BR112019006251A2 - leito de catalisador fixo que compreende corpos de espuma de metal e processo para reação catalítica - Google Patents
leito de catalisador fixo que compreende corpos de espuma de metal e processo para reação catalíticaInfo
- Publication number
- BR112019006251A2 BR112019006251A2 BR112019006251A BR112019006251A BR112019006251A2 BR 112019006251 A2 BR112019006251 A2 BR 112019006251A2 BR 112019006251 A BR112019006251 A BR 112019006251A BR 112019006251 A BR112019006251 A BR 112019006251A BR 112019006251 A2 BR112019006251 A2 BR 112019006251A2
- Authority
- BR
- Brazil
- Prior art keywords
- metal foam
- foam bodies
- catalyst bed
- catalytic reaction
- fixed catalyst
- Prior art date
Links
- 238000006555 catalytic reaction Methods 0.000 title abstract 2
- 239000006262 metallic foam Substances 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 238000005259 measurement Methods 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J25/00—Catalysts of the Raney type
- B01J25/02—Raney nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/248—Reactors comprising multiple separated flow channels
- B01J19/2495—Net-type reactors
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/30—Loose or shaped packing elements, e.g. Raschig rings or Berl saddles, for pouring into the apparatus for mass or heat transfer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/31—Density
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/612—Surface area less than 10 m2/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/657—Pore diameter larger than 1000 nm
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0278—Feeding reactive fluids
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/24—Preparation of compounds containing amino groups bound to a carbon skeleton by reductive alkylation of ammonia, amines or compounds having groups reducible to amino groups, with carbonyl compounds
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
- C07C29/172—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with the obtention of a fully saturated alcohol
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/002—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by dehydrogenation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/30—Details relating to random packing elements
- B01J2219/304—Composition or microstructure of the elements
- B01J2219/30475—Composition or microstructure of the elements comprising catalytically active material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/30—Details relating to random packing elements
- B01J2219/304—Composition or microstructure of the elements
- B01J2219/30491—Foam like materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Nanotechnology (AREA)
- Laminated Bodies (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
a presente invenção se refere a um leito fixo de corpos de espuma de metal ativos cataliticamente que tem um volume de não mais do que 500 ml o qual consiste em uma medida de pelo menos 95% em peso de metais. o leito fixo é usado para reações catalíticas em uma mistura de reação trifásica.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP16191751.3A EP3300798A1 (de) | 2016-09-30 | 2016-09-30 | Katalysatorfestbett enthaltend metallschaumkörper |
EP16191751.3 | 2016-09-30 | ||
PCT/EP2017/074491 WO2018060245A1 (en) | 2016-09-30 | 2017-09-27 | Fixed catalyst bed comprising metal foam bodies |
Publications (2)
Publication Number | Publication Date |
---|---|
BR112019006251A2 true BR112019006251A2 (pt) | 2019-06-25 |
BR112019006251B1 BR112019006251B1 (pt) | 2022-08-23 |
Family
ID=57083170
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112019006251-3A BR112019006251B1 (pt) | 2016-09-30 | 2017-09-27 | Leito de catalisador fixo que compreende corpos de espuma de metal e processo para reação catalítica |
Country Status (10)
Country | Link |
---|---|
US (1) | US11090637B2 (pt) |
EP (2) | EP3300798A1 (pt) |
JP (1) | JP7479149B2 (pt) |
KR (1) | KR102444992B1 (pt) |
CN (1) | CN109789389A (pt) |
AR (1) | AR109768A1 (pt) |
BR (1) | BR112019006251B1 (pt) |
MX (1) | MX2019003614A (pt) |
TW (1) | TWI782921B (pt) |
WO (1) | WO2018060245A1 (pt) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3300799A1 (de) | 2016-09-30 | 2018-04-04 | Evonik Degussa GmbH | Verfahren und katalysator zur herstellung von 1,4-butandiol |
EP3752477B1 (en) | 2018-02-14 | 2024-05-22 | Evonik Operations GmbH | Method for the preparation of c3-c12-alcohols by catalytic hydrogenation of the corresponding aldehydes |
CN113226531A (zh) | 2019-09-25 | 2021-08-06 | 赢创运营有限公司 | 催化反应器 |
EP3797901B1 (de) | 2019-09-25 | 2021-09-08 | Evonik Operations GmbH | Metallschaumkörper und verfahren zu seiner herstellung |
KR20220070213A (ko) * | 2019-09-25 | 2022-05-30 | 에보닉 오퍼레이션스 게엠베하 | 금속체 및 그 제조 방법 |
JP2022549860A (ja) * | 2019-09-25 | 2022-11-29 | エボニック オペレーションズ ゲーエムベーハー | 金属発泡体担持触媒およびその製造方法 |
EP4063012A1 (de) * | 2021-03-23 | 2022-09-28 | Evonik Operations GmbH | Beschichtete metallkörperzuschnitte und verfahren zu ihrer herstellung |
EP4234525B1 (de) * | 2022-02-25 | 2024-01-31 | Evonik Operations GmbH | Verfahren zur hydrierung von aldehyden in mindestens zwei hydrierstufen |
EP4234527B1 (de) * | 2022-02-25 | 2024-01-31 | Evonik Operations GmbH | Verfahren zur hydrierung von c9-aldehyden in mindestens zwei hydrierstufen |
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JP2019532059A (ja) | 2016-09-23 | 2019-11-07 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | Coの存在下およびモノリシック触媒成形体を含む触媒固定床の存在下で有機化合物を水素化する方法 |
SG11201901567PA (en) | 2016-09-23 | 2019-04-29 | Basf Se | Process for activating a catalyst |
EP3300799A1 (de) | 2016-09-30 | 2018-04-04 | Evonik Degussa GmbH | Verfahren und katalysator zur herstellung von 1,4-butandiol |
DE102017202404A1 (de) | 2017-02-15 | 2018-08-16 | Evonik Degussa Gmbh | Verfahren zur Herstellung von Isophoronaminoalkohol (IPAA) |
EP3752477B1 (en) | 2018-02-14 | 2024-05-22 | Evonik Operations GmbH | Method for the preparation of c3-c12-alcohols by catalytic hydrogenation of the corresponding aldehydes |
EP3797901B1 (de) | 2019-09-25 | 2021-09-08 | Evonik Operations GmbH | Metallschaumkörper und verfahren zu seiner herstellung |
CN113226531A (zh) | 2019-09-25 | 2021-08-06 | 赢创运营有限公司 | 催化反应器 |
KR20220068220A (ko) | 2019-09-25 | 2022-05-25 | 에보닉 오퍼레이션스 게엠베하 | 금속 발포체 및 이의 제조 방법 및 이의 촉매로서의 사용 |
JP2022549860A (ja) | 2019-09-25 | 2022-11-29 | エボニック オペレーションズ ゲーエムベーハー | 金属発泡体担持触媒およびその製造方法 |
KR20220070213A (ko) | 2019-09-25 | 2022-05-30 | 에보닉 오퍼레이션스 게엠베하 | 금속체 및 그 제조 방법 |
-
2016
- 2016-09-30 EP EP16191751.3A patent/EP3300798A1/de not_active Withdrawn
-
2017
- 2017-09-27 TW TW106133099A patent/TWI782921B/zh active
- 2017-09-27 JP JP2019517219A patent/JP7479149B2/ja active Active
- 2017-09-27 WO PCT/EP2017/074491 patent/WO2018060245A1/en unknown
- 2017-09-27 BR BR112019006251-3A patent/BR112019006251B1/pt active IP Right Grant
- 2017-09-27 KR KR1020197012065A patent/KR102444992B1/ko active IP Right Grant
- 2017-09-27 US US16/338,044 patent/US11090637B2/en active Active
- 2017-09-27 EP EP17777243.1A patent/EP3519090A1/en active Pending
- 2017-09-27 MX MX2019003614A patent/MX2019003614A/es unknown
- 2017-09-27 CN CN201780060485.5A patent/CN109789389A/zh active Pending
- 2017-09-29 AR ARP170102726A patent/AR109768A1/es active IP Right Grant
Also Published As
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TW201815463A (zh) | 2018-05-01 |
MX2019003614A (es) | 2019-06-17 |
US11090637B2 (en) | 2021-08-17 |
KR20190055831A (ko) | 2019-05-23 |
CN109789389A (zh) | 2019-05-21 |
BR112019006251B1 (pt) | 2022-08-23 |
TWI782921B (zh) | 2022-11-11 |
KR102444992B1 (ko) | 2022-09-19 |
EP3519090A1 (en) | 2019-08-07 |
WO2018060245A1 (en) | 2018-04-05 |
JP2019530572A (ja) | 2019-10-24 |
US20190232257A1 (en) | 2019-08-01 |
EP3300798A1 (de) | 2018-04-04 |
AR109768A1 (es) | 2019-01-23 |
JP7479149B2 (ja) | 2024-05-08 |
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