP JP2000579346A patent/JP5166658B2/ja not_active Expired - Fee Related
- 1999-10-28 KR KR1020017005486A patent/KR100600458B1/ko not_active IP Right Cessation
- 1999-10-28 AT AT99968770T patent/ATE224230T1/de not_active IP Right Cessation
- 1999-10-28 DE DE69903058T patent/DE69903058T2/de not_active Expired - Fee Related
- 1999-10-28 EP EP99968770A patent/EP1131156B1/en not_active Expired - Lifetime
- 1999-10-28 AU AU26595/00A patent/AU2659500A/en not_active Abandoned
-
2001
- 2001-05-08 ZA ZA200103702A patent/ZA200103702B/en unknown
-
2002
- 2002-07-09 US US10/191,439 patent/US20030073571A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
US20030073571A1 (en) | 2003-04-17 |
KR20010083935A (ko) | 2001-09-03 |
JP5166658B2 (ja) | 2013-03-21 |
DE69903058T2 (de) | 2003-06-05 |
AU2659500A (en) | 2000-05-22 |
EP1131156B1 (en) | 2002-09-18 |
JP2003524515A (ja) | 2003-08-19 |
WO2000025915A2 (en) | 2000-05-11 |
TW583027B (en) | 2004-04-11 |
KR100600458B1 (ko) | 2006-07-13 |
US6461993B1 (en) | 2002-10-08 |
DE69903058D1 (de) | 2002-10-24 |
EP1131156A2 (en) | 2001-09-12 |
ZA200103702B (en) | 2002-05-13 |
ES2184520T3 (es) | 2003-04-01 |
ATE224230T1 (de) | 2002-10-15 |
WO2000025915A3 (en) | 2000-08-10 |
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Legal Events
Date | Code | Title | Description |
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B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 7A, 8A E 9A ANUIDADES. |
|
B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO DESPACHO PUBLICADO NA RPI 1962 DE 12/08/2008. |