BR9711886A - Processos para o tratamento de um efluente de gerador de dióxido de cloro, e, para o tratamento de torta salgada de subproduto efluente de cloro subatmosférico - Google Patents
Processos para o tratamento de um efluente de gerador de dióxido de cloro, e, para o tratamento de torta salgada de subproduto efluente de cloro subatmosféricoInfo
- Publication number
- BR9711886A BR9711886A BR9711886-9A BR9711886A BR9711886A BR 9711886 A BR9711886 A BR 9711886A BR 9711886 A BR9711886 A BR 9711886A BR 9711886 A BR9711886 A BR 9711886A
- Authority
- BR
- Brazil
- Prior art keywords
- effluent
- acid
- chlorine dioxide
- treatment
- chlorine
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/69—Sulfur trioxide; Sulfuric acid
- C01B17/90—Separation; Purification
- C01B17/901—Recovery from spent acids containing metallic ions, e.g. hydrolysis acids, pickling acids
- C01B17/904—Recovery from spent acids containing metallic ions, e.g. hydrolysis acids, pickling acids by ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/02—Oxides of chlorine
- C01B11/022—Chlorine dioxide (ClO2)
- C01B11/023—Preparation from chlorites or chlorates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D5/00—Sulfates or sulfites of sodium, potassium or alkali metals in general
- C01D5/16—Purification
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/09—Reaction techniques
- Y10S423/14—Ion exchange; chelation or liquid/liquid ion extraction
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Geology (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Processing Of Solid Wastes (AREA)
- Paper (AREA)
- Treatment Of Water By Ion Exchange (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
"PROCESSOS PARA O TRATAMENTO DE UM EFLUENTE DE GERADOR DE DIóXIDO DE CLORO, E, PARA O TRATAMENTO DE TORTA SALGADA DE SUBPRODUTO EFLUENTE DE CLORO SUBPRODUTO EFLUENTE DE CLORO SUBATMOSFéRICO". Um processo empregando uma Unidade de Retardamento ácido (ARU) de leito de resina fixa para separar ácido despendido de geradores de dióxido de cloro em um componente sulfato de sódio desacidificado e um componente ácido sulfúrico purificado. O sulfato de sódio desacidificado produzido é retornado para o ciclo de recuperação química da usina de "kraft" no lugar do efluente de gerador de dióxido de cloro ácido deste modo evitando a destruição de alcalinidade em licores de usina de polpa. Em adição, ácido sulfúrico é purificado fornecendo uma oportunidade para reutilização em várias aplicações de usina, e/ou concentrado e reciclado para o gerador. Alternativamente, para evitar custos de evaporação altos, o ácido purificado por ser usado para regenerar uma unidade de troca catiónica (CEU) usada na conversão de clorato de sódio em uma mistura ácido clórico/clorato de sódio que é alimentada no gerador no lugar de clorato de sódio e ácido sulfúrico. Usando esta abordagem, o requisito de ácido sulfúrico de geradores de dióxido de cloro e, sucessivamene, a quantidade de efluente de gerador ácido pode ser reduzida. O processo é aplicável a geradores de dióxido de cloro tanto atmosféricos como subatmosféricos. No último caso, a concentração do ácido sulfúrico purificado da ARU ou qualquer outro sistema de separação de ácido pode ser aumentada usando-se uma porção dele para dissolver o subproduto sesquissulfato de sódio de tais geradores.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/729,148 US5792441A (en) | 1996-10-11 | 1996-10-11 | Fixed-resin bed technologies for the treatment of the chlorine dioxide generator effluent and feeds stream |
PCT/CA1997/000750 WO1998016462A1 (en) | 1996-10-11 | 1997-10-09 | Treatment of chlorine dioxide generator effluent and feed streams with fixed-resin bed |
Publications (1)
Publication Number | Publication Date |
---|---|
BR9711886A true BR9711886A (pt) | 1999-09-21 |
Family
ID=24929785
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR9711886-9A BR9711886A (pt) | 1996-10-11 | 1997-10-09 | Processos para o tratamento de um efluente de gerador de dióxido de cloro, e, para o tratamento de torta salgada de subproduto efluente de cloro subatmosférico |
Country Status (9)
Country | Link |
---|---|
US (1) | US5792441A (pt) |
EP (1) | EP0946408B1 (pt) |
JP (1) | JP3413210B2 (pt) |
AU (1) | AU4546897A (pt) |
BR (1) | BR9711886A (pt) |
CA (1) | CA2265728C (pt) |
DE (1) | DE69704121T2 (pt) |
ID (1) | ID21237A (pt) |
WO (1) | WO1998016462A1 (pt) |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2548522A1 (en) * | 2003-12-18 | 2005-07-07 | Johnsondiversey, Inc. | Addition of salt to depress ph in the generation of chlorine dioxide |
US7754057B2 (en) * | 2004-07-29 | 2010-07-13 | Pureline Treatment Systems, Llc | Chlorine dioxide solution generator |
US7799198B2 (en) * | 2004-07-29 | 2010-09-21 | Pureline Treatment Systems, Llc | Chlorine dioxide solution generator with temperature control capability |
US7833392B2 (en) * | 2004-07-29 | 2010-11-16 | Pureline Treatment Systems, Llc | Chlorine dioxide solution generator |
DE102004053090A1 (de) * | 2004-11-03 | 2006-05-04 | Basf Ag | Verfahren zur Herstellung von Natriumdithionit |
US7632479B2 (en) * | 2006-08-31 | 2009-12-15 | Iogen Energy Corporation | Process for producing ammonia and sulfuric acid from a stream comprising ammonium sulfate |
ES2366069T3 (es) * | 2007-01-12 | 2011-10-17 | Akzo Nobel N.V. | Procedimiento para la producción de dióxido de cloro. |
FI20080298L (fi) * | 2007-06-15 | 2009-10-22 | Andritz Oy | Menetelmä nestevirtojen käsittelemiseksi ja käyttämiseksi sellutehtaalla |
US20100239467A1 (en) | 2008-06-17 | 2010-09-23 | Brent Constantz | Methods and systems for utilizing waste sources of metal oxides |
WO2010009273A1 (en) | 2008-07-16 | 2010-01-21 | Calera Corporation | Co2 utilization in electrochemical systems |
US8869477B2 (en) | 2008-09-30 | 2014-10-28 | Calera Corporation | Formed building materials |
CN101918614A (zh) | 2009-02-10 | 2010-12-15 | 卡勒拉公司 | 用氢和电催化电极低电压生产碱 |
EP2250127A4 (en) | 2009-03-02 | 2011-04-06 | Calera Corp | SYSTEMS AND METHODS FOR REMOVAL OF MULTI-POLLUTANTS FROM GASEOUS CURRENTS |
US8246779B2 (en) * | 2009-09-24 | 2012-08-21 | Noram Engineering And Constructors Ltd. | Maintenance of sulfur concentration in Kraft pulp processes |
WO2011097468A2 (en) * | 2010-02-05 | 2011-08-11 | Calera Corporation | Acid separation by acid retardation on an ion exchange resin in an electrochemical system |
CL2010001609A1 (es) * | 2010-12-29 | 2011-03-18 | Univ De Concepcion 50% | Proceso para obtener tall oil util que comprende la reaccion entre una solucion de sesquisulfato de sodio y jabon de tall oil. |
CA2981729C (en) | 2015-04-21 | 2018-10-02 | Fpinnovations | Method for recovering an acid from acid/sugar solutions |
AU2018232890B2 (en) * | 2017-12-19 | 2024-09-26 | Eco-Tec Inc. | Catalytic Regeneration of Resin for Antimony Removal |
CN110386639B (zh) * | 2018-04-18 | 2022-01-21 | 国家能源投资集团有限责任公司 | 含二价阴离子盐和一价阴离子盐的盐水的处理方法和系统 |
CN108975556B (zh) * | 2018-08-08 | 2021-07-30 | 昆山尚道源环境技术有限公司 | 净化回收老化磷酸抛光液的方法 |
CN109231603A (zh) * | 2018-11-21 | 2019-01-18 | 江苏南大环保科技有限公司 | 在粘胶纤维生产工艺中协同处置酸性废液的方法及装置 |
CN115304135A (zh) * | 2022-07-22 | 2022-11-08 | 安徽润岳科技有限责任公司 | 一种用于发泡剂母液水回收利用的电渗析系统 |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3067007A (en) * | 1960-01-27 | 1962-12-04 | Dow Chemical Co | Separation of strong polybasic acids from their salts |
US3099529A (en) * | 1960-01-29 | 1963-07-30 | Dow Chemical Co | Separation of nitric acid from its salts |
US3810969A (en) * | 1971-06-22 | 1974-05-14 | Hooker Chemical Corp | Process for the production of chlorine dioxide |
US3975505A (en) * | 1974-12-13 | 1976-08-17 | Hooker Chemicals & Plastics Corporation | Production of chlorine dioxide |
CA1080433A (en) * | 1976-03-19 | 1980-07-01 | Erco Industries Limited | High efficiency chlorine dioxide production at low acidity |
CA1079482A (en) * | 1976-05-27 | 1980-06-17 | John Howard | Method of separating sulfuric acid from neutral sodium sulphate |
ZA786778B (en) * | 1978-01-03 | 1980-07-30 | Erco Ind Ltd | Improved washing procedure in chlorine dioxide production |
US4325934A (en) * | 1980-09-22 | 1982-04-20 | Erco Industries Limited | Production of chlorine dioxide with conversion of by-product solid phase sodium acid sulphate to its neutral form |
JPS5935700A (ja) * | 1982-08-18 | 1984-02-27 | Nippon Rensui Kk | 金属表面処理浴の管理方法 |
US4483740A (en) * | 1983-08-03 | 1984-11-20 | A. H. Lundberg Associates, Inc. | Method for recovery of reusable chemicals from C102 generator effluent |
CA1242306A (en) * | 1984-07-30 | 1988-09-27 | Tenneco Canada Inc. | Acid recovery in chlorine dioxide generation |
SE452756B (sv) * | 1985-03-04 | 1987-12-14 | Eka Nobel Ab | Forfarande for framstellning av klordioxid |
JPS63134512A (ja) * | 1986-11-26 | 1988-06-07 | Sumitomo Metal Mining Co Ltd | 芒硝の精製方法 |
US4798715A (en) * | 1988-02-05 | 1989-01-17 | Eltech Systems Corporation | Producing chlorine dioxide from chlorate salt |
US4915927A (en) * | 1988-10-21 | 1990-04-10 | Tenneco Canada Inc. | Production of chloric acid |
US5084148A (en) * | 1990-02-06 | 1992-01-28 | Olin Corporation | Electrochemical process for producing chloric acid - alkali metal chlorate mixtures |
US5242552A (en) * | 1990-03-21 | 1993-09-07 | Eltech Systems Corporation | System for electrolytically generating strong solutions by halogen oxyacids |
US5108560A (en) * | 1990-03-30 | 1992-04-28 | Olin Corporation | Electrochemical process for production of chloric acid from hypochlorous acid |
US5064514A (en) * | 1990-03-30 | 1991-11-12 | Olin Corporation | Apparatus for the production of chloric acid |
JP2839636B2 (ja) * | 1990-05-07 | 1998-12-16 | 株式会社東芝 | 半導体装置およびその製造方法 |
CA2023733C (en) * | 1990-08-21 | 1998-04-14 | Marek Lipsztajn | Chlorine dioxide generation from chloric acid |
US5116595A (en) * | 1991-04-22 | 1992-05-26 | Tenneco Canada Inc. | Metathesis of acidic by-product of chlorine dioxide generating process |
-
1996
- 1996-10-11 US US08/729,148 patent/US5792441A/en not_active Expired - Lifetime
-
1997
- 1997-10-09 CA CA002265728A patent/CA2265728C/en not_active Expired - Lifetime
- 1997-10-09 EP EP97943702A patent/EP0946408B1/en not_active Expired - Lifetime
- 1997-10-09 JP JP51786398A patent/JP3413210B2/ja not_active Expired - Fee Related
- 1997-10-09 DE DE69704121T patent/DE69704121T2/de not_active Expired - Lifetime
- 1997-10-09 AU AU45468/97A patent/AU4546897A/en not_active Abandoned
- 1997-10-09 WO PCT/CA1997/000750 patent/WO1998016462A1/en active IP Right Grant
- 1997-10-09 ID IDW990170A patent/ID21237A/id unknown
- 1997-10-09 BR BR9711886-9A patent/BR9711886A/pt not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EP0946408B1 (en) | 2001-02-21 |
ID21237A (id) | 1999-05-06 |
AU4546897A (en) | 1998-05-11 |
CA2265728C (en) | 2002-07-30 |
EP0946408A1 (en) | 1999-10-06 |
DE69704121D1 (de) | 2001-03-29 |
CA2265728A1 (en) | 1998-04-23 |
WO1998016462A9 (en) | 1999-04-01 |
DE69704121T2 (de) | 2001-09-13 |
US5792441A (en) | 1998-08-11 |
JP3413210B2 (ja) | 2003-06-03 |
JP2000514398A (ja) | 2000-10-31 |
WO1998016462A1 (en) | 1998-04-23 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] | ||
B25A | Requested transfer of rights approved |
Owner name: ECO-TEC LIMITED (CA) , FPINNOVATIONS (CA) Free format text: TRANSFERIDO DE: PULP AND PAPER RESEARCH INSTITUTE OF CANADA |
|
B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time |
Free format text: REFERENTE A 18A ANUIDADE. |
|
B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |
Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2327 DE 11-08-2015 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |