BR9904171A - Processo para a prepração de oxo-álcoois superiores a partir de misturas de olefinas - Google Patents
Processo para a prepração de oxo-álcoois superiores a partir de misturas de olefinasInfo
- Publication number
- BR9904171A BR9904171A BR9904171-5A BR9904171A BR9904171A BR 9904171 A BR9904171 A BR 9904171A BR 9904171 A BR9904171 A BR 9904171A BR 9904171 A BR9904171 A BR 9904171A
- Authority
- BR
- Brazil
- Prior art keywords
- alcohols
- mixtures
- oxo
- hydroformylation
- olefins
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 4
- 239000000203 mixture Substances 0.000 title abstract 4
- 239000004435 Oxo alcohol Substances 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical class OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 title abstract 2
- 238000007037 hydroformylation reaction Methods 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/02—Monohydroxylic acyclic alcohols
- C07C31/125—Monohydroxylic acyclic alcohols containing five to twenty-two carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
- C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Patente de Invenção: <B>"PROCESSO PARA A PREPARAçãO DE OXO-áLCOOIS SUPERIORES A PARTIR DE MISTURAS DE OLEFINAS"<D>. A invenção refere-se a um processo para a preparação de oxo-álcoois superiores a partir de misturas de olefinas isómeras com 5 até 24 átomos de carbono mediante hidroformilação na presença de um catalisador em temperatura elevada e sob pressão elevada, no qual se efetua a hidroformilação em uma etapa, se limita a conversão das oelfinas para uma passagem a 40 até 90 %, se hidrogena seletivamente a mistura de reação, convenientemente após a separação do catalisador, se separa a mistura de hidrogenação por destilação e se reconduz a fração de olefina para a hidroformilação.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19842371A DE19842371A1 (de) | 1998-09-16 | 1998-09-16 | Verfahren zur Herstellung von höheren Oxo-Alkoholen aus Olefingemischen |
Publications (1)
Publication Number | Publication Date |
---|---|
BR9904171A true BR9904171A (pt) | 2000-09-19 |
Family
ID=7881140
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR9904171-5A BR9904171A (pt) | 1998-09-16 | 1999-09-15 | Processo para a prepração de oxo-álcoois superiores a partir de misturas de olefinas |
Country Status (19)
Country | Link |
---|---|
US (1) | US6407295B1 (pt) |
EP (1) | EP0987242B1 (pt) |
JP (1) | JP2000086555A (pt) |
KR (1) | KR100619455B1 (pt) |
CN (1) | CN1185190C (pt) |
AR (1) | AR020449A1 (pt) |
AT (1) | ATE228988T1 (pt) |
BR (1) | BR9904171A (pt) |
CA (1) | CA2282215A1 (pt) |
DE (2) | DE19842371A1 (pt) |
ES (1) | ES2185282T3 (pt) |
ID (1) | ID23133A (pt) |
MY (1) | MY126463A (pt) |
PL (1) | PL193417B1 (pt) |
RO (1) | RO120903B1 (pt) |
RU (1) | RU2249587C2 (pt) |
SG (1) | SG89297A1 (pt) |
TW (1) | TW546280B (pt) |
ZA (1) | ZA995925B (pt) |
Families Citing this family (39)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19925384A1 (de) * | 1999-06-02 | 2000-12-07 | Oxeno Olefinchemie Gmbh | Verfahren zur katalytischen Durchführung von Mehrphasenreaktionen, insbesondere Hydroformylierungen |
DE19957528A1 (de) * | 1999-11-30 | 2001-05-31 | Oxeno Olefinchemie Gmbh | Verfahren zur Hydroformylierung von Olefinen |
DE10058383A1 (de) * | 2000-11-24 | 2002-05-29 | Oxeno Olefinchemie Gmbh | Neue Phosphininverbindungen und deren Metallkomplexe |
DE10062448A1 (de) | 2000-12-14 | 2002-06-20 | Oxeno Olefinchemie Gmbh | Verfahren zur Hydrierung von Hydroformylierungsgemischen |
DE10135906A1 (de) | 2001-07-24 | 2003-02-06 | Oxeno Olefinchemie Gmbh | Verfahren zur Hydroformylierung von höheren Olefinen mit Kobaltverbindungen als Katalysator |
US6774275B2 (en) * | 2001-08-21 | 2004-08-10 | Catalytic Distillation Technologies | Pulse flow reaction |
EP1430014B1 (de) * | 2001-09-26 | 2007-11-07 | Oxeno Olefinchemie GmbH | Phthalsäurealkylestergemische mit kontrollierter viskosität |
DE10149348A1 (de) | 2001-10-06 | 2003-04-10 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von 1-Olefin mit Palladiumcarbenverbindungen |
EP1485341A2 (de) | 2002-03-15 | 2004-12-15 | Oxeno Olefinchemie GmbH | Verfahren zur hydroformylierung von olefinen |
DE10220801A1 (de) * | 2002-05-10 | 2003-11-20 | Oxeno Olefinchemie Gmbh | Verfahren zur Rhodium-katalysierten Hydroformylierung von Olefinen unter Reduzierung der Rhodiumverluste |
DE10225565A1 (de) | 2002-06-10 | 2003-12-18 | Oxeno Olefinchemie Gmbh | Katalysator und Verfahren zur Hydrierung von aromatischen Verbindungen |
PL206145B1 (pl) | 2002-08-31 | 2010-07-30 | Oxeno Olefinchemie Gmbhoxeno Olefinchemie Gmbh | Sposób hydroformylowania związków nienasyconych olefinowo, w szczególności olefin, w obecności cyklicznych estrów kwasów karboksylowych |
KR100988732B1 (ko) | 2002-08-31 | 2010-10-20 | 에보니크 옥세노 게엠베하 | 사이클릭 탄산 에스테르의 존재하에 개질되지 않은 금속 착물에 의해 촉매된 올레핀계 불포화 화합물의 하이드로포밀화에 의해 알데하이드를 제조하는 방법 |
DE10257499A1 (de) | 2002-12-10 | 2004-07-01 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von 1-Olefinen durch katalytische Spaltung von 1-Alkoxyalkanen |
DE10329042A1 (de) * | 2003-06-27 | 2005-01-13 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von 1-Octen aus Crack-C4 |
DE10359628A1 (de) * | 2003-12-18 | 2005-07-21 | Oxeno Olefinchemie Gmbh | Katalysator und Verfahren zur Herstellung von 1-Olefinen aus 2-Hydroxyalkanen |
DE10360772A1 (de) * | 2003-12-23 | 2005-07-28 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von Organoacylphosphiten |
DE10360771A1 (de) * | 2003-12-23 | 2005-07-28 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von dreiwertigen Organophosphor-Verbindungen |
DE102004033410A1 (de) * | 2004-02-14 | 2005-09-01 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von Olefinen mit 8 bis 12 Kohlenstoffatomen |
DE102004013514A1 (de) * | 2004-03-19 | 2005-10-06 | Oxeno Olefinchemie Gmbh | Verfahren zur Hydroformylierung von Olefinen in Anwesenheit von neuen phosphororganischen Verbindungen |
DE102004021128A1 (de) * | 2004-04-29 | 2005-11-24 | Oxeno Olefinchemie Gmbh | Vorrichtung und Verfahren für die kontinuierliche Umsetzung einer Flüssigkeit mit einem Gas an einem festen Katalysator |
US7208646B2 (en) * | 2004-05-14 | 2007-04-24 | Catalytic Distillation Technologies | Selective hydrogenation of butadiene |
DE102005036039A1 (de) | 2004-08-28 | 2006-03-02 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von 2,7-Octadienylderivaten |
DE102004059292A1 (de) * | 2004-12-09 | 2006-06-14 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von Alkoholen aus Olefinen durch Hydroformylierung und Hydrierung |
DE102004059293A1 (de) * | 2004-12-09 | 2006-06-14 | Oxeno Olefinchemie Gmbh | Verfahren zur Hydroformylierung von Olefinen |
DE102004063673A1 (de) * | 2004-12-31 | 2006-07-13 | Oxeno Olefinchemie Gmbh | Verfahren zur kontinuierlichen katalytischen Hydrierung von hydrierbaren Verbindungen an festen, im Festbett angeordneten Katalysatoren mit einem wasserstoffhaltigen Gas |
DE102005035816A1 (de) * | 2005-07-30 | 2007-02-01 | Oxeno Olefinchemie Gmbh | Verfahren zur Hydrierung von Oxo-Aldehyden mit hohen Estergehalten |
DE102005042464A1 (de) * | 2005-09-07 | 2007-03-08 | Oxeno Olefinchemie Gmbh | Carbonylierungsverfahren unter Zusatz von sterisch gehinderten sekundären Aminen |
DE102008007080A1 (de) | 2008-01-31 | 2009-08-06 | Evonik Oxeno Gmbh | Verfahren zur Herstellung von C9-Alkohol aus C8-Olefinen |
WO2009124979A1 (de) * | 2008-04-10 | 2009-10-15 | Basf Se | C17-alkoholgemisch |
KR101206214B1 (ko) | 2009-01-16 | 2012-12-03 | 주식회사 엘지화학 | 올레핀으로부터의 알코올을 제조하는 시스템 |
US9447018B2 (en) | 2009-10-20 | 2016-09-20 | Greenyug, Llc | Ethyl acetate production |
KR101278375B1 (ko) * | 2010-01-18 | 2013-07-05 | 주식회사 엘지화학 | 올레핀 유래 알데히드로부터 알코올로의 변환방법 및 이에 사용되는 반응 장치 |
US9079851B2 (en) | 2012-02-01 | 2015-07-14 | Greenyug, Llc | Ethyl acetate production |
EP2958881A4 (en) | 2013-02-19 | 2016-12-21 | Greenyug Llc | PREPARATION OF HIGHER ALCOHOLS |
US10081588B2 (en) | 2013-12-04 | 2018-09-25 | Rescurve, Llc | Production of butyl acetate from ethanol |
CA2994846C (en) | 2015-08-19 | 2024-02-20 | Rescurve, Llc | Composition of catalysts for conversion of ethanol to n-butanol and higher alcohols |
JP7447116B2 (ja) | 2018-11-29 | 2024-03-11 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | ヒドロホルミル化プロセス |
CN114478215A (zh) * | 2020-10-27 | 2022-05-13 | 中国石油化工股份有限公司 | 一种连续制备醛、醇的方法和装置 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1935900C3 (de) * | 1969-07-15 | 1975-03-13 | Chemische Werke Huels Ag, 4370 Marl | Verfahren zur Entfernung von Aldehyden und Ketonen aus Kohlenmonoxid enthaltenden Gasströmen |
DE2538037C3 (de) * | 1975-08-27 | 1988-11-10 | Hüls AG, 4370 Marl | Verfahren zur Hydroformylierung von Olefinen |
JPS5841830A (ja) * | 1981-09-07 | 1983-03-11 | Nissan Chem Ind Ltd | オキソ法によるアルコ−ルの製造方法 |
GB8430223D0 (en) * | 1984-11-30 | 1985-01-09 | Exxon Research Engineering Co | Hydroformylation of olefins |
DE3530839A1 (de) * | 1985-08-29 | 1987-03-05 | Ruhrchemie Ag | Verfahren zur herstellung von 2-ethylhexanol |
JPH0669974B2 (ja) * | 1987-12-17 | 1994-09-07 | 三菱化成株式会社 | 可塑剤用アルコールの製造法 |
DE3803464A1 (de) * | 1988-02-05 | 1989-08-17 | Huels Chemische Werke Ag | Verfahren zur herstellung von 2-ethylhexanol durch hydrierung von 2-ethylhexenal in der fluessigphase und katalysator zu seiner herstellung |
DE19524969A1 (de) | 1995-07-08 | 1997-01-09 | Huels Chemische Werke Ag | Verfahren zur Herstellung von 3.3.5-Trimethylcyclohexanon |
DE19524970A1 (de) | 1995-07-08 | 1997-01-09 | Huels Chemische Werke Ag | Verfahren zur Herstellung von 2-Ethylhexanal |
DE19524971A1 (de) | 1995-07-08 | 1997-01-09 | Huels Chemische Werke Ag | Verfahren zur katalytischen Selektivhydrierung von mehrfach ungesättigten organischen Substanzen |
DE19654340A1 (de) | 1996-12-24 | 1998-08-06 | Huels Chemische Werke Ag | Verfahren zur Herstellung von höheren Oxo-Alkoholen |
-
1998
- 1998-09-16 DE DE19842371A patent/DE19842371A1/de not_active Withdrawn
-
1999
- 1999-07-07 ID IDP990650A patent/ID23133A/id unknown
- 1999-07-31 ES ES99115271T patent/ES2185282T3/es not_active Expired - Lifetime
- 1999-07-31 DE DE59903634T patent/DE59903634D1/de not_active Expired - Fee Related
- 1999-07-31 AT AT99115271T patent/ATE228988T1/de not_active IP Right Cessation
- 1999-07-31 EP EP99115271A patent/EP0987242B1/de not_active Expired - Lifetime
- 1999-09-08 TW TW088115487A patent/TW546280B/zh not_active IP Right Cessation
- 1999-09-13 JP JP11258861A patent/JP2000086555A/ja active Pending
- 1999-09-15 AR ARP990104621A patent/AR020449A1/es active IP Right Grant
- 1999-09-15 KR KR1019990039534A patent/KR100619455B1/ko not_active IP Right Cessation
- 1999-09-15 PL PL335434A patent/PL193417B1/pl not_active IP Right Cessation
- 1999-09-15 CA CA002282215A patent/CA2282215A1/en not_active Abandoned
- 1999-09-15 BR BR9904171-5A patent/BR9904171A/pt not_active IP Right Cessation
- 1999-09-15 ZA ZA9905925A patent/ZA995925B/xx unknown
- 1999-09-15 US US09/396,402 patent/US6407295B1/en not_active Expired - Fee Related
- 1999-09-15 CN CNB991188616A patent/CN1185190C/zh not_active Expired - Fee Related
- 1999-09-15 MY MYPI99003990A patent/MY126463A/en unknown
- 1999-09-15 RU RU99119725/04A patent/RU2249587C2/ru not_active IP Right Cessation
- 1999-09-16 SG SG9904525A patent/SG89297A1/en unknown
- 1999-09-16 RO RO99-00990A patent/RO120903B1/ro unknown
Also Published As
Publication number | Publication date |
---|---|
ATE228988T1 (de) | 2002-12-15 |
CA2282215A1 (en) | 2000-03-16 |
ES2185282T3 (es) | 2003-04-16 |
PL193417B1 (pl) | 2007-02-28 |
SG89297A1 (en) | 2002-06-18 |
PL335434A1 (en) | 2000-03-27 |
DE19842371A1 (de) | 2000-03-23 |
RO120903B1 (ro) | 2006-09-29 |
KR100619455B1 (ko) | 2006-09-06 |
MY126463A (en) | 2006-10-31 |
KR20000023180A (ko) | 2000-04-25 |
ZA995925B (en) | 2000-04-04 |
ID23133A (id) | 2000-03-15 |
TW546280B (en) | 2003-08-11 |
CN1185190C (zh) | 2005-01-19 |
EP0987242A1 (de) | 2000-03-22 |
RU2249587C2 (ru) | 2005-04-10 |
US6407295B1 (en) | 2002-06-18 |
CN1255476A (zh) | 2000-06-07 |
EP0987242B1 (de) | 2002-12-04 |
JP2000086555A (ja) | 2000-03-28 |
DE59903634D1 (de) | 2003-01-16 |
AR020449A1 (es) | 2002-05-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 8A E 9A ANUIDADES |
|
B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO DESPACHO PUBLICADO NA RPI 1990 DE 25/02/2009. |