BR112017003296B1 - Método de preparação de polibuteno - Google Patents

Método de preparação de polibuteno Download PDF

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Publication number
BR112017003296B1
BR112017003296B1 BR112017003296-1A BR112017003296A BR112017003296B1 BR 112017003296 B1 BR112017003296 B1 BR 112017003296B1 BR 112017003296 A BR112017003296 A BR 112017003296A BR 112017003296 B1 BR112017003296 B1 BR 112017003296B1
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BR
Brazil
Prior art keywords
polybutene
isomerization
butene
isobutene
reactor
Prior art date
Application number
BR112017003296-1A
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English (en)
Portuguese (pt)
Other versions
BR112017003296A2 (pt
Inventor
Kim Myeong Seok
Park Min Sup
Seo Hyung Jae
Lee Se Hyun
Original Assignee
Daelim Industrial Co., Ltd
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Publication date
Application filed by Daelim Industrial Co., Ltd filed Critical Daelim Industrial Co., Ltd
Publication of BR112017003296A2 publication Critical patent/BR112017003296A2/pt
Publication of BR112017003296B1 publication Critical patent/BR112017003296B1/pt

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C08F210/10—Isobutene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/245—Stationary reactors without moving elements inside placed in series
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0403—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal
    • B01J8/0407—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more cylindrical annular shaped beds
    • B01J8/0419—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more cylindrical annular shaped beds the beds being placed in separate reactors
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/23—Rearrangement of carbon-to-carbon unsaturated bonds
    • C07C5/25—Migration of carbon-to-carbon double bonds
    • C07C5/2506—Catalytic processes
    • C07C5/2556—Catalytic processes with metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C07C5/2708—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767—Changing the number of side-chains
    • C07C5/277—Catalytic processes
    • C07C5/2775—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C08F110/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C08F210/10—Isobutene
    • C08F210/12—Isobutene with conjugated diolefins, e.g. butyl rubber
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/06—Butadiene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
BR112017003296-1A 2014-08-22 2015-08-21 Método de preparação de polibuteno BR112017003296B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
KR10-2014-0109548 2014-08-22
KR1020140109548A KR101658545B1 (ko) 2014-08-22 2014-08-22 폴리부텐의 제조방법
PCT/KR2015/008776 WO2016028123A1 (ko) 2014-08-22 2015-08-21 폴리부텐의 제조방법

Publications (2)

Publication Number Publication Date
BR112017003296A2 BR112017003296A2 (pt) 2017-11-28
BR112017003296B1 true BR112017003296B1 (pt) 2022-02-08

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ID=55350988

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Application Number Title Priority Date Filing Date
BR112017003296-1A BR112017003296B1 (pt) 2014-08-22 2015-08-21 Método de preparação de polibuteno

Country Status (9)

Country Link
US (1) US10202476B2 (enExample)
EP (1) EP3184557B1 (enExample)
JP (1) JP6673904B2 (enExample)
KR (1) KR101658545B1 (enExample)
CN (1) CN106604936A (enExample)
BR (1) BR112017003296B1 (enExample)
MY (1) MY182242A (enExample)
SG (1) SG11201701392VA (enExample)
WO (1) WO2016028123A1 (enExample)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10167352B1 (en) * 2017-06-28 2019-01-01 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
JP6988642B2 (ja) * 2018-03-29 2022-01-05 国立大学法人九州大学 アリル化合物の異性化方法
JP7188543B2 (ja) * 2018-03-29 2022-12-13 国立大学法人九州大学 アリル化合物の異性化方法
CN115703855A (zh) * 2021-08-13 2023-02-17 南京中科康润新材料科技有限公司 用于c4液化石油气阳离子聚合的催化剂体系及聚丁烯生产方法
US11932597B2 (en) 2022-03-10 2024-03-19 Lummus Technology Llc Converting isobutane and refinery C4S to propylene
US20240384013A1 (en) 2023-05-19 2024-11-21 Ntp Tec, Llc Processes for converting c4 feeds to isobutylene, polyisobutylene, or derivatives thereof

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR930006910B1 (ko) 1990-03-28 1993-07-24 재단법인 한국화학연구소 폴리부텐의 제조방법과 그 장치
GB9404368D0 (en) * 1994-03-07 1994-04-20 Bp Chem Int Ltd Production of polyisobutenes
US5981818A (en) 1995-03-21 1999-11-09 Stone & Webster Engineering Corp. Integrated cracking and olefins derivative process utilizing dilute olefins
FR2733986B1 (fr) 1995-05-11 1997-06-13 Inst Francais Du Petrole Procede et installation pour la conversion de coupes c4 olefiniques en polyisobutenes et en propylene
FR2757506B1 (fr) * 1996-12-23 1999-02-19 Inst Francais Du Petrole Procede de production d'isobutene de haute purete combinant une distillation reactive d'hydroisomerisation et une isomerisation squelettale
FR2757505B1 (fr) * 1996-12-23 1999-02-19 Inst Francais Du Petrole Procede de production d'isobutene de haute purete combinant une distillation reactive d'hydroisomerisation, une distillation et une isomerisation squelettale
GB9707075D0 (en) * 1997-04-08 1997-05-28 Bp Chem Int Ltd Polymerisation process
DE19952031A1 (de) * 1999-10-28 2001-05-03 Basf Ag Verfahren zur Herstellung hochreaktiver Polyisobutene
KR100486044B1 (ko) 2000-11-13 2005-04-29 대림산업 주식회사 폴리부텐의 제조방법
JP4907771B2 (ja) 2001-01-29 2012-04-04 Ｊｘ日鉱日石エネルギー株式会社 ブテンポリマー処理における分解反応抑制方法
KR20040014688A (ko) * 2002-08-10 2004-02-18 주식회사 엑스텔테크놀러지 음성통신 단말기의 잡음제거장치 및 그 방법
DE10361633A1 (de) * 2003-12-30 2005-07-28 Basf Ag Herstellung hochreaktiver Polyisobutene mit niedrigem Halogengehalt
US20080214762A1 (en) 2005-07-12 2008-09-04 Basf Aktiengesellschaft Method for the Production of High-Grade Polyisobutene
WO2007141277A1 (de) * 2006-06-06 2007-12-13 Basf Se Herstellung reaktiver, im wesentlichen halogenfreier polyisobutene aus isobuten-armen c4-kohlenwasserstoff-gemischen
KR100851639B1 (ko) * 2007-03-22 2008-08-13 대림산업 주식회사 고농도 이소부텐을 이용한 고반응성 폴리이소부텐의제조방법
KR101331551B1 (ko) 2011-02-22 2013-11-20 대림산업 주식회사 글리콜 모노-터셔리-부틸에테르 화합물의 제조 방법
KR101458404B1 (ko) * 2013-01-17 2014-11-05 대림산업 주식회사 폴리부텐의 제조 방법

Also Published As

Publication number Publication date
JP6673904B2 (ja) 2020-03-25
US10202476B2 (en) 2019-02-12
EP3184557B1 (en) 2023-12-20
WO2016028123A1 (ko) 2016-02-25
EP3184557A4 (en) 2018-04-18
US20170267795A1 (en) 2017-09-21
EP3184557A1 (en) 2017-06-28
BR112017003296A2 (pt) 2017-11-28
EP3184557C0 (en) 2023-12-20
MY182242A (en) 2021-01-18
KR20160023321A (ko) 2016-03-03
SG11201701392VA (en) 2017-04-27
KR101658545B1 (ko) 2016-09-21
CN106604936A (zh) 2017-04-26
JP2017526779A (ja) 2017-09-14

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