ES2184520T3 - Procedimiento para la puesta a punto de un sistema de catalizador de hidrogenacion. - Google Patents

Procedimiento para la puesta a punto de un sistema de catalizador de hidrogenacion.

Info

Publication number
ES2184520T3
ES2184520T3 ES99968770T ES99968770T ES2184520T3 ES 2184520 T3 ES2184520 T3 ES 2184520T3 ES 99968770 T ES99968770 T ES 99968770T ES 99968770 T ES99968770 T ES 99968770T ES 2184520 T3 ES2184520 T3 ES 2184520T3
Authority
ES
Spain
Prior art keywords
catalyst system
hydrogenation catalyst
activation
hydrogen
commissioning
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES99968770T
Other languages
English (en)
Inventor
Der Heijden Harry Van
De Weg Hendrik Van
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Application granted granted Critical
Publication of ES2184520T3 publication Critical patent/ES2184520T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/04—Reduction, e.g. hydrogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/121—Metal hydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/02—Hydrogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/49—Hafnium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Un método para preparar un sistema catalizador de hidrogenación que implica la reacción de un metaloceno de grupo 4 (A) con un hidruro metálico o un compuesto organometálico (B) y con una relación molar (B)/(A) que es mayor de 10, seguida de la activación de la mezcla catalizadora resultante con hidrógeno a una presión de hidrógeno p (en MPa) y a una temperatura T (en °C), en el que se añade un agente neutralizador (C) que es capaz de reaccionar con el compuesto (B) añadido a la mezcla catalizadora: a) antes de la activación, o b) dentro de t horas después de la activación, donde t es igual a x dividido por (p * T * (B)/(A)), y x corresponde a 10.000.
ES99968770T 1998-10-30 1999-10-28 Procedimiento para la puesta a punto de un sistema de catalizador de hidrogenacion. Expired - Lifetime ES2184520T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP98308932 1998-10-30

Publications (1)

Publication Number Publication Date
ES2184520T3 true ES2184520T3 (es) 2003-04-01

Family

ID=8235140

Family Applications (1)

Application Number Title Priority Date Filing Date
ES99968770T Expired - Lifetime ES2184520T3 (es) 1998-10-30 1999-10-28 Procedimiento para la puesta a punto de un sistema de catalizador de hidrogenacion.

Country Status (12)

Country Link
US (2) US6461993B1 (es)
EP (1) EP1131156B1 (es)
JP (1) JP5166658B2 (es)
KR (1) KR100600458B1 (es)
AT (1) ATE224230T1 (es)
AU (1) AU2659500A (es)
BR (1) BR9914924A (es)
DE (1) DE69903058T2 (es)
ES (1) ES2184520T3 (es)
TW (1) TW583027B (es)
WO (1) WO2000025915A2 (es)
ZA (1) ZA200103702B (es)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2002233185A1 (en) * 2000-07-28 2002-05-06 Kraton Polymers Research B.V. Process for preparing partially hydrogenated butadiene polymers
ITMI20022055A1 (it) 2002-09-27 2004-03-28 Enitecnologie Spa Procedimento per la idrogenazione di omopolimeri e copolimeri di dieni coniugati.
US7166679B2 (en) * 2003-09-24 2007-01-23 Kraton Polymers Llc Conjugated diene polymers and copolymer blocks having high vinyl content prepared using mixed microstructure control agents and process for preparing same
US20110119993A1 (en) * 2009-11-24 2011-05-26 Exxonmobil Research And Engineering Company High severity hydroprocessing interstitial metal hydride catalysts and associated processes
US8618010B2 (en) * 2009-11-24 2013-12-31 Exxonmobil Research And Engineering Company Interstitial metal hydride catalyst activity regeneration process
US20110119990A1 (en) * 2009-11-24 2011-05-26 Exxonmobil Research And Engineering Companhy Group 13-15 interstitial metal hydride catalysts and associated processes
US20110119992A1 (en) * 2009-11-24 2011-05-26 Exxonmobil Research And Engineering Company Oxidation resistant interstitial metal hydride catalysts and associated processes
US8637424B2 (en) 2010-11-09 2014-01-28 Exxonmobil Research And Engineering Company Integrated interstitial metal hydride catalyst support systems and associated processes
US8765628B2 (en) 2010-11-09 2014-07-01 Exxonmobil Research And Engineering Company Poison resistant catalyst systems and associated processes
US8598067B2 (en) 2010-11-09 2013-12-03 Exxonmobil Research And Engineering Company Interstitial metal hydride catalyst systems and associated processes
ES2673316T3 (es) * 2012-09-21 2018-06-21 Asahi Kasei Kabushiki Kaisha Composición de catalizador de hidrogenación y procedimiento de hidrogenación que utiliza dicha composición de catalizador de hidrogenación
IN2015DN01779A (es) * 2012-09-21 2015-05-29 Asahi Kasei Chemicals Corp
TWI586693B (zh) 2013-07-23 2017-06-11 財團法人工業技術研究院 選擇性氫化共聚物的方法
JP6733875B2 (ja) 2014-09-04 2020-08-05 株式会社クラレ アニオン重合体の製造方法

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3401983A (en) * 1967-01-24 1968-09-17 Henriette L Williams Vehicle brake control
BE737574A (es) 1968-09-05 1970-02-02
DE2722221A1 (de) * 1977-05-17 1978-11-23 Studiengesellschaft Kohle Mbh Alkalimetallkomplexverbindungen, verfahren zu ihrer herstellung und ihre verwendung zur hydrierung und nitridierung von alkalimetallen
US4501857A (en) 1983-01-20 1985-02-26 Asahi Kasei Kogyo Kabushiki Kaisha Method for hydrogenation of polymer
US4656230A (en) * 1985-07-12 1987-04-07 Phillips Petroleum Company Hydrogenation process
JP2718059B2 (ja) 1988-04-28 1998-02-25 日本合成ゴム株式会社 重合体の水素添加方法および触媒
JP2969771B2 (ja) * 1989-12-22 1999-11-02 ジェイエスアール株式会社 オレフィン性不飽和重合体の水素添加方法および水素添加用触媒組成物
US5039755A (en) 1990-05-29 1991-08-13 Shell Oil Company Selective hydrogenation of conjugated diolefin polymers
US5141997A (en) * 1990-08-15 1992-08-25 Shell Oil Company Selective hydrogenation of conjugated diolefin polymers
US5206307A (en) * 1991-09-09 1993-04-27 Shell Oil Company Process for selective hydrogenation of conjugated diolefin polymers
US5132372A (en) 1991-09-09 1992-07-21 Shell Oil Company Process for selective hydrogenation of conjugated diolefin polymers
US5270274A (en) 1991-11-28 1993-12-14 Japan Synthetic Rubber Co., Ltd. Catalyst composition for hydrogenating olefinically unsaturated polymers
US5173537A (en) 1991-12-20 1992-12-22 Shell Oil Company Selective hydrogenation of conjugated diolefin poylmers
US5242961A (en) * 1992-05-28 1993-09-07 Shell Oil Company Color prevention in titanium catalyzed hydrogenated diene polymers
JP3282166B2 (ja) * 1992-09-01 2002-05-13 ジェイエスアール株式会社 オレフィン性不飽和重合体の水素化方法および水素添加触媒
US5583185A (en) * 1992-11-03 1996-12-10 Repsol Quimica S.A. Process for hydrogenation in solution of the double bonds of conjugated dienes, and hydrogenated block copolymer produced
US5244980A (en) * 1992-12-07 1993-09-14 Shell Oil Company Selective hydrogenation of conjugated diolefin polymers with Tebbe's reagent
JP3326773B2 (ja) * 1993-01-26 2002-09-24 ジェイエスアール株式会社 オレフィン性不飽和結合を含有する重合体の水素化方法および水素添加触媒
FI97141C (fi) 1994-03-14 1996-10-25 Neste Oy Menetelmä tyydyttämättömien polymeerien selektiiviseksi hydrogenoimiseksi
JP3617553B2 (ja) 1994-05-18 2005-02-09 旭化成ケミカルズ株式会社 オレフィン水添複合触媒及び水添共役ジエン系重合体の製造方法
JPH09121783A (ja) 1995-09-01 1997-05-13 Res Inst For Prod Dev 魚介類用餌料
MX9701870A (es) * 1996-03-15 1998-04-30 Shell Int Research Proceso para la hidrogenacion de polimeros de dieno conjugados y composiciones catalizadoras adecuadas para usarse en el mismo.
US5705571A (en) * 1996-05-17 1998-01-06 Taiwan Synthetic Rubber Corporation Process for selective hydrogenation of conjugated diene polymer
JPH1053614A (ja) 1996-05-29 1998-02-24 Shell Internatl Res Maatschappij Bv 共役ジエンポリマーの水素化のためのプロセスとこのプロセスで使用するのに適した触媒組成物
IT1284105B1 (it) * 1996-07-04 1998-05-08 Enichem Elastomers Procedimento per la preparazione di un catalizzatore utile per la idrogenazione di copolimeri stirene-butadiene
JPH10101727A (ja) * 1996-09-24 1998-04-21 Shell Internatl Res Maatschappij Bv オレフィン又はポリマーを水素化するための触媒及び方法
IT1295266B1 (it) * 1997-10-03 1999-05-04 Enichem Spa Procedimento e catalizzatore per l'idrogenazione di composti olefinicamente insaturi
JP3777810B2 (ja) * 1998-07-24 2006-05-24 Ｊｓｒ株式会社 オレフイン性不飽和化合物の水素添加触媒および水素添加方法
KR100348761B1 (ko) * 1999-11-26 2002-08-13 금호석유화학 주식회사 공액디엔을 포함하는 중합체의 선택적 수소화 방법

Also Published As

Publication number Publication date
US20030073571A1 (en) 2003-04-17
JP2003524515A (ja) 2003-08-19
EP1131156A2 (en) 2001-09-12
US6461993B1 (en) 2002-10-08
JP5166658B2 (ja) 2013-03-21
WO2000025915A2 (en) 2000-05-11
KR100600458B1 (ko) 2006-07-13
TW583027B (en) 2004-04-11
BR9914924A (pt) 2001-07-10
KR20010083935A (ko) 2001-09-03
AU2659500A (en) 2000-05-22
WO2000025915A3 (en) 2000-08-10
DE69903058T2 (de) 2003-06-05
ATE224230T1 (de) 2002-10-15
DE69903058D1 (de) 2002-10-24
ZA200103702B (en) 2002-05-13
EP1131156B1 (en) 2002-09-18

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