BR9904171A - Processo para a prepração de oxo-álcoois superiores a partir de misturas de olefinas - Google Patents

Processo para a prepração de oxo-álcoois superiores a partir de misturas de olefinas

Info

Publication number
BR9904171A
BR9904171A BR9904171-5A BR9904171A BR9904171A BR 9904171 A BR9904171 A BR 9904171A BR 9904171 A BR9904171 A BR 9904171A BR 9904171 A BR9904171 A BR 9904171A
Authority
BR
Brazil
Prior art keywords
alcohols
mixtures
oxo
hydroformylation
olefins
Prior art date
Application number
BR9904171-5A
Other languages
English (en)
Inventor
Alfred Dr Kaizik
Bernhard Dr Scholz
Walter Dr Toetsch
Martin Dr Trocha
Wilfried Dr Bueschken
Franz Dr Nierlich
Original Assignee
Oxeno Olefinchemie Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oxeno Olefinchemie Gmbh filed Critical Oxeno Olefinchemie Gmbh
Publication of BR9904171A publication Critical patent/BR9904171A/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02Monohydroxylic acyclic alcohols
    • C07C31/125Monohydroxylic acyclic alcohols containing five to twenty-two carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/16Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Patente de Invenção: <B>"PROCESSO PARA A PREPARAçãO DE OXO-áLCOOIS SUPERIORES A PARTIR DE MISTURAS DE OLEFINAS"<D>. A invenção refere-se a um processo para a preparação de oxo-álcoois superiores a partir de misturas de olefinas isómeras com 5 até 24 átomos de carbono mediante hidroformilação na presença de um catalisador em temperatura elevada e sob pressão elevada, no qual se efetua a hidroformilação em uma etapa, se limita a conversão das oelfinas para uma passagem a 40 até 90 %, se hidrogena seletivamente a mistura de reação, convenientemente após a separação do catalisador, se separa a mistura de hidrogenação por destilação e se reconduz a fração de olefina para a hidroformilação.
BR9904171-5A 1998-09-16 1999-09-15 Processo para a prepração de oxo-álcoois superiores a partir de misturas de olefinas BR9904171A (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19842371A DE19842371A1 (de) 1998-09-16 1998-09-16 Verfahren zur Herstellung von höheren Oxo-Alkoholen aus Olefingemischen

Publications (1)

Publication Number Publication Date
BR9904171A true BR9904171A (pt) 2000-09-19

Family

ID=7881140

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9904171-5A BR9904171A (pt) 1998-09-16 1999-09-15 Processo para a prepração de oxo-álcoois superiores a partir de misturas de olefinas

Country Status (19)

Country Link
US (1) US6407295B1 (pt)
EP (1) EP0987242B1 (pt)
JP (1) JP2000086555A (pt)
KR (1) KR100619455B1 (pt)
CN (1) CN1185190C (pt)
AR (1) AR020449A1 (pt)
AT (1) ATE228988T1 (pt)
BR (1) BR9904171A (pt)
CA (1) CA2282215A1 (pt)
DE (2) DE19842371A1 (pt)
ES (1) ES2185282T3 (pt)
ID (1) ID23133A (pt)
MY (1) MY126463A (pt)
PL (1) PL193417B1 (pt)
RO (1) RO120903B1 (pt)
RU (1) RU2249587C2 (pt)
SG (1) SG89297A1 (pt)
TW (1) TW546280B (pt)
ZA (1) ZA995925B (pt)

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DE19925384A1 (de) * 1999-06-02 2000-12-07 Oxeno Olefinchemie Gmbh Verfahren zur katalytischen Durchführung von Mehrphasenreaktionen, insbesondere Hydroformylierungen
DE19957528A1 (de) * 1999-11-30 2001-05-31 Oxeno Olefinchemie Gmbh Verfahren zur Hydroformylierung von Olefinen
DE10058383A1 (de) * 2000-11-24 2002-05-29 Oxeno Olefinchemie Gmbh Neue Phosphininverbindungen und deren Metallkomplexe
DE10062448A1 (de) 2000-12-14 2002-06-20 Oxeno Olefinchemie Gmbh Verfahren zur Hydrierung von Hydroformylierungsgemischen
DE10135906A1 (de) 2001-07-24 2003-02-06 Oxeno Olefinchemie Gmbh Verfahren zur Hydroformylierung von höheren Olefinen mit Kobaltverbindungen als Katalysator
US6774275B2 (en) * 2001-08-21 2004-08-10 Catalytic Distillation Technologies Pulse flow reaction
EP1430014B1 (de) * 2001-09-26 2007-11-07 Oxeno Olefinchemie GmbH Phthalsäurealkylestergemische mit kontrollierter viskosität
DE10149348A1 (de) 2001-10-06 2003-04-10 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 1-Olefin mit Palladiumcarbenverbindungen
EP1485341A2 (de) 2002-03-15 2004-12-15 Oxeno Olefinchemie GmbH Verfahren zur hydroformylierung von olefinen
DE10220801A1 (de) * 2002-05-10 2003-11-20 Oxeno Olefinchemie Gmbh Verfahren zur Rhodium-katalysierten Hydroformylierung von Olefinen unter Reduzierung der Rhodiumverluste
DE10225565A1 (de) 2002-06-10 2003-12-18 Oxeno Olefinchemie Gmbh Katalysator und Verfahren zur Hydrierung von aromatischen Verbindungen
PL206145B1 (pl) 2002-08-31 2010-07-30 Oxeno Olefinchemie Gmbhoxeno Olefinchemie Gmbh Sposób hydroformylowania związków nienasyconych olefinowo, w szczególności olefin, w obecności cyklicznych estrów kwasów karboksylowych
KR100988732B1 (ko) 2002-08-31 2010-10-20 에보니크 옥세노 게엠베하 사이클릭 탄산 에스테르의 존재하에 개질되지 않은 금속 착물에 의해 촉매된 올레핀계 불포화 화합물의 하이드로포밀화에 의해 알데하이드를 제조하는 방법
DE10257499A1 (de) 2002-12-10 2004-07-01 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 1-Olefinen durch katalytische Spaltung von 1-Alkoxyalkanen
DE10329042A1 (de) * 2003-06-27 2005-01-13 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 1-Octen aus Crack-C4
DE10359628A1 (de) * 2003-12-18 2005-07-21 Oxeno Olefinchemie Gmbh Katalysator und Verfahren zur Herstellung von 1-Olefinen aus 2-Hydroxyalkanen
DE10360772A1 (de) * 2003-12-23 2005-07-28 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Organoacylphosphiten
DE10360771A1 (de) * 2003-12-23 2005-07-28 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von dreiwertigen Organophosphor-Verbindungen
DE102004033410A1 (de) * 2004-02-14 2005-09-01 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Olefinen mit 8 bis 12 Kohlenstoffatomen
DE102004013514A1 (de) * 2004-03-19 2005-10-06 Oxeno Olefinchemie Gmbh Verfahren zur Hydroformylierung von Olefinen in Anwesenheit von neuen phosphororganischen Verbindungen
DE102004021128A1 (de) * 2004-04-29 2005-11-24 Oxeno Olefinchemie Gmbh Vorrichtung und Verfahren für die kontinuierliche Umsetzung einer Flüssigkeit mit einem Gas an einem festen Katalysator
US7208646B2 (en) * 2004-05-14 2007-04-24 Catalytic Distillation Technologies Selective hydrogenation of butadiene
DE102005036039A1 (de) 2004-08-28 2006-03-02 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 2,7-Octadienylderivaten
DE102004059292A1 (de) * 2004-12-09 2006-06-14 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Alkoholen aus Olefinen durch Hydroformylierung und Hydrierung
DE102004059293A1 (de) * 2004-12-09 2006-06-14 Oxeno Olefinchemie Gmbh Verfahren zur Hydroformylierung von Olefinen
DE102004063673A1 (de) * 2004-12-31 2006-07-13 Oxeno Olefinchemie Gmbh Verfahren zur kontinuierlichen katalytischen Hydrierung von hydrierbaren Verbindungen an festen, im Festbett angeordneten Katalysatoren mit einem wasserstoffhaltigen Gas
DE102005035816A1 (de) * 2005-07-30 2007-02-01 Oxeno Olefinchemie Gmbh Verfahren zur Hydrierung von Oxo-Aldehyden mit hohen Estergehalten
DE102005042464A1 (de) * 2005-09-07 2007-03-08 Oxeno Olefinchemie Gmbh Carbonylierungsverfahren unter Zusatz von sterisch gehinderten sekundären Aminen
DE102008007080A1 (de) 2008-01-31 2009-08-06 Evonik Oxeno Gmbh Verfahren zur Herstellung von C9-Alkohol aus C8-Olefinen
WO2009124979A1 (de) * 2008-04-10 2009-10-15 Basf Se C17-alkoholgemisch
KR101206214B1 (ko) 2009-01-16 2012-12-03 주식회사 엘지화학 올레핀으로부터의 알코올을 제조하는 시스템
US9447018B2 (en) 2009-10-20 2016-09-20 Greenyug, Llc Ethyl acetate production
KR101278375B1 (ko) * 2010-01-18 2013-07-05 주식회사 엘지화학 올레핀 유래 알데히드로부터 알코올로의 변환방법 및 이에 사용되는 반응 장치
US9079851B2 (en) 2012-02-01 2015-07-14 Greenyug, Llc Ethyl acetate production
EP2958881A4 (en) 2013-02-19 2016-12-21 Greenyug Llc PREPARATION OF HIGHER ALCOHOLS
US10081588B2 (en) 2013-12-04 2018-09-25 Rescurve, Llc Production of butyl acetate from ethanol
CA2994846C (en) 2015-08-19 2024-02-20 Rescurve, Llc Composition of catalysts for conversion of ethanol to n-butanol and higher alcohols
JP7447116B2 (ja) 2018-11-29 2024-03-11 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化プロセス
CN114478215A (zh) * 2020-10-27 2022-05-13 中国石油化工股份有限公司 一种连续制备醛、醇的方法和装置

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DE2538037C3 (de) * 1975-08-27 1988-11-10 Hüls AG, 4370 Marl Verfahren zur Hydroformylierung von Olefinen
JPS5841830A (ja) * 1981-09-07 1983-03-11 Nissan Chem Ind Ltd オキソ法によるアルコ−ルの製造方法
GB8430223D0 (en) * 1984-11-30 1985-01-09 Exxon Research Engineering Co Hydroformylation of olefins
DE3530839A1 (de) * 1985-08-29 1987-03-05 Ruhrchemie Ag Verfahren zur herstellung von 2-ethylhexanol
JPH0669974B2 (ja) * 1987-12-17 1994-09-07 三菱化成株式会社 可塑剤用アルコールの製造法
DE3803464A1 (de) * 1988-02-05 1989-08-17 Huels Chemische Werke Ag Verfahren zur herstellung von 2-ethylhexanol durch hydrierung von 2-ethylhexenal in der fluessigphase und katalysator zu seiner herstellung
DE19524969A1 (de) 1995-07-08 1997-01-09 Huels Chemische Werke Ag Verfahren zur Herstellung von 3.3.5-Trimethylcyclohexanon
DE19524970A1 (de) 1995-07-08 1997-01-09 Huels Chemische Werke Ag Verfahren zur Herstellung von 2-Ethylhexanal
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Also Published As

Publication number Publication date
ATE228988T1 (de) 2002-12-15
CA2282215A1 (en) 2000-03-16
ES2185282T3 (es) 2003-04-16
PL193417B1 (pl) 2007-02-28
SG89297A1 (en) 2002-06-18
PL335434A1 (en) 2000-03-27
DE19842371A1 (de) 2000-03-23
RO120903B1 (ro) 2006-09-29
KR100619455B1 (ko) 2006-09-06
MY126463A (en) 2006-10-31
KR20000023180A (ko) 2000-04-25
ZA995925B (en) 2000-04-04
ID23133A (id) 2000-03-15
TW546280B (en) 2003-08-11
CN1185190C (zh) 2005-01-19
EP0987242A1 (de) 2000-03-22
RU2249587C2 (ru) 2005-04-10
US6407295B1 (en) 2002-06-18
CN1255476A (zh) 2000-06-07
EP0987242B1 (de) 2002-12-04
JP2000086555A (ja) 2000-03-28
DE59903634D1 (de) 2003-01-16
AR020449A1 (es) 2002-05-15

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Legal Events

Date Code Title Description
B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

Free format text: REFERENTE A 8A E 9A ANUIDADES

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: REFERENTE AO DESPACHO PUBLICADO NA RPI 1990 DE 25/02/2009.