BR112014009591A2 - sistema de leito catalisador para um processo de desidrogenação catalítica endotérmica e processo de desidrogenação endotérmica - Google Patents
sistema de leito catalisador para um processo de desidrogenação catalítica endotérmica e processo de desidrogenação endotérmicaInfo
- Publication number
- BR112014009591A2 BR112014009591A2 BR112014009591A BR112014009591A BR112014009591A2 BR 112014009591 A2 BR112014009591 A2 BR 112014009591A2 BR 112014009591 A BR112014009591 A BR 112014009591A BR 112014009591 A BR112014009591 A BR 112014009591A BR 112014009591 A2 BR112014009591 A2 BR 112014009591A2
- Authority
- BR
- Brazil
- Prior art keywords
- catalyst bed
- dehydrogenation process
- endothermic
- bed system
- volume
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
- C07C5/3332—Catalytic processes with metal oxides or metal sulfides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
- B01J8/025—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical shaped bed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0285—Heating or cooling the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0292—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds with stationary packing material in the bed, e.g. bricks, wire rings, baffles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0403—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal
- B01J8/0407—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more cylindrical annular shaped beds
- B01J8/0419—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more cylindrical annular shaped beds the beds being placed in separate reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0496—Heating or cooling the reactor
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
- C07C5/3335—Catalytic processes with metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00522—Controlling the temperature using inert heat absorbing solids outside the bed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/26—Chromium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/26—Chromium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Abstract
resumo patente de invenção: "sistema de leito catalisador para um processo de desidrogenação catalítica endotérmica e processo de desidrogenação endotérmica". a presente invenção refere-se a um sistema de leito catalisador compreendendo um leito catalisador horizontal compreendendo uma mistura de pelo menos um material catalítico e pelo menos um primeiro material inerte, um volume predeterminado de pelo menos um segundo material inerte disposto a montante do leito catalisador, em que o volume do reator acima do sistema de leito catalisador não é preenchido por nenhum material sólido (espaço vazio). o sistema de leito catalisador é caracterizado pelo fato de que a razão do volume do segundo material inerte para o volume do reator acima do segundo material inerte (espaço vazio) está entre 0,04 e 0,73, de preferência entre 0,06 e 0,3, o mais preferivelmente entre 0,09 e 0,2. a presente invenção também se refere a um processo de desidrogenação usando esse sistema de leito catalisador.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP11186322.1A EP2586524A1 (en) | 2011-10-24 | 2011-10-24 | A catalyst bed system for an endothermic catalytic dehydrogenation process and an endothermic dehydrogenation process |
PCT/EP2012/070860 WO2013060640A1 (en) | 2011-10-24 | 2012-10-22 | A catalyst bed system for an endothermic catalytic dehydrogenation process and an endothermic dehydrogenation process |
Publications (2)
Publication Number | Publication Date |
---|---|
BR112014009591A2 true BR112014009591A2 (pt) | 2017-05-09 |
BR112014009591B1 BR112014009591B1 (pt) | 2019-11-12 |
Family
ID=47221311
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112014009591-4A BR112014009591B1 (pt) | 2011-10-24 | 2012-10-22 | processo para desidrogenação catalítica endotérmica utilizando um sistema de leito catalisador |
Country Status (13)
Country | Link |
---|---|
US (1) | US9926241B2 (pt) |
EP (2) | EP2586524A1 (pt) |
KR (1) | KR101941616B1 (pt) |
CN (1) | CN103889567B (pt) |
BR (1) | BR112014009591B1 (pt) |
CA (1) | CA2851427C (pt) |
EA (1) | EA025815B1 (pt) |
IN (1) | IN2014KN01094A (pt) |
MX (1) | MX364478B (pt) |
MY (1) | MY171930A (pt) |
UA (1) | UA114610C2 (pt) |
WO (1) | WO2013060640A1 (pt) |
ZA (1) | ZA201402604B (pt) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10155702B2 (en) | 2015-11-04 | 2018-12-18 | Exxonmobil Chemical Patents Inc. | Processes and systems for converting hydrocarbons to cyclopentadiene |
CN108349841B (zh) * | 2015-11-04 | 2021-04-20 | 埃克森美孚化学专利公司 | 集成的燃气涡轮和转化系统方法 |
EP3661638A1 (en) * | 2017-07-31 | 2020-06-10 | SABIC Global Technologies B.V. | System and method for dehydrogenating isobutane to isobutylene |
US10836690B1 (en) | 2019-07-26 | 2020-11-17 | Tpc Group Llc | Dehydrogenation process and system with reactor re-sequencing |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2419997A (en) | 1943-03-05 | 1947-05-06 | Houdry Process Corp | Catalytic dehydrogenation of aliphatic hydrocarbons |
NL301296A (pt) * | 1962-12-03 | 1900-01-01 | ||
US4560824A (en) | 1985-05-07 | 1985-12-24 | Air Products And Chemicals, Inc. | Heat balance control in catalytic dehydrogenation of isobutane |
US5510557A (en) * | 1994-02-28 | 1996-04-23 | Abb Lummus Crest Inc. | Endothermic catalytic dehydrogenation process |
NO316512B1 (no) * | 2000-01-25 | 2004-02-02 | Statoil Asa | Fremgangsmate og reaktor for autoterm dehydrogenering av hydrokarboner |
US6392113B1 (en) | 2000-10-03 | 2002-05-21 | Abb Lummus Global Inc. | Catalytic hydrocarbon dehydrogenation system with prereaction |
US8063261B2 (en) | 2002-01-14 | 2011-11-22 | Sud-Chemie Inc. | Multi-layered dehydrogenation catalyst system and process of use |
DE10237514A1 (de) | 2002-08-16 | 2004-02-26 | Basf Ag | Isothermes Verfahren zur Dehydrierung von Alkanen |
US7566429B2 (en) * | 2005-06-14 | 2009-07-28 | Sandia Corporation | Catalytic reactive separation system for energy-efficient production of cumene |
US7491860B2 (en) | 2005-08-03 | 2009-02-17 | Süd-Chemie Inc. | Dehydrogenation process |
US7622623B2 (en) | 2005-09-02 | 2009-11-24 | Sud-Chemie Inc. | Catalytically inactive heat generator and improved dehydrogenation process |
US7973207B2 (en) | 2005-09-02 | 2011-07-05 | Sud-Chemie Inc. | Endothermic hydrocarbon conversion process |
DE102006035718A1 (de) * | 2006-07-28 | 2008-01-31 | Basf Ag | Verfahren zum Langzeitbetrieb einer kontinuierlich betriebenen heterogen katalysierten partiellen Dehydrierung eines zu dehydrierenden Kohlenwasserstoffs |
CN101734987B (zh) * | 2008-11-07 | 2012-11-21 | 中国石油化工股份有限公司 | 一种由c4烃制备乙烯、丙烯的方法 |
-
2011
- 2011-10-24 EP EP11186322.1A patent/EP2586524A1/en not_active Withdrawn
-
2012
- 2012-10-22 EA EA201400463A patent/EA025815B1/ru active IP Right Grant
- 2012-10-22 UA UAA201405215A patent/UA114610C2/uk unknown
- 2012-10-22 KR KR1020147012124A patent/KR101941616B1/ko active IP Right Grant
- 2012-10-22 BR BR112014009591-4A patent/BR112014009591B1/pt active IP Right Grant
- 2012-10-22 MY MYPI2014001041A patent/MY171930A/en unknown
- 2012-10-22 CN CN201280051896.5A patent/CN103889567B/zh active Active
- 2012-10-22 IN IN1094KON2014 patent/IN2014KN01094A/en unknown
- 2012-10-22 EP EP12790440.7A patent/EP2771101B1/en active Active
- 2012-10-22 CA CA2851427A patent/CA2851427C/en active Active
- 2012-10-22 WO PCT/EP2012/070860 patent/WO2013060640A1/en active Application Filing
- 2012-10-22 US US14/353,619 patent/US9926241B2/en active Active
- 2012-10-22 MX MX2014004909A patent/MX364478B/es active IP Right Grant
-
2014
- 2014-04-09 ZA ZA201402604A patent/ZA201402604B/en unknown
Also Published As
Publication number | Publication date |
---|---|
KR101941616B1 (ko) | 2019-01-23 |
MX2014004909A (es) | 2014-07-09 |
EP2586524A1 (en) | 2013-05-01 |
KR20140084129A (ko) | 2014-07-04 |
CN103889567A (zh) | 2014-06-25 |
ZA201402604B (en) | 2019-10-30 |
CN103889567B (zh) | 2017-02-22 |
EA201400463A1 (ru) | 2014-08-29 |
CA2851427C (en) | 2021-04-27 |
IN2014KN01094A (pt) | 2015-10-09 |
BR112014009591B1 (pt) | 2019-11-12 |
EA025815B1 (ru) | 2017-01-30 |
EP2771101B1 (en) | 2019-08-21 |
EP2771101A1 (en) | 2014-09-03 |
WO2013060640A1 (en) | 2013-05-02 |
CA2851427A1 (en) | 2013-05-02 |
MY171930A (en) | 2019-11-07 |
MX364478B (es) | 2019-04-29 |
US20140296606A1 (en) | 2014-10-02 |
US9926241B2 (en) | 2018-03-27 |
UA114610C2 (uk) | 2017-07-10 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B06F | Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette] | ||
B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 22/10/2012, OBSERVADAS AS CONDICOES LEGAIS. (CO) 20 (VINTE) ANOS CONTADOS A PARTIR DE 22/10/2012, OBSERVADAS AS CONDICOES LEGAIS |